• Title/Summary/Keyword: Zinc alloy

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The effect of pulse current electrolysis on the composition and themicrostructure of Tin-Zinc electrodeposits (주석-아연 합금도금층의 조성 및 조직에 미치는 파형전류전해의 영향)

  • 예길촌;박성진;김대영
    • Journal of the Korean institute of surface engineering
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    • v.34 no.4
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    • pp.303-312
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    • 2001
  • Composition and microstructure of the tin-zinc alloys electroplated in gluconate bath were studied according to pulse current parameters. The cathode current efficiency increased with both the mean current density and the off-time decrease. Zinc content of the alloy deposits increased with increasing mean current density, while it decreased noticebly with increasing the off-time from 10-30ms to 100-150ms. The preferred orientation of the alloy deposits changed with the increase of peak current density in the sequence of (220)longrightarrow(220)+(420) or (220)+(420)+(321) mixed structure. The equiaxed grain size of the alloy increased with the increase of off-time and the decrease of mean current density.

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Atomic-resolution Transmission Electron Microscopy Investigation of η2 Precipitate Growth in Al-Zn-Mg Alloy (원자단위 투과전자현미경을 활용한 알루미늄-아연-마그네슘 합금 내부 η2 석출물 성장 메커니즘 규명)

  • H. Kim;H. N. Han
    • Transactions of Materials Processing
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    • v.33 no.1
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    • pp.12-17
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    • 2024
  • Aluminum-zinc-magnesium alloy is a well-known alloy that is both strong and lightweight. Precipitation strengthening plays a significant role in the strength mechanism of this alloy, with nano-sized η-based precipitates being the representative precipitates. However, the growth of η precipitates can lead to a decrease in strength, necessitating research into ways to control their growth. In this study, we observed the atomic-level behavior of η2 precipitates and discovered that the precipitates grew through a combination with magnesium after a zinc segregation layer was formed around them.

A Study on the Characteristics of Galvalume Sheet (55%A1-43.4%Zn-1.6%Si) (55% A1 - 43.4% Zn - 1.6% Si 합금도금 강판의 특성에 관한 연구)

  • 김순경
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1997.10a
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    • pp.310-315
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    • 1997
  • An extensive corrosion study was initiated by galvalume steel sheet manufacturing company to clarify the corrosion behavior of zinc and zinc and zinc-alloy coated automotive sheet steel in out panel and electrical application. Since the early 1980's the use of zinc and aluminum alloy coated steel for vehicular corrosion protection has increased drastically. This paper describes the evaluation of formability, weldability and painted corrosion performance of galvalume steel sheet. This paper presents an overview of the program and some initial test results on the weldability, lifetime of the electrode tip shape of the spot welding and corrosion protection. Galvalume steel sheet improved corrosion performance and spot weldability of galvalume steel has no problem for the variation of welding current. And tip lifetime was changed according to the influence of shape.

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A Simulation Case Study on Impact Safety Assessment of Roadside Barriers Built with High Anti-corrosion Hot-dip Alloy-coated Steel (용융합금도금 강판 적용 노측용 방호울타리 충돌 안전성 평가 해석 사례 연구)

  • Noh, Myung-Hyun
    • Journal of the Korean Society of Safety
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    • v.31 no.2
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    • pp.83-89
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    • 2016
  • As the world's industrial development quickens, the highways and regional expressways have been expanding to serve the logistics and transportation needs of people. The burgeoning road construction has led to a growing interest in roadside installations. These must have reliable performance over long periods, reduced maintenance and high durability. Steel roadside barriers are prone to corrosion and other compromises to their functionality. Therefore, using high anti-corrosion steel material is now seen as a viable solution to this problem. Thus, the objective of this paper is to expand the scope of applications for high anti-corrosion steel material for roadside barriers. This paper assesses the impact safety such as structural performance, occupant protection performance and post-impact vehicular response performance by a simulation review on roadside barriers built with high strength anti-corrosion steel materials named as hot-dip zinc-aluminium-magnesium alloy-coated steel. The simulation test results for the roadside barriers built with high strength anti-corrosion steels with reduced sectional thickness meet the safety evaluation criteria, hence the proposed roadside barrier made by high strength and high anti-corrosion hot-dip zinc-aluminium-magnesium alloy-coated steel will be a good solution to serve safe impact performance as well as save maintenance cost.

Effect of Fe(NO3)2 Concentration on Electrochemical Behavior of SCM430 in Zinc Phosphate Conversion Coating Solution (아연계 인산염 피막용액에서 Fe(NO3)2 농도가 SCM430 합금의 전기화학적 거동에 미치는 영향)

  • Kwon, Duyoung;Song, Pung-Keun;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.52 no.4
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    • pp.233-238
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    • 2019
  • The formation behavior of zinc phosphate conversion coating (ZPCC) on SCM430 alloy was investigated in 25 vol.% of 1M ZnO + 170 ml/L solution containing various $Fe(NO_3)_2$ concentrations, using open-circuit potential(OCP), electrochemical impedance spectroscopy(EIS), cyclic polarization(CP) curve and tape peel test. OCP of SCM430 alloy and corrosion current density increased with increasing $Fe(NO_3)_3$ concentration. Resistance of films formed on SCM430 alloy by chemical conversion treatment decreased with increasing $Fe(NO_3)_3$ concentration. Color and adhesion of chemical conversion coatings became darker and worse, respectively, with increasing $Fe(NO_3)_3$ concentration. It is concluded that addition of $Fe(NO_3)_3$ into a zinc phosphating bath leads to faster reaction to form porous surface coatings with poor adhesion and corrosion resistance.

Effect of Deposit Conditions on Composition of Sn-Zn Alloy Deposits (Sn-Zn합금도금 조성에 미치는 도금조건의 영향)

  • 배대철;김현태;장삼규;조경목
    • Journal of the Korean institute of surface engineering
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    • v.34 no.6
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    • pp.537-544
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    • 2001
  • In the present study, tin-zinc alloys were coated on a cold-rolled steel sheet with variations of electrolyte concentration, additives quantity and current density employing the Hull cell and circulation cell simulator. With an addition of additives of 2m1/L, tin-zinc deposits containing 10 to 40 percent Zn revealed a good surface appearance with weak acidic electrolytes. The organic additives suppressed the Sn deposition rate and thus increased the zinc contents in tin-zinc coating layers. The zinc contents in the tin-zinc coating layers depended almost linearly on the concentrations of metal ions of tin and zinc. Temperature of the electrolyte affected the composition tin-zinc coating layer. However, the concentration of complexants revealed little effectiveness. The surface morphology of tin-zinc coating showed dense tin and zinc phases with fine equiaxed grains with the high current density.

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Effects of Alloying Element and Grain Refinement on the Tensile Properties of Mg-Alloy Casted with Sand Mold (사형 주조 마그네슘 합금의 인장 특성에 미치는 합금 원소와 결정립 미세화의 영향)

  • Han, Jae-Jun;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.31 no.4
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    • pp.212-217
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    • 2011
  • The effects of alloying element and grain refinement on the tensile properties of magnesium alloy poured into sand mold were investigated. The strength of magnesium alloy was greatly increased by the addition of aluminium and that was increased with the increased aluminum content added up to 8.10 wt% and decreased beyond that. Even though the strength of Mg-8.10 wt%Al alloy was rather decreased by the addition of zinc, that was increased with increased zinc content added up to 0.50 wt% and decreased with the increased one beyond that. The maximum tensile strength was obtained with 0.50 wt%Mn added. The strength and elongation were simultaneously increased with grain refinement and the optimum amount of strontium addition for this was 0.30 wt%. The optimum chemical composition was obtained and the yield strength, tensile strength and elongation of the alloy with this composition were 90.2, 176.3MPa and 4.43%, respectively.

Effects of Ultrasonic Waves on Electrodeposition on Nickel-Zinc Alloys(I) (Ni-Zn 합금도금에 미치는 초음파의 영향(I))

  • Yang, Hack-Hui
    • Journal of the Korean institute of surface engineering
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    • v.20 no.1
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    • pp.4-14
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    • 1987
  • The nickel-zinc alloy depositions have been studied in nickel chloride added chloride baths, to find out the effects of ultrasonic irradiation for the electrodeposition processes. The compositions of deposited alloys, the current efficiencies and the metallographic appearances in various conditions of Electrodeposition were investigated, in the range of ultrasonic irradiation of 50,500 and 1,000 Kc/s respectively. The results obtained are as follows; 1. Generally the nickel deposition process is more preferably activated than that of zinc by the ultrasonic irradiation. 2. The radios of nickel to zinc in the deposit are higher according to increase of nickel ion concentration and bath temperatures in irradiated baths. 3. The current efficiencies are also higher in the irradiated baths, so that the depolarization effect is noticeable. 4. The brightness and leveling effect of the deposits are appreciably better in the irradiated baths than in non-irradiated in 0.3M and 0.6M of nickel chloride and zinc chloride solutions and the current density of 3A/$dm^2$. 5. The mechanism of alloy deposition has been tentatively suggested in the case of ultrasonic irradiation.

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Effect of Sodium Chloride on Weight Loss of AA1100 Aluminum Alloy and SGACD Zinc coated Steel Lap Joint

  • Maulidin, Achmad;Kimapong, Kittipong
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.39-45
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    • 2015
  • This research aims to study an effect of sodium chloride solution concentration on the corrosion rate of AA1100 aluminium alloy and SGACD zinc coated steel lap joint with a test duration of 30 days and a test temperature of $45^{\circ}$. The summarized results are as follows. Increase of the NaCl solution concentration increased the weight loss of Al, corrosion rate of Al, weight loss of Fe and also decreased the corrosion rate of Fe. Increase of the test duration affected to increase the weight loss and corrosion rate of Al and also decrease the weight loss and corrosion rate of Fe. The corrosion that was formed in a lap joint consisted of the uniform corrosion on the surface of the metals and the galvanic corrosion in the lap area of the joint. The maximum weight loss of AA 1100 aluminium and SGACD zinc coated steel that was occurred in the sodium chloride with 3.25% was 2.203% and 3.208%, respectively.. The maximum corrosion rate of AA 1100 aluminium and SGACD zinc coated steel that was occurred in 4.00% and 3.5% sodium chloride solution was 0.156 mm/year and 0.479 mm/year, respectively.

Crashworthiness Evaluation of Bridge Barriers Built with Hot-dip Zinc-aluminium-magnesium Alloy-coated Steel (고내식성 용융합금도금강판 적용 교량난간의 충돌성능 평가)

  • Noh, Myung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.3
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    • pp.171-176
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    • 2016
  • This paper proposes road safety facilities applying Hot-dip zinc-aluminum-magnesium alloy-coated steel sheets and coils to reduce the loss of function caused by the corrosion of steel in the service state. Vehicle crash simulations and full-scale crash tests were carried out to provide reliable information on evaluating the crash performance with the products of road safety facilities built with hot-dip zinc-aluminum-magnesium alloy-coated steel. From the results of the simulations and full-scale crash tests, the impact behaviors evaluated by the three-dimensional crash simulations considering the strain-rate dependency in a constitutive model were similar to those obtained from the full-scale crash test results. The full-scale crash test results met the crashworthiness evaluation criteria; hence, the proposed bridge barrier in this paper is ready for field applications.