• Title/Summary/Keyword: Zn electrode

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The Effect of $Pb_3O_4$ on Corrosion Resistance of Zn electrode added (아연/산화은 2차전지에서 $Pb_3O_4$ 첨가량에 따른 아연 전극의 내식성 변화)

  • Park, Kyung-Wha;Kim, Dae-Kyeong;Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Ha, Yoon-Cheol
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1734-1736
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    • 2004
  • Zn electrode is being widely used as an anode material in alkaline battery systems. However the corrosion resistance of Zn electrode in KOH electrolyte is very low. So, to improve the corrosion resistance of Zn electrode $Pb_3O_4$ was mixed to Zn material. And 5 wt.% Pb3O4 addition was most appropriate quantity.

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Study on the Electrical Stability of Al-doped ZnO Thin Films For OLED as an alternative electrode

  • Jung, Jong-Kook;Lee, Seong-Eui;Lim, Sil-Mook;Lee, Ho-Nyeon;Lee, Young-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1469-1472
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    • 2006
  • We investigated the electrical and optical properties of ZnO:Al thin films as a function of the thermal process conditions. The film was prepared by RF magnetron sputtering followed by annealing in a box furnace in air. An ZnO:Al (98:2) alloy with the purity of 99.99% (3 inch diameter) was used as the target material. The electrical properties of the transparent electrode, exhibited surface oxidation as a result of rapid oxygen absorption with increasing annealing temperature. The processed ZnO:Al films and commercial ITO(indium-tin-oxide) were applied to an OLED stack to investigate the current density and luminescence efficiency. The efficiency of the device using the ZnO:Al electrode was higher than that from the device using the ITO electrode.

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Optical Characteristics of AC PDP Cell with ZnO Electrode (ZnO 투명전극을 이용한 AC PDP 셀의 제작 및 광학적 특성)

  • Lee, Sung-Wook;Lee, Kyu-Suk;Park, Kyung-Suk;Lim, Dong-Gun;Park, Min-Woo;Kawk, Dong-Joo
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1948-1950
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    • 2005
  • In the recent years, much interests and attraction has been paid on the plasma display panel. To achieve high performance display panel, there has been a strong demands for studies on the transparent conducting films such as ITO and ZnO. In this study, we propose PDP cell with ZnO transparent conducting electrode. The electrical and optical characteristics of PDP cell with ZnO transparent electrode were studied and compared with that of conventional ITO electrode.

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Discharge Luminous Phenomena Caused Between ZnO Surge Arrester Block and Electrodes (산화아연 피뢰기 소자와 전극사이에 발생하는 방전광 현상)

  • Lee, Bok-Hee;Park, Keon-Young;Kang, Sung-Man
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.3
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    • pp.44-50
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    • 2005
  • This paper deals with the characteristics and reduction methods of the plasma luminosity caused between the ZnO surge arrester block and metal electrodes. In this study, the impulse current generator that can generate $8/20[{\mu}s]$ impulse currents with a peak short-circuit of 10[kA] is designed and fabricated. Plasma luminosity phenomena for fine and used ZnO blocks were observed as a function of the contact states between the ZnO block and electrodes and the polarity of applied impulse voltages. As a result, discharge luminous events are produced near the contact edges between the ZnO block and metal electrodes. The discharge plasma luminosity between the ZnO surge arrester block and low potential electrode is more intensive than that between the ZnO surge arrester block and high potential electrode. Surface flashover of ZnO blocks are mainly caused by plasma generation near the edge of metal electrode. Also, plasma luminosity for the fine ZnO blocks is less than that for the used ZnO blocks. Plasma luminosity at the contact of the ZnO block and ring-type electrode is more intensive than that at the contact of ZnO block and disk electrode. It is desirable to use the disk electrode with the proper contact area to reduce the plasma luminosity caused at the contact point between the ZnO block and electrodes.

Electric Conduction Properties of NaCl Electrolyte as a Function of Electrode Materials (전극재료에 따른 NaCl 전해질의 전기전도특성)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.11
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    • pp.2026-2031
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    • 2010
  • The electrical characteristics of galvanic cell which is composed of the cathode electrode(graphite, carbon and copper) and the anode electrode(Zn and Mg) were investigated. For this research as electrolyte 2~12 wt% NaCl aqueous solution were used. At graphite cathode electrodes which use Zn and Mg with the anode electrode, the open circuit voltage was 1.3V most highly. The maximum output power increased as the electrolyte concentration increased, due to a increase in ion density. When Zn and Mg with the anode electrode, the maximum output power respectively was evaluated as 2.2mW and 5.5mW about the graphite cathode electrode in the NaCl 4wt%. The research results indicated that the output power of cell which is composed with graphite with the cathode and Mg with the anode was most excellent and the efficiency of the cell could be enhanced by increasing the electrolyte concentration.

A Study on the Effect of Electrolyte Additives on Zn Electrode with Pb3O4 in Zn-AgO Secondary Battery System (Zn-AgO 이차 전지에서 Pb3O4가 첨가된 아연 전극에 미치는 전해질 첨가제의 영향에 관한 연구)

  • Park, Kyung-Wha;Moon, Kyung-Man
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.242-249
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    • 2003
  • Zn electrode was widely used as an anode material in alkaline battery systems in highly concentrated KOH electrolyte, however it was well known that its cycle life is significantly shortened by growth of dendrite due to the high dissolution of $Zn(OH)_2$ and rapid electrochemical reaction. In this study when by the additives such as $Ca(OH)_2$, Citrate, tartrate and Gluconate were added to $40\%$ KOH electrolyte at solution temperature of $25^{\circ}C$ and the amount of $5wt\%\;Pb_3O_4$ was mixed to Zn electrode and then the effect of $Pb_3O_4$ and additives on the electrochemical behavior of Zn electrode was investigated by Potentiodynamic Polarization Curves, Cyclic Voltammetry, Accelerated Life Cycle lest, and SEM image analyses. The addition of $Pb_3O_4$ reduced the corrosion rate of Zn electrode. The corrosion potential of Zn electrode with $Pb_3O_4$ was higher or lower than that of pure Zn electrode however was not influenced practically to the open circuit voltage. And the addition of 4 type additives had an important role in improving both cycle life in accelerated cycle life test and corrosion resistance. Furthermore the additive of Tartrate indicated comparatively a good effect to corrosion resistance as well as charging-discharging property Improvement among those four type additives.

Photoelectrochemical Deposition of CdZnSe Thin Films on the Se-Modified Au Electrode

  • Ham, Sun-Young;Jeon, So-Yeon;Lee, Ungki;Paeng, Ki-Jung;Myung, No-Seung
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.939-942
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    • 2008
  • Photoelectrochemical deposition of CdZnSe thin films on the Se-modified Au electrode using electrochemical quartz crystal microgravimetry (EQCM) and voltammetry is described. Corrosion of pre-deposited Se electrodes by illumination at a fixed potential resulted in $Se^{2-}$ species, which was manifest from the EQCM frequency changes. $Se^{2-}$ species generated from the photocorrosion reacted with $Cd^{2+}$ and $Zn^{2+}$ ions in the electrolyte to form CdZnSe films on the Au electrode. The effect of electrolyte composition on the composition and band gap of CdZnSe films was studied in detail. Also, photoelectrochemistry, EDX, Raman spectroscopy were used for the characterization of CdZnSe thin films.

A Study on the frequency characteristic of ZnO Piezoelectric transducers (ZnO 압전변환기의 주파수특성에 관한 연구)

  • 정규원;이종덕;정광천;박상만;송준태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.189-192
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    • 1996
  • In this paper ZnO Piezoelectric transducers were fabricated as follows, counter electrode (pt 99.9%) was deposited on the sapphire substrates by DC sputter method, and then piezoelectric layer (ZnO 99.999%) was deposited on the counter electrode according to the sputtering parameters, and then top electrode (pt 99.9%) was deposited on the piezoelectric layer by Electron Beam Gun Evaporator. Structural characteristic of deposited ZnO thin film was measured by XRD, SEM. Also, Frequency characteristic of ZnO transducer was analyzed theoretically and practically for input frequencies.

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Development of Highly Efficient Dye-Sensitized Solar Cells Using ZnO Post-Treated TiO2 Photoelectrodes (ZnO로 후처리된 TiO2 광전극을 이용한 고효율의 염료감응형 태양전지의 개발)

  • PARK, JUN-YONG;YUN, BYEONG-RO;KIM, TAE-OH
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.419-425
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    • 2017
  • In this study, an efficient dye-sensitive solar cells (DSSC) was developed after post-treatment of ZnO on $TiO_2$ photoelectrode. The $TiO_2$ electrode with ZnO post treatment was prepared with Titanium isoporopoxide in Zinc Nitrate Hexahydrate aqueous solution by incineration for 30 min at $450^{\circ}C$. The ZnO-post treated $TiO_2$ electrode showed strong dispersion force between particles in relation to the control $TiO_2$, referring high specific surface area and dye-adsorption rate. Proper addition of ZnO enhanced electron mobility and reduced internal resistance and electron recombination. Light conversion efficiency of DSSCs containing the ZnO-posttreated $TiO_2$ electrode increased 35.4% when compared to the DSSCs using $TiO_2$ electrode. It is similar to the DSSCs with $TiCl_4$ post treatment $TiO_2$ electrode. Increasing of light conversion efficiency was due to high specific surface area and dispersion force, and low dye-adsorption rate and electron recombination. Taken together, ZnO may be used as posttreatment of photoelectrode and replaced $TiCl_4$ that has high toxicity and causticity.

Effect of Coating Layer on Electrode Life for Resistance Spot Welding of Al-Coated Hpf and Zn-Coated Trip Steels (Al 도금 HPF 강판과 전기아연도금 TRIP 강판의 저항 점 용접 시 연속타점 전극의 수명에 미치는 도금층의 영향)

  • Son, Jong Woo;Seo, Jong-Dock;Kim, Dong Cheol;Park, Yeong-Do
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.29-36
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    • 2012
  • The resistance spot welding of high strength steel degrades the weldability because of its high strength with rich chemical composition and coating layer to protect from corrosion. During the each resistance welding process the electrodes tip reacts with coating layer, then subsequently deteriorates and shorten electrode life. In this study, the Al-coated HPF (Hot Press Forming) steels and Zn-coated TRIP steels were used to investigate the electrode life for resistance spot welding. Experimental results show that the reactivity of Al-coating on HPF steels to electrode tip surface behaviors different from the conventional Zn-coated high strength steels. The electrode tip diameter and nugget size in electrode life test of Al-coated HPF steels are observed to be constant with respect to weld numbers. For Al-coated HPF steels, the hard aluminum oxide layer being formed during high temperature heat treatment process reduces reactivity with copper electrode during the resistance welding process. Eventually, the electrode life in resistance spot welding of Al-coated HPF steels has the advantage over the galvanized steel sheets.