• Title/Summary/Keyword: Zirconate

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An anisotropic ultrasonic transducer for Lamb wave applications

  • Zhou, Wensong;Li, Hui;Yuan, Fuh-Gwo
    • Smart Structures and Systems
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    • v.17 no.6
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    • pp.1055-1065
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    • 2016
  • An anisotropic ultrasonic transducer is proposed for Lamb wave applications, such as passive damage or impact localization based on ultrasonic guided wave theory. This transducer is made from a PMNPT single crystal, and has different piezoelectric coefficients $d_{31}$ and $d_{32}$, which are the same for the conventional piezoelectric materials, such as Lead zirconate titanate (PZT). Different piezoelectric coefficients result in directionality of guided wave generated by this transducer, in other words, it is an anisotropic ultrasonic transducer. And thus, it has different sensitivity in comparison with conventional ultrasonic transducer. The anisotropic one can provide more information related to the direction when it is used as sensors. This paper first shows its detailed properties, including analytical formulae and finite elements simulations. Then, its application is described.

Compensation of temperature effect on impedance responses of PZT interface for prestress-loss monitoring in PSC girders

  • Huynh, Thanh-Canh;Kim, Jeong-Tae
    • Smart Structures and Systems
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    • v.17 no.6
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    • pp.881-901
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    • 2016
  • In this study, a method to compensate the effect of temperature variation on impedance responses which are used for prestress-loss monitoring in prestressed concrete (PSC) girders is presented. Firstly, an impedance-based technique using a mountable lead-zirconate-titanate (PZT) interface is presented for prestress-loss monitoring in the local tendon-anchorage member. Secondly, a cross-correlation-based algorithm to compensate the effect of temperature variation in the impedance signatures is outlined. Thirdly, lab-scale experiments are performed on a PSC girder instrumented with a mountable PZT interface at the tendon-anchorage. A series of temperature variation and prestress-loss events are simulated for the lab-scale PSC girder. Finally, the feasibility of the proposed method is experimentally verified for prestress-loss monitoring in the PSC girder under temperature-varying conditions and prestress-loss events.

Fabrication of PZT Tubular Structures by a Template-wetting Process

  • Shaislamov, U.A.;Hong, S.K.;Yang, B.
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.141-143
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    • 2007
  • Nanotubes and microtubes of ferroelectric lead zirconate titanate (PZT) were synthesized by means of a simple and convenient process called a template-wetting process. Nanoporous alumina and macroporous Si were used as template materials to fabricate the corresponding tubes. For the improvement of the wetting properties of the wetting solution, the PZT solution was mixed with a polymer. The polymer was removed completely during annealing. The grain growth processes of the PZT nanotubes during baking and furnace annealing were examined by means of field emission electron microscope (FE-SEM) and X-ray diffractometry (XRD).

Measured Polarization Hysteresis and Predicted Reference Remnant Polarization and Strains of Ferroelectric Ceramics at Various Electric Field Loading Rates and Temperatures (다양한 전계인가율과 온도에서 강유전 세라믹의 이력선도 계측과 기준 잔류 분극 및 변형률 거동 예측)

  • Ji, Dae Won;Kim, Sang-Joo
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.591-597
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    • 2014
  • A poled lead zirconate titanate (PZT) rectangular parallelepiped specimen was subjected to through-thickness electric fields at five loading rates and four temperatures. The rates of the electric field were 0.01, 0.10, 0.25, 0.50, and $1.00MVm^{-1}s^{-1}$; the temperatures were 20, 50, 80, and $110^{\circ}C$. From the measured polarization hysteresis responses, the so-called reference remnant polarization and strains were calculated. Using the calculated reference remnant polarization hysteresis loops, the effects of loading rates and temperature were discussed; using the calculated reference remnant strains, strain butterfly loops were calculated and compared with observations.

Experiment and Prediction of Nonlinear Behavior at High Temperatures of Ferroelectric Ceramics Switched by Electric Field at Room Temperature

  • Ji, Dae Won;Kim, Sang-Joo
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.235-242
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    • 2017
  • Changes in polarization and thermal expansion coefficients during temperature increase of a poled lead zirconate titanate (PZT) cube specimen switched by an electric field at room temperature are measured. The measured data are analyzed to construct governing differential equations for polarization and strain changes. By solving the differential equations, an experimental formula for the high temperature behavior of ferroelectric materials is obtained. It is found that the predictions by the formula are in good agreement with measures. From the viewpoint of macroscopic remnant state variables, it appears that the processes of electric field-induced switching at different temperatures are identical and independent of temperature between $20^{\circ}C$ and $110^{\circ}C$.

Low Temperature Sintering of PZTN by the Liquid Phase Transient Processing (액상천이공정에 의한 PZTN의 저온소결에 관한 연구)

  • Kim, Chan-Yeong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.12
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    • pp.593-598
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    • 2001
  • Transient liquid phase processing was investigated to decrease processing temperatures while maintaining useful piezoelectric properties in the lead zirconate titanate (PZT) system. Niobium oxide$(Nb_2O_5)$ modified crystalline PZT (PZTN) powder was combined with lead silicate $(PS; PbO-SiO_2)$ glass powder and crystalline titania, zirconia, and niobia. Firing above the melting temperature of the lead silicate $(PS; Tm \risingdotseq\; 714^{\circk}C)$ resulted in liquid phase densification of the PZTN followed by dissolution of the titania, zirconia, and niobia into the liquid phase, and crystallization of additional PZTN. The addition of crystalline titania, zirconia, and niobia to react with the lead oxide from the lead silicate phase resulted in an increase in the dielectric and Piezoelectric properties.

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Ferroelectirc Properties of Eu-doped PZT Thin Films (Eu 첨가에 따른 PZT 박막의 강유전 특성)

  • 김창일;손영훈;김경태;김동표;이병기
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.7
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    • pp.611-615
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    • 2003
  • Eu-doped lead zirconate titanate(Pb$\sub$1.1/(Zr$\sub$0.6/Ti$\sub$0.4/)O$_3$; PZT) thin films on the Pt/Ti/SiO$_2$/Si substrates prepared by a sol-gel method. The effect on structural and electrical properties of PZT thin films measured according to the Eu content. Eu-doping altered significantly dielectric and ferroelectric properties. The remanent polarization and the coercive field decreased with the increasing Eu content. The dielectric constant and the dielectric loss of PZT thin films decreased with the increasing Eu content. The 0.5 mol% of Eu-doped PZT thin film showed improved fatigue characteristic comparing to the undoped PZT thin film.

PROPOSE NEW MIXTURE TARGET FOR LOW-TEMPERATURE AND HIGH- RATE DEPOSITION OF PZT THIN FILMS BY REACTIVE SPUTTERING

  • Hata, Tomonobu;Zhang, WeiXiao;Sasaki, Kimihiro
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.330-337
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    • 1996
  • A rf reactive sputter deposition technique was adopted to deposit ferroelectric lead zirconate titanate (PZT) thin films with high rate from a ZrTi alloy target combined with PbO pellets. Deposition characterisitics including the effects of PbO are ratio were discussed. A new deposition mode called the quasi-metallic mode was observed. Perovskite PZT films were prepared at a growth temperature as low as$ 450^{\circ}C$. However, because the target structure is unstable, weproposed a mixture target consisted of Zr, Ti and PbO. Fundamental experiments were investigated using the powder target. Perovskite PZT film could be obtained at $450^{\circ}C$ with better electrical properties also.

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Electrical and Piezoelectric Properties on the Piezoceramics PZT Substituted for B-Sites (압전 세라믹(PZT)의 B-Site 치환에 따른 전기 및 압전 특성)

  • 이수호;박준범;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.05a
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    • pp.133-136
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    • 1992
  • Electrical resistivity and piezoelectric properties were investigated in Lead Zirconate-Titante(PZT) with Nb$_2$O$\sub$5/dopant, fabricated from conventional mixed-oxide powders and molten salt synthesis. The resistivity and electromechanical coupling factor(K$\sub$p/) were increased with increasing Nb content. The reason for increasing of the electrical resistivity below the Curie Temperature(TC). It is believed that the Curie Temperature(Tc). It is believed that the p-type electrical conduction in PZT is due to lead vacancies. The electromechanical coupling factor(K$\sub$p/) and piezoelectric constant d$\sub$33/ were improved. This behavior can be explained as a compensation effect and Nb$\^$5+/ can serve as a donar and contribute electrons to the conduction process. As a result, the optimized Nb$_2$O$\sub$5/ dopants on the PZT specimens were 0.75 wt%.

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The Piezoelectric Characteristics of PZ-PT-PMS Ceramics for Large Displacement Application (고진동레벨에서의 PZ-PT-PMS계 세라믹의 압전특성)

  • 이동준;권순석;신달우;정수현;임기조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.250-253
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    • 1997
  • Generally, Piezoelectric ceramics based lead-zirconate-titanate(PZT) system are well known to use in high power devices. In this pacer. Pb(Mn$\sub$1/3//Sb$\sub$2/3/)O$_3$(PMS) ceramics which have been shown to be adaptable for a high power usage is introduced. The stability of piezoelectric properties in PZ-PT-PMS solid solution system such as piezoelectric constants. electromechanical coupling coefficient and mechanical quality factor is discussed by the addition effect of CeO$_2$ as a additive. The CeO$_2$ ratio ranges from 0 to 2 wt%. The resonant and anti-resonant frequencies. mechanical quality factor, and force factor are also measured as a function of vibration velocity

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