• Title/Summary/Keyword: ZnS: Cu

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A Study on the Removal of Heavy Metals in Soil by Sewage Sludge Biochar (하수슬러지의 Biochar특성을 이용한 토양내 중금속 제거 연구)

  • Kim, Hye-Won;Bae, Sunyoung;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.58-64
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    • 2013
  • This study proposed a low temperature hydrothermal carbonization to treat and recycle sewage sludge and determined the optimal conditions for the biochar production. The physical and chemical properties of biochar were analyzed and its sorption capacity for heavy metals was evaluated. To produce biochar, 50 g of sewage sludge was heated at 220, 230, and $240^{\circ}C$ for 1, 2, 3, 5, 8, and 10 hours in a reactor. The optimal conditions to produce biochar was $230^{\circ}C$ and 8 hours. Sorption capacity tests were conducted for arsenic (As), cadmium (Cd), copper (Cu), lead (Pb), zinc (Zn) and nickel (Ni). Among them, lead was shown the highest heavy metal adsorption efficiency of biochar, followed by copper, cadmium, zinc, and nickel, but arsenic was hardly adsorbed overall.

A Study on Soil Pollution of Elementary School Grounds in Ulsan City (울산시 초등학교 운동장의 토양오염실태에 관한 연구)

  • Cha, Seong-Woong
    • Journal of the Korean Society of School Health
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    • v.21 no.2
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    • pp.89-95
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    • 2008
  • Purpose: The purpose of this study is to investigate the heavy metal pollution of playgrounds of elementary schools in the Ulsan Metropolitan City. Soil pollution is one of the most dangerous problems of the utmost concern to both children and teachers. The result of this study would be an educational datum for improving children's health and establishing educational policy. Methods: For the analysis, fifteen representative schools were selected from five sample areas such as Dong-gu, Nam-gu, Jung-gu, Buk-gu and Ulju-gun of the Ulsan city. And from each school playground, soil was extracted from five spots and mingled into one sample. These fifteen samples were pretreated by the microwave extraction method, and the extracted heavy metals(As, Cd, Cu, Pb, Cr⁶⁺, Zn and Hg) were quantified by the ICP(Inductively Coupled Plasma) system. Results: The results of the analysis shows that the level of heavy metal pollution of elementary school playgrounds in Ulsan city did not exceed the permitted limit of each heavy metal. This means that the soil pollution of playgrounds in the Ulsan Metropolitan City is not so serious as it is expected. But it should be added that the soil is not too safe to be ignored.

Growth and Foliar Constituents of Mulberry ($M_5$) Cultivated under Organic Based Nutrient Management

  • Rashmi, Krishnegowda;Shankar, Maruvanahalli Ankegowda;Shashidhar, Kaluvarahalli Ramanna;Narayanaswamy, Talagavara Kempaiah
    • International Journal of Industrial Entomology and Biomaterials
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    • v.19 no.1
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    • pp.165-169
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    • 2009
  • A field experiment to evaluate the effect of application of different organic manures and inorganic fertilizers on growth, yield and quality of leaf was studied during 2004-05 has showed that, the application of 10 kg each of Azospirillum brasilense and Aspergillus awamori+20% each of recommended N through compost+green manure (Glyricidia maculata)+castor cake+vermicompost+Urea and remaining P and K through fertilizers ($T_{11}$) has recorded significantly higher leaf yield (250 g/ plant and 34.70 tonnes/ha/yr, respectively) with improvement in growth characters as compared to control. Leaf quality status was also improved in terms of N (3.19%), P (1.97%), K (1.28%), total soluble protein (8.39 mg/ml), total soluble sugars (14.40 mg/ml), secondary nutrients viz., Ca (3.00%), Mg (0.60%), S (0.35%) and micronutrients viz., Cu (0.410 ppm), Mn (0.454 ppm) and Zn (0.112 ppm) contents. The mulberry grown with 20 tonnes of compost+300:120:120 Kg of NPK/ha/year through fertilizer ranked second for growth and foliar constituents.

A Study on Fracture Behavior in Shear Band during Micro Hole Punching Process (미세 홀 펀칭시 전단 파괴 거동 연구)

  • 유준환;임성한;주병윤;오수익
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.230-235
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    • 2003
  • In the micro hole punching, the size and shape of burr and burnish zone are very important factors to evaluate quality of micro holes which depend on punch-die clearance, stain rate, workpiece material and etc. To get micro holes with small burr and wide burnish zone for industrial demands, not only the parametric study but also a study on fracture behavior in shear band are necessary. In this study, 100 $\mu\textrm{m}$, 25 $\mu\textrm{m}$ micro holes in diameter were fabricated on brass (Cu63/Zn37) and SUS 316 foils as aspect ratio 1:1, and the characteristics of micro holes was investigated comparing with man holes over several mm by scanning electron microscopic views and section views. Like macro hole, micro hole is also composed of 4 portions, rollover, burnish zone, fracture zone and it shows similar fracture behavior in shear band, but? by high strain rate (10$^2$∼ 10$^3$s$\^$-1/) unlike macro hole fabrication and increment of relative grain size several different results are shown.

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Evaluation of Stored Rainwater Quality at Galmoe Middle School Rainwater Harvesting System (갈뫼중학교 빗물이용시설에서의 저장 빗물수질평가)

  • Han, Moo-Young;Lee, Soon-Jai
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.1
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    • pp.31-37
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    • 2005
  • One of the major obstacles confronted in promoting the rainwater harvesting is the concerns of acid rain and heavy metals. Although there are many data concerning the quality of rainwater precipitation for the study of acid rain, the study on the quality of stored rainwater has been limited. In this study, we monitored the quality of stored rainwater at Galmoe middle school, where a rainwater harvesting system is installed and in use for more than two years. We measured water quality parameters such as pH, Electro Conductivity(EC), Dissolved Oxygen(DO), and some metals (aluminium (Al), chromium(Cr), manganese(Mn), zinc(Zn), copper(Cu), arsenic(As), cadmium(Cd), lead(Pb)). The monitoring period was during one year from September 9th 2003 to August 5th 2004. It was observed that the average pH of stored rainwater is neutral. DO is similar to tap water and EC is lower than tap water. Metal Concentrations are within the concentration specified in Drinking Water Quality Standard. Overall, the stored rainwater quality is good enough for sundry use and there's no threat of acid rain and air pollution, if the rainwater harvesting system is well designed and maintained.

Sediment Pollution of Heavy Metal and Potential Ecological Risk Assessment in Baiyangdian Lake, China

  • Li Guibao;Yang Zhuo;Wang Dianwu;Hao Hong
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.1-8
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    • 2005
  • Baiyangdian Lake, the largest freshwater lake in North China, is known as 'Pearl of North China' and 'kidney of North China' fur its abundant products and multiple ecological services. However, from the 1970s, due to the ever-increasing discharge of polluted water from upstream rivers, it has been severely polluted. Sediment Investigation and analysis were conducted on contents of heavy metal (Cu, Zn, Cd and Pb) from Baiyangdian Lake in June 2004. Results showed that pollution situation at downriver regions are more serious than that of upstream regions. The seriously polluted spots are access of Fuhe River, original wastewater reservoir of Tanghe River, densely populated Chunshui Village and Wangjiazhai Village. By using method of the potential ecological risk assessment, the heavy metal evaluation of polluted sediment has been conducted. The results showed that the contents of Cd and Pb were very high in sediment of Baiyangdian Lake. There were extremely stronger ecological risk for Cd and slight- medium ecological risk for Pd. According to the current situation of Baiyangdian Lake, countermeasures and suggestions have been put forward.

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A Study on Shear Fracture Behavior of Metal in Micro Hole Punching Process (금속 소재의 미세 홀 펀칭 시 전단 파괴 거동 연구)

  • 유준환;임성한;주병윤;오수익
    • Transactions of Materials Processing
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    • v.12 no.4
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    • pp.314-319
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    • 2003
  • In the micro hole punching, the size and shape of burr and burnish zone are very important factors to evaluate quality of micro holes which depend on punch-die clearance, strain rate, workpiece material and etc. To get micro holes with small burr and wide burnish zone for industrial demands, not only the parametric study but also a study on fracture behavior in shear band are necessary. In this study, 100 $\mu$m, 25 $\mu$m micro holes in diameter were fabricated on brass (Cu63/Zn37) and SUS 316 foils as aspect ratio 1:1, and the characteristics of micro holes was investigated comparing with those of macro holes over several mm by scanning electron microscopic views and section views. Like macro hole, micro hole is also composed of 4 portions, rollover. burnish zone, fracture zone and burr, and it shows similar fracture behavior in shear band. But by high strain rate (10$^2$∼10$^3$s$^{-1}$ ) condition unlike that of macro hole fabrication and by the increment of relative grain size in the direction of the workpiece thickness, fracture zone is not observed.

Purification and Properties of an Extracellular Acid Phytase from Pseudomonas fragi Y9451

  • In, Man-Jin;Jang, Eun-Seok;Kim, Young-Jin;Oh, Nam-Soon
    • Journal of Microbiology and Biotechnology
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    • v.14 no.5
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    • pp.1004-1008
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    • 2004
  • An extracellular acid phytase from Pseudomonas fragi Y9451 was purified to homogeneity from the culture supernatant by salting-out, DEAE-Sepharose column chromatography, CM-Sepharose column chromatography, and Sephacryl S-300 gel filtration. The molecular weight of the purified enzyme was estimated to be 74 kDa on gel filtration and 54 kDa and 25 kDa on SDS-PAGE, suggesting that the native enzyme was a heterodimeric protein. The purified enzyme was most active at pH 4.5 and $70^{\circ}C$ and fairly stable from pH 4.0- 6.0. It was specific for phytate and exhibited a $K_{m}$ value of 27 mM (sodium phytate, pH 4.5, $50^{\circ}C$). The phytase activity was strongly inhibited (at maximum by 87%) by $Fe^{3+},\;Cu^{2+},\;Fe^{2+}$, and $Zn^{2+}$ at 5 mM concentration, and greatly inhibited by $Ca^{2+}$ at 10 mM concentration. However, EDTA notably stimulated the phytase activity at 10 mM concentration. With optimum pH and stability, Pseudomonas fragi phytase could be a potential candidate for animal feed applications.

Characterization of a Smelting Furnace in Ungyo Site in Wanju, Jeollabuk-do, Through Slag Analysis

  • Lee, Su Jeong;Cho, Nam Chul;Kang, Byoung Sun
    • Journal of Conservation Science
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    • v.35 no.4
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    • pp.373-383
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    • 2019
  • We characterized the smelting process and smelting furnace through scanning electron microscopy-energy dispersive spectroscopy, wavelength dispersive X-ray fluorescence, X-ray diffraction, and raman micro-spectroscopy with 13 relics including slags and furnace walls excavated from square-shaped building sites and pits of the Three Kingdoms site at the Ungyo site section I. Our results revealed that the principal components were FeO and SiO2; and CuO, PbO, and ZnO were contained in small quantities. Furthermore, fayalite, magnetite, augite, copper, and cuprite were found. High contents of FeO or SiO2 components seem to have been added to form fayalite to remove gangue in the smelting process. The relatively low content of S detected in the copper prills suggests that roasting was performed well. Cristobalite and mullite, which are minerals that indicate high-temperature found in the furnace wall, show that the smelting temperature was higher than 1,250℃. The findings of this study show a high possibility that the Wanju Ungyo site is smelting remains of copper ores, which are nonferrous metals, rather than iron. Various smelting byproducts excavated in this area in the future will help us better understand the copper smelting process that may have been performed since ancient times.

온천수가 반죽의 발효와 품질에 미치는 영향

  • 이예경;김순동;이명예;김미영
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.121.1-121
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    • 2003
  • 증류수, 수도수, 온천수(경산 사이판 온천) 희석액 (55배 희석; I, 4배 희석; II, 2배희석; III을 사용한 반죽의 발효와 빵의 품질에 미치는 영향을 조사하였다. 경산사이판 온천수는 총고형물이 8,765 ppm 이였으며 주요 무기질로는 Na가 2296 ppm, Ca가 287 ppm, Mg와 K가 각각 65 및 8 ppm을 함유하였다. Fe, Cu, Co, F. Zn Al, S, Mo, Se 및 Si 등이 0.002~5.2 ppm을 함유하였다. 온천수를 사용한 반죽의 pH는 6.95~7.68로 증류수의 6.40보다 높았다. 반죽부피는 온천수의 농도가 높아짐에 따라 감소하였다. pH를 5.5로 조정한 온천수를 사용한 반죽의 부피는 대조구 보다 오히려 높았다. 온천수를 사용한 빵의 경도 (hardness)와 신장성(strength)는 대조구 보다 높았으나 pH를 조정한 온천수의 경우는 낮았다. 점착성은 경도 및 신장성과는 역으로 희석 온천수에서 낮았다. pH 조정 없이 구운 빵의 부드러운 정도는 4배로 희석한 온천수가 증류수 및 55배, 2배 희석 온천수보다 높았다. 쫄깃한 맛도 온천수가 대조구에 비하여 높았으며 종합적인 기호도는 4배 희석 온천수가 가장 좋았다.

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