• Title/Summary/Keyword: Zirconate

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Effect of PZN addition on microstructure of PZT thick films by aerosol deposition process (에어로졸 증착법에 의한 PZT 후막의 미세구조에 미치는 PZN 첨가의 영향)

  • Jang, Joo-Hee;Park, Yoon-Soo;Park, Dong-Soo;Park, Chan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.1
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    • pp.14-20
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    • 2018
  • Lead zinc niobate (PZN) added lead zirconate titanate (PZT) thick films with thickness of $5{\sim}10{\mu}m$ were fabricated on silicon and sapphire substrates using aerosol deposition method. The contents of PZN were varied from 0 %, 20 % and 40 %. The initial particles (PZT, 2PZN-8PZT, 4PZN-6PZT) had irregular shape and submicron sizes. The as-deposited film had fairly dense microstructure without any crack, and showed only a perovskite single phase formed with nano-sized grains. The as-deposited films on silicon were annealed at the temperatures of $700^{\circ}C$, and the films deposited on sapphire were annealed at $900^{\circ}C$ in the electrical furnace. The effects of PZN addition on the microstructural evolution were observed using by FE-SEM and HR-TEM.

DLC Structure Layer for Piezoelectric MEMS Switch (압전 MEMS 스위치 구현을 위한 DLC 구조층에 관한 연구)

  • Hwang, Hyun-Suk;Lee, Kyong-Gun;Yu, Young-Sik;Lim, Yun-Sik;Song, Woo-Chang
    • Journal of Satellite, Information and Communications
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    • v.6 no.1
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    • pp.28-31
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    • 2011
  • In this paper, a new set of structural and sacrificial material that is diamond like carbon (DLC)/photoresist for high performance piezoelectric RF-MEMS switches which are actuated in d33 mode is suggested. To avoid curing problem of photoresist sacrificial layer, DLC structure layer is deposited at room temperature by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) method. And lead zirconate titanate (PZT) piezoelectric layer is deposited on structure layer directly at room temperature by rf magnetron sputtering system and crystallized by rapid thermal annealing (RTA) equipment. Particular attention is paid to the annealing of PZT film in order to crystallize into perovskite and the variation of mechanical properties of DLC layer as a function of annealing temperature. The DLC layer shows good performance for structure layer in aspect to Young's modulus and hardness. The fabrication becomes much simpler and cheaper with use of a photoresist.

Phase Evolution and Thermal Conductivities of (La1-xGdx)2Zr2O7 Oxides for Thermal Barrier Coatings (열차폐코팅용 (La1-xGdx)2Zr2O7 산화물의 상형성과 열전도도)

  • Kwon, Chang-Sup;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Jang, Byung-Koog;Kim, Seong Won
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.429-434
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    • 2012
  • With increase in operating temperature of gas turbine for higher efficiency, it is necessary to find new materials of TBC for replacement of YSZ. Among candidate materials for future TBCs, zirconate-based oxides with pyrochlore and fluorite are prevailing ones. In this study, phase structure and thermal conductivities of $(La_{1-x}Gd_x)_2Zr_2O_7$ oxide system are investigated. $(La_{1-x}Gd_x)_2Zr_2O_7$ system are comprised by selecting $La^{3+}/Gd^{3+}$ as A-site ions and $Zr^{4+}$ as B-site ion in $A_2B_2O_7$ pyrochlore structures. With powder mixture from each oxide, $(La_{1-x}Gd_x)_2Zr_2O_7$ oxides are fabricated via solid-state reaction at $1600^{\circ}C$. Either pyrochlore or fluorite or mixture of both appears after heat treatment. For the developed phases along $(La_{1-x}Gd_x)_2Zr_2O_7$ compositions, thermal conductivities are examined, with which the potential of $(La_{1-x}Gd_x)_2Zr_2O_7$ compositions for TBC application is also discussed.

Simulation of PZT monitoring of reinforced concrete beams retrofitted with CFRP

  • Providakis, C.P.;Triantafillou, T.C.;Karabalis, D.;Papanicolaou, A.;Stefanaki, K.;Tsantilis, A.;Tzoura, E.
    • Smart Structures and Systems
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    • v.14 no.5
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    • pp.811-830
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    • 2014
  • A numerical study has been carried out to simulate an innovative monitoring procedure to detect and localize damage in reinforced concrete beams retrofitted with carbon fiber reinforced polymer (CFRP) unidirectional laminates. The main novelty of the present simulation is its ability to conduct the electromechanical admittance monitoring technique by considerably compressing the amount of data required for damage detection and localization. A FEM simulation of electromechanical admittance-based sensing technique was employed by applying lead zirconate titanate (PZT) transducers to acquire impedance spectrum signatures. Response surface methodology (RSM) is finally adopted as a tool for solving inverse problems to estimate the location and size of damaged areas from the relationship between damage and electromechanical admittance changes computed at PZT transducer surfaces. This statistical metamodel technique allows polynomial models to be produced without requiring complicated modeling or numerous data sets after the generation of damage, leading to considerably lower cost of creating diagnostic database. Finally, a numerical example is carried out regarding a steel-reinforced concrete (RC) beam model monotonically loaded up to its failure which is also retrofitted by a CFRP laminate to verify the validity of the present metamodeling monitoring technique. The load-carrying capacity of concrete is predicted in the present paper by utilizing an Ottosen-type failure surface in order to better take into account the passive confinement behavior of retrofitted concrete material under the application of FRP laminate.

Design and Evaluation of a Piezoelectric Energy Harvester Produced with a Finite Element Method

  • Kim, Chul-Min;Kim, Chang-Il;Lee, Joo-Hee;Paik, Jong-Hoo;Cho, Jeong-Ho;Chun, Myoung-Pyo;Jeong, Young-Hun;Lee, Young-Jin
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.5
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    • pp.206-211
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    • 2010
  • Piezoelectric energy harvesting uses piezoelectric, which is able to convert unused mechanical vibration energy to electrical energy, such as with motor and machinery. The piezoelectric energy harvester was constructed with a cantilever made of lead zirconate titanate with a metal plate. The primary material was soft lead zirconium titanate (PZT-5H) due to the large strain availability, acceptable mechanical strength and high piezoelectric constant. This technique's drawback is that the energy efficiency is lower than the other energy harvesting methods, but this study increases the output electric power efficiency by analyzing a finite element method for the structure of the piezoelectric energy harvester. We manufactured two cantilever types as follows: the L-60 and L-33 bimorph piezoelectric energy harvesters. Their resulting energy harvesters were able to obtain high voltage values as follows: 27.4 mV and 40.6 mV. Moreover, these results have a similar band of resonance frequency it comparison to the simulation. Consequently, this study was confirmed with validity. The output electric powers of the L-60 and L-33 types have 3.1 mW/s and 5.8 mW/s with 47 Hz and 148 Hz of resonance frequency and then, the load resistivities were $100k\Omega$ and $10k\Omega$, respectively.

Evaluation of Nondestructive Damage Sensitivity on Single-Basalt Fiber/Epoxy Composites using Micromechanical Test and Acoustic Emission with PZT and PVDF Sensors (PZT 및 PVDF 센서에 따른 음향방출과 Micromechanical 시험법을 이용한 단일 Basalt 섬유 강화 에폭시 복합재료의 비파괴 손상감지능 평가)

  • Kim, Dae-Sik;Park, Joung-Man;Jung, Jin-Kyu;Kong, Jin-Woo;Yoon, Dong-Jin
    • Composites Research
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    • v.17 no.4
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    • pp.61-67
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    • 2004
  • Nondestructive damage sensitivity on single-basalt fiber/epoxy composites was evaluated by micromechanical technique and acoustic emission (AE). Piezoelectric lead-zirconate-titanate (PZT), polyvinylidene fluoride (PVDF) and poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) copolymer were used as AE sensor, respectively. In single-fiber composite, the damage sensing with different sensor types were compared to each other. Piezoelectric PVDF polymer sensor was embedded in and attached on the composite, whereas PZT sensor was only attached on the surface of specimen. In case of embedded polymer sensors, responding sensitivity was higher than that of the attached case. It can be due to full constraint inside specimen to transfer elastic wave coming from micro-deformation. For both the attached and the embedded cases, the sensitivity of P(VDF-TrFE) sensor was almost same as that of conventional PVDF sensor.

Structural health monitoring of high-speed railway tracks using diffuse ultrasonic wave-based condition contrast: theory and validation

  • Wang, Kai;Cao, Wuxiong;Su, Zhongqing;Wang, Pengxiang;Zhang, Xiongjie;Chen, Lijun;Guan, Ruiqi;Lu, Ye
    • Smart Structures and Systems
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    • v.26 no.2
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    • pp.227-239
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    • 2020
  • Despite proven effectiveness and accuracy in laboratories, the existing damage assessment based on guided ultrasonic waves (GUWs) or acoustic emission (AE) confronts challenges when extended to real-world structural health monitoring (SHM) for railway tracks. Central to the concerns are the extremely complex signal appearance due to highly dispersive and multimodal wave features, restriction on transducer installations, and severe contaminations of ambient noise. It remains a critical yet unsolved problem along with recent attempts to implement SHM in bourgeoning high-speed railway (HSR). By leveraging authors' continued endeavours, an SHM framework, based on actively generated diffuse ultrasonic waves (DUWs) and a benchmark-free condition contrast algorithm, has been developed and deployed via an all-in-one SHM system. Miniaturized lead zirconate titanate (PZT) wafers are utilized to generate and acquire DUWs in long-range railway tracks. Fatigue cracks in the tracks show unique contact behaviours under different conditions of external loads and further disturb DUW propagation. By contrast DUW propagation traits, fatigue cracks in railway tracks can be characterised quantitatively and the holistic health status of the tracks can be evaluated in a real-time manner. Compared with GUW- or AE-based methods, the DUW-driven inspection philosophy exhibits immunity to ambient noise and measurement uncertainty, less dependence on baseline signals, use of significantly reduced number of transducers, and high robustness in atrocious engineering conditions. Conformance tests are performed on HSR tracks, in which the evolution of fatigue damage is monitored continuously and quantitatively, demonstrating effectiveness, adaptability, reliability and robustness of DUW-driven SHM towards HSR applications.

Proposal of Equation on Changable Performance Stroke (Δ h) and Radius of Curvature (ρ) According to the CERP Ply Orientation in PZTCA (CFRP 배향각에 따라 변화하는 PZTCA의 작동변위(Δ h)와 곡률반경(ρ)의 관계식 제안)

  • Hong Jung-Hwa;Yoon Kwang-Joon;Kim Cheol-Woong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.3 s.246
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    • pp.318-327
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    • 2006
  • Due to the diversified use of recent Piezoelectric Zirconate Titanate Composite Actuate. (PZTCA), various PZTCAs with the different ply orientation of the fiber layer have been applied. For this reason, the applicable bending moment equation is necessary even though the fiber layer ply orientation and the laminate configuration are changed. The aim of this research is to evaluate the relationship between the total effective moment $(M^E)$ and Bernoulli-Euler bending moment (M) when the ply orientations of UD CFRP are changed. In conclusions, firstly, as the performance test results by the CFRP ply orientation, the performance of [0] and [90] were stable. However, while the performance of [+45] was suddenly decreased after 5 hours. Secondly, the change of $(M^E)$ by the CFRP ply orientation was evaluated. As the CFRP ply orientation was increased from [0] to [+60], the $(M^E)$ were gradually decreased. However, they became a little bit increased from [+60] to [90]. Finally, after the change of M by the CFRP ply orientation was evaluated, it was found that $M^E=2.2M$ was valid for just [0] and that there was a relationship between $M^E$ and M according to the ply orientation.

Modal Strain Energy-based Damage Monitoring in Beam Structures using PZT's Direct Piezoelectric Response (PZT 소자의 정압전 응답을 이용한 보 구조물의 모드 변형에너지기반 손상 모니터링)

  • Ho, Duc-Duy;Lee, Po-Young;Kim, Jeong-Tae
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.25 no.1
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    • pp.91-99
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    • 2012
  • The main objective of this study is to examine the feasibility of using lead zirconate titanate (PZT)'s direct piezoelectric response as vibrational feature for damage monitoring in beam structures. For the purpose, modal strain energy (MSE)-based damage monitoring in beam structures using dynamic strain response based on the direct piezoelectric effect of PZT sensor is proposed in this paper. The following approaches are used to achieve the objective. First, the theoretical background of PZT's direct piezoelectric effect for dynamic strain response is presented. Next, the damage monitoring method that utilizes the change in MSE to locate of damage in beam structures is outlined. For validation, forced vibration tests are carried out on lab-scale cantilever beam. For several damage scenarios, dynamic responses are measured by three different sensor types (accelerometer, PZT sensor and electrical strain gage) and damage monitoring tasks are performed thereafter. The performance of PZT's direct piezoelectric response for MSE-based damage monitoring is evaluated by comparing the damage localization results from the three sensor types.

Fabrication and Characterization of La2Zr2O7/YSZ Double-Ceramic-Layer Thermal Barrier Coatings Fabricated by Suspension Plasma Spray (서스펜션 플라즈마 용사법을 이용한 La2Zr2O7/YSZ 2층세라믹 열차폐코팅의 제조와 특성평가)

  • Kwon, Chang-Sup;Lee, Sujin;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Jang, Byung-Koog;Kim, Seongwon
    • Journal of the Korean institute of surface engineering
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    • v.48 no.6
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    • pp.315-321
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    • 2015
  • Rare-earth zirconates, such as $La_2Zr_2O_7$ and $Gd_2Zr_2O_7$, have been investigated as one of the candidates for replacing conventional yttria-stabilized zirconia (YSZ) for thermal barrier coating (TBC) applications at higher turbine inlet temperatures. In this study, double-ceramic-layer (DCL) TBCs of YSZ 1st layer and $La_2Zr_2O_7$ top coat layer are fabricated by suspension plasma spray with serial liquid feeders. Microstructures, hardness profiles, and thermal durability of DCL-TBCs are also characterized. Fabricated DCL-TBCs of YSZ/$La_2Zr_2O_7$ exhibit excellent properties, such as adhesion strength (>25 MPa) and electrical thermal fatigue (~1429 cycles), which are comparable with TBCs fabricated by atmospheric plasma spray.