• Title/Summary/Keyword: absorption kinetic

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ORFEUS SURVEYS OF THE INTERSTELLAR MOLECULAR HYDROGEN (ORFEUS 위성을 이용한 성간 수소분자의 전천 관측)

  • Lee, Dae-Hee;Seon, Kwang-Il;Min, Kyoung-Wook
    • Publications of The Korean Astronomical Society
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    • v.20 no.1 s.24
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    • pp.11-20
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    • 2005
  • We present measurements of interstellar $H_2$ absorption lines in the continuum spectra of 54 early-type stars in the Galactic disk and halo and 3 stars in the Magellanic Clouds. The data were obtained with the Berkeley Extreme and Far-Ultraviolet Spectrometer (BEFS), part of the ORFEUS telescope, which flew on the ORFEUS-SPAS I and II space-shuttle missions in 1993 and 1996, respectively. The spectra extend from the interstellar cutoff at $912{\AA}$ to about $1200{\AA}$ with a spectral resolution of ${\sim}3000$ and statistical signal-to-noise ratios between 10 and 65. Assuming a velocity profile derived from optical observations (when available), we model the column densities N(J) of the rotational levels J = 0 through 5 for each line of sight. Our data reproduce the relationships among molecular and total hydrogen column density, fractional molecular abundance, and reddening first seen in Copernicusobservations of nearby stars (Savage et al. 1977). The results show that most of these molecular clouds have $H_2$ total column densities between $10^{15}cm^{-2}$ and $10^{21}cm^{-2}$, and kinetic temperatures from 21 K to 232 K, with average of 89 K, consistent with the result of Copernicus (Savage et al. 1977).

Analysis of the Dye Absorption Behavior in Accordance with the Dye Structure in the Cold Pad Batch Dyeing of Cotton Knit (면니트의 CPB 염색에서 염료 구조에 따른 흡진 거동 분석)

  • Hong, Seok Il;Nam, Chang Woo;Lee, Woosung
    • Textile Coloration and Finishing
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    • v.28 no.3
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    • pp.175-182
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    • 2016
  • To investigate dyeing behaviors in accordance with dye structure in cold pad batch dyeing of cotton knit, monochlorotriazine-vinylsulfone bifunctional dyes and monofluorotriazine-vinylsulfone bifunctional dyes were prepared. The spectral property and solubility of the dyes were tested and compared with the imported dyes. In addition, exhaustion behaviors of individual and mixed dye solutions were measured to examine the influence of dye structure on dyeing behavior in cold pad batch dyeing. The substantivity, fixation, migration index and half dyeing time were also calculated for further analysis of dyeing behavior of the prepared dyes. As a result, both dyes exhibited the superior solubilities and satisfactory light absorption properties. Also, monofluorotriazine-vinylsulfone bifunctional dyes showed moderate sensitivity to alkalinity and proper kinetic index values compared with the monochlorotriazine-vinylsulfone bifunctional dyes and the imported dyes. The results indicated monofluorotriazine-vinylsulfone bifunctional structure of the dye is suitable for cold pad batch dyeing.

Evaluations of Hydrogen Properties of MgHx-Nb2O5 Oxide Composite by Hydrogen Induced Mechanical Alloying (수소 가압형 기계적 합금화법으로 제조한 MgHx-Nb2O5 산화물 복합 재료의 수소화 특성 평가)

  • Lee, Nari;Lee, Soosun;Hong, Taewhan
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.429-436
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    • 2012
  • Mg and Mg-based alloys are regarded as strong candidate hydrogen storage materials since their hydrogen capacity exceeds that of known metal hydrides. One of the approaches to improve kinetic is addition of metal oxide. In this paper, we tried to improve the hydrogenation properties of Mg-based hydrogen storage composites. The effect of transition metal oxides, such as $Nb_2O_5$ on the kinetics of the Magnesium hydrogen absorption kinetics was investigated. $MgH_x$-5wt.% $Nb_2O_5$ composites have been synthesized by hydrogen induced mechanical alloying. The powder fabricated was characterized by X-ray diffraction (XRD), Field Emission-Scanning Electron Microscopy (Fe-SEM), Energy Dispersive X-ray (EDX), BET and simultaneous Thermo Gravimetric Analysis / Differential Scanning Calorimetry (TG/DSC) analysis. The Absorption / desorption kinetics of $MgH_x$-5wt.% $Nb_2O_5$ (type I and II) are determined at 423, 473, 523, 573 and 623 K.

The Effect of Foot Landing Type on Lower-extremity Kinematics, Kinetics, and Energy Absorption during Single-leg Landing

  • Jeong, Jiyoung;Shin, Choongsoo S.
    • Korean Journal of Applied Biomechanics
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    • v.27 no.3
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    • pp.189-195
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    • 2017
  • Objective: The aim of this study was to examine the effect of foot landing type (forefoot vs. rearfoot landing) on kinematics, kinetics, and energy absorption of hip, knee, and ankle joints. Method: Twenty-five healthy men performed single-leg landings with two different foot landing types: forefoot and rearfoot landing. A motion-capture system equipped with eight infrared cameras and a synchronized force plate embedded in the floor was used. Three-dimensional kinematic and kinetic parameters were compared using paired two-tailed Student's t-tests at a significance level of .05. Results: On initial contact, a greater knee flexion angle was shown during rearfoot landing (p < .001), but the lower knee flexion angle was found at peak vertical ground reaction force (GRF) (p < .001). On initial contact, ankles showed plantarflexion, inversion, and external rotation during forefoot landing, while dorsiflexion, eversion, and internal rotation were shown during rearfoot landing (p < .001, all). At peak vertical GRF, the knee extension moment and ankle plantarflexion moment were lower in rearfoot landing than in forefoot landing (p = .003 and p < .001, respectively). From initial contact to peak vertical GRF, the negative work of the hip, knee, and ankle joint was significantly reduced during rearfoot landing (p < .001, all). The contribution to the total work of the ankle joint was the greatest during forefoot landing, whereas the contribution to the total work of the hip joint was the greatest during rearfoot landing. Conclusion: These results suggest that the energy absorption strategy was changed during rearfoot landing compared with forefoot landing according to lower-extremity joint kinematics and kinetics.

Surface Plasmon Effect in Hot Electron Based Photovoltaic Devices

  • Lee, Yeong-Geun;Jeong, Chan-Ho;Park, Jong-Hyeok;Park, Jeong-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.162-162
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    • 2011
  • Nanometer-sized noble metals can trap and guide sunlight for enhanced absorption of light based on surface plasmon that is beneficial for generation of hot electron flows. A pulse of high kinetic energy electrons (1-3 eV), or hot electrons, in metals can be generated after surface exposure to external energy, such as in the absorption of light or in exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms. It is highly probable that the correlation between hot electron generation and surface plasmon can offer a new guide for energy conversion systems [1-3]. We show that hot electron flow is generated on the modified gold thin film (<10 nm) of metal-semiconductor (TiO2) Schottky diodes by photon absorption, which is amplified by localized surface plasmon resonance. The short-circuit photocurrent obtained with low energy photons (lower than bandgap of TiO2, ~3.1-3.2 eV) is consistent with Fowler's law, confirming the presence of hot electron flows. The morphology of the metal thin film was modified to a connected gold island structure after heating to 120, 160, 200, and 240$^{\circ}C$. These connected island structures exhibit both a significant increase in hot electron flow and a localized surface plasmon with the peak energy at 550-570 nm, which was separately characterized with UV-Vis [4]. The result indicates a strong correlation between the hot electron flow and localized surface plasmon resonance with possible application in hot electron based solar cells and photodetectors.

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A Power-Generation System using Cavitation jet flow (케비테이션 제트 유동을 이용한 발전 시스템)

  • Na, Jeoungsu;Lee, Kangju;Lee, Bongyeol;Joo, Namsik
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.162.1-162.1
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    • 2010
  • Cavitation phenomenon has long been a difficult problem that regarded as negative event to fluid machines or industrial facilities. In the latest, however, some engineers became to understand the power of cavitation and use it to cleaning wall after developing cavitation nozzle. In this paper, we introduce new concept for power-generation system using cavitation jet flow maid by nozzle and impulse turbine in vacuum condition. The vacuum needed to make cavitation is generated naturally by Torricelli's vacuum, 10.23m effective head drop without additional power. We analyzed water's boiling and the steam's mean free path according to vacuum purity levels for nozzles and turbine blades. The nozzles make water accelerate in the neck and boil in expansion section of the nozzles. The shape of the impulse turbine is designed for absorption of the molecule's kinetic energy of the steam.

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Expanding Thermal Plasma CVD of Silicon Thin Films and Nano-Crystals: Fundamental Studies and Applications

  • Sanden, Richard Van De
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.78-78
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    • 2012
  • In this presentation I will review the expanding thermal plasma chemical vapour deposition (ETP-CVD) technology, a deposition technology capable of reaching ultrahigh deposition rates. High rate deposition of a-Si:H, ${\mu}c$-Si:H, a-SiNx:H and silicon nanocrystals will be discussed and their various applications, mainly for photovoltaic applications demonstrated. An important aspect over the years has been the fundamental investigation of the growth mechanism of these films. The various in situ (plasma) and thin film diagnostics, such as Langmuir probes, retarding field analyzer, (appearance potential) mass spectrometry and cavity ring absorption spectroscopy, spectroscopic ellipsometry to name a few, which were successfully applied to measure radical and ion density, their temperature and kinetic energy and their reactivity with the growth surface. The insights gained in the growth mechanism provided routes to novel applications of the ETP-CVD technology, such as the ultrahigh high growth rate of silicon nanorystals and surface passivation of c-Si surfaces.

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Modeling of Piston Crevice Hydrocarbon Oxidation in SI Engines (전기점화 기관 간극 체적 내 미연탄화수소의 산화 모델링)

  • Choi, Hoi-Myung;Kim, Se-Jun;Min, Kyung-Doug
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.884-889
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    • 2001
  • Combustion chamber crevices in SI engines are identified as the largest contributor to the engine-out hydrocarbon emissions. The largest of crevice region is the piston ring pack crevice. To predict and understand the oxidation process of piston crevice hydrocarbons, a 3-dimensional numerical simulation method was developed. A engine shaped computational mesh with moving grid for piston and valve motions was constructed. And a 4-step oxidation model involving 7 species was used and the 16 coefficients in the rate expressions were optimized based on the results from a detailed chemical kinetic mechanism for the oxidation condition of engine combustion chamber. Propane was used as a fuel in order to eliminate oil layer absorption and liquid fuel effect.

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Actinomycins에 의한 Adenosine Deaminase의 억제

  • 김경자;조성진
    • Microbiology and Biotechnology Letters
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    • v.24 no.3
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    • pp.380-383
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    • 1996
  • Adenosine deaminase inhibitor was extracted from culture broth of Streptomyces sp. strain V-8 with ethylacetate. The ethylacetate extract showed the characteristic UV absorption spectrum of actinomycins at 440-450 nm. The ethylacetate extract was compared with respect to inhibitory behavior against adenosine deaminase from calf intestinal mucosa with actinomycin D, -C complex and actinomycin V. The Ki values for actnomycin D, -C complex, and actinomycin V against adenosine deaminase were determined to be 9.9 $\times$ 10$^{-6}$ M, 9.6 $\times$ 10$^{-6}$ M and 9.3 $\times$ 10$^{-6}$ M, respectively. The Ki value for the ethylacetate extract of culture broth against adenosine deaminase was determined to be 5.7 $\times$ 10$^{-6}$ M. The kinetic parameters of actinomycin D, -C complex, -V and ethylacetate extract of culture broth for adenosine deaminase were as follows:I$_{50}$ = 1.5 $\times$ 10$^{-5}$ M (actinomycin D), 2.7 $\times$ 10$^{-5}$ M (actinomycin C complex), 3.5 $\times$ 10$^{-5}$ M (actinomycin V), 8.9 $\times$ 10$^{-6}$ M (ethylacetate extract of culture broth). The adenosine deaminase was inhibited noncompetitively by ethylacetate extract of culture broth as well as by actinomycin D, -C complex and actinomycin V.

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Kinetics of $CO_2$ Absorption in Aqueous AMP (2-amino-2-methyl -1-propanol) Solutions

  • Park, Moon-Ki
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.1
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    • pp.85-90
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    • 1998
  • The reaction rate of $CO_2$ with 2-amino-2-methyl-1-propanol (AMP), MEA monoethanolamine(MEA) and diethanolamine (DEA) in aqueous solutions has been determined using a stirred vessel with a plane gas-liquid interface over a wide range of concentrations of amines at different temperatures. The results show that the overall reaction rate is first order with respect to both $CO_2$ and amine. The reaction rate constant varies with temperature according to the relationship which agrees with the experimental data. The proposed interpretation is that the kinetic rate determining step is a reaction of $CO_2$ with amine to form carbamic acid which is then totally and immediately ionized.

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