• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.6
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• pp.1807-1818
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• 1991

The frictional characteristic of Zn-Ni electrogalvanized steel sheet was investigated by experimental procedures. To clarify the effect of surface property on the frictional characteristic of Zn-Ni coated steel sheet, Micro-hardness test, SEM analysis and X-ray diffraction analysis were carried out. Coefficients of friction for various stamping lubricant and Ni content in coated layer were measured by a draw bead friction test. The results show that frictional characteristic is very sensitive to Ni content of coated layer and depends on stamping lubricant. For Ni content less than about 11%, selection of proper lubricant is necessary to obtain low coefficient of friction in Zn-Ni coated steel sheet such as in case of cold rolled steel sheet.

• Corrosion Science and Technology
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• v.22 no.5
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• pp.387-392
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• 2023

The objective of this study was to evaluate corrosion resistance of Zn-Al-Mg alloy coated steel in residential water with trace quantities of Cl^-. Comparative evaluations were performed using two commercial coated steel products, GI and Galvalume, as reference samples. Examination of corrosion morphology and measurement of weight loss revealed that the Zn-Al-Mg alloy coated steel exhibited higher corrosion resistance than reference samples. This finding suggests that the alloy coated steel possesses long-term corrosion resistance not only in highly Cl^- concentrated environments such as seawater, but also in environments with extremely low levels of Cl^- found in residential water. The primary factor contributing to the superior corrosion resistance of the Zn-Al-Mg alloy coated steel in residential water is the formation of an inhibiting corrosion product composed primarily of two phases: Zn₅(OH)₆(CO₃)₂ and Zn₅(OH)₈Cl₂·H₂O. The preferential dissolution of Mg from the corroded coating layer can increase alkalinity, which might enhance the thermodynamical stability of Zn₅(OH)₆(CO₃)₂.

• Macromolecular Research
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• v.13 no.3
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• pp.223-228
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• 2005

In the present work, a low-density polyethylene (LDPE) composite, filled with Zn-ion coated structural silica encapsulated with the diglycidyl ether of bisphenol-A (DGEBA), was synthesized using the conventional melt-blending technique in a sigma internal mixer. The catalytic activity of the Zn-ions (originating from the structural silica) towards the oxirane group (diglycidyl ether of bisphenol-A (DGEBA): encapsulating agent) was assessed by infrared spectroscopy. Two composites, each with a filler content of $2.5 wt\%$ were developed. The first one was obtained by melt blending the Zn-ion coated structural silica with LDPE in a co-rotating sigma internal mixer. The second one was obtained by melt blending the same LDPE, but with DGEBA encapsulated Zn-ion coated structural silica. Epoxy resin encapsulation of the Zn-ion coated structural silica resulted in its having good interfacial adhesion and a homogeneous dispersion in the polymer matrix. Furthermore, the encapsulation of epoxy resin over the Zn-ion coated structural silica showed improvements in both the mechanical and thermal properties, viz. a $33\%$ increase in the elastic modulus and a rise in the onset degradation temperature from 355 to $371^{\circ}C$, in comparison to the Zn-ion coated structural silica.

• Macromolecular Research
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• v.11 no.6
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• pp.506-510
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• 2003

A Zn ion-coated nanosilica filler has been developed and tested, in chlorosulfonated polyethylene (CSPE) and polychloroprene (CR), as a vulcanizing activator, cum was reinforcing filler. In this study, ZnO was replaced by the Zn ion-coated nanosilica filler with an aim of studying the dual role of this nanofiller in CSPE and CR. In the case of CSPE vulcanizates, the presence of MgO deteriorated the state and rate of cure when the Zn ion-coated nanosilica filler was used, but in the case of CR it improved the state of cure and enhanced the modulus and tensile strength. The Zn ion-coated filler proved to be a better reinforcing-cum-curing agent than was externally added ZnO and NA-22 also proved to be a better curative in the presence of the Zn ion-coated nanosilica filler for both CSPE and CR.

• Corrosion Science and Technology
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• v.23 no.2
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• pp.121-130
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• 2024

In recent years, Zn-Al-Mg alloy galvanized steel sheets have been widely used as coated steel sheets to support social capital in the infrastructure field. A feature of Zn-Al-Mg alloy-coated steel sheets is that they provide a better corrosion protection period than Zn-coated steel sheets. In this study, the corrosion resistance of a new Zn-Al-Mg alloy-coated steel sheet was investigated and compared to that of conventional commercially available coated steel sheets. The investigation confirmed that increasing the Mg concentration in the Zn-Al-Mg-coated steel sheet improved corrosion resistance, which was more than 10 times that of the galvanized steel sheet specified in JIS G 3302. The study findings also confirmed that the corrosion resistance reached more than twice that of the coated steel sheet specified in JIS G 3323. If such galvanized steel sheets are applied to social infrastructures that are exposed to severely corrosive environments, the service life of the infrastructure might be extended.

• Corrosion Science and Technology
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• v.22 no.2
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• pp.123-130
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• 2023

This study aimed to evaluate corrosion resistance of steel coated with GI and Zn-Al-Mg alloy using cyclic corrosion test (CCT) with electrochemical polarization and impedance measurements. Results showed that the Zn-Al-Mg alloy coated steel had a much higher corrosion rate than GI coated steel in early stages of corrosion. With prolonged immersion, however, the corrosion rate of the Zn-Al-Mg alloy coated steel greatly decreased, mainly owing to a significant decrease in the cathodic reduction reaction and an increase in polarization resistance at the surface. This was closely associated with the formation of protective corrosion products including Zn₅(OH)₈Cl₂·H₂O and Zn₆Al₂(OH)₁₆CO₃. Moreover, when the steel substrate was locally exposed due to mechanical damage, the kinetics of anodic dissolution from the coating layer and the formation of protective corrosion products on the surface of the Zn-Al-Mg alloy coated steel became much faster compared to the case of GI coated steel. This could provide a longer-lasting corrosion inhibition function for Zn-Al-Mg alloy coated steel used in plant farms.

• Laser Solutions
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• v.13 no.3
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• pp.1-6
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• 2010

The in-process monitoring of $CO_2$ welding of Zn-coated steel plates has been studied and compared with that of conventional thin plates. Relationships between weld defects and plasma emission signals were evaluated in laser lap joint of thick Zn-coated steel. According to the study, weld defects were found to increase with Zn content. As a result, measured plasma emission signals also decreased. In case of plate with $15{\mu}m$-thick Zn-coated layer, defects caused by evaporation of Zn could, therfore, controled by gap of 0.1mm, resulting in a stable emission signals. However, the amplitude of signals fluctuated very widely. Variation of amplitude sould be limited in 3-8V by FFT smoothing.

• Journal of Welding and Joining
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• v.29 no.1
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• pp.90-98
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• 2011

Al-Si coated Boron steel and Zn coated DP steel were welded using DISK laser and the microstructure and hardness of the weld were investigated. Full penetration was obtained, when the welding speed was lower than 4m/min. In the specimen welded with laser power of 3 kW and welding speed of 2 m/min, the hardness was the highest in the heat affect zone in the boron steel (HAZ-B) and that of the heat affect zone in the DP steel (HAZ-D) was lower than HAZ-B. The hardness of fusion zone was in between those of HAZ-B and HAZ-D. The decreased hardness from each HAZ to base metal(BM) could be explained that ferrite contents increases when access to the BM. The variation of hardness in the welds could be explained by the difference of microstructure, that is, full martensite in HAZ-B, mixture of martensite and bainite in the fusion zone, and the mixture of martensite, ferrite and bainite in HAZ-D.

• Corrosion Science and Technology
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• v.8 no.1
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• pp.40-43
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• 2009

We investigated the corrosion resistance of Zn and Cu coated steel pipes as a substitute for Cu pipe in an air-conditioner system. In addition, the galvanic corrosion tendency between two dissimilar metal parts was studied. The corrosion resistance of the Cu electroplated steel was similar to that of Cu, while the corrosion rate of the Zn electro- galvanized and the galvalume (Zn-55 % Al) coated steels was much higher and not suitable for Cu substitute in artificial sea water and acidic rain environments. Furthermore, the galvanic difference between Cu electroplated steel and Cu was so small that the Cu coated steel pipe can be used as a substitute for Cu pipe in an air-conditioner system.

• Journal of Welding and Joining
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• v.14 no.3
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• pp.41-47
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• 1996

The spot weldability of coated steels for automobile has been investigated. Coated steels of SPC-Zn DC, SPC Zn-Ni SC, SPC Zn-Ni DC, SPC Zn-Fe DC and OCCS were welded under different conditions of welding current, force and time. Coating thickness at the welded surface was reduced as increased welding current. Tensile shear strength(TSS) and cross tensile strength (CTS) were increased up to expulsion began, then dropped as increased current. Optimum conditions of welding force and time were different, however 200~250kgf and 15~20cycle were optimum for coated SPC (Steel Plate Cold). Weldability lobes were measured for each coated steel and they showed narrow range of working welding current. The organic composite coated steel (OCCS) had the highest current to get $\sqrt5{t}$ nugget size and narrowest working welding current range.