• Applied Chemistry for Engineering
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• v.8 no.2
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• pp.161-171
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• 1997

Anodic regeneration of PCB enchant and cathodic deposition of copper using electrochemical method has been studied. Cu(I)/Cu(II) concentration ratio as a function of Cu(I) oxidation at the anode was measured from the potential difference between platinum and Ag/AgCl/4M KCl electrodes. Chlorine gas evolution was minimized by maintaining Cu(I) concentration above a specific concentration and using non-porous graphite electrode. Dendritic copper deposition was observed at the cathode and the optimum conditions for Cu deposition was identified as the current density of $360mA/cm^2$, and copper concentration of 12 g/l. Titanium was the most effective cathode material which showed a higher current efficiency and copper recovery. The current efficiency decreased with increasing temperature, but the highest power efficiency was achieved at $50^{\circ}C$.

• 보존과학연구
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• s.27
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• pp.165-180
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• 2006

The research was conducted to understand type of iron used by those who lived at dwelling site of Yangsoo-ri in between the first century B.C. and the first century A.D. to make steel products and their technique such as steel making process and heat treatment, based on micro structure information obtained through microscopic metallographic structure analysis with SEM-EDS of six steel productsexhumed at the site. Key findings are summarized as below. In the sense that Si-Ca-Al style and less than 0.5% of Ti were found in the non-metallic inclusion, the material used for forged iron ware was magnetite resolved in that. It is, however, unclear whether magnetite was resolved at high temperature or at low temperature. Microscopic structure analysis revealed that forged steel products were made through repeated hot working, the technique of molding by hitting after heating in the process of resolving and molding iron. As a result, the iron used here for the products was not the iron ore which was produced through resolution from discarded cast iron axe, ingot iron. It is probable that to make those steel products, disposed-of cast iron was reused after being molded by decarburizing. Although a few of relics were analyzed for the research, they were of critical importance in defining the process of ironware production from the first century B.C. and the first century A.D. at the Yangsoo-ri region. Judging from the iron from A-19 dwellingsite, it is possible to conclude that the iron was manufactured from cast iron decarburized and yet more research has to be done into relics yetto be exhumed in order to ascertain the finding. All of these findings are believed to play a critical role in further studies to define the steel-manufacturing technique used on the central Korean peninsular in the ancient times.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.108.1-108.1
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• 2010

분류층 가스화기는 석탄과 산소(공기) 및 수증기가 반응하여 $1200{\sim}1600^{\circ}C$의 고온, 20~60기압의 고압에서 작동되어 합성가스를 생성하며 합성가스에 포함된 입자 및 황화합물 등을 정제설비를 통하여 정제 후 발전 및 화학원료로 사용한다. 석탄가스화 중 석탄에 포함된 대부분의 회분은 용융슬래그 형태로 가스화기 벽면을 따라 흘러 내려 가스화기 하부의 냉각수조에서 급랭되어 배출된다. 이때 용융슬래그의 원활한 배출을 위해서는 일정범위의 점도를 유지하는 것이 필요하다. 슬래그의 점도는 가스화기 온도 및 Ash의 조성에 따라 크게 변하며 가스화기 설계 및 운전 시 매우 중요한 변수이다. 따라서 최적의 설계 및 운전을 위해서는 Ash의 점도예측이 중요하며, 분류층 가스화기내부에서 Ash 점도 예측을 위한 DooVisco 프로그램을 개발하였다. DooVisco는 가스화기 내부에서 슬래그 용융온도 및 온도별 점도, 가스화기 최소 운전온도 및 석회석 투입 효과 분석뿐만 아니라 석탄의 혼합 사용 시의 특성 예측도 가능하도록 개발되었다. DooVisco는 슬래그 주요 4성분인 SiO2, Al2O3, CaO, FeO 성분에 대한 Phase Diagram을 이용하여 1차적으로 슬래그용융온도(Liquidus Temperature)를 예측하고, 주요 4 성분 외에 Na2O, MgO, K2O, TiO2 등을 고려한 Kalmanovich Model을 이용하여 점도를 예측한다. 최종적으로 슬래그 용융온도와 점도를 활용하여 분류층 가스화기 운전가능 온도범위를 예측한다. 개발된 DooVisco를 활용하여 300MW급 실증 IGCC 플랜트에 사용가능성이 있는 석탄을 대상으로 슬래그의 용융온도 및 점도 등을 예측하였으며 최적 운전을 위한 슬form점도 조절용 Flux인 석회석 투입량 등을 평가하였다. 평가 결과 슬래그 용융온도가 $1700^{\circ}C$ 이상으로 석회석 투입이 필요하다고 판단되었다. 약 가스화기 내부 온도를 $1500^{\circ}C$ 정도에서 원활한 운전을 위해서는 석탄 대비 약 10% 내외의 석회석 투입이 필요할 것으로 평가되었다. DooVisco는 분류층 가스화기 설 계시 가스화기 최적 운전 온도 설정 및 Flux 투입필요성, 종류, 투입량 선정에 활용될 수 있을 뿐만 아니라 플랜트 운전시 석탄의 탄종 적합성 등을 판단하는데 활용될 수 있을 것이라 판단된다.

• Journal of the Korea Society of Computer and Information
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• v.10 no.5 s.37
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• pp.313-322
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• 2005

In this paper, we implement and verify performance monitor for parallel signal processing system, using DSP Starter Kit(DSK) of which the basic Processor is TMS302C6711 chip. The key ideas of this performance monitor is, using Real Time Data Exchange(RTDX) for the Purpose of real-time data transfer and function of DSP/BIOS, the ability to measure the Performance measure like DSP workload, memory usage, and bridge traffic. In the simulation, FFT, 2D FFT, Matrix Multiplication, and Fir Filter, which are widely used DSP algorithms, have been employed. Using performance monitor and Code Composer Studio from Texas Instrument(Tl) , the result has been recorded according to different frequencies, data sizes, and buffer sizes for a single wave file. The accuracy of our performance monitor has been verified by comparing those recorded results.

• KIEE International Transactions on Electrophysics and Applications
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• v.5C no.3
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• pp.102-110
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• 2005

Piezoelectric transformers(PT) are expected to be small, thin and highly efficient, and which are attractive as a transformer with high power density for step down voltage. For these reasons, we have attempted to develop a step-down PT for the miniaturized adaptor. We propose a PT, operating in thickness extensional vibration mode for step-down voltage. This PT consists of a multi-layered construction in the thickness direction. In order to develop the step-down PT of 10 W class and turn ratio of 0.1 with high efficiency and miniaturization, the piezoelectric ceramics and PT designs are estimated with a variety of characteristics. The basic composition of piezoelectric ceramics consists of ternary yPb(Zr$_{x}$Ti$_{1-x}$)O$_{3}$-(1-y)Pb(Mn$_{1/3}$Nb1$_{1/3}$Sb$_{1/3}$)O$_{3}$. In the piezoelectric characteristics evaluations, at y=0.95 and x=0.505, the electromechanical coupling factor(K$_{p}$) is 58$\%$, piezoelectric strain constant(d$_{33}$) is 270 pC/N, mechanical quality factor(Qr$_{m}$) is 1520, permittivity($\varepsilon$/ 0) is 1500, and Curie temperature is 350 $^{\circ}C$. At y = 0.90 and x = 0.500, kp is 56$\%$, d33 is 250 pC/N, Q$_{m}$ is 1820, $\varepsilon$$_{33}$$^{T}$/$\varepsilon$$_{0}$ is 1120, and Curie temperature is 290 $^{\circ}C$. It shows the excellent properties at morphotropic phase boundary regions. PZT-PMNS ceramic may be available for high power piezoelectric devices such as PTs. The design of step-down PTs for adaptor proposes a multi-layer structure to overcome some structural defects of conventional PTs. In order to design PTs and analyze their performances, the finite element analysis and equivalent circuit analysis method are applied. The maximum peak of gain G as a first mode for thickness extensional vibration occurs near 0.85 MHz at load resistance of 10 .The peak of second mode at 1.7 MHz is 0.12 and the efficiency is 92$\%$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.6
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• pp.252-256
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• 2015

Nitrogen oxides ($NO_X$) was emitted from flue gas of stationary sources and exhaust gas of mobile sources, can leads to various environments problems. Selective Catalysts Reduction (SCR) is the most effective $NO_X$ removal system. Commercial $V_2O_5-WO_3/TiO_2$ catalysts, usually containing $V_2O_5$ 0.5~3 wt%, $WO_3$ 5~10 wt%, and $V_2O_5$ is active in the reduction of $NO_X$ but also in the desired oxidation of $SO_2$ to $SO_3$. To reduce the amount of vanadium, using graphene matrix supported vanadium to synthesize nanocomposite. Then, we fabricated to 1 inch honeycomb type of SCR catalysts adding graphene-vanadium nanocomposite. The chemical-physical characteristics and the catalytic activity were performed by XRD, XRF, BET and Micro-Reactor (MR). As a result, the De-NOX performance was showed, similar to the commercial catalyst activity as 77.8 % and using nanocomposite catalyst as 77.1 % at $350^{\circ}C$.

• Journal of Sensor Science and Technology
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• v.10 no.6
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• pp.295-303
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• 2001

White emission thin film electroluminecent device was fabricated with ZnS for phosphor layers and BST ferroelectric thin film for insulating layers. The ZnS:Mn and $ZnS:SmF_3$ layers were used for emission of red color. Also the $ZnS:TbF_3$ and $ZnS:AgF_3$ layers were used to emission of green and blue color, respectively. And the fabrication conditions of the BST insulating layers were followings, that is, the composition ratio of target, substrate temperature, working pressure and operating gas ratio were $Ba_{0.5}Sr_{0.5}Ti_{0.3}$, $400^{\circ}C$, 30 mTorr and 9:1, respectively. The thickness of phosphor were 150 nm for each layers and the insulating layers of upper and bottom were 400 nm and 200 nm, respectively. The luminesence threshold voltage was $75\;V_{rms}$ and the maximum brightness of the thin film electroluminecent device was $3200\;cd/m^2$ at $100\;V_{rms}$.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.21 no.1
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• pp.27-34
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• 2015

Heating patterns depending on the packaging materials were examined in order to investigate the causes of thermal deformation of packages used for ready-to-eat foods for microwave heating due to the non-uniformity of microwaves. Physical properties including tensile strength, heat-resistance and elongation of four different CPP grades were compared. High retortable CPP had higher sealing strength and heat resistance compared to the conventional CPPs. All CPP samples tested were proved to have melting temperatures around $160^{\circ}C$. However, they were all thermally deformed by microwave heating due to a limited penetration of microwave and non-uniform heating within the spicy sauce of high viscosity contained high salt, especially on the above the filling line and sealing edge of pouches. When the laminated stand-up pouches composed of G-PET/PET/PET/CPP and G-PET/PET/NY/CPP were retorted and microwaved, significant deformations were noticed in both samples after retorting. Besides, pouches contained titanium dioxide showed more intense thermal deformation than the control. When the $10{\mu}m$ aluminium foil was affixed on the pouch, small thermal deformation was observed only in the bottom layer. More studies are required to prevent the thermal deformation of packaging materials used for RTE foods during microwave heating by developing the technologies to increase the thermal stability of CPP layer and the modification of packaging design to modify the microwave access into the package.

• Journal of Sensor Science and Technology
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• v.6 no.4
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• pp.265-273
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• 1997

The TMA gas sensors are fabricated with the ZnO-based thin films grown by a RF magnetron sputtering method. We investigate the surface carrier concentration, Hall electron mobility, electrical resistivity and sensitivity according to temperature variation and TMA gas concentration. The ZnO-based thin film sensors prepared by sputtering in oxygen showed higher surface carrier concentration, higher Hall mobility, higher sensitivity, and lower electrical resistivity than sensors prepared by sputtering in argon. The doping ZnO-based thin film sensors showed the same electrical properties in comparison with nondoping sensors. In case of sputtering on the oxygen gaseous atmosphere, the ZnO-based thin film sensors doped with 4.0 wt.% $Al_{2}O_{3}$, 1.0 wt.% $TiO_{2}$, and 0.2 wt.% $V_{2}O_{3}$ showed the highest surface carrier concentration of $5.95{\times}10^{20}cm^{-3}$, Hall electron mobility of $177\;cm^{2}/V{\cdot}s$, lowest electrical resistivity of $0.59{\times}10^{-4}{\Omega}{\cdot}cm$ and highest sensitivity of 12.1(working temperature, $300^{\circ}C$, TMA gas, 8 ppm).

• Journal of the Korean Vacuum Society
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• v.20 no.3
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• pp.205-210
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• 2011

Structural and electrochemical properties of spinel oxide $LiMn_2O_4$ thin films prepared by using a sol-gel method on Pt/Ti/$SiO_2$/Si substrates were investigated. When Li/Mn molar ratio of the film was smaller than 0.5, $Mn_2O_3$hase was found to coexist with $LiMn_2O_4$. Half-cell batteries fabricated using the $LiMn_2O_4$ films as the cathode were put into chargedischarge (C-D) cycles and the change in structural properties of the cathode after the cycles was examined by X-ray diffraction and Raman spectroscopy. As the C-D cycle number increases, the discharge capacity of pure $LiMn_2O_4$ battery gradually decreases, being reduced to 72% of the initial capacity at 300 cycles. Such capacity fading is attributable to the decrease in the number of $Li^+$ ions that return to the tetrahedral sites of the spinel structure during the discharge step and the resultant increase in $Mn^{4+}$ density in the film. Also, $Mn_2O_3$ phase gradually appeared in the film as the cycle number increases.