• Title/Summary/Keyword: Zn/Mg ratio

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Crystal Structure and Electrochemical Properties of LiMn2-yMyO4 Cathode Material by Complex Substitution of Mg and Zn (Mg와 Zn의 복합치환에 따른 LiMn2-yMyO4 정극 활물질의 결정 구조 및 전기화학적 특성)

  • 정인성;정해덕;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.4
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    • pp.361-366
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    • 2002
  • Spinel $LiMn_{2-y}M_yO_4$ and $LiMn_{2-y}M_yO_4$ (M=Mg, Zn) powders were synthesized by solid-state method at $800^{\circ}C$ for 37h. Crystal structure and electrochemical properties were analyzed by X-ray diffraction, charge-discharge test, cyclic voltammetry and ac impedance to $LiMn_{2-y}M_yO_4$. All cathode material showed spinel structure in X-ray diffraction. Ununiform distortion which calculated by (111) face and (222) face was almost constant in spite of the change of the kind and the substituting ratio of the metal cation in $LiMn_{2-y}M_yO_4$ (M=Mg, Zn). $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$ cell substituted $Mg^{+2}$ and $Zn^{+2}$ showed excellent discharge capacities than other cells, which it presented about 120mAh/g at the 1st cycle and about 73mAh/g at the 250th cycle, respectively. AC impedance of $LiMn_{2-y}M_yO_4/Li$ cells showed the similar resistance of about 65~110$\Omega$ before cycling.

The Correlatin of Dietary Cr, Cu and Zn Levels with Serum Lipid Healthy College Women Living in Choongnam Area

  • Kim, Ae-Jung;Yuh, Chung-Suk;Kim, Hye-Kyng;Kim, Sun-Yeon;Kim, Soon-Kyung;Chang, Ock-Ja
    • Nutritional Sciences
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    • v.3 no.1
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    • pp.42-46
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    • 2000
  • The purpose of this study was to examine the intake of Cr, Cu, and Zn, which play important roles in lipid metabolism, and the relationship of these microminerals with serum lipids of healthy college living in the Choongnam area. The nutritional status of the subjects(35 women) was evaluated based on anthropometric measurements, 24-hr dietary recall for 3 days. Three-day meals and fasting blood were collected to analyze Cr, Cu, and Zn. The mean age, height, weight and BMI were 20 years, 158 cm, 55kg and 22.42kg/$m^2$ respectively. The mean daily energy intake was 85.9% of RDA for Koreans. The ratio of energy from carbohydrate, protein and fat was 60 : 24 : 16. The mean daily intake of Cr, Cu, and Zn was 60.07 $\mu\textrm{g}$/day, 2.64 mg/day, and 11.35 mg/day, respectively. The mean serum levels of Cr, Cu, and Zn were 143$\mu$g/dl, 81.34$\mu$g/dl, adn 101.54$\mu$g/dl, respectively. The mean serum levels of total cholesterol, triglycerides, HDL-cholesterol, LDL-cholesterol were 158.56mg/dl, 29.27 mg/dl, 56.00mg/dl, 6.12mg/dl, respectively. In conclusion, the subjects of the present study were healthy and consumed normal levls of dietary Cr, Cu and Zn, which play roles in lipid metabolism. Therefore, serum lipids of the subjects were all in the normal range. There was no significant correlation between dietary microminerals and serum lipids.

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Effects of Load Ratio on Fatigue Crack Growth in a TMT Treated Al-Zn-Mg Alloy (가공열처리한 Al-Zn-Mg 합금의 피로균열 성장거동에 미치는 하중비의 영향)

  • Byun, E.S.;Kim, S.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.2 no.4
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    • pp.19-26
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    • 1989
  • Fundmental fatigue crack propagation tests with C-T type specimens were conducted at various load ratios (R) such as 0.1, 0.3 and 0.5 in T6 and Thermomechanically treated (TMT) conditions of 7039 Al alloy. Better mechanical properties from monotonic test as well as fatigue crack propagation were obtained by TMT process owing to uniform distribution of fine microstructures and non-existence of precipitation free zone (PFZ). Through the measurement of Kop and ${\Delta}K$ at various R the concept of effective stress intensity factor range ratio, U was reviewed to asses the load ratio effect on fatigue crack propagation. A relationship between U and variables such as ${\Delta}K$ and R was obtained empirically. This may enable us to predict ${\Delta}K_{eff}$ that is of critical importance for prediction of fatigue crack propagation rate.

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Improvement of PMOLED life time using Mg-Zn-F thin film passivation

  • Kim, Jae-Hyun;Seo, Jun-Seon;Hong, Seok-Min;Kang, Byoung-Ho;Kim, Do-Eok;Lee, Sung-Youp;Shin, Byong-Wook;Lee, Hyeong-Rag;Kim, Hak-Rin;Kang, Shin-Won
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.794-797
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    • 2009
  • We manufactured a novel gas permeation thin film passivation by using inorganic Mg-Zn-F target which has better optical characteristics and high electronegativity. We fabricated targets in various composition ratio and formed about 200nm which is limited thickness of the flexible display. Applied to PLED device, the target which composed of $MgF_2$ and Zn at the ratio of 4:6, WVTR was reached the measurement limit of the equipment, $10^{-3}g/m^2{\cdot}day$ and the life time was increased 25 times better than PLED device which is non-passivation.

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Synthesis of Spinel Pigment on ZnO-Fe2O3 System (ZnO-Fe2O3계 Spinel안료에 대한 연구)

  • 이진성;이응상
    • Journal of the Korean Ceramic Society
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    • v.26 no.2
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    • pp.187-194
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    • 1989
  • Synthesis of spinel pigment on ZnO-Fe2O3 system. The object of this research is the synthesis of new spinel pigments on the basic of ZnO-Fe2O3 system which was substituted by ZnO-Fe2O3 by MgO-Al2O3. This research was progressed by measuring the X-ray diffraction and the reflectances of the substitued ZnO-Fe2O3 group. Which was obtained by sintering at the temperature of 1,00$0^{\circ}C$, 1,10$0^{\circ}C$, 1,20$0^{\circ}C$ and 1,25$0^{\circ}C$ and them by regrinding. In order to coloring test, here basic compositions of Barium glaze, Zinc glaze, Lime glaze, Lead glaze and Talc glaze used in this experiment are obtained from the ceramic work. Adding synthetic stains in these basic glazes with 3%, mixing and glazing on the specimen. The specimens was fired at 1,28$0^{\circ}C$ in reducing and oxidizing atmosphere in the gas kiln. The results of the research as follow. 1. Many kinds of spinel pigment was produced on ZnO-Fe2O3 system that is to say, not always only spinel. 2. Spinel peak was observed strongly on the ZnO-Fe2O3 system withsubstituting by MgO-Fe2O3 and MgO-Al2O3 group(the ratio of MgO, Al2O3 being increased, observed more strongly). 3. The most effective temperature ranges was 1,20$0^{\circ}C$~1,25$0^{\circ}C$. 4. The color of spinel pigments on this system was observed by "stable YR". 5. It was yellow red in oxidizing and green in reducing atmosphere on the coloring test.ring test.

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Characteristics on the Hot Extrusion of Semi-Solid Al-Zn-Mg Alloy (반응고 Al-Zn-Mg 합금의 고온 압출 시 특성 평가)

  • Cho, Kuk-Rae;Kim, Jeoung-Han;Yeom, Jong-Taek;Shim, Sung-Yong;Lim, Su-Gun;Park, Nho-Kwang
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.405-408
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    • 2007
  • Semi-solid Al-Zn-Mg alloys were produced using a cooling plate method in order to investigate the extrudability. Al melt was poured on cooling plate which was adjusted at $60^{\circ}$ with respect to the horizontal plane, and the melt was cooled by water circulation underneath. Obtained Semi-solid feedstock has globular microstructure but also contains considerable amount of gas pore. Due to the pore, tensile elongation of the semi-solid feedstock was very low and it doesn't show yield point phenomenon. Isothermal hot extrusion was carried out using at $400^{\circ}C$ with a ram speed of 1mm/sec and an extrusion ratio of 25:1. The extruded bar show noticeably improved tensile ductility and strength because pore volume fraction decreased from 5% to 0.8% after extrusion. Mechanical properties of the semi-solid extruded bar were compared with that of commercial casting alloy..

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Characteristics on the Hot Extrusion of Semi-Solid Al-Zn-Mg Alloy (반용융 Al-Zn-Mg합금의 고온 압출 시 특성 평가)

  • Cho, Kuk-Rae;Yeom, Jong-Taek;Shim, Sung-Yong;Lim, Su-Gun;Park, Nho-Kwang;Kim, Jeoung-Han
    • Transactions of Materials Processing
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    • v.16 no.5 s.95
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    • pp.391-395
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    • 2007
  • Semi-solid Al-Zn-Mg alloys were produced by using a cooling plate method in order to investigate the extrudability. Al melt was poured on cooling plate which was adjusted at $60^{\circ}$ with respect to the horizontal plane, and the melt was cooled by water circulation underneath. Obtained Semi-solid feedstock has globular microstructure but also contains considerable amount of gas pore. Due to the pore, tensile elongation of the semi-solid feedstock was very low and it doesn't show yield point phenomenon. Isothermal hot extrusion was carried out using at $400^{\circ}C$ with a ram speed of 1mm/sec and an extrusion ratio of 25:1. The extruded bar show noticeably improved tensile ductility and strength because pore volume fraction decreased from 5% to 0.8% after extrusion. Mechanical properties of the semi-solid extruded bar were compared with that of commercial casting alloy.

The Photoluminescence and Decay time of the Green Phosphor $Zn_2$$SiO_4$:Mn, Mg (Mg와 Mn이 도핑된 $Zn_2$$SiO_4$ : Mn, Mg 녹색 형광체의 빛 발광과 잔광시간 특성)

  • 조봉현;황택성;손기선;박희동;장현주
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1101-1106
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    • 1998
  • Various $Zn_{2-x}SiO_4$:xMn based green phosphors were investigated in association with a co-dopant. The co-dopant incorporated into the phosphors are believed to alter the internal energy state of $Zn_{2-x}SiO_4$ : xMn So that the improvement in their intensity could be expected. Phosphor samples were prepared using the solid state reaction therein raw powders are mixed in the acetone and successively fired at $1300^{\circ}C$ for 4 hour. The fired powders are also heated up to $900^{\circ}C$ for 2 hour in the reduced atmoshpere and thereby giving The fired powders are also heated up to $900^{\circ}C$ for 2 hour in the reduced atmosphere and thereby giving rise to conspicuous enhancement of radiative efficiency. Basically the 0.08 mole ratio of the Mn con-centrations has the maximum value of the intensity so that a co-dopant are added to this Mn con-centration. When the Mg is co-doped with Mn luminescent intensity is proven to be promoted significantly.

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Preparation of Activated Carbon from Waste Citrus Peels by ZnCl2 (ZnCl2를 이용하여 폐감귤박으로부터 활성탄 제조)

  • Kang, Kyung-Ho;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.16 no.9
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    • pp.1091-1098
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    • 2007
  • Activated carbon was prepared from waste citrus peels by chemical activation with $ZnCl_2$. The optimal condition of carbonization was at $300^{\circ}C$ for 1.5 hr. Activation experiments with carbonized samples prepared at optimal carboniztion condition were carried out under various conditions such as activation temperature of 400 to $900^{\circ}C$, activation time of 0.5 to 2.0 hr, and $ZnCl_2$ ratio of 100 to 300%. In order to investigate the physical properties of the activated carbons prepared, iodine adsorptivities and specific surface areas were measured and their morphologies were observed from scanning electron microscopy. As $ZnCl_2$ ratio increased, activation yield decreased, while iodine adsorptivity and specific surface area increased. The optimal condition of activation was at 300% $ZnCl_2$ ratio and $300^{\circ}C$ for 1.5 hr, and then iodine adsorptivity and specific surface area was measured as about 862 mg/g and $756m^2/g$, respectively. SEM photography showed that the surface morphology was changed and many active pore were produced by chemical activation.

Effects of dietary supplementation of a lipid-coated zinc oxide product on the fecal consistency, growth, and morphology of the intestinal mucosa of weanling pigs

  • Byun, Young-Jin;Lee, Chul Young;Kim, Myeong Hyeon;Jung, Dae Yun;Han, Jeong Hee;Jang, Insurk;Song, Young Min;Park, Byung-Chul
    • Journal of Animal Science and Technology
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    • v.60 no.1
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    • pp.29.1-29.6
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    • 2018
  • Background: Dietary supplementation of zinc oxide (ZnO) to 2000 to 4000 mg/kg is known to be effective for the prevention and treatment of post-weaning diarrhea in the pig. Such a 'pharmacological' supplementation, however, can potentially result in environmental pollution of the heavy metal, because dietary ZnO is mostly excreted unabsorbed. Two experiments (Exp.) were performed in the present study to determine the effects of a lipid-coated ZnO supplement Shield Zn (SZ) compared with those of ZnO. Methods: In Exp. 1, a total of 240 21-day-old weanling pigs were fed a diet supplemented with 100 mg Zn/kg as ZnO (ZnO-100), ZnO-2500, SZ-100, or SZ-200 in 24 pens for 14 days on a farm with its post-weaning pigs exhibiting a low incidence of diarrhea. Exp. 2 was performed using 192 24-day-old piglets as in Exp. 1 on a different farm, which exhibited a high incidence of diarrhea. Results: In Exp. 1, fecal consistency (diarrhea) score (FCS) was less for the ZnO-2500 and SZ-200 groups than for the SZ-100 group (P < 0.05), with no difference between the SZ-100 and ZnO-100 groups. Both average daily gain (ADG) and gain:feed ratio were less for the SZ-200 group than for the ZnO-2500 group, with no difference between the ZnO-100 group and SZ-100 or SZ-200 group. The villus height (VH), crypt depth (CD), and VH:CD ratio of the intestinal mucosa were not influenced by the treatment. In Exp. 2, FCS was lowest for the ZnO-2500 group, with no difference among the other groups. However, neither the ADG nor gain:feed ratio was influenced by the treatment. Conclusion: Results suggest that physiological SZ supplementation has less beneficial effects than pharmacological ZnO for the alleviation of diarrhea irrespective of its severity and for promoting growth without influencing their integrity of the intestinal mucosal structures with little advantage over physiological ZnO in weanling pigs with a small pen size.