• 한국세라믹학회지
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• 제45권3호
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• pp.157-160
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• 2008

A series of $La_2O_3$-added zincborosilicate glasses was fabricated by systematically varying $La_2O_3$ addition up to 15mol% under the constraint of a ZnO:$B_2O_3$ ratio of 1:2. The degree of water leaching after ball milling of the prepared glasses in water medium was relatively quantified by the change in zinc peak intensity in energy dispersive spectroscopy. 8mol% of $La_2O_3$ was the most efficient addition in inhibiting the glass leaching by water. The role of $La_2O_3$ in inhibiting the leaching was explained in terms of change of structural units in the glass network. When the optimum 8mol% $La_2O_3$-added ZnO-$B_2O_3$ glass was used as sintering aid for $Al_2O_3$, the fabricated alumina-glass composite at $875^{\circ}C$ demonstrated dielectric constant of 6.11 and quality factor of 15470 GHz, indicating the potential of leaching-minimized $La_2O_3-ZnO-B_2O_3$ glass for application to low temperature co-firing ceramic technology.

• 자원리싸이클링
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• 제9권3호
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• pp.29-36
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• 2000

아연제련잔사로부터 고순도 갈륨을 회수하기 위하여 알칼리 갈륨의 용매추출실험을 수행하였다 실험결과 Isopropyl Ether에 의한 갈륨의 추출시 수용액의 염산농도가 증가할수록 갈륨의 추출이 증가하여 약 7.4M/L의 염산농도에서 증가할수록 추출이 증가하여 갈륨과 분리하기가 매우 어렵다. 그러나 D2EHPA에 의해 추출할 경우 철은 염산농도 2M/L 까지는 100% 추출되고 있으나, 갈륨은 염산농도 2M/L에서는 거의 추출이 이루어지지 않아 수용액의 염산농도를 조절함으로써 갈륨과 철을 용이하게 분리. 회수할 수 있다. 아연제련잔사로부터 알칼리침출, 중화침전, Isopropyl Ether과 D2EHPA를 사용한 용매추출공정을 거쳐 갈륨을회수한 결과, 순도 99wt%, 이상의 $Ga_2O_3{\cdot}H_2O$를 얻을 수 있었다.

• 자원리싸이클링
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• 제26권1호
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• pp.30-36
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• 2017

양극흙에 함유된 금과 은을 회수하기 위해 무기산(염산, 질산, 황산)과 thiourea 및 thiosulfate에 의한 침출실험을 수행했다. 산화제를 첨가하지 않은 조건에서 금은 무기산용액에 전혀 용해되지 않았다. 3종류의 무기산의 농도가 동일한 조건에서 황산용액에서 은의 침출율이 가장 높았으며, 염산의 농도가 증가함에 따라 $AgCl_2{^-}$의 형성에 따라 은의 침출율이 증가하였다. 한편 주석은 질산용액에 전혀 용해되지 않았으나, 구리, 니켈과 아연은 본 실험조건에서 모두 용해되었다. 황산과 thiourea의 혼합용액에서 금과 은은 모두 용해되었다. Thiosulfate용액에 은의 일부가 용해되었으나, 금은 전혀 용해되지 않았다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.193-197
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• 2001

This study was carried out to recover gold, silver and other valuable metals from the printed circuit boards (PCB) of waste computers. PCB samples were crushed to under 1mm by a shredder and initially separated into 30% conducting and 70% non-conducting materials by an electrostatic separator. The conducting materials, which contained the valuable metals, were then used as the feed material for magnetic separation where it was found that 42% was magnetic and 58% non- magnetic. The non-magnetic materials contained 0.227mg/g Au and 0.697mg/g Ag. Further leaching of the non-magnetic component using 2.0M sulfuric acid and 0.2M hydrogen peroxide at 85$^{\circ}C$ extracted more than 95% copper, iron, zinc, nickel and aluminium. Au and Ag were not extracted in this solution, however, more than 95% of Au and 100% of Ag were selectively leached with a mixed solvent (0.2M ammonium thiosulfate, 0.02M copper sulfate, 0.4M ammonium hydroxide). Finally, the residues were reacted with a NaCl solution to leach out Pb while sulfuric acid was used to leach out Sn. Recoveries reached 95% and 98% in solution, respectively.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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• pp.618-623
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• 2003

Solvent extraction experiments for separation of impurities from Ni-rich solution were carried out for manufacturing of high purity Ni compounds from acid leaching solution of spent Ni-Cd secondary battery. Artificial and leaching solutions were used as aqueous phases and PC88A saponified by sodium in kerosene were used as organic phase. The extraction order is Zn>Mn>Co>Ni and extraction percentage of metal ions was increased with increase of the concentration of extractant, initial pH of aqueous phase and ratio of O/A. The separation of cobalt, zinc and manganese from nickel was effectively accomplished at the condition of extraction stage=l, O/A=1 and initial pH 5.0 with 1.0 $mol/dm^3$ PC88A saponified to $50\%$ with NaOH.

• 환경위생공학
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• 제14권3호
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• pp.71-79
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• 1999

The Hg, Cd, Cu, Mn, and Zn in bottom sediments of han river and their tributaries were analyzed to evaluate the seasonal variations of heavy metals. Leaching tests were also performed for estimation of availability of heavy metal retention in sediments. Sediments of Anyang stream showed the highest concentration of heavy metal in the sediment samples. Heavy metal concentration was heavily depended upon the heavy metal source of tributaries of han river and particle distribution. Clay and silt had higher concentration of heavy metals than very fine san and fine sand due to difference of retention capability of heavy metal. The highest concentration of heavy metal was observed in bottom sediments irrespective of sites investigated. Heavy metals and ignition loss showed positive relations, and higher relationships with p-value <0.01 were observed between copper and lead. copper and zinc, and depended on the pH condition of leaching test, and leachated fraction increased with decrease of the pH.

• 자원리싸이클링
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• 제4권1호
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• pp.46-51
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• 1995

증류공정으로 수은을 제거한 폐산화은 전지에는 은이 약 30% 이상 함유되어 있는데 이를 효과적으로 분리, 회수할 목적으로 폐전지 잔사를 질산으로 침출시켜 전지중에 함유된 금속이온들(은, 아연, 철, 니켈)의 침출율을 조사하였다. 잔사의 침출공정시 반응온도, 반응시간, 질산농도, 고액농도 등에 의한 영향을 살펴보았으며 실험결과 반응온도 40~6$0^{\circ}C$, 질산농도 2N, 고액농도 10g/200ml의 조건에서 6시간 반응 시 가장 좋은 침출율을 나타내었다. 이때 은과 아연은 99% 이상의 침출율을 나타낸 반면, 철과 니켈은 전지의 외부 합금용기로 남아있어 50% 이하의 낮은 침출율을 나타내었다.

• 한국물환경학회지
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• 제27권6호
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• pp.862-867
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• 2011

Pozzolanic-based stabilization/solidification (S/S) is an effective and economic remediation technology to immobilize heavy metals in contaminated soils. In this study, quick lime (CaO) was used to immobilize cadmium and zinc present in waste mine contaminated clayey sand soils. Addition of 5% quicklime to the contaminated soils effectively reduced heavy metal leachability after 2 bed volume operation below the drinking water regulatory limits. Lime addition was revealed to increase the immobilization for all heavy metals in tested pH ranges, so it could be an optimal choice for short-term remediation of heavy metal contaminated soil. The mass balances for these column tests show metal reduction of 92% for Cd and 87% for Zn of total resolved mass in case of 5% lime application.

• 대한환경공학회지
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• 제22권7호
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• pp.1357-1364
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• 2000

본 연구는 소각 비산재의 물리 화학적 특성이 중금속의 용출 거동에 미치는 영향을 알아보고자 수행되었다. 영향인자로는 비산재의 pH, CEC, 입자크기, 연속추출방법에 의해 분류된 중금속의 존재형태 중에서 exchangeable fraction을 고려하였다. KSLT법에 의한 중금속의 용출율은 pH에 크게 의존적이고 원소에 따라 차이를 보였다. 카드뮴과 구리의 용출율은 pH가 증가함에 따라 감소한 반면, 납과 아연은 중성 또는 강알칼리성 조건에서 증가하는 것으로 나타났는데, 중금속의 용출 거동이 용해도에 의해 제한됨을 나타내 준다. CEC가 중금속의 용출율에 미치는 영향은 pH와 비슷한 것으로 나타났다. 비산재의 입자크기 중에서 $D_{10}$은 KSLT법에 의한 중금속의 용출량과 음의 상관성을 나타내었다. Exchangeable fraction의 경우는 비산재의 CEC 값이 40 meq/100g 미만인 시료는 선형관계에 있지만, 그 외의 CEC 값에서는 비선형관계를 보여주었다.

• 환경위생공학
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• 제17권1호
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• pp.57-62
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• 2002

Carbon cast iron and Zinc coated steel were the most widely used portable water of supply and distribution Pipeline system. The leaching of red water in portable water could produce sericus environmental sanitary problems. Due to the red water was the most alternative to inner scale of metal pipeline. So this study was conducted the impact of red water on scale products, and was evaluated by the corrosive metal contaminants of 20 fears over. Surface tests, metal surface composition measurements of samples XRF, XRD, and SEM(EDS), analysis were used to investigate the corrosion characteristies of carbon cast iron and Zinc coated steel. As the contaminants of Fe increased the red water of carbon castiron pipe increased due to the scale products amount of $Fe_2O_3$ (Hemite).