• Title/Summary/Keyword: abs

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Surface Modification by Atmospheric Pressure DBDs Plasma: Application to Electroless Ni Plating on ABS Plates

  • Song, Hoshik;Choi, Jin Moon;Kim, Tae Wan
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.3
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    • pp.133-138
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    • 2013
  • Acrylonitrile-butadiene-styrene (ABS) plastic is a polymer material extensively used in electrical and electronic applications. Nickel (Ni) thin film was deposited on ABS by electroless plating, after its surface was treated and modified with atmospheric plasma generated by means of dielectric barrier discharges (DBDs) in air. The method in this study was developed as a pre-treatment for electroless plating using DBDs, and is a dry process featuring fewer processing steps and more environmentally friendliness than the chemical method. After ABS surfaces were modified, surface morphologies were observed using a scanning electron microscope (SEM) to check for any physical changes of the surfaces. Cross-sectional SEM images were taken to observe the binding characteristics between metallic films and ABS after metal plating. According to the SEM images, the depths of ABS by plasma are shallow compared to those modified by chemically treatment. The static contact angles were measured with deionized (DI) water droplets on the modified surfaces in order to observe for any changes in chemical activities and wettability. The surfaces modified by plasma showed smaller contact angles, and their modified states lasted longer than those modified by chemical etching. Adhesion strengths were measured using 3M tape (3M 810D standard) and by 90° peel-off tests. The peel-off test revealed the stronger adhesion of the Ni films on the plasma-modified surfaces than on the chemically modified surfaces. Thermal shock test was performed by changing the temperature drastically to see if any detachment of Ni film from ABS would occur due to the differences in thermal expansion coefficients between them. Only for the plasma-treated samples showed no separation of the Ni films from the ABS surfaces in tests. The adhesion strengths of metallic films on the ABS processed by the method developed in this study are better than those of the chemically processed films.

Effects of Compatibilizer on Mechanical, Morphological, and Rheological Properties of Polypropylene/Poly(acrylonitrile-butadiene-styrene) Blends

  • Kum, Chong-K.;Sung, Yu-Taek;Kim, Yong-Su;Lee, Hyung-Gon;Kim, Woo-Nyon;Lee, Heon-Sang;Yoon, Ho-Gyu
    • Macromolecular Research
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    • v.15 no.4
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    • pp.308-314
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    • 2007
  • The effects of a compatibilizer on polypropylene (PP)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were studied. Blends of the PP/ABS, with PP-g-SAN copolymer as a compatibilizer, were prepared using a twin screw extruder. The flexural and impact strength of the PP/ABS blends with the PP-g-SAN copolymer increased significantly with PP-rich compositions on the addition of the PP-g-SAN copolymer at 3 phr. The increase in the mechanical properties of the PP/ABS/PP-g-SAN blend may have been due to the toughening effects of the ABS in the PP-rich compositions. In the morphology study of the PP/ABS/PP-g-SAN (80/20) blend with the PP-g-SAN copolymer, the minimum droplet size, $5.1{\mu}m$, was observed with the addition on phr of the PP-g-SAN copolymer. The complex viscosity of the PP/ABS/PP-g-SAN (80/20) blends increased with the addition of3 phr of the PP-g-SAN copolymer. From the above mechanical properties, morphology and complex viscosity results for the PP/ABS blends, it is suggested that the compatibility is more increased with the PP-rich composition (PP:ABS=80/20 wt%) of the PP/ABS blend on the addition of 3 phr of the PP-g-SAN copolymer.

Effects of PE (Polyethylene) and GF (Glass Fiber) Addition on Tensile Strength and Elongation of ABS (Acrylonitrile Butadiene Styrene) Recovered from Waste LCDs (폐(廢)LCD에서 회수(回收)된 ABS(Acrylonitrile Butadiene Styrene)의 인장강도(引張强度)와 연신율(延伸率)에 미치는 PE(Polyethylene)와 유리섬유(纖維)(Glass Fiber) 첨가효과(添加效果))

  • Lee, Sungkyu;Cho, Sung-Su;Lee, Soo-Young;Park, Jae Layng;Hong, Myung Hwan;Hong, Hyun Seon
    • Resources Recycling
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    • v.22 no.3
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    • pp.50-56
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    • 2013
  • Recycled plastic composites of ABS/PE (50/50 and 20/80) and ABS/GF (90/10) were fabricated from plastic components of waste LCDs and effects of PE composition on elongation of ABS/PE composites were investigated. Increased PE contents improved elongation of the composite from 2.4% to 13%, which was attributed to increased crystalline behavior of the ABS/PE composite afforded by ductile PE fraction: SEM fractographs showed some sign of plastic deformation of PE matrix before ductile fracture of the composites.

Development of Triboelectrostatic Separation Technique for Material Separation of ABS and PS Mixed Plastic Waste (ABS와 PS 혼합(混合) 폐플라스틱 재질분리(材質分利)를 위한 마찰하전형정전선별(摩擦荷電型靜電選別) 기술개발(技術開發))

  • Lee, Eun-Seon;Baek, Sang-Ho;Kim, Su-Kang;Choi, Woo-Zin;Chin, Ho-Ill;Jeon, Ho-Seok
    • Resources Recycling
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    • v.22 no.6
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    • pp.33-40
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    • 2013
  • Due to the environmental problem caused by plastics largely used in various fields, the importance of recycling is being emphasized. A research on material separation of ABS and PS mixed plastic waste, using a triboelectrostatic separator, was carried out for recovery the ABS. As a results of research on charging characteristic for choosing charging material, it was confirmed that ABS was optimum charging material for a tribo-charger in the material separation of ABS and PS. In the material separation using ABS charger, ABS grade of 99.5% and recovery of 92.5% were achieved at 20 kV, splitter position +2 cm from the center and 30% relative humidity. Therefore, material separation technique for recycling ABS and PS mixed plastic waste was established.

Design of an Interface System IC for Automobile ABS/TCS (자동차용 ABS/TCS 인터페이스 시스템 IC의 설계)

  • Lee, Sung-Pil;Kim, Chan
    • Journal of the Institute of Convergence Signal Processing
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    • v.7 no.4
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    • pp.195-200
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    • 2006
  • The conventional discrete circuit for ABS/TCS system was examined and the problems of the system were analyzed by computer simulation. In order to improve the performance of ABS/TCS system, interface IC which has error compensation, comparator and under voltage lock-out circuit was designed and their electrical characteristics were investigated. The voltage regulator was included to compensate the temperature variation in the temperature range from $-20^{\circ}C$ to $120^{\circ}C$ for automobile environment. ABS and brake signal were separated using the duty factor of same frequency or different frequencies. UVLO(Under Voltage Lock-Out) circuit and constant current circuit were applied for the elimination of noise, and protection circuit was applied to cut the excess current off. Layout for IC fabrication was designed to enhance the electrical performance of ABS/TCS system. Layout was consisted of 11 masks, arrayed effectively 8 pads to reduce the current loss. We can see that the result of layout simulation was better than the result of bread board.

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Reflectance and Flexural Modulus of ABS/TiO2 Composite Sheets (ABS/TiO2 복합체 쉬트의 반사율과 굴곡 탄성률)

  • Kim, Jun Hong;Yoon, Kwan Han
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.103-107
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    • 2014
  • Poly(acrylonitrile-butadiene-styrene) (ABS) composite sheets containing titanium dioxide ($TiO_2$), barium sulfate ($BaSO_4$), calcium carbonate ($CaCO_3$) were prepared by using a co-rotating twin screw extruder, and the reflectance and flexural modulus of the composite sheets were measured. The fillers were well dispersed in ABS matrix. The reflectance of composite sheet was increased with increasing $TiO_2$ and $BaSO_4$ content. Sheet having $TiO_2$ 20 wt% composition, with 5~20 wt% $BaSO_4$ resulted in more than 95% of reflectance. The flexural modulus of composite sheet was increased from 1864 MPa for $ABS/TiO_2/BaSO_4$ 85/10/5 (w/w/w) to 3134 MPa for $ABS/TiO_2/BaSO_4$ 55/20/25 (w/w/w).

Microbial Degradation of Anionic Synthetic Detergents (음이온계 합성세제의 미생물분해)

  • 김영배;이수래
    • Microbiology and Biotechnology Letters
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    • v.4 no.3
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    • pp.117-121
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    • 1976
  • A microbial strain capable of degrading ABS (alkyl benzene sulfonate) was isolated and identified as Pseudomonas caryophylli. During the incubation of the isolated bacterium in a synthetic effluent containing 10 ppm of ABS, the extents of removal of ABS, BOD and COD were 40%, 89% and 71%, respectively. The degradability of ABS by pure culture with the isolated strain was twice higher than that of mixed culture with natural microflora. The biodegradability of some commercial detergents in Korea by the isolated organism was as follows: Hiti 46.2%, Kleenup 37.5%, No.1 29%, and OK 27.9%.

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Studies on the Properties of ABS/AES Blonds (ABS/AES 블렌드의 물성에 관한 연구)

  • Kang, Dong-Il;Ha, Chang-Sik;Cho, Won-Jei
    • Elastomers and Composites
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    • v.27 no.1
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    • pp.13-19
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    • 1992
  • In this work, properties of ABS/AES blends were investigated. Blends were prepared by casting from THF. The thermal stability, light resistance, storage modulus and flame retardancy were measured by thermogravimetric analysis, cole. difference in Fade-o-meter, Rheovibron, and limiting oxygen index(LOI). The thermal stability, light resistance and storage modulus increased with increasing contents of AES. ABS and AES showed similar LOI. The LOI of the ABS/AES blends increased with rising contents of AES but all the blends were found to be flammable. It was observed that ABS and AES was incompatible from the morphology by scanning electron microscope(SEM).

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Synthesis of Flame Retardants for ABS using Cyclophosphazene (Cyclophosphazene을 이용한 ABS용 난연제의 합성)

  • Shin, Young-Jae;Kim, Hae-Young;Shin, Jae-Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.2
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    • pp.142-151
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    • 2007
  • Non-halogen flame retardant have been focus of extensive research because of environmental problem. Hexakisphenokycyclotriphosphazene was synthesized in order to use as the flame retardant of ABS resin. And using bisphenol A, bisphenol S, and resorcinol, the polymers which contained cyclophosphazene structure were synthesized in order to also use as the flame retardants of ABS resin. All of the synthesized polymers themselves got the excellent flame retardancy. And as the molecular weight of the compound were increased, the thermal stability was increased. But when the synthesized compounds were used as the flame retardants for ABS resin, the lower molecular weight compound in these compounds showed the better flame retardancy and the better physical properties of ABS resin. In case of using resorcinol, it showed the best flame retardancy.

A Study on the Effect of Various Brominated Flame Retardants and the Compatibilities Between Polymer and Flame Retardants in PC/ABS Blend System (PC/ABS 블랜드의 난연화 및 상용성에 관한 연구)

  • 이영순;전종한
    • Journal of the Korean Society of Safety
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    • v.5 no.3
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    • pp.63-68
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    • 1990
  • The effects of various brominated flame retardants were investigated in PC/ABS blend system. The compatibilities between polymers and flame retardants were expected with the solubility parameter using group contribution theory. Tetrabromobisphenol A carbonate oligomer, among the flame retardants in this experiment, has been shown good miscibility for PC and ABS, respectively. But polydibromophenylene oxide and octabromodiphenyl oxide has immiscibility. The flame retardant PC/ABS blends containning tetrabromobisphenol A carbonate oligomer have been exhibited higher mechanical properties, tensile strengths and notch Izod impact strengths, at varlous content of flame retardants, than containning other flame retardants. It could be seen that the trends of mechanical properties for the flame retardant PC/ABS blends have a good concidence with the expectation of compatibility.

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