• 한국자원식물학회:학술대회논문집
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• 한국자원식물학회 2018년도 춘계학술발표회
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• pp.93-93
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• 2018

This study disclosed the aqueous fruits extract of Rubus coreanus as a sustainable agent for the synthesis of Rubus coreanus zinc oxide nanoparticle (Rc-ZnO Nps) using as a reducing and capping precursor for co-precipitation method. The development of Rc-ZnO was assured by white precipitated powder and analyzed by spectroscopic and analytical instruments. The UV-visible (UV-Vis) studies indicate the maximum absorbance at 357nm which confirmed the formation of ZnO Nps and the purity, functional group and monodispersity were assured by field emission transmission electron microscopy (FE-TEM), Fourier Transform Infrared (FTIR) Spectroscopy and dynamic light scattering (DLS). The X-ray powder diffraction (XRD) data revealed the Nps is 23.16 nm in size, crystalline in nature and possess hexagonal wurtzite structure. The Rc-ZnO Nps were subjected for catalytic studies. The Malachite Green dye was degraded by Rc- ZnO NPs in both dark and light (100 W tungsten) conditions and it degraded about 90% at 4 hours observation in both cases. The biodegradable, low cost Rc-ZnO NPs can be a better weapon for waste water treatment.

• 대한금속재료학회지
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• 제46권8호
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• pp.495-505
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• 2008

With the high proportion of zinc coated steels in body-in-white assembly, newly developed surface roughness textured galvannealed steel sheets have been introduced. In this study, zinc coated and surface roughness textured steel sheets were welded by resistance spot welding to investigate its weldability including electrode wear test. Based on the results of tensile-shear test, nugget diameter changes, and electrode tip growth test, it was clear that both surface roughness textured steels (GA-T and GA-E) showed good weldability. Also, there was no large difference in weldability and electrode wear behavior between GA-T and GA-E steels which have different surface roughness morphology. An analysis of electrode degradation showed Fe and Zn penetration through the electrode tip surface at 2400 welds reached $55{\sim}60{\mu}m$ and $75{\sim}80{\mu}m$, respectively. Therefore, there is no significant effect of surface roughness morphology on spot weldability of surface roughness textured galvannealed steel sheets. However, slight difference in thickness of alloying layers existing on electrode tip was found between GA-T and GA-E steels.

• 한국세라믹학회지
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• 제14권3호
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• pp.187-192
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• 1977

For the purpose researching to the influence of tetrahedral and octahedral preference of cations of $Ni^{2+}$, $Ti^{4+}$ upon the formation and the color development of the $ZnO-SnO_2$ spinel containing $Ni^{2+}$ and $Ti^{4+}$ ions, the gradual substitution of $Ni^{2+}$ ions for $Zn^{2+}$ ions and of $Ti^{4+}$ ions for $Sn^{4+}$ ions of the spinel in NiO-ZnO-$SnO_2$-$TiO_2$ system was carried out. On samples prepared by calcining the oxide and basic cabonate mixtures at $1300^{\circ}C$ for 2 hours, the X-ray analysis, measurement of reflectance and the test of their stabilaity as a glaze pigment were also carried out. The results are summarized as follows 1) Single spinel was formed completely to x=1 in the $xNiO\cdot(2-x)ZnO\cdot{SnO}_2$system, and gave brilliant lightgreen hue. Moreover, $NiO\cdot{ZnO}\cdot{SnO}_2$ formed easily spinel than $NiO\cdot{MgO}\cdot{SnO}_2$ because Zn^{2+}$ ions had more strong tetrahedral preference than $Mg^{2+}$ ions. 2) As the gradual substitution of $Ti^{4+}$ ions for $Sn^{4+}$ ions in $NiO\cdot{MgO}\cdot{SnO}_2$ system, the spinels formed well and was nearly not changed in the hue. 3) The results of glaze test. (1) As the gradual substitution of $Ni^{2+}$ ions for $Zn^{2+}$ ions, the color changed from dull white to graish broun gradually in calcium-zinc glaze and calcium glaze, and from white to beige in tile glaze. (2) As the gradual substitution of $Ti^{4+}$ ions for $Sn^{4+}$ ions in $NiO-ZnO-SnO_2-TiO_2$ system, the color was become dull generally and was not change in tile glaze.

• Journal of Preventive Medicine and Public Health
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• 제28권2호
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• pp.398-405
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• 1995

We experienced a case of occupational lead poisoning employed in a secondary lead smelting plant for 12 years. The patient was 39-year-old male and had been felt dizziness, recent memory impairment and intermittent severe abdominal pain for 2 years. On admission, blood lead level was $92.9{\mu}g/dl$, urinary lead level was $19.9{\mu}g/l$ and zinc protoporphyrin level was $226.0{\mu}g/dl$. On the blood test, hemoglobin was 10.6g/dl and showed normocytic normochromic anemia. There were no abnormal findings in the biochemical and hormonal tests. Decrease of I.Q. and use of words in speaking were found in the psychiatric and psychologic examinations. We observed the finding of motor polyneuropathy in the nerve conduction velocity test. Computed tomographic finding showed calcification lesions in the basal ganglia, dentate nuclei, caudate nuclei, and especially characteristic multiple calcifications were located in the subcortical white matter.

• 동굴
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• 제61호
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• pp.5-16
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• 2000

Recently many environmental researcher are concerned about the ecological environment and the issue of environmental pollution in cave. In this paper we discuss about air pollution, water pollution, state of water quality, ecological environment and situation of environmental public damage in cave The concerning of air pollution in cave is mainly to the type of secondary contamination, which much is developed in various fields recently. The natural water in the most of cave is no problems but ground water has slitting with natural water during much raining period. The state of water quality is gradually contaminated with artificial environmental pollution, that is, the contents of kinds of Aluminum, Nickel, Copper, Zinc and Calcium are higher than before. On the other hand it is very important things to keep the control of constant temperature, darkness and humidity in cave. The contamination by lamp flora and even black colored contamination are appeared nowadays. The ecological environment in cave destructed by growing of mi coorganism. In fact the internal of cave is shielded with the state of climate of cave external but the environment of internal cave is contaminated, because blowing from external climate state. In addition to environmental pollution caused by carbon dioxide and body temperature of tourists. By the way eco-examination of cave is black color public damage, green color one and white color one has been discovered, so we need to have the situation of demand of environmental reservation alternatives.

• 한국기계가공학회지
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• 제5권4호
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• pp.7-12
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• 2006

Galvanized steel pipe, copper pipe and stainless steel pipe, which is being used in waterworks piping materials. In case of galvanized steel pipe, the precipitation of a product is being generated due to the pollution of the tap water, a white water phenomenon, and various corrosion reaction because a zinc ion is melted by tap water. And in case of a cupper pipe, many problems which is harm in sanitation appeared because of a inflow of harmfulness substance by a frequent accident of a water leakage. So, to prevent these problems, it is substituted for stainless steel pipe. However, those problems is still occurring because of badness of welding, a problem of a water leakage in connection part, and a increment of construction expenses. Therefore, this research has examined the laying period according to each piping thickness and a corrosion shape according to each laying depth after laying in various soils(sandy loam, loamy, clay loam, clay) using galvanized steel pipe, copper pipe, and stainless steel pipe. That is, we has studied the data which is necessary for a rational method of preserving the quality of water by examining the corrosion properties of piping materials in the soil environment which waterworks piping materials is being used.

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3644-3652
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• 2010

The metallo-$\beta$-lactamases ($M{\beta}Ls$) are clinically significant enzymes which readily hydrolyze most $\beta$-lactam antibiotics. Discovering potential inhibitors for the $M{\beta}Ls$ is an expensive, time consuming endeavor. Virtual screening can sieve out inhibitor candidates with incompatible features prior to synthesis, decreasing these costs. Using Autodock 4.0, the binding locations and energies of four previously-studied potential inhibitors and four additional compounds obtained from the National Cancer Institute (NCI) database were computationally calculated. Based on the docking models of these eight compounds, we then designed several hypothetical inhibitor structures, compounds A through F, and performed their respective docking experiments. The docking results for compound F showed that it binds to the zinc containing active sites with a lowest predicted binding energy of -6.70 kcal/mol, suggesting F is the most likely potential $M{\beta}L$ inhibitor.

• Journal of Welding and Joining
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• 제34권4호
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• pp.48-54
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• 2016

The use of Zn coated steel has increased in the automotive industry due to its excellent corrosion resistance. Conventionally the BIW(body-in-white) structure and the hang-on parts have been made of Zn coated steel and more recently Zn coated steel began to be applied in the chassis parts. During gas metal arc (GMA) welding of the chassis part, lap fillet joint used to be adopted but spatter generation and porosities are most important concerns. In the industrial applications, an intentional joint gap was made to avoid the weld defects but it is not easy to control the size of joint gap. In this research, gas tungsten arc (GTA) is combined with GMA welding where GTA precedes GMA. As pulsed arc was adopted as GMA, GTA was oscillated along the longitudinal direction by pulsing GMA, but the arc oscillation did not disturb the molten droplet transfer of GMA welding. By increasing the distance between GTA and GMA, the length of weld pool increased and porosity could be reduced. Moreover porosity in the welds was fully removed when the distance between two arcs was 15 mm.

• 분석과학
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• 제32권3호
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• pp.113-119
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• 2019

Enhancement of footwear impressions in urine on the surface of tiles by using p-dimethylaminocinnamaldehyde (DMAC), which react with urea, and ninhydrin, 1,8-diazafluoren-9-one (DFO), 1,2-indanedione/zinc (1,2-IND/Zn), which react with amino acid, was studied. As a result of comparing the application methods of reagents, the ninhydrin and the 1,2-IND/Zn were suitable for application with spray method, which is spray directly on footwear impression, DFO and DMAC were suitable for application with dry contact method, which is applying heat with press to DMAC impregnated paper on footwear impression. In addition, DMAC applied with dry contact method showed best contrast and enhancement result in both white and black colored tiles by comparing of the sensitivity by different dilution ratio of urine and the aging time of footwear impressions in urine. And the result of applied with DMAC (with dry contact method) on the floor tiles collected at various places in a building's men's and women's bathrooms, it can be successfully enhanced that footwear impressions in urine. So it is believed that the method can be used to recover footwear impressions in urine from real crime scenes.

• 자원환경지질
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• 제30권6호
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• pp.505-517
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• 1997

광신 연-아연 광산은 단층 열극을 충진한 열극 충진 광상으로서 조선계의 삼태산층과 시대미상의 서창리층에 발달된 석영과 탄산엽맥으로 이루어져 있다. 광화작용은 3회에 걸쳐 진행되었으며, 각 광화시기의 특징은 다음과 같다. 광화 I기=barren한 석영의 침전기, 광화 II기=석영과 능망간석에 수반된 연-아연 광물의 주 침전기, 광화 III기=barren한 방해석의 침전기. 특히, 연-아연 광물은 주로 광화 IIb기에 침전하였다. 유체포유물 연구에 의하면, 광화 IIb기 광화유체의 온도와 염농도는 $182^{\circ}{\sim}276^{\circ}C$와 2.7~5.4 wt. % NaCl 상당 염농도였으며, 연-아연 광물의 침전은 주로 비등작용과 더불어 후기의 천수 혼입작용에 기인하였음을 지시한다. 광화작용은 약 600~700 m의 심도에서 이루어진 것으로 판단된다. 섬아연석과 유비철석의 성분 함량을 이용하여 추정한 광화 IIb기의 황분압($log\;fs_2$)은 -15.5~11.8 atm이다. 황화물의 황동위원소 조성 (${\delta}^{34}S_{CDT}=9.0{\sim}14.5$ ‰)에 근거한 열수유체의 전(全) 황동위원소값 (${\delta}^{34}S_{{\Sigma}S}$)은 약 14 ‰로서 매우 높은데, 이는 심부 화성기원의 황이 퇴적암류내의 황산염과 다소 혼합 된 결과로 사료된다. 산소-수소 동위원소 분석 연구에 의하면, 광화유체는 낮은 수-암비 환경 하에서 주로 주변 모암인 삼태산층 (${\delta}^{18}O=20.1{\sim}24.9$ ‰)과 상당히 반응한 심부 순환 천수로부터 형성되었다. 한편, 광화유체의 산소동위원소값 (${\delta}^{18}O_{H2O}$)은 광화작용의 진행과 더불어 체계적으로 감소 (광화 I기, 14.6~10.1 ‰; 광화 IIa기, 5.8~2.2 ‰; 광화 IIb기, 0.8~-2.0 ‰; 광화 IIc기, -6.1~-6.8 ‰)하였다. 이는 열수계 내로의 천수 혼입이 시간 경과와 더불어 점진적으로 증가하였음을 지시한다.