• 분석과학
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• 제24권1호
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• pp.15-23
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• 2011

본 연구에서는 미지 대사물질 동정을 위해 GC-TOF/MS의 양이온 화학적 이온화 방법(positive chemical ionization, $CI^+$)을 이용, 정확한 질량 값(accurate mass)과 동위원소 비(isotope ratio) 측정을 위한최적 조건을 확립하였다. 분자이온 $[M+H]^+$ 세기를 증가시킬 수 있는 high mass tune 방법이 사용되었으며, 화합물들의 분리 및 감도에 따른 검출조건이 고려되어 졌다. 24종의 trimethylsilyl (TMS)기로 유도체화 된 표준 대사물질들을 분석한 결과 $[M+H]^+$의 경우 이론 값 과의 절대평균오차는 6.8 ppm이였으며, 동위원소 비(M+1/M, M+2/M)의 경우는 각각 1.5%와 1.7%였다. 얻어진 질량 값과 동위원소 비를 원소조성 알고리즘에 적용한 결과 21개의 화합물의 구조식이 2순위 내에서 일치하였다.

• 천문학회보
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• 제41권2호
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• pp.61.1-61.1
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• 2016

Black hole (BH) mass is a fundamental quantity to understand BH growth, galaxy evolution, and connection between them. Thus, obtaining accurate and precise BH mass estimates over cosmic time is of paramount importance. The rest-frame UV CIV ${\lambda}1549$ broad emission line is commonly used for BH mass estimates in high-redshift AGNs (i.e., $2{\leq}z{\leq}5$) when single-epoch (SE) optical spectra are available. Achieving correct and accurate calibration for CIV-based SE BH mass estimators against the most reliable reverberation-mapping based BH mass estimates is thus practically important and still useful. By performing multi-component spectral decomposition analysis to obtained high-quality HST UV spectra for the updated sample of local reverberation-mapped AGNs including new HST STIS observations, CIV emission line widths and continuum luminosities are consistently measured. Using a Bayesian hierarchical model with MCMC sampling based on Hamiltonian Monte Carlo algorithm (Stan NUTS), we provide the most consistent and accurate calibration of CIV-based BH mass estimators for the three line width characterizations, i.e., full width at half maximum (FWHM), line dispersion (${\sigma}_{line}$), and mean absolute deviation (MAD), in the extended BH mass dynamic range of log $M_{BH}/M_{\odot}=6.5-9.1$.

• 한국자동차공학회논문집
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• 제9권5호
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• pp.131-139
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• 2001

Highly accurate control of the air-fuel ratio is important to reduce exhaust gas emissions of the gaseous-fuel engines. In order to achieve this purpose, inlet air mass flow must be measured exactly, and precise engine models are necessary to design engine control systems. In this paper, the effects of water vapor and gaseous fuel that change the air mass flow are studied. The effective air mass ratio is defined as the air mass flow divided by the mixture mass flow, and also it is applied to the estimation of the inlet air mass flow. The presence of the gaseous fuel and the water vapor in the mixture reduces the air partial pressure and the effective air mass ratio of the gaseous-fuel engines. The Experimental results for an LPG engine show that the estimation of the inlet ai mass flow based upon the effective air mass ratio is more accurate than that of the normal air mass flow.

• Mass Spectrometry Letters
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• 제2권2호
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• pp.37-40
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• 2011

Saccharin is a commonly used artificial sweetener in foodstuffs. However, for its carcinogenic dispute, it has been regulated by government bodies. In this study, isotope dilution mass spectrometry (ID-MS) was introduced for the accurate quantification of saccharin. To employ ID-LC/MS, we obtained its isotope analogue, $^{13}C_1$-sodium saccharin, by customized synthesis. Samples were spiked with $^{13}C_1$-sodium saccharin and analyzed with LC/MS in negative mode. Chromatographic conditions were optimized for the adequate chromatographic retention and separation of saccharin with a $C_{18}$ column. MS was operated with electrospray ionization by the selected ion monitoring (SIM) mode of $[M-H]^-$ for saccharin (m/z 182) and $[M-Na]^-$ for its isotope analogue (m/z 183). To validate the ID-LC/MS method for accurate measurement, we prepared a batch of a candidate material by sortifying quasi-tea-drinks with saccharin and analyzed samples gravimetrically fortified in various levels of concentration. The repeatability and reproducibility of this method was tested by analyzing the reference material. Result show that ID-LC/MS is a reliable method for the quantitative analysis of saccharin.

• 제어로봇시스템학회논문지
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• 제7권3호
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• pp.198-208
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• 2001

In this paper, vibration suppression of an elastic beam fixed on a moving cart and carrying a fixed or moving mass is considered. A modified pulse sequence method with RIC(Robust Internal-loop Compensator) is proposed to suppress the single model residual vibration and to get accurate positioning of the beam-mass-cart system. The performance of the proposed input preshaping method is compared with that of the previous ones through simulations and experiments. Using the proposed method, it is able to suppress the initial vibration of the beam-mass-cart system carrying a concentrated mass. Accurate PTP(point-to-point) positioning of the moving mass without residual vibration is also obtained experimentally by modifying the proposed pulse sequence method. Finally, the proposed input preshaping method is applied successfully to the system to follow square trajectories of the moving mass without residual vibration.

• 콘크리트학회논문집
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• 제11권3호
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• pp.59-67
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• 1999

The mass concrete structures are generally constructed in an incremental manner by deviding the whole structures by a series of many blocks. The temperature and stress distributions of any specific block are continuously affected by the blocks placed before and after the specific block. For an accurate analysis of mass concrete structures, the sequence of all the blocks must be accordingly considered including the change of material properties with time for those blocks considered. The purpose of this study is to propose a realistic analysis method which can take into account not only the influence of the sequence, time interval and size of concrete block placement on the temperatures and stresses, but also the change of material properties with time. It is seen from this study that the conventional simplified analysis, which neglects material property changes of some blocks with time and does not consider the effect of adjacent blocks in the analysis, may yield large discrepancies in the temperature and stress distributions of mass concrete structures. This study gives a method to choose the minimum number of blocks required to obtain reasonably accurate results in analysis. The study provides a realistic method which can determine the appropriate size and time interval of block placement, and can be efficiently used in the design and construction of mass concrete structures.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2005년도 전력전자학술대회 논문집
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• pp.427-429
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• 2005

In order to tune the speed controller in the linear servo applications the accurate information of a mover mass including a load mass is always required. This paper suggests the mass estimation method of a permanent magnet linear synchronous motor(PMLSM) by using the parameter estimation method of Least-Squares algorithm. First, the deterministic autoregressive moving average(DARMA) model of the mechanical dynamic system is derived. The application of the Least-Squares algorithm shows that the mass can be accurately estimated both in the simulation results and in the experimental results.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 1997년도 추계학술대회논문집; 한국과학기술회관; 6 Nov. 1997
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• pp.110-115
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• 1997

A modeling method for the bending vibration analysis of rotating Timoshenko beams with concentrated mass and mass moment of inertia is presented. The shear and rotary inertia effects become critical for the accurate estimation of the natural frequencies and modeshapes as the slenderness ratio decreases. The effect of the concentrated mass and mass moment of inertia on the natural frequencies are also investigated with the modeling method.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 추계학술대회 논문집 전력기술부문
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• pp.101-105
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• 2001

Due to their elastic anisotropy, ultrasonic testing of austenitic welds, frequently used in nuclear power plants, is much more difficult than that of isotropic elements. For accurate testing of austenitic welds, ultrasonic wave phenomena therein must be full understood. This study uses an accurate and effective numerical model, the mass-spring lattice model, for such phenomena. By comparing the numerical results with the corresponding analytical results, it is shown that the model is capable of accurately predicting the generation, reflection, refraction, and scattering phenomena of ultrasonic waves in anisotropic austenite welds. Therefore, the mass-spring lattice model will provide a very useful tool for simulating ultrasonic testing of austenitic welds, and thus will contribute to the enhancement of reliability of such ultrasonic testing.

• Maxillofacial Plastic and Reconstructive Surgery
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• 제18권4호
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• pp.701-705
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• 1996

There are many kind of diagnostic entities in submandibular or neck masses, and we can set up treatment plan and estimate treatment result, prognosis by accurate diagnosis. By reasoning medical and dental history, physical examination, anatomical consideration of masses in submandibular or neck area, location of masses, laboratory and radiographic studies, we can formulate a clinical diagnosis or differential diagnosis. Although a clinical diagnosis might suffice in some instances, a definitive(microscopic) diagnosis is frequently required for proper treatment. In order to get some information about making accurate diagnosis and setting up appropriate treatment plan, we did clinical study and histopathologic classification of 82 patients who visited and were operated for submandibular masses at Department of Oral and Maxillofacial Surgery in Seoul National University Hospital from 1988 to 1992. The result were as follows : 1. Submandibular masses occured most frequently in forties and fifties, and there was no sex predilection. 2. Chief complaints were in order of mass, swelling, pain and consistency were soft mass, mobile hard mass, firm mass, diffuse swelling in descending order. 3. Most frequent pathologic finding was lymphadenitis. 4. Site of submandibular masses were submandible, neck, submental, retromandible in descending order, and there was no predilection between left and right side. 5. Accuracy rate between clinical impression and result was 51.2%.