• 제목/요약/키워드: absorption line

검색결과 403건 처리시간 0.033초

Analyses on Fine Structure and Electronic Structure of Cr-doped Li4Ti5O12 by Using X-ray Absorption Spectroscopy and First Principle Calculation (X-선 흡수실험 및 제일원리계산을 통한 Cr-doped Li4Ti5O12의 미세구조 및 전자구조 해석)

  • Song, Han-Nah;Kim, Hyung-Sun;Cho, Byung-Won;Kim, Yong-Tae
    • Journal of the Korean Electrochemical Society
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    • 제14권1호
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    • pp.33-37
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    • 2011
  • $Li_4Ti_5O_{12}$ has been considered a potential material for high power lithium batteries. Since $Li_4Ti_5O_{12}$ is however an insulator having a broad band gap, various methods have been employed to improve the conductivity. In this study, we have investigated the change of fine structure and electronic structure by Cr doping using X-ray absorption spectroscopy and First Principle Calculation. Doping with Cr, we could obtain an enhanced electronic conductivity by locating the Fermi level at the center position of Cr d-band and identify the change of XANES pre-edge and white line peak due to the increase of electron density of Ti d-band.

Heat Resistant Electromagnetic Noise Absorber Films Using Poly(amide imide)/Soft Magnet Composite (내열성 전자기 노이즈 흡수 폴리(아미드-이미드)/연자성체 복합체 필름)

  • Han, Ji-Eun;Jeon, Byung-Kuk;Goo, Bon-Jae;Cho, Seung-Hyun;Kim, Sung-Hoon;Lee, Kyung-Sub;Park, Yun-Heum;Lee, Jun-Young
    • Polymer(Korea)
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    • 제33권1호
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    • pp.91-95
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    • 2009
  • We fabricated the electromagnetic (EM) noise absorber films for high temperature use by blending a soft magnetic powder with poly(amide imide) (PAI). The EM noise absorber films of PAI/soft magnet composite were prepared by casting the solution of poly(amide amic acid)/soft magnet powder into glass substrate with casting applicator device and then thermal imidization. The obtained films were fully characterized and their physical properties including thermal behavior, thermal stability and mechanical properties were studied. The EM noise absorption ability was also investigated using micro-strip line method. At 1 GHz, the power loss of composite film with 150 ${\mu}m$ thickness was about 25%.

W-type hexaferrite-epoxy composites for wide-band radar absorption (광대역 레이다 흡수용 W-type 육방정 페라이트-에폭시 복합 소재)

  • Su-Mi Lee;Tae-Woo Lee;Young-Min Kang;Hyemin Kim
    • Journal of Aerospace System Engineering
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    • 제17권1호
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    • pp.42-50
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    • 2023
  • In this study, hexagonal ferrite powder with chemical formula SrZn2-xCoxFe16O27 was synthesized by a solid-state reaction method and its electromagnetic (EM) wave absorption characteristics were evaluated in the frequency range of 0.1-18 GHz with absorber thickness range of 0 - 10 mm. Reflection loss (RL) affecting electromagnetic wave absorption performance was calculated based on the transmission line theory using measured complex permeabilities and permittivities. RL spectra were also directly measured for some samples. They were well matched with calculated results. High-frequency complex permeability characteristics were changed gradually according to the amount of Co substitution (x). The EM wave absorption frequency band could be tuned accordingly. Hexaferrite samples with x = 1.0, 1.25, and 1.5 exhibited remarkable maximum electromagnetic wave absorption performances with minimum RL (RLmin) lowered than -50 dB. They also showed a very broad frequency band (Δf > 10 GHz) in which more than 90% of the EM wave energy absorption occurred (RL ≤ -10 dB).

Investigation of the Effects of Wavelength Range and Absorption Cross-Section on Sulfur Dioxide Slant Column Density Retrieval Using Ground-Based UV Scattered Sunlight Measurement (지상 기반 태양 UV 산란광 관측을 이용한 이산화황 경사칼럼농도 산출 시 파장 구간 및 흡수단면적에 따른 영향 조사)

  • Gyeong Park;Buju Gong;Minji Kim;Hanlim Lee
    • Korean Journal of Remote Sensing
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    • 제40권4호
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    • pp.377-385
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    • 2024
  • We investigated the effect of spectral fitting wavelength interval variations and selection of absorption cross-section on the sulfur dioxide slant column density (SCD) retrievals from the scattered sunlight observation using a UV-Vis hyperspectral instrument. The sulfur dioxide slant column densities were retrieved from the combinations of multiple spectral fitting intervals and absorption cross-sections. The observation was carried out at the site 0.53 km away from a combustion site located in Gimhae from December 1, 2023, to January 23, 2024. The radiances were obtained on the line of measurement sight toward the stack of the combustion facility. The best spectral fitting intervals were found to be from 305.7 to 321.1 nm. In terms of the absorption cross-section dependency, the SO2 (293 K), O3 (223 K, 243 K) show the best spectral fitting for the observed radiances with both the smallest fitting residual and SCD error. The effects of the fitting interval and cross sections found in this study can be useful information for improving SO2 retrievals based on UV hyperspectral measurements.

Effect of Genotype on Whole-body and Intestinal Metabolic Response to Monensin in Mice

  • Fan, Y.K.;Croom, W.J.;Daniel, Linda;McBride, B.W.;Koci, M.;Havenstein, G.B.;Eisen, E.J.
    • Asian-Australasian Journal of Animal Sciences
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    • 제19권4호
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    • pp.554-562
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    • 2006
  • Two lines of mice, M16 selected for rapid growth and a randomly selected control ICR as well as their reciprocal crosses were used to study the effects of genotype on whole-body energetics and intestinal responses to monensin. Six mice, eight weeks of age, from each line or reciprocal cross were assigned to one of two treatments, 1) drinking water containing 20 mmol/L monensin dissolved in 0.5% V/V ethanol, and 2) drinking water containing 0.5% V/V ethanol (control) for two weeks. After 11 days (age of 9 weeks and 4 days), whole-body $O_2$ consumption was measured. At the end of two weeks, jejunal $O_2$ consumption, intestinal tissue composition and histomorphometrics as well as the rate and efficiency of glucose absorption were estimated. In comparison with the control, monensin administration in drinking water resulted in less daily water intake (13.4 vs. 15.5 ml/mouse, p<0.01), less protein to DNA ratio of jejunal mucosa (5.41 vs. 6.01 mg/mg, p<0.05), lower villus width (88 vs. $100{\mu}m$, p<0.05), and less jejunal tissue $O_2$ consumption enhancement by alcohol (7.2 vs. 10.5%, p<0.01) in mice. Other than those changes, monensin had little (p>0.05) effect on variables measured in either line of mice or their reciprocal cross. In contrast, the M16 line, selected for rapid growth, as compared to the ICR controls or the reciprocal crosses, had less initial (pre-monensin treatment) whole-body $O_2$ consumption per gram of body weight (1.68 vs. $2.11-2.34{\mu}mol/min{\cdot}g$ BW, p<0.01) as compared to the ICR and reciprocal crosses. In addition, the M16 mice exhibited greater growth (412 vs. 137-210 mg/d, p<0.05), better feed efficiency (41.7 vs. 19.9-29.3 mg gain/g feed, p<0.05), shorter small intestines adjusted for fasted body weight (1.00 vs. 1.22-1.44 cm/g FBW, p<0.05), wider villi (109 vs. $87-93{\mu}m$, p<0.05), more mature height of enterocytes (28.8 vs. $24.4-25.1{\mu}m$, p<0.05) and a lower rate (91 vs. $133-145{\eta}mol\;glucose/min{\cdot}g$ jejunum, p<0.05) and less energetic efficiency (95 vs. $59-72{\eta}mol$ ATP expended/${\eta}mol$ glucose uptake, p<0.05) of glucose absorption compared to the ICR line and the reciprocal cross. Monensin had little (p>0.05) effect on whole-body $O_2$ consumption and jejunal function, whilst selection for rapid growth resulted in an apparent down-regulation of intestinal function. These data suggest that genetic selection for increased growth does not result in concomitant changes in intestinal function. This asynchrony in the selection for production traits and intestinal function may hinder full phenotypic expression of genotypic growth potential.

ON THE NATURE OF SODIUM EXCESS OBJECTS

  • Jeong, Hyunjin;Yi, Sukyoung K.;Kyeong, Jaemann;Sarzi, Marc;Sung, Eon-Chang;Oh, Kyuseok
    • The Bulletin of The Korean Astronomical Society
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    • 제38권2호
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    • pp.38.2-38.2
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    • 2013
  • Several studies have reported the presence of sodium excess objects having neutral atomic absorption lines at $5895{\AA}$ (NaD) and $8190{\AA}$ that are deeper than expected based on stellar population models that match the stellar continuum. The origin of these lines is therefore hotly debated. van Dokkum & Conroy proposed that low-mass stars (0.3M) are more prevalent in massive early-type galaxies, which may lead to a strong NaI 8190 line strength. It is necessary to test this prediction, however, against other prominent optical line indices such as NaD, Mgb, and Fe5270, which can be measured with a significantly higher signal-to-noise ratio than NaI 8190. We identified a new sample of roughly one thousand NaD excess objects (NEOs; ~8% of galaxies in the sample) based on NaD line strength in the redshift range 0.00${\alpha}$-enhanced" ([${\alpha}/Fe$] ~ 0.3), "metal-rich" ([Z/H] ~ 0.3), and, especially, "Na-enhanced" ([Na/Fe] ~ 0.3).

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Soot Temperature and Concentration Measurement Using Emission/Transmission Tomography in Laminar Diffusion Flame (방사와 투과를 이용한 층류확산화염내 매연입자의 온도 및 농도 측정)

  • 송상종;박성호;김상수
    • Transactions of the Korean Society of Mechanical Engineers
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    • 제17권10호
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    • pp.2563-2573
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    • 1993
  • The measurements of monochromatic line-of-sight flame emission and light transmission in the same path having small spatial resolution were performed in an axisymmetric laminar propane $C_{3}H_{8}$ diffusion flame. The light wavelengthes of 632 nm, 800nm, 900nm were used. From these measurements, local point soot radiances (by Kirchhoff's law) and absorption coefficients were reconstructed by tomography. Thus local point soot temperatures and concentrations were obtained. The reconstructed soot temperatures and concentrations of local points have no differences between the case of visible range (632 nm) and the case of infrared range (800 nm and 900 nm). In these ranges, the scattering coefficient is much lower than the absorption coefficient. Soot mean temperature over the path also matches well with local soot temperature in outer region of the flame. Temperature measurement by thermocouple with different bead diameters $(222{\mu}m and 308{\mu}m)$ was carried in the same flame. Rapid insertion technique was used and radiation effect was considered. Radiation correction in the sooting region was carried out and the corrected result was in good agreement with the local soot temperature.

Abundant Methanol Ices toward a Massive Young Stellar Object in the Galactic Center

  • An, Deokkeun;Sellgren, Kris;Adwin Boogert, A.C.;Ramirez, Solange V.;Pyo, Tae-Soo
    • The Bulletin of The Korean Astronomical Society
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    • 제41권2호
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    • pp.57.1-57.1
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    • 2016
  • Methanol ($CH_3OH$) is a key species in the formation of complex organic molecules. We report the first detection of solid $CH_3OH$ in a line of sight toward the Galactic center (GC) region, based on L-band spectra taken with the Subaru telescope, aided by L'-band imaging data and moderate-resolution spectra from NASA/IRTF. It is found toward a background star, ~8000 AU in projected distance from a newly discovered massive young stellar object (YSO). This YSO also exhibits a strong $CO_2$ ice absorption band at ${\sim}15{\mu}m$ in Spitzer/IRS data, which has a prominent long-wavelength wing. It confirms that a high $CH_3OH$ abundance is responsible for the broad $15{\mu}m$ $CO_2$ ice absorption towards massive YSOs in the GC. Clearly, $CH_3OH$ formation in ices is efficient in the GC region, as it is in star-forming regions in the Galactic disk. We discuss implications of our result on the astrochemical processes in the hostile GC molecular clouds.

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ORFEUS SURVEYS OF THE INTERSTELLAR MOLECULAR HYDROGEN (ORFEUS 위성을 이용한 성간 수소분자의 전천 관측)

  • Lee, Dae-Hee;Seon, Kwang-Il;Min, Kyoung-Wook
    • Publications of The Korean Astronomical Society
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    • 제20권1호
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    • pp.11-20
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    • 2005
  • We present measurements of interstellar $H_2$ absorption lines in the continuum spectra of 54 early-type stars in the Galactic disk and halo and 3 stars in the Magellanic Clouds. The data were obtained with the Berkeley Extreme and Far-Ultraviolet Spectrometer (BEFS), part of the ORFEUS telescope, which flew on the ORFEUS-SPAS I and II space-shuttle missions in 1993 and 1996, respectively. The spectra extend from the interstellar cutoff at $912{\AA}$ to about $1200{\AA}$ with a spectral resolution of ${\sim}3000$ and statistical signal-to-noise ratios between 10 and 65. Assuming a velocity profile derived from optical observations (when available), we model the column densities N(J) of the rotational levels J = 0 through 5 for each line of sight. Our data reproduce the relationships among molecular and total hydrogen column density, fractional molecular abundance, and reddening first seen in Copernicusobservations of nearby stars (Savage et al. 1977). The results show that most of these molecular clouds have $H_2$ total column densities between $10^{15}cm^{-2}$ and $10^{21}cm^{-2}$, and kinetic temperatures from 21 K to 232 K, with average of 89 K, consistent with the result of Copernicus (Savage et al. 1977).

TEMPORAL VARIATION OF HCO+ 1-0 GALACTIC ABSORPTION LINES TOWARD NRAO 150 AND BL LAC

  • Han, Junghwan;Yun, Youngjoo;Park, Yong-Sun
    • Journal of The Korean Astronomical Society
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    • 제50권6호
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    • pp.185-190
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    • 2017
  • We present observations of $HCO^+$ 1-0 absorption lines toward two extragalactic compact radio sources, NRAO 150 and BL Lac with the Korean VLBI Network in order to investigate their time variation over 20 years by Galactic foreground clouds. It is found that the line shape of $-17kms^{-1}$ component changed marginally during 1993-1998 period and has remained unaltered thereafter for NRAO 150. Its behavior is different from that of $H_2CO$ $1_{10}-1_{11}$, suggesting chemical differentiation on ~ 20 AU scale, the smallest ever seen. On the other hand, BL Lac exhibits little temporal variation for the $HCO^+$ and $H_2CO$ lines. Our observation also suggests that Korea VLBI Network performs reliably in the spectrum mode in that the shapes of the new $HCO^+$ 1-0 spectra are in good agreement with the previous ones to an accuracy of a few percent except the time varying component toward NRAO 150.