• Macromolecular Research
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• v.12 no.3
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• pp.276-281
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• 2004

In this study we investigated the spectral properties, including electric absorption, circular and linear dichroism (CD and LD), and fluorescence emission, of DNA in a DNA-branched polyethyleneimine (BPEI) polyplex at various polymer molecular weights (M$\_$w/) and BPEI-amine-to-DNA-phosphate ratios (N/P ratios). All BPEIs exhibited a common N/P dependence in their absorption and CD spectra. At N/P ratios ＜ 1.0, we observed some hyperchromism in the absorption spectrum, red-shifts in CD bands, and decreases in LD intensity and fluorescence intensity of intercalated ethidium. At intermediate N/P ratios, complete collapse of all spectra occurred. As the N/P ratio increased further, the polyplex dissolved in water. From its characteristic CD spectrum obtained under these conditions, we conclude that the DNA exists in a B-like form. The fluorescence and LD intensities never recovered even at high N/P ratios- which indicates that the dissolved polyplex possesses positive charges and the DNA in the polyplex is condensed despite its B-form CD spectrum. The N/P range in which the absorption and CD signals collapsed was wider when the BPEIs M$\_$w/ decreased. In the case where the BPEIs M$\_$w/ was 0.8 k, recovery of the absorption and CD spectral properties at a high N/P ratio was never achieved, which suggests that the molecular weight of the polymer plays an important role in its dissolution at a high N/P ratio.

• Bulletin of the Korean Chemical Society
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• v.33 no.3
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• pp.993-996
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• 2012

We investigated fluorescence and fluorescence excitation of diphenylsilane (DPS) in a solution and molecular beams in combination with the aid of the DFT method. When the molecule was photoexcited at 250 nm in a cyclohexane solution, normal and excimer fluorescences were observed in the ranges of 260-320 and 330-450 nm, respectively. The fluorescence excitation spectrum indicates that the channel leading to the intramolecular excimer formation is not efficient in comparison with the normal fluorescence. Vibrationally resolved fluorescence excitation spectra were measured for the DPS molecules cooled in pulsed supersonic expansion of He in the range 262.2-271.7 nm, in which we can see several electronic excitation spectra exhibiting the electronic band origins. We found that the simulated absorption spectrum based on the time-dependent densityfunctional theory calculations accords well with the absorption spectrum.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.155.1-155.1
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• 2015

Nowadays, Plasma has been used in biological, medical such as wound healing, plant grow, killing cancer. When plasma generated, UV light and ROS(Reactive oxygen species), RNS(Reactive nitrogen species) can generated and those things effect to biological material. So we made simple plasma device using needle type of electrode and generated plasma. We used three kinds of gas and measured applied voltage and current. Also we observed optical emission spectrum. Using deuterium ramp, we can observed absorption spectrum and calculated radical density by lambert-beer's law. It is around ~1016cm3. And we can see the time-resolved absorption spectrum from monochromator, PMT(photo multiply tube), IV-converter, oscilloscope.

• Bulletin of the Korean Chemical Society
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• v.19 no.4
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• pp.449-457
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• 1998

We compared various spectroscopic properties of a norfloxacin-single stranded DNA complex with those of norfloxacin-double stranded DNA complex. Norfloxacin binds to both double-and single stranded DNA, and we observed the following spectroscopic changes for both complexes: hypochromism in the norfloxacin absorption region in the absorption spectrum, the characteristic induced CD spectrum consisting of a weak positive band at 323 nm and a strong positive band at 280-300 nm followed by a negative band in the 260 nm region, a strong decrease in the fluorescence intensity and a red-shift in the fluorescence emission spectrum, and shorter fluorescence decay times. These results indicate that the environments of the bound norfloxacin in both DNAs are similar, although the equilibrium constant of the norfloxacin-single stranded DNA was twice as high as the norfloxacin-double stranded DNA complex. Both complexes were thermodynamically favored with similar negative Δ$G^o$. Negative Δ$H^o$ terms contribute to these spontaneous reactions; Δ$S^o$ term was unfavorable.

• Proceedings of the KIEE Conference
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• 1999.07e
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• pp.2450-2452
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• 1999

Presently, it is now developing the optical remote gas sensor system which can measure combustible gases such as $CH_4$ and $C_2H_2$ generating by partial discharges inside the cable and connection parts to detect thermal deterioration of Oil-Filled (OF) power cable at the appropriate time. It is the most important parameter to select central wavelength of laser diode (LD) by analyzing the absorption bend of measuring gases in the infrared region. In this research, we proposed the optical spectrum analyzer to absorption band of $CH_4$ and $C_2H_2$ for the preliminary research of optical fiber gas detecting system.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.2
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• pp.143-148
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• 2022

For the purpose of treating health checkups and recovery of patients in a super-aged society, hospitals use devices designed with a reduction circuit of electromagnetic waves associated with the specific absorption rate of electromagnetic waves absorbed by the human body. In this paper, we proposed a filter improvement design method capable of reducing electromagnetic waves. As a result of confirming the validity of the proposed technique through simulation and experimental results, the following result values were obtained. Applying the common-mode (CM) inductor 4 mH to a calibration circuit, noise decreased in a multiband spectrum. Using the differential mode(DM) inductor 40 µH element in the primary calibration circuit, the noise decreased by 15 dB or more in the 3 MHz band spectrum. Also, applying the Admittance Capacitance (Y-Cap) 10 nF element in the secondary calibration circuit resulted in the decrease by more than 30 dB in the band spectrum before 2 MHz. After using a common-mode inductor 4 mH element in the tertiary calibration circuit, it decreased by more than 15 dB in the band spectrum after 2 MHz.

• Journal of KSNVE
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• v.4 no.3
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• pp.377-384
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• 1994

This paper is an investigation of the performance of absorption diffusers to suppress the vent noise emitted when high pressure gas is throttled. First, experiment for the static performance is carried out. When there is no through-flow, the insertion loss has been obtained in terms of 1/3 octave band spectrum and the effect of the number of diffusers and the thickness of the absorption material on the static performance has been obtained. And the similarity in the spectrum of the static insertion loss is confirmed by comparing two similar models with different size. Second, the dynamic performance has been obtained by experiment using blow-down of compressed air from a storage tank through an orifice of diameter 10 mm. The back pressure by the diffuser is measured and compared with that of a single diffuser. It is found that the insertion loss of asingle diffuser is very low around 3 dB at high frequencies with negative value at low frequencies. By absorption material between the diffuser tubes, however, the performance is increased considerably. Without flow the static insertion loss increases by 3 - 4 dB by doubling the thickness or the density of the absorptionmaterial. With flow, however, the dynamic insertion loss increases. While, the back pressure by the diffuser is small enough to be neglected.

• Journal of the Korean Graphic Arts Communication Society
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• v.13 no.2
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• pp.47-53
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• 1995

Photosensitive resin of azide type is good for resolution and inner solvent, but it is really problem to development of practical use because fanctional groups of polymer has many hydrophilic radicals. By careful attention to this point, this study was investigated synthesis term, photo property and development property of composed photosensitive resin of azida type, it is to this effect. 1) H-NMR spectrum of compared DABCI showed amion redical by $\delta$6.0~6.1ppm to substitude for azide radical by amino radical by $\delta$8.9~9.45ppm, and FT-IR absorption spectra showed the absorption bends at 2100cm. 2)FT-IR absorption spectra of PHS1-DAB, PHS2-DAB, CMM-DAB and CHM-DAB showed azida radical pick to be lost at after irradiation by UV light. 3) According to exposuer change of PHS1-DAB, PHS2-DAB, CMM-DAB and CHM-DAB, absorption maximum value of UV spectrum change was 280nm. 4) to compared relative sensitivity of compared photosensitive resin, PHS2-DAB was the best and to compared insolubility rate of compared photosensitive resin, CMM-DAB was the lower. 5)Solubility if NaOH was the best by 1.0mol/$\ell$ and solubility of developing solution of ethanol to water was it in the ratio of 4 to 1.

• Bulletin of the Korean Chemical Society
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• v.28 no.2
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• pp.263-270
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• 2007

New mono- and bis-Cu(II)-triazacyclononane(tacn) complex that conjugated with 9-aminoacridine were synthesized, and their binding modes and DNA cleavage activity were investigated in this study. When the classic intercalator, 9-aminoacridine, was conjugated to mono- and bis-Cu(II)-tacn complexes, a significant red-shift and hypochromism in absorption spectrum was apparent in the acridine absorption region upon binding to DNA. Furthermore, the magnitude of the negative reduced linear dichroism signal in the substrate absorption region appeared to be larger than that in the DNA absorption region. These spectral observations indicated that the acridine moiety intercalated when the Cu(II)-tacn complex was conjugated. In contrast, from a close analysis of the circular and linear dichroism spectrum, the aminoacridine-free bis-Cu(II)-tacn complex was concluded to bind at the phosphate groups of DNA. The 9-aminoacridine-free-bis-Cu(II)-tacn complex produces the nicked and linear DNA. On the other hand, 9-aminoacridine conjugated mono-and bis-Cu(II)-tacn complexes showed unspecific binding with negligible DNA cleavage.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.1
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• pp.78.2-78.2
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• 2016

There are many telluric absorption lines which are laid on the science spectrum in ground based spectroscopic observations. In especial, the IR region spectra are considerably contaminated by telluric lines. Therefore, many scientists have a difficulty in removing the telluric effect. We thus tried removing telluric lines with IGRINS data by two methods. One is using the standard stellar spectrum as telluric lines. The other adopt calculated synthetic telluric spectrum. Here we present the results of test for precise removing telluric lines on IGRINS spectra.