• Title/Summary/Keyword: ZnS:Mn Mg

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Neutron Activation Analysis of Human Hair for Human Health Assessment (인체보건 환경평가를 위한 모발의 중성자방사화분석)

  • Chung, Young-Sam;Kang, Sang-Hoon;Moon, Jong-Hwa;Kang, Young Hwan;Cho, Seung-Yon
    • Analytical Science and Technology
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    • v.14 no.2
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    • pp.131-139
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    • 2001
  • There is personal difference in the concentrations of trace elements in human hair according to human life or history suck as occupation, race, sex, age, food habit, social condition and so on. It is also found that the individual's deviation of elemental concentrations is reflecting the degree of environmental pollutants exposure to human body, intakes of food and metabolism. To compare the degree of accumulation in the hair tissue, human hair samples were collected from five positions of head and analyzed by non-destructive neutron activation analysis with and without washing according to IAEA's recommended method. Analytical quality control is performed using the certified reference material. The relative error of Cu, Cr, Na, Co, Mg, As, Se, Zn and those of Mn, Ca, Fe, Sr are within ${\pm}5%$ and ${\pm}10%$, respectively and the relative standard deviation of elements are within ${\pm}10%$. The deviations between the individuals and hair sampling positions were estimated. The deviation of individual was seven times more than that of positions. Under the defined condition, the difference and the correlation of elemental concentrations were compared with two different groups, office and factory workers. The result can be used as a fundamental data for human health and environment assessment.

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Effect of Incorporation Rate of Polyacrylamide Hydrogel on Changes in Chemical Properties of Root Media (Polyacrylamide 고흡수성 수지의 혼합 비율이 상토의 화학성에 미치는 영향)

  • Wang, Hyun-Jin;Choi, Jong-Myung;Lee, Jong-Suk
    • Journal of Bio-Environment Control
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    • v.14 no.3
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    • pp.190-195
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    • 2005
  • This research was conducted to investigate the changes in soil chemical properties of root media as influenced by incorporation rate of a polyacryl amide hydrogel, Stocksorb C. The pH at 5 weeks after treatment in four root media such as peatmoss + vermiculite (1:1, v/v; PV), peatmoss + composted rice hull (1:1; PR), peatmoss + composted saw dust (1:1; PD) and peatmoss + composted pine bark (1:1; PB) containing STSB were in the range from 7.04 to 7.30, which was too high. Elevated incorporation rate of STSB resulted in increase of EC in soil solution of four root media with linear and quadratic response. The concentrations of $NH_4^+-N,\;NO_3^--N,\;PO_4-P^{3-},\;K^+,\;Ca^{2+}and\;Mg^{2+}$ in four kinds of root media increased as incorporation rates of STSB were elevated. But the $NO_3^-$-N concentrations in PS media were lower than those in other there root media tested. The Fe concentrations in PV, PR and PS media increased as incorporation rates of STSB were elevated, but those in PB medium did not show significant different. The concentrations of $Fe^{2+},\;Mn^{2+},\;Zn^{2+}and\;Cu^{2+}$ in PS media were higher than those in other three root media.

Investigation of Dynamic Elemental Distribution in Six Human Tissues by Neutron Activation Analysis (중성자방사화분석에 의한 인체 6개 조직 내 기능성원소 함량 분포 조사)

  • Kang, Sang-Hoon;Moon, Jong-Hwa;Chung, Yong-Sam;Cho, Seung-Yeon;Lee, Han-Young
    • Analytical Science and Technology
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    • v.15 no.4
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    • pp.365-372
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    • 2002
  • In this study, inorganic elemental distribution in Korean adult human tissue of liver, lung, muscle, kidney, rib and thyroid has been investigated. These tissues were collected from human's body within 48 hours after their death according to IAEA's recommended method, dried by freeze drying method and then pulverized. Neutron activation analysis was applied to these samples to determine the concentrations of 5 major elements of Ca, Mg, Na, K, and Cl and 12 trace elements of Mn, I, Sr, As, Br, Co, Cr, Cs, Fe, Rb, Se, and Zn. To confirm accuracy of analytical result was performed using three kinds of standard reference materials and resulted that the relative error is within 10% for the most of elements and the Z-score indicating a performance of analysis is within 2. The elemental distribution shows that the major elements are distributed homogeneously with a specific concentration and that the trace elements shows a distribution of different concentration with kinds of tissue and their age. Particularly, iodine shows higher concentration with 1000 ${\mu}g/g$ in thyroid, and calcium and strontium show the concentration with 15.9% and 84.4 ${\mu}g/g$ in rib, respectively.

Molecular cloning and characterization of β-mannanase B from Cellulosimicrobium sp. YB-43 (Cellulosimicrobium sp. YB-43의 mannanase B 유전자 클로닝과 특성 분석)

  • Yoon, Ki-Hong
    • Korean Journal of Microbiology
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    • v.52 no.3
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    • pp.336-343
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    • 2016
  • A mannanase gene was cloned into Escherichia coli from Cellulosimicrobium sp. YB-43, which had been found to produce two kinds of mannanase, and sequenced completely. This mannanase gene, designated manB, consisted of 1,284 nucleotides encoding a polypeptide of 427 amino acid residues. Based on the deduced amino acid sequence, the ManB was identified to be a modular enzyme including two carbohydrate binding domains besides the catalytic domain, which was highly homologous to mannanases belonging to the glycosyl hydrolase family 5. The N-terminal amino acid sequence of ManB, purified from a cell-free extract of the recombinant E. coli carrying a Cellulosimicrobium sp. YB-43 manB gene, has been determined as QGASAASDG, which was correctly corresponding to signal peptide predicted by SignalP4.1 server for Gram-negative bacteria. The purified ManB had a pH optimum for its activity at pH 6.5~7.0 and a temperature optimum at $55^{\circ}C$. The enzyme was active on locust bean gum (LBG), konjac and guar gum, while it did not exhibit activity towards carboxymethylcellulose, xylan, starch, and para-nitrophenyl-${\beta}$-mannopyranoside. The activity of enzyme was inhibited very slightly by $Mg^{2+}$, $K^+$, and $Na^+$, and significantly inhibited by $Cu^{2+}$, $Zn^{2+}$, $Mn^{2+}$, and SDS. The enzyme could hydrolyze mannooligosaccharides larger than mannobiose, which was the most predominant product resulting from the ManB hydrolysis for mannooligosaccharides and LBG.

Quantitative Analysis of X-Ray Fluorescence for Understanding the Effect of Elevated Temperatures on Cement Pastes (XRF (X-ray fluorescence)를 활용한 고온환경에 노출된 시멘트 페이스트 분석의 이해)

  • Kil-Song Jeon;Young-Sun Heo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.6
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    • pp.130-137
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    • 2023
  • By using XRF (X-ray fluorescence), this study investigates the variation of chemical properties in cement pastes at elevated temperatures. High-temperature conditions were prepared by using an electric furnace, planning a total of 11 target temperatures ranging from room temperature to 1000 ℃. A standard library of geo-quant basic was applied for the analysis of 12 elements in cement paste, including Ca, Si, Al, Fe, S, Mg, Ti, Sr, P, Mn, Zn and K. The results revealed that, as the temperature increased, the proportion of each element in the cement paste also increased. With the exception of a few elements present in extremely low amounts in the cement pastes, the variation in the composition ratio of most elements exhibited a strong correlation with temperature, with an R-squared value exceeding 0.98. In this study, cement pastes exposed to normal and high-temperature environments were compared. The authors established that the reasons for the different results in this comparison can be explained from the same perspective as when comparing raw cement with cement paste. Furthermore, this study discussed the potentially most dominant parameter when investigating the properties of cement paste using XRF.

Physicochemical Characteristics of Ethanol Extracts from Each Part of the Pleurotus eryngii (새송이버섯(Pleurotus eryngii) 부위별 추출물의 이화학적 특성)

  • Ahn, Myung-Soo;Kim, Hyun-Jeung;Seo, Mi-Sook
    • Journal of the Korean Society of Food Culture
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    • v.21 no.3
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    • pp.297-302
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    • 2006
  • This study has examined the physicochemical properties of the Pleurotus eryngii, including their proximate components, amount mineral content, total dietary fiber, total sugar, reducing sugar and free sugar. Additionally, it measured the P. egii ethanol extracts and the total amounts of polyphenol compounds as well as its electron donating ability (EDA) of the substance fraction (SF). The P. eryngii powder's moisture content was 9.0% and each of the other element content such as carbohydrate, crude protein, crude ash and crude fat was found to be 63.06%, 20.70%, 5.20% and 2.0% respectively. Potassium (K) was shown to be the greatest inorganic content and manganese (Mn) was the lowest. Furthermore fructose, galactose, glucose lactose and maltose free sugar content was found in this order. 387 mg% of the total amounts of polyphenol was found in the P. eryngii whole body ethanol extract, 158 mg% in the stipe extract, 593 mg% in the pileus extract and 607 mg% in the substance fraction (SF). Electron donating ability (EDA) was highest at 91.12% in the whole body extract and lowest at 62.90% in the stipe extract. Additionally, the EDA for substance fraction (SF) 0.02%-0.1% was found to be 57.78-77.33%, which was lower than the 0.02%-tocopherol (93.92%) and BHT (96.72%). From these results, it can be assumed that P. eryngii offers superior antioxidative effects with its high content of fiber, inorganic materials and total amounts of polyphenol as well as high electron donating ability (EDA), thereby making it ideal for use in functional foods and industrial materials.

Effect of pre-planting liming fertilization in peatmoss based substrates on plug seeding growth of 'Red Madness' petunia and changes in soil chemical properties (피트모스 혼합상토에 기비로 혼합된 석회질 비료가 'Red Madness' 페튜니아 플러그 묘 생장과 상토화학성에 미치는 영향)

  • Lee, Poong-Ok;Lee, Jong-Suk;Choi, Jong-Myung
    • Korean Journal of Agricultural Science
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    • v.38 no.1
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    • pp.17-23
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    • 2011
  • This research was conducted to investigate the influence of application rate of liming fertilizers on changes in soil chemical properties and growth of 'Red Madness' petunia in plug production. To achieve this, dolomite (DO) with 0, 1.0, 3.5, 8.0 or 13.0 $g{\cdot}L^{-1}$ and calcium carbonate (CC) with 0, 2.0, 2.5, 3.0, 3.5, or 4.0 $g{\cdot}L^{-1}$ were incorporated into peatmoss + vermiculite (1:1, v/v) during the root substrates formulation. The treatments of 3.5 $g{\cdot}L^{-1}$ of DO and 2.5 or 3.0 $gL^{-1}$ of CC had acceptable ranges of pH and EC in soil solution such as 5.6~6.2 and 0.7~1.0 $dS{\cdot}m^{-1}$, respectively. The faster rising of pH was observed in root media containing CC rather than those of DO. This indicates that the solubility of CC is higher than DO. The soil Ca concentrations in all treatments of CC were 1.8 times as high as those of DO. The treatments of 3.5 or 8.0 $g{\cdot}L^{-1}$ of DO had the highest soil Mg concentrations, but all treatments of CC had lower soil Mg concentrations than control treatment indicating that additional application of Mg fertilizers are required. The elevated application rate of DO or CC resulted in the increase of fresh and dry weight. But plant heights were not influenced by application of liming fertilizers. The results of tissue analysis showed that application of DO or CC influenced the $PO_4{^-}P$, Ca and Mg contents, but not influenced the contents of other nutrients such as N, P, Fe, Mn, Zn and Cu.

Studies on Constituents of the Higher Fungi of Korea (LV) -The Antitumor Components and Culture of Lyophyllum decastes- (한국산(韓國産) 고등(高等) 균류(菌類)의 성분(成分) 및 배양(培養)에 관한 연구(硏究)(제55보)(第55報) -Lyophyllum decastes의 항암(抗癌) 성분(成分) 및 배양(培養)-)

  • Lee, Chong-Ock;Kim, Hyung-Soo;Choi, Eung-Chil;Kim, Byong-Kak
    • Korean Journal of Pharmacognosy
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    • v.17 no.1
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    • pp.23-34
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    • 1986
  • To find antitumor components of Lyophyllum decastes, the mycelia of L. decastes were cultured in artificial media and a new antitumor component which showed potent antitumor activity against sarcoma 180 implanted in mice, was isolated and named 'Lyophyllan A'. Lyophyllan A was composed of a polysaccharide moiety (86%) and a protein moiety (2%). The polysaccharide moiety was found to be a heteroglycan which consisted of glucose (48.1%), mannose (30.8%), galactose, xylose and fucose. The protein moiety contained 18 amino acids. Cultural characteristics of L. decastes were investigated by shake culture method. The best result was obtained when L. decastes was cultured in medium glucose 50g, peptone 10g, corn steep liquor 30ml, $KH_2PO_4$ 0.87g, $MgSO_4$ $7H_2O$ 0.5g, $CaCl_2$ 0.3g, $FeSO_4{\cdot}7H_2O$ 10mg, $MnCl_2{\cdot}4H_2O$ 7mg, $ZnSO_4{\cdot}7H_2O$ 4mg and $CuSO_4{\cdot}5H_2O$ 1mg per one liter at $26^{circ}C$, 180rpm, for 9 days.

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Origin of Manganese Nodules and Their Distribution in the KODOS-89 Area, Northeastern Equatorial Pacific. (KODOS-89 지역 망간단괴의 성인과 분포)

  • 정회수;정갑식
    • 한국해양학회지
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    • v.25 no.4
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    • pp.189-204
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    • 1990
  • In the KODOS (Korea Deep Ocean Study)-89 area, western part of clarion-Clipperton fracture zones in the northeastern equatorial Pacific, magnate nodules and sediments were sampled during the 'Farnella' cruise in Oct., 1989. Bulk chemical and mineralogical analyses have been made on a suit of ferromanganese nodules and sediments to study the origin and distribution pattern of the nodules. The nodules are classified into three groups based on their origin: diagenetic nodules with high Mn/Fe ratio, Cu, Ni, Zn, Mg, todorokite contents and rough surface texture; hydrogenetic nodules with high Fe, Co, vernadite contents and smooth surface texture; and transitional nodules with intermediate characters between diagenetic and hydrogenetic nodules. Study area is divided into four zones according to the origin and abundance of nodules: far north area where nodules are hydrogenetic and intermediate in abundance; north area where nodules are diagenetic and low in abundance; south area where nodules are diagenetic and intermediate in abundance; seamount area where nodules are hydrogenetic and high in abundance. distribution pattern of manganese nodules in the KODOS-89 area seems to be controlled by latitudinal variation of productivity in water column and sea bottom morphology.

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An Evaluation on Airborne Particulate and It's Components in the Welding Workplace for the Ship Construction Industry (조선업 용접작업장의 공기중 입자상물질 및 구성성분에 관한 연구)

  • Kang, Yong-Seon;Shin, Joong-Kyu;Lee, Song-Kwon;Yoon, Chung-Sik;Lim, Moo-Hyuk;Park, Man-Chul;Sim, Sang-Hyo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.17 no.3
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    • pp.245-253
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    • 2007
  • This research was performed to evaluate the airborne personal concentration of hazardouse materials during the process of ship construction and surveyed from May 23 to June 30, 2007 in Kyungnam West Distirct, Korea. The subject was 94 ship construction workers exposed to welding fume and respirable particulate. The airborne concentrations of those were compared to Permissible Exposure Limit(PEL) from the Ministry of Labor in Korea. The airborne concentration of 23 samples(48.9%) of welding fumes was less than $5mg/m^3$, that of 16 (34.0%) was between 5 and $10mg/m^3$, and that of 8 (17.0%) was greater than $10mg/m^3$. The airborne concentration of 27 (57.4%) of respirable particulate masses was less than $5mg/m^3$ and the othere are greater than $5mg/m^3$. The welding fumes were identified containing the heavy metasl such as Fe, Mn, Zn, Mg, Ca, and Cu. The respirable particulates has similiar tendency with welding fumes in the component of heavy metals. But the concentration of Ca, Cu, Cr, and Ni turned out to be higher in welding fumes. Twenty (42.6%) of the 47 samples of welding fumes were exceeded PEL. In the heavy metals in welding fumes, ten (21.3%) of the 47 samples of Mn were exceeded PEL. Based on the results, the higher airborne hazardous materials were still exposed to wokers in ship construction process. It is suggested that the appropriate engineering control be applied to minimize the exposed cocnetration in ship building processes.