• Title/Summary/Keyword: absorption rates

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Extraction Process of Isobutylene from $C_4$-raffinate - Absorption and Reaction of Isobutylene in Para-Toluene Sulfonic Acid - ($C_4$-추잔물에서의 이오부틸렌 추출공정 - 파라톨루엔 설폰산에서 이오부틸렌의 흡수 및 반응 -)

  • 선용호;최대기이윤용
    • KSBB Journal
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    • v.6 no.1
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    • pp.99-103
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    • 1991
  • The optimum conditions and rates of absorption of isobutylene in aqueous para-toluene sulfonic acid(PTSA) were studied experimentally in a stirred reactor. The effects of acid concentration(30-70 wt%), acid loading (0.3-5), mixing intensity(400-1000 rpm), and temperature ($20-80^{\circ}C$) on the absorption conditions were examined. The absorption rate of isobutylene was first order in isobutylene and variable order in PTSA concentrations. The apparent energy of activation was found to be 13 Kcal/mole.

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A Study on a Steel Slag Asphalt Concrete Design Method Considering Density and Absorption (밀도와 흡수율을 고려한 제강슬래그 아스팔트 콘크리트의 배합설계 방법 연구)

  • Kim, Kyungnam;Jo, Shinheang;Kim, Nakseok;Kim, Hyunwook
    • International Journal of Highway Engineering
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    • v.20 no.1
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    • pp.59-67
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    • 2018
  • PURPOSES : This paper presents a mix design method for using steel slag as an aggregate for asphalt mixtures. METHODS : Steel slag has a different density and absorption rate than natural aggregates. The asphalt content was calculated according to the steel slag characteristics, and the formula for aggregate-gradation correction was presented. RESULTS : The asphalt mix was designed using the proposed equations. Using the proposed mix design method, it was possible to design the asphalt mixture according to the target-usage amount of the recycled aggregate. CONCLUSIONS : The suggested method can be used for asphalt mix design using aggregates with different densities and absorption rates. It is expected to contribute to quality improvement by ensuring accurate calculation of mixing ratios for steel slag asphalt mixtures.

A Kinetic Study of Phosphate Absorption by Rice Roots (벼에 의한 인산흡수의 기작에 관한 연구)

  • 장남기
    • Journal of Plant Biology
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    • v.21 no.1_4
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    • pp.33-38
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    • 1978
  • Phosphate absorption from a Na2H32PO4 solution by Oryza sativa L. was studied in order to elucidate kinetic mechanisms of ion transport. The rates of phosphate absorption from different concentraitons indicated the presence of dual mechanisms in root tips, one in the low (1$\times$10-6 to 8$\times$10-5M) and the other in the high (1$\times$10-4 to 8$\times$10-3M). A phosphate compensation point of phosphate transport was revealed with a 1$\times$10-6M solution of Na2H32PO4. The kinetic model that ion transport involves an exchange reaction of absorption and desorptin is prosposed as follows: where C represents an ionic-specific organic carrier in the membrane; M, Mo and Mi are the mineral ions, M-outside and M-inside; MC is a carrier-ion complex; and the K's represent rate constants. In this model, the Mi velocity, v, is given by: {{{{v= {dMi} over {dt}= {(K1K3Mo-K2K4Mi) Ct} over {(K2+K3)+K1Mo+K4Mi} }} where Ct is equal to C+MC, and t is time.

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Dielectric Characteristics through 2D-correlation Analysis of SiOCH Thin Film deposited by BTMSM/O2 High Flow Rates (BTMSM/O2 고유량으로 증착된 SiOCH 박막의 2차원 상관관계 분석을 통한 유전특성 연구)

  • Kim, Min-Seok;Hwang, Chang-Su;Kim, Hong-Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.544-551
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    • 2008
  • We have studied the dielectric characteristics of low-k interlayer dielectric materials fabricated by PECVD for various precursor's flow rates. BTMSM precursor was introduced with the flow rates from 42 sccm to 60 sccm by 2 sccm step in the constant flow rate of 60 sccm $O_2$. The absorption intensities of Si-O-$CH_x$ bonding group and Si-$CH_x$ bonding group changed synchronously for the variation of precursor flow rate, but the intensity of Si-O-Si(C) responded asynchronously with the $CH_x$ combined bonds. The heat treatment reduced the FTIR absorption intensity of Si-O-$CH_x$ bonding group and Si-$CH_x$ bonding group but increased the intensity of Si-O-Si(C). The nanopore and free space formed by the increasement of caged link mode and cross link mode of Si-O-Si(C) group implied the origin of low-k SiOCH films.

Mechanical Properties of Different Anatomical Sites of the Bone-Tendon Origin of Lateral Epicondyle

  • Han, Jung-Soo
    • Journal of Mechanical Science and Technology
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    • v.15 no.7
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    • pp.1013-1021
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    • 2001
  • A series of rabbit common extensor tendon specimens of the humeral epicondyle were subjected to tensile tests under two displacement rates (100mm/min and 10mm/min) and different elbow flexion positions 45°, 90°and 135°. Biomechanical properties of ultimate tensile strength, failure strain, energy absorption and stiffness of the bone-tendon specimen were determined. Statistically significant differences were found in ultimate tensile strength, failure strain, energy absorption and stiffness of bone-tendon specimens as a consequence of different elbow flexion angles and displacement rates. The results indicated that the bone-tendon specimens at the 45°elbow flexion had the lowest ultimate tensile strength; this flexion angle also had the highest failure strain and the lowest stiffness compared to other elbow flexion positions. In comparing the data from two displacement rates, bone-tendon specimens had lower ultimate tensile strength at all flexion angles when tested at the 10mm/min displacement rate. These results indicate that creep damage occurred during the slow displacement rate. The major failure mode of bone-tendon specimens during tensile testing changed from 100% of midsubstance failure at the 90°and 135°elbow flexion to 40% of bone-tendon origin failure at 45°. We conclude that failure mechanics of the bone-tendon unit of the lateral epicondyle are substantially affected by loading direction and displacement rate.

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Moisture Absorption and Desorption Properties of Douglas Fir, Hinoki, Larch, Plywood, and WML Board in Response to Humidity Variation

  • PARK, Hee-Jun;JO, Seok-Un
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.4
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    • pp.488-502
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    • 2020
  • In this study, the moisture absorption and desorption properties presented by the Health-Friendly Housing Construction Standards of South Korea were compared using the wood of three tree species (Douglas-fir, Hinoki, Larch) and two types of wood-based materials(Plywood, WML Board). The national standards for functional building materials present that the amounts of moisture absorption and desorption should be at least 65g/㎡ on average, respectively according to the test method under KS F 2611:2009. Therefore, in this study, the moisture absorption/desorption properties of materials with no treatment (Control), with punching, and with surface stain finishing and the moisture absorption/desorption property improvement effects of the treatments were compared and analyzed. According to the results of this study, it was evaluated that all five types of wood and wood-based materials tested did not satisfy the amount of moisture absorption/desorption of at least 65g/㎡, which is the performance standard for moisture absorption/desorption functional building materials, indicating that untreated wood and wood-based materials cannot be applied as functional finishing materials according to the Health-Friendly Housing Construction Standards. The surface stain finishing greatly reduced the moisture absorption and desorption rates of the materials, and the amounts of moisture absorbed and desorbed were also shown to decrease by at least two times on average. When the surfaces of the materials were punched with Ø4mm holes at intervals of 20 mm, the moisture absorption/desorption areas increased from 18% to 51%, and this increase was shown to be capable of increasing the amounts of moisture absorbed/desorbed by 29% on average at the minimum, and 81% on average at the maximum. The effects of punching were shown to be identical even in cases where the materials were stain finished. For the application of wood or wood-based materials as eco-friendly, health-friendly, and moisture absorption/desorption functional building materials hereafter, it is judged that new physical and chemical improvement studies should be conducted, and treatment methods should be developed.

Effects of Vehicles and Penetration Enhancers on the Percutaneous Absorption of Apomorphine (기제와 피부투과촉진제가 아포모르핀의 피부투과에 미치는 영향)

  • Choi, Young-Geun;Cui, Yu;Kim, Keun-Nam;Park, Eun-Seok;Chi, Sang-Cheol
    • Journal of Pharmaceutical Investigation
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    • v.33 no.2
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    • pp.129-133
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    • 2003
  • In order to evaluate the effects of vehicles and penetration enhancers on skin permeation of apomorphine, the skin permeation rates of apomorphine from vehicles of different composition were determined using Franz diffusion cells fitted with excised rat skins. Solubility of apomorphine in various solvents was investigated to select a vehicle suitable for the percutaneous absorption of apomorphine. The solvents used were propylene glycol (PG), $Transcutol^{\circledR},\;Labrasol^{\circledR},\;Labrafac hydro WL^{\circledR},\;Labrafil WL 2609 BS^{\circledR}$ and isopropyl alcohol. Even though permeation rates of apomorphine from each vehicle were low $(0.008-0.36\;{\mu}g/cm^2/hr)$, the combination of PG and $Labrafac^{\circledR}$ increased it significantly. The permeation rates of apomorphine from $PG/Labrafac^{\circledR}$ mixtures increased as the volume fraction of PG in the mixture increased. The maximum permeation rate of $18\;{\mu}g/cm^2/hr$ was achieved at 30% of PG, which decreased with further increase of PG fraction. A series of fatty acids, alcohols and monoterpenes were employed as penetration enhancers. Incorporation of each enhancer in the $PG/Labrafac^{\circledR}$ (30:70) mixture at the level of 10% improved the skin permeation significantly. The highest permeation rate, $117\;{\mu}g/cm^2/hr$, was attained with myristic acid.

Performance Characteristics of Type II LiBr-H2O Absorption Heat Pump in Accordance with the Refrigerant Heat Exchanger Configuration (냉매 열교환기 구성방법에 따른 제 2종 흡수식 히트펌프의 성능 특성 변화에 관한 연구)

  • Lee, Chang Hyun;Yoon, Jun Seong;Kim, In Gwan;Kwon, Oh Kyung;Cha, Dong An;Bae, Kyung Jin;Kim, Min Su;Park, Chan Woo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.7
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    • pp.373-384
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    • 2017
  • The objective of this study was to determine the effect of refrigerant heat exchanger on the performance of type II absorption heat pump performance using numerical analysis. Two heat exchange installation methods were used: solution to refrigerant and waste hot water to refrigerant. These methods were compared to the standard model of hot water flow without using refrigerant heat exchanger. When waste hot waters were bypassed to refrigerant heat exchanger, COP was not affected. However, steam mass generation rates were increased compared to those of the standard model. When solutions were bypassed to the refrigerant heat exchanger, results were different depending on the place where the solution rejoined. COP and steam mass generation rates were lower compared to those when waste heat water was passed to refrigerant heat exchanger. Thus, it is possible to obtain higher steam mass generation rates by using waste water and installing refrigerant heat exchanger.

Periodic Immersion of the Bangudae Petroglyphs and Rock Weathering Characteristics (반구대 암각화의 주기적인 침수와 구성암석의 풍화 특성)

  • Hwang, Sang-Ill;Park, Kyung-Geun;Yoon, Soon-Ock
    • Journal of the Korean Geographical Society
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    • v.45 no.3
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    • pp.342-359
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    • 2010
  • The Bangudae Petroglyphs locate at Bangudong, Daegok-ri, Eonyang-eup, Ulju-gun, Ulsan and was designated as the No. 285 national treasure since 1995. After the construction of Sayeon-dam in 1965, there were many controversies of the rock weathering problems by the periodic immersion for approximately a few months. The isopleths of water content on the rock are drawn and the result shows relationships between the isopleths and distribution of joints or exfoliations. The distributions of water content rates in the Petroglyphs show the downward increasing pattern. This may suggest that the rates of water content are further influenced by the duration of immersion. Also, the upper part of the Petroglyphs with dense joints shows high rates of water content. If the water content rates in rocks increase, the water absorption rates increase too, because of the increasement of coefficient of permeability and porosity. The weathering damages of the Petroglyphs in which the pores are saturated by the periodic immersion are in the critical conditions.

Hydrolysis Rate Study of Chelated Ti Alkoxide by Using U.V. Spectrophotometer (자외선 흡수대를 이용한 Chelated Ti Alkoxide의 수화반응 연구)

  • 김선욱;윤만순;송인호
    • Journal of the Korean Ceramic Society
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    • v.28 no.12
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    • pp.975-980
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    • 1991
  • Chelated titanium alkoxides are hydrolysed showly and stable enough to prepare multicomponent gels of titania without its precipitation due to the fast hydrolysis of Ti alkoxide. The alkoxy groups of chelated titanium alkoxide are hydrolysed as fast as that of titanium alkoxide but the chelating groups are stable even in aqueous solution. The chelating groups showed different rates of hydrolysis in aqueous ammonia solution and water added one. Those rates were monitored with UV-VIS spectrophotometer by using their unique absorption bands before and after hydrolysis.

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