• Title/Summary/Keyword: absorption abilities

Search Result 68, Processing Time 0.022 seconds

Comparison of Phenyl Ethylamine and Hyamine Base as an Absorbent of $Carbon^{14}$ Dioxide ($C^{14}O_2$의 흡수제(吸收劑)로서 폐닐에칠아민과 하이아민베이스의 비교(比較))

  • Chiang, Yun-Hwan
    • Applied Biological Chemistry
    • /
    • v.14 no.1
    • /
    • pp.51-57
    • /
    • 1971
  • In order to compare their absorption abilities of carbon dioxide, Hyamine base and phenyl ethylamine were employed in wet combustion experiments. The known content of liver lipid and uniformly mixed palmitic $acid-C^{14}$ were oxidized with sulfuric acid and phosphoric acid. Carbon dioxide produced was trapped by the amines tested through thin tube. The amines absorbed carbon dioxide were mixed with diotal scintillator and counted by liquid scintillation counter. The counting efficiencies and radioactivity recoveries were 50 to 60 % and nearly 100 % for both amines. However, the absorption ability of carbon dioxide by phenyl ethylamine was about two times that of Hyamine base. This technique would not be necessary for the counting of liver lipid of swim, because the efficiencies were not increased and counting accuracies were similar to those of direct counting.

  • PDF

Dyeability and Functionality of Pine Needles Extract (part I) -Characteristics of Pine Needles Extract and Dyeing Properties of Cellulose Fiber- (솔잎 추출물의 염색성과 기능성 (제1보) -솔잎 추출물의 특성과 셀룰로오스섬유에 대한 염색성-)

  • Woo, Hyo-Jung;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.35 no.2
    • /
    • pp.218-229
    • /
    • 2011
  • Dyeing properties of cotton and ramie fabrics with pine needles colorants were studied by investigating the analysis of pine needles colorants, the effect of dyeing conditions (such as dye concentration, dyeing temperatures and times on dye uptakes), effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use; in addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of the maximum absorption for pine needles extract was 285nm, and pine needles colorants produced a yellow color. From FT-IR and GC-MS results, it was assumed that chromophoric substance from pine needles extracts were mixed with flavonol tannin and flavanol tannin. An increased dyeing concentration resulted in a larger dye uptake and a Freundlich absorption isotherm was obtained. A larger dye uptake occurred as the dyeing time and temperature increased. Post-mordanting was more effective than pre-mordanting and the dye uptake of fabrics improved by mordanting. The colorfastness of dyed fabrics showed a low rating; however, colorfastness to washing and dry cleaning of cotton fabrics mordanted with N.Cu, and friction fastness of ramie fabric mordanted with Cu improved. The dyed fabrics showed very good antimicrobial abilities of 99.9%. In addition, the ultraviolet-cut ability and deodorant ability improved in fabrics dyed with pine needles extracts.

Dyeability and Functionality of Bamboo Extracts (Part I) -Characteristics of Bamboo Extracts and Dyeing Properties of Cotton- (대나무 추출물의 염색성과 기능성 (제1보) -대나무 추출물의 특성과 면직물에 대한 염색성-)

  • Jung, Go-Eun;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.35 no.2
    • /
    • pp.206-217
    • /
    • 2011
  • The dyeing properties of cotton fabrics with bamboo colorants were studied by investigating the analysis of bamboo colorants, the effect of dyeing conditions (dye concentrations, dyeing temperatures and times on dye uptakes), effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use; in addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were also estimated. In the UV-Visible spectrum, the wavelength of the maximum absorption for bamboo stems and leaves extracts was found to be 280nm and 295nm, respectively; in addition, bamboo colorants produced a yellow color. From the FT-IR and GC-MS results, it was assumed that the chromophoric substance from bamboo extracts was composed of flavones substances with tricin. An increased dyeing concentration resulted in a larger dye uptake and a Freundlich absorption isotherm was obtained. A larger dye uptake occurred as the dyeing time and temperature increased. The post-mordanting was more effective than pre-mordanting. Mordants, Fe and N.Fe, were effective for an increased dye uptake. The color of fabrics mordanted with Cu and N.Cu changed to GY. Regardless of mordanting, the colorfastness on the washing of dyed fabrics showed a low rating compared to other fastness. Mordanting adversely affected the lightfastness of dyed fabric. The dyed fabric showed very good antimicrobial abilities of 99.9%. In addition, the ultraviolet-cut ability and deodorant ability improved in cotton fabric dyed with bamboo extracts.

Dyeability and Functionality of Pine Needles Extract (Part II) -Dyeing Properties of Protein Fiber- (솔잎 추출물의 염색성과 기능성 (제2보) -단백질섬유에 대한 염색성-)

  • Woo, Hyo-Jung;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.35 no.4
    • /
    • pp.466-475
    • /
    • 2011
  • The dyeing properties of protein fiber with pine needles colorants were studied through an investigation of the effect of dyeing conditions such as dye concentration, dyeing temperatures and time on dye uptakes, effect of mordants, and color change. In addition, the various colorfastness of dyed silk and wool fabrics were evaluated for practical use. The antimicrobial ability, ultraviolet-cut ability, and deodorant ability were also estimated. The dye uptake increased as the dyeing concentration increased and this enabled the obtainment of the Langmuir absorption isotherm. The dye uptake increased as the dyeing time and temperature increased. Pine needles colorants showed relatively good affinity to protein fiber and produced a yellow color. Post-mordanting was more effective than the pre-mordanting, and the dye uptake of fabrics improved by mordanting. Except for washing, the colorfastness of dyed fabrics showed a low rating. However, the colorfastness to light and the dry cleaning of fabrics mordanted with N.Cu, and the friction fastness of fabrics mordanted with Cu improved. The guide fabrics showed very good antimicrobial abilities of 99.9%; in addition, the ultraviolet-cut ability and deodorant ability improved in fabrics dyed with pine needles extracts.

Photocatalytic Behaviors of Transition Metal Ions Doped TiO2 Synthesized by Mechanical Alloying (기계적 합금화법을 이용한 전이금속 도핑에 따른 TiO2분말의 광촉매 특성)

  • Woo S.H.;Kim W.W.;Kim S.J.;Rhee C.K.
    • Journal of Powder Materials
    • /
    • v.12 no.4 s.51
    • /
    • pp.266-272
    • /
    • 2005
  • Transition metal ions($Ni^{2+}$, $Cr^{3+}$ and $V^{5+}$) doped $TiO_2$ nanostructured powders were synthesized by mechanical alloying(MA) to shift the adsorption threshold into the visible light region. The synthesized powders were characterized by XRD, SEM, TEM and BET for structural analysis, UV-Vis and photoluminescence spectrum for the optical study. Also, photocatalytic abilities were evaluated by decomposition of 4-chlorophenol(4CP) under ultraviolet and visible light irradiations. Optical studies showed that the absorption wavelength of transition metal ions doped $TiO_2$ powders moved to visible light range, which was believed to be induced by the energy level change due to the doping. Among the prepared $TiO_2$ powders, $NiO^{2+}$ doped $TiO_2$ powders, showed excellent photooxidative ability in 4CP decomposition.

A Study on the Effect of the Rhizobacterium, Bacillus sp. SH1RP8 and Potassium Family Polymers on the Crop Growth under Saline (염 환경 하에서 Bacillus sp. SH1RP8와 Polyacrylate Polymers가 작물 생장에 미치는 영향에 관한 연구)

  • Hong, Sun Hwa;Kim, Ji Seul;Park, Jang Woo;Lee, Eun Young
    • KSBB Journal
    • /
    • v.30 no.3
    • /
    • pp.97-102
    • /
    • 2015
  • This study aimed to evaluate the potential plantgrowth promoting effects of potassium polyacrylate, a superabsorbent polymer, and Bacillus sp. SH1RP8, a family of plant-growth-promoting bacteria. Potassium polyacrylate was selected as the polymer for use due to its high molecular weight and its ability to retain and continuously supply moisture. Plant-growth-promoting rhizobacteria (PGPR) were isolated from the soil and applied to plants growing in dry environments, such as saline conditions. The moisture absorption and retention abilities of potassium polyacrylate were evaluated at a high temperature ($50^{\circ}C$) and in a dry condition, during which time the polymer showed a water retention potential of 19606.07% after 29 days. To overcome the reaming problem in the soil environment, natural polymers (such as cellulose) were mixed with the potassium acrylate. The shoot growths of Peucedanum japonicum Thunb and Arundo donax were significantly enhanced when treated with the mixture of the isolated rhizosphere bacterium SH1RP8 and potassium polyacrylate (63.5 and 124.3%, respectively).

Preparation and Photocatalytic Effect of Brookite Phase TiO2 Colloidal Sol for Thin Film Coating (Brookite TiO2 코팅용 졸의 제조 및 광촉매 효과)

  • Kim, Sun-Jae;Lee, Nam-Hee;Lee, Kang;Choi, Chang-Joo
    • Journal of the Korean Ceramic Society
    • /
    • v.42 no.7 s.278
    • /
    • pp.461-468
    • /
    • 2005
  • Transparent TiO$_{2}$ sols were prepared by hydrothermal synthesis to heat Ti precursor solutions, from Ti hydroxides obtained with neutralizing aqueous TiOCl$_{2}$ solutions having various concentrations of NaCI by aqueous NaOH solution, in the autoclave at 120$^{\circ}C$ The photocatalytic abilities of glass beads coated with the sol for gaseous benzene were evaluated. As a result, it was found that due to the increase of brookite phase in TiO$_{2}$ by controlling the concentration of Na ion the optical absorption of TiO$_{2}$ increases toward long wavelength but that in the area of short wavelength becomes relatively low and consequently the photocatalytic performance of TiO$_{2}$ thin film for benzene gas rather decreases, compared to that of composite film of anatase and brookite phases. These results suggest that in order for coated TiO$_{2}$ thin film to have high dissociation performance for benzene gas it is effective to form anatase and brookite phases compositely in TiO$_{2}$.

Dyeability and Functionality of Chaenomelis Fructus Extract (모과 추출물의 염색성과 기능성)

  • Nam, Ki-Yeon;Lee, Jung-Soon
    • Fashion & Textile Research Journal
    • /
    • v.14 no.3
    • /
    • pp.478-485
    • /
    • 2012
  • The dying properties of fabrics with Chaenomelis Fructus extract were studied through an investigation of the characteristic of Chaenomelis Fructus colorants, the effect of dyeing conditions (dye temperature, dyeing concentration, and times on dye uptakes), effect of mordant, effect of UV irradiation, and color change in addition, antimicrobial ability and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of maximum absorption of Chaenomelis Fructus extract was 280 nm and showed that tannin is the major pigment component. From the increase of absorbance by UV irradiation, it was assumed that catechol tannin color was developed through UV irradiation. An increased dyeing concentration resulted in a larger dye uptake. Dye uptake increased as the dyeing time and temperature increased. Chaenomelis Fructus extract showed relatively good affinity to silk than cotton. Mordant, Fe and Cu were effective to increase the dye uptake of cotton fabric in addition, the dye uptake of silk fabric mordanted with Fe and K improved. UV irradiation let the color of dyed fabrics develop regardless of the UV irradiation stage however, UV irradiation on the dyed fabric was more effective than on the extract for the color development. Dyed silk fabric showed very good antimicrobial abilities of 99.9% in addition, deodorant ability improved in the fabric dyed with Chaenomelis Fructus extract.

Synthesis of Bi2WO6 Nanometer Sheet Shaped and Approach to the Photocatalysis

  • Kim, Dong-Young;Kim, Su-Jung;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.3
    • /
    • pp.630-635
    • /
    • 2009
  • For use as a photocatalyst, bismuth tungsten oxide, $Bi_2WO_6$, was successfully synthesized by hydrothermal treatment at pH = 11 and heating at 200 ${^{\circ}C}$ for 24h, and samples were subsequently thermal treated at 400, 600, and 800 ${^{\circ}C}$ to increase crystallinity. TEM results revealed that the initial untreated particles were sheet‐shaped, grain size was below 80 nm, and it increased with treated temperatures. These $Bi_2WO_6$ samples absorbed at around 400 nm in the visible light range and the intensity of absorption was particularly strongest in samples thermal treated at 600 ${^{\circ}C}$. Their photoluminescence abilities, related to the recombination between the excited electrons and holes, were overall small for other general photocatalysts such as TiO2, and the smallest in the case of thermal treatment at 600 ${^{\circ}C}$, as reversible result of UV‐visible absorbance. Methyl orange of 5.0 ppm aqueous solution was almost completely removed after 2 h when treated over the $Bi_2WO_6$ thermal treated at 600 ${^{\circ}C}$.

Mechanism of Metal Ion Binding to Chitosan in Solution. Cooperative Inter- and Intramolecular Chelations

  • Joon Woo Park;Myung Ok Park;Kwanghee Koh Park
    • Bulletin of the Korean Chemical Society
    • /
    • v.5 no.3
    • /
    • pp.108-112
    • /
    • 1984
  • Interactions between metal ions and chitosan in solution were studied by spectroscopic and viscometric measurements. $Cu^{++}$-chitosan complex exhibited an absorption band at 265 nm, whereas D-glucosamine complex showed one at 245 nm. The difference in ${\lambda}_{max}$ was attributed to the different amine to $Cu^{2+}$ ratios of the complexes, that is, 2 : 1 for chitosan and 1 : 1 for D-glucosamine. The molar absorptivities and binding constants of the complexes were evaluatatled. The binding of $Cu^{2+}$ to chitosan was cooperative near pH 5, and both intra- and intermolecular chelations depending on chitosan and $Cu^{2+}$concentrations were observed, The intermolecular chelation was stabilized by addition of salts. The cooperative intermolecular chelation of $Ni^{++}$ was also observed at pH 6.2. No significant binding of other divalent ions was observed. The reported high adsorption abilities of chitosan particles for these ions were attributed to the deposition of metal hydroxide aggregates in pores of chitosan particles rather than chelation to amine groups.