• Title/Summary/Keyword: Zinc-Aluminum

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Characterization of Al:ZnO thin films deposited at different oxygen pressure (산소 분위기압의 변화에 따른 Al:ZnO 박막의 특성)

  • No, I.J.;Kim, Il;Shin, P.K.;Song, J.H.;Kim, Y.W.;Kim, C.Y.;Jeung, Y.S.
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1349-1350
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    • 2007
  • Epitaxial thin films of aluminum-doped zinc oxide (AZO) have been deposited on commercial corning glass using an Nd:YAG pulsed laser deposition technology. The structural, electrical and optical properties of these films were investigated as a function of oxygen pressure. The experimental results show that the electrical resistivity of films deposited at 5 mTorr with substrate temperature of $300^{\circ}C$ were $4.633{\times}10^{-4}$. The average transmission of AZO thin films in the visible range were over 90%.

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A Study of Heavy Metal Contents in Shellfished of Various Areas in Jeonbuk (전북 해안 지역별 패류의 중금속 함량)

  • 김인숙;한성희
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.5
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    • pp.758-761
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    • 2000
  • This study was performed to investigate the contamination levels of harmful heavy metals that sampled from June. 1 to June. 31, 1999, at 3 areas in Jeonbuk west cost area. The heavy metal contents were determinated by ICPS (Inductively Coupled Plasma Spectrometer) method. The levels of total lead, cadmium, aluminum, zinc and copper were determined and the results were summarized as follows: The minimum and maximum values (ppm) of 3 areas of shellfishes (shortneck clam, hard clam, cockle clam, snail and top sell) were Pb: 1.29~4.35, Cd:0.12~0.37, Al: 9.45~54.06, Zn: 9.65~15.14, Cu: 0.62~1.64 ppm.

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A Study on the Effect of Process Pressure on AZO Thin Films Sputtered for the Windows Layers of CIGS Solar Cells (CIGS 태양전지의 윈도우 층에 적용 가능한 스퍼터링으로 증착한 AZO 박막의 공정압력의 영향에 따른 특성 연구)

  • Yoon, Yeo-Tak;Cho, Eou-Sik;Kwon, Sang-Jik
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.2
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    • pp.89-93
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    • 2017
  • For various process pressures, aluminum doped zinc oxide(AZO) films were deposited by in-line pulsed-DC sputtering. The deposited AZO films were optically and electrically investigated and analyzed for the window layers of CIGS solar cell systems. As the pressure was increased from 9 mtorr to 15 mtorr, the thickness of AZO was decreased as a result of scattering and its sheet resistance was rapidly increased. The transmittance of AZO was slightly decreased as the pressure was increased and the calculation of figure of merit(F.O.M) was dependent on the sheet resistance. The structural characteristics of AZO thin films analyzed by X-ray diffraction(XRD) showed no significant dependency according to the pressure.

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Anti Corrosive Performance of Al and Zn Coatings Deposited by Plasma Arc Thermal Spray Process in Artificial Ocean Water (인공해양환경에서 플라즈마 아크 용사 공법이 적용된 Al 및 Zn 코팅의 부식 방지 성능 평가)

  • Adnin, Raihana Jannat;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.52-53
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    • 2020
  • The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.

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Performance of Al-Zn Coating by Arc Thermal and Plasma arc Thermal Spray Processes in 3.5% NaCl Solution (3.5% NaCl에서 Arc Thermal and Plasma Arc Spray 공법이 적용된 Al- Zn 코팅 강재의 내 식 성능 평가에 관한 연구)

  • Jannat, Adnin Raihana;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.17-18
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    • 2021
  • In the present study, Al-Zn coating was deposited by Arc thermal (AT) and plasma arc thermal (PAT) spray processes, and their corrosion characteristics were studied in 3.5% NaCl through electrochemical impedance spectroscopy (EIS), scanning electron microscope (SEM) and mechanical tests. The bond adhesion result showed that plasma arc sprayed coating had a higher value attributed to compact, dense, and less porous coating compared to arc thermal spray coating which contains defects/pores and uneven morphology as revealed by scanning electron microscope analysis. Electrochemical results revealed that the plasma arc sprayed coating had a high polarization resistance at early stage of immersion, suggesting its excellent corrosion protection performance.

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Stress Evaluation to Heavy Metal Exposure using Molecular Marker in Chironomus riparius (분자지표 유전자 발현을 통한 Chironomus riparius 중금속 노출 스트레스 평가)

  • Kim, Won-Seok;Park, Kiyun;Kwak, Ihn-Sil
    • Korean Journal of Ecology and Environment
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    • v.53 no.2
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    • pp.165-172
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    • 2020
  • Heavy metals are common pollutants in the freshwater environment and have toxicological effect in habitat organisms. The heavy metals highly accumulated in sediment and organism, and observed various physiological responses. In this study, we investigated the molecular response to heavy metal toxicity (Al, Aluminum; Cr, Chromium; Cu, copper; Mn, Manganese; Zn, Zinc) through expression of heat shock protein 40, 70, 90 (HSP40, 70, 90), cytochrome 450 (CYP450), Glutathione S-transferase (GST) and Serine-type endopeptidase (SP). HSPs showed up-regulation in Cu and Zn exposures. Furthermore, HSPs expression in treated groups tended to be higher than the control group. The tendency of CYP450 and GST mRNA expression was higher for Cr and Cu than for other exposure group. The expression of SP gene was low at Al exposure and other group were measured to be similar to control. These results suggest that heavy metal toxicity in freshwater ecosystem may affect physiological and molecular process. Also, the comprehensive gene expression in the aquatic midge Chironomus riparius give useful information to potential molecular biomarkers for assessing heavy metal toxicity.

Microstructure analyses of aluminum nitride (AlN) using transmission electron microscopy (TEM) and electron back-scattered diffraction (EBSD) (투과전자현미경과 전자후방산란회절을 이용한 AlN의 미세구조 분석)

  • Joo, Young Jun;Park, Cheong Ho;Jeong, Joo Jin;Kang, Seung Min;Ryu, Gil Yeol;Kang, Sung;Kim, Cheol Jin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.127-134
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    • 2015
  • Aluminum nitride (AlN) single crystals have attracted much attention for a next-generation semiconductor application because of wide bandgap (6.2 eV), high thermal conductivity ($285W/m{\cdot}K$), high electrical resistivity (${\geq}10^{14}{\Omega}{\cdot}cm$), and high mechanical strength. The bulk AlN single crystals or thin film templates have been mainly grown by PVT (sublimation) method, flux method, solution growth method, and hydride vapor phase epitaxy (HVPE) method. Since AlN suffers difficulty in commercialization due to the defects that occur during single crystal growth, crystalline quality improvement via defects analyses is necessary. Etch pit density (EPD) analysis showed that the growth misorientations and the defects in the AlN surface exist. Transmission electron microscopy (TEM) and electron back-scattered diffraction (EBSD) analyses were employed to investigate the overall crystalline quality and various kinds of defects. TEM studies show that the morphology of the AlN is clearly influenced by stacking fault, dislocation, second phase, etc. In addition EBSD analysis also showed that the zinc blende polymorph of AlN exists as a growth defects resulting in dislocation initiator.

Development of Single-Frame PIV Velocity Field Measurement Technique Using a High Resolution CCD Camera (고해상도 CCD카메라를 이용한 Single-Frame PIV 속도장 측정기법 개발)

  • Lee, Sang-Joon;Shin, Dae-Sig
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.1
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    • pp.21-28
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    • 2000
  • Although commercial PIV systems have been widely used for the non-intrusive velocity field measurement of fluid flows, they are still under development and have considerable room for improvement. In this study, a single-frame double-exposure PIV system using a high-resolution CCD camera was developed. A pulsed Nd:Yag laser and high-resolution CCD camera were synchronized by a home-made control circuit. In order to resolve the directional ambiguity problem encountered in the single-frame PIV technique, the second particle image was genuinely shifted in the CCD sensor array during the time interval dt. The velocity vector field was determined by calculating the displacement vector at each interrogation window using cross-correlation with 50% overlapping. In order to check the effect of spatial resolution of CCD camera on the accuracy of PIV velocity field measurement, the developed PIV system with three different resolution modes of the CCD camera (512 ${\times}$ 512, lK ${\times}$ IK, 2K ${\times}$ 2K) was applied to a turbulent flow which simulate the Zn plating process of a steel strip. The experimental model consists of a snout and a moving belt. Aluminum flakes about $1{\mu}m$ diameter were used as scattering particles for the liquid flow in the zinc pot and the gas flow above the zinc surface was seeded with atomized olive oil with an average diameter of 1-$3{\mu}m$. Velocity field measurements were carried out at the strip speed $V_s$=1.0 m/s. The 2K ${\times}$ 2K high-resolution PIV technique was significantly superior compared to the smaller pixel resolution PIV system. For the cases of 512 ${\times}$ 512 and 1K ${\times}$ 1K pixel resolution PIV system, it was difficult to get accurate flow structure of viscous flow near the wall and small vortex structure in the region of large velocity gradient.

Evaluation of the Corrosion Resistance of Steel Coated with Zinc Using a Cr-free Coating Solution as a Function of Heat Treatment Time (Cr-free 코팅액에 의한 아연도금강판의 건조시간에 따른 내식특성)

  • Seo, Hyun-Soo;Moon, Hee-Joon;Kim, Jong-Soon;Ahn, Seok-Hwan;Moon, Chang-Kwon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.24 no.5
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    • pp.67-74
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    • 2010
  • Chromate conversion coating is a coating technique used to passivate aluminum, zinc, cadmium, copper, silver, magnesium, tin, and their alloys to slow corrosion. The process uses various toxic chromium compounds, which may include hexavalent chromium. The industry is developing less toxic alternatives in order to comply with substance restriction legislation, such as RoHS. One alternative is to develop a Cr-free coating solution. In this study, eco-friendly, Cr-free solutions (urethane solution S-700, organic/inorganic solution with Si LRO-317) were used. Test specimens were dried in a drying oven at $190^{\circ}C$ for 3, 5, 7, and 9 minutes. Corrosion resistance was evaluated using a salt spray test for 72 hours. The results show that the optimum corrosion resistance was achieved at $190^{\circ}C$ for five minutes for EGI and three or five minutes for HDGI, respectively. The adhesive properties of the two types of coating solutions were superior regardless of drying time.

Oxygen Partial Pressure Dependency of Al-donor Solubility in ZnO (ZnO내 Al-도우너의 용해도의 산소분압 의존성)

  • 김은동;김남균
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1093-1096
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    • 2001
  • The Solid solution of A $l_2$ $O_3$ into ZnO can be defined by the substitution reaction of Al$\^$3+/ ions into the Zn$\^$2+/ sites of ZnO crystal lattice, the tetrahedral interstices composed of four neighbor oxygen ions in the wurtzite structure. Since the reaction either creates new zinc vacancies or consumes the oxygen vacancies, it should be in equilibrium with ZnO nonstoichiometry and disorder reactions. The relationships make oxygen partial pressure P$\sub$o2/ control the concentrations of the vacancies and consequently limit the Al solubility in ZnO, [Al$\sub$zn/]$\sub$max/. This paper firstly reports with a refined model for defect quilibria in ZnO that the solubility decrease with the increase of P$\sub$o2/, [Al$\sub$zn/]$\sub$max/ P$\sub$o2/$\^$-1/4/.

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