• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.9
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• pp.546-550
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• 2017

Ferroelectric properties are governed by domain structures and domain wall motions, so it is of significance to understand domain evolution processes under mechanical stress. In the present study, in situ piezoresponse force microscopy (PFM) observation under compressive stress was carried out for a near-morphotropic PZT. Both $180^{\circ}$ and $non-180^{\circ}$ domain structures were observed from PFM images, and their habit planes were identified using electron backscatter diffraction in conjunction with PFM data. By externally applied mechanical stress, needle-like $non-180^{\circ}$ domain patterns were broadened via domain wall motions. This was interpreted via phenomenological approach such that the total energy minimization can be achieved by domain wall motion rather than domain nucleation mainly due to the local gradient energy. Meanwhile, no motion was observed from curvy $180^{\circ}$ domain walls under the mechanical stress, validating that $180^{\circ}$ domain walls are not directly influenced by mechanical stress.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.164-164
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• 2009

A multilayer piezoelectric transformer(MPT) for step-down voltage was made by ceramic stack process. And then, the characteristics of piezoelectric transformer, such as resonance frequency, matching impedance, electro-mechanical coupling coefficient, voltage gain, heat generation and efficiency, are analyzed. The piezoelectric transformer consists of a lead zirconate titanate ceramic with a high electromechanical quality factor. The piezoelectric transformer, with a multilayered construction in the thickness direction, was formed with dimensions 15mm long, 15mm wide and 5mm thick.

• Journal of the Korean Ceramic Society
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• v.29 no.11
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• pp.870-876
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• 1992

Lead lanthanum zirconate titanate (PLZT, 6/65/35) powders, crack-free and dense thin films have been prepared by polymeric sol-gel process. Pyrolysis of the gel, crystallization and optical transmittance behavior of the PLZT thin film onto sapphire substrate have been studied. Esterification occurs during synthesis of PLZT complexation. Crystalline Pb phase was transiently formed near 450$^{\circ}C$. Content of perovskite phase in the films were increased with increasing thickness of film, but the kinetics of formation of perovskite phase in films was slower than that of powders. Transmittance of the films was decreased with increasing the temperature of heat treatment. Ferroelectric hysteresis loop measurements indicated increments of remanent polarization and coercive field for plenty more of perovskite phase.

• Journal of the Korean Ceramic Society
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• v.26 no.5
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• pp.601-608
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• 1989

Electrical properties of ZrF4-based heavy metla fluoride glasses were measured by the ac complex impedance method. The effects of alkali and chloride ions addition into fluoro zirconate glasses on the electrical conductivity were examined. The electrical conductivities of fluoride glasses show Arrhenian behavior in the temperature range of the experiment and were decreased by the addition of sodium fluoride up to 15mol%. Mixed alkali substitution resulted in conductivity minimum at intermediate composition which is commonly observed as mixed alkali effect' in alkali oxide glasses. Chloride ion substituted for fluoride ion was found to lower the conductivity.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2005.05a
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• pp.188-191
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• 2005

Taguchi method is used to determine the optimal configuration of PZT (Lead Zirconate-Titanate) patch on the host structure for improving the performance of piezoelectric shunt system. The charges generated on the surface of PZT patch are selected to be the objective function in the Taguchi method. Full three dimensional finite element models are used to simulate vibration of smart panel and to obtain the admittance of the piezoelectric shunt system. Using Taguchi method in Minitab, the optimal model is obtained. The experiment with piezoelectric shunt circuit is performed to verify the validity of the optimal model comparing with initial model.

• Proceedings of the KIEE Conference
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• 2011.07a
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• pp.1434-1435
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• 2011

In this study, NKN-LST ceramics were prepared by a conventional mixed oxide method and their structure and piezoelectric properties were investigated with the variations of sintering temperature. It was observed that the various sintering temperatures influenced the electrical properties and structural properties of the NKN-LST ceramics. It was found that the piezoelectric properties of NKN-LST ceramic sintered at $1080^{\circ}C$ for 4h has a piezoelectric constant and a planar electromechanical coupling coefficient of 161pC/N and 0.311% respectively. This ceramics look very promising as possible, practicable, lead-free replacements for lead zirconate titanate.

• Proceedings of the KIEE Conference
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• 1992.07b
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• pp.721-723
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• 1992

The electrical resistivity and piezoelectric properties have been studied for Lead Zirconate-Titanate(PZT) with $Nb_2O_5$ dopant, fabricated from conventional mixed-oxide powders and molten salt synthesis. The resistivity and electromechanical coupling factor(Kp) were increased with increasing Nb contents. The reason for increasing of the electrical resistivity below the Curie Temperature(Tc), It is believed that the p-type electrical conduction in PZT is caused by the lead vacancies. The electromechanical coupling factor(Kr) and piezoelectric constant $d_{33}$ were improved by Nb additives. This behavior can be explained as a compensation effect and $Nb^{5+}$ can serve as a donar and contribute electrons to the conduction process. As a result, the optimized $Nb_2O_5$ dopants on the PZT specimens were 0.75 wt%.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.2
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• pp.94-97
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• 2018

Lead zirconate titanate/poly-vinylidene fluoride (PZT/PVDF) piezoelectric devices were fabricated by incorporating carbon nanotubes (CNTs), for use as flexible energy harvesting devices. CNTs were added to maximize the formation of the ${\beta}$ phase of PVDF to enhance the piezoelectricity of the devices. The phase transition of PVDF induced by the addition of CNTs was confirmed by analyzing the X-ray diffraction patterns, scanning electron microscopy images, and atomic force microscopy images. The enhanced output efficiency of the PZT/PVDF piezoelectric devices was confirmed by measuring the output current and voltage of the fabricated devices. The maximum output current and voltage of the PZT/PVDF piezoelectric devices was 200 nA and 350 mV, respectively, upon incorporation of 0.06 wt% CNTs.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.14 no.3
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• pp.32-37
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• 2005

Several types of smart materials and control scheme are available to adjust the structure actively in various external disturbances. A control scheme was introduced for a specific material. But the effectiveness of the control scheme has some limitation according to the choice of the smart materials and the response of the structure. The ER(Electrorheological) fluid is adequate for a large control force, and the PZT(lead zirconate titanate) patches are suitable for small but arbitrary control force at any point of the structure. It can be used for active control of structure by changing the dynamic characteristics of the structure. But it has some difficulty in suppressing the excited vibration in broad band. To compensate this resonance of the controlled structure, a hybrid controller was constructed using PPF(Positive position feedback) control with PZT and ER fluid control.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.05a
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• pp.263-263
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• 2007

In the future, self-contained sensors and processing units will need on-board, renewable power supplies to be truly autonomous. One way of supplying such power is through energy harvesting, processes by which ambient forms of energy are converted into electricity. One energy harvesting technique involves converting kinetic energy, in the form of vibrations, into electrical energy through the use of piezoelectric materials. Researchers are currently investigating how piezoelectric materials can be used to harvest power. This study examines the use of auxiliary structures, consisting of a mechanical fixture and a lead zirconate/lead titanate (PZT) piezoelectric element, which can be attached to any boundary conditions vibrating beam of the any boundary conditions. Adjusting various boundary conditions of these structures can maximize the strain induced in the attached PZT element and improve power output.