• 제목/요약/키워드: Zinc Plating Process

검색결과 23건 처리시간 0.029초

Chemical Active Liquid Membranes in Inorganic Supports for Metal Ion Separations

  • Yi, Jongheop
    • 한국막학회:학술대회논문집
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    • 한국막학회 1994년도 추계 총회 및 학술발표회
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    • pp.8-11
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    • 1994
  • Disposal of hazardous ions in the aqueous streams is a significant industrial waste problem.. Waste streams from electronics, electroplating, and photographic industries contain metal ions such as copper, nickel, zinc, chromium(IV), cadmium, aluminum, silver, and gold, amongst others in various aqueous solutions such as sulfates, chlorides, fluorocarbons, and cyanides. Typical plating solutions having similar compositions are listed in Table 1. Spent process streams in catalyst manufacturing facilities also contain precious metals such as Ag, Pt, and Pd. Developing an effective recovery process of these metal ions for reuse is important.

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COG용 Solder Bump 제작을 위한 Ni 무전해 도금 공정에 관한 연구 (A Study on Ni Electroless Plating Process for Solder Bump COG Technology)

  • 한정인
    • 한국재료학회지
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    • 제5권7호
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    • pp.794-801
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    • 1995
  • LCD 모듈을 위한 실장 기술인 Chip on Glass 공정 기술을 개발함에 있어 구동 IC와 기판d의 Al 전극을 연결하기 위하여 기존의 기술과의 연관성 및 공정의 연속성, 제조단가등을 고려하여 Pb-Sn 범프를 사용하고자 하였으며 이를 위해 Al 금속 박막위에 니켈 무전해 도금하는 방법을 연구 하였다. Al 전극에 무전해 니켈 도금하기 위해서는 광레지스트 차폐막을 손상하지 않는 전처리 방법이 필요하기 때문에 전처리 방법으로서 알칼리 아연산염 처리법과 불화물을 이용한 아연산염 처리법을 선택하여 실시하였다. 이 가운데 산성불화암모늄(NH$_4$HF)을 1.5 g/$\ell$ 함유하고 황산아연(ZnSO$_4$)을 100 g/$\ell$ 함유한 산성 아연산염 용액에서는 광레지스트 차폐막이 손상되지 않았으며 처리시간을 적절히 조절함으로써 알루미늄 박막상에 선택적으로 니켈 무전해 도금을 할 수 있었다. 아연산염 응액중의 첨가제와 무전해 도금액 중의 억제제인 Thiourea는 도금층의 평활도를 높이는 역할을 하였다. 또한 아연산염 처리를 하기 전에 산세 처리를 함으로써 도금층의 균일성을 향상시킬 수 있었다.

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도금폐수내 유리시안과 착염시안 및 중금속의 처리특성 (I) (Treatment Characteristics of Plating Wastewater Containing Freecyanide, Cyanide Complexes and Heavy Metals (I))

  • 정연훈;이수구
    • 한국물환경학회지
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    • 제25권6호
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    • pp.979-983
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    • 2009
  • The mean pH of wastewater discharged from the plating process is 2, so a less amount of alkali is required to raise pH 2 to 5. In addition, if sodium sulfite is used to raise pH 5 to 9 in the secondary treatment, caustic soda or slaked lime is not necessary or only a small amount is necessary because sodium sulfite is alkali. Thus, it is considered desirable to use only $FeSO_4{\cdot}7H_2O$ in the primary treatment. At that time, the free cyanide removal rate was highest as around 99.3%, and among heavy metals, Ni showed the highest removal rate as around 92%, but zinc and chrome showed a low removal rate. In addition, the optimal amount of $FeSO_4{\cdot}7H_2O$ was 0.3g/L, at which the cyanide removal rate was highest. Besides, the free cyanide removal rate was highest when pH value was 5. Of cyanide removed in the primary treatment, the largest part was removed through the precipitation of ferric ferrocyanide: $[Fe_4(Fe(CN)_6]_3$, and the rest was precipitated and removed through the production of $Cu_2[Fe(CN)_6]$, $Ni_2[Fe(CN)_6]$, CuCN, etc. Furthermore, it appeared more effective in removing residual cyanide in wastewater to mix $Na_2SO_3$ and $Na_2S_2O_5$ at an optimal ratio and put the mixture than to put them separately, and the optimal weight ratio of $Na_2SO_3$ to $Na_2S_2O_5$ was 1:2, at which the oxidative decomposition of residual cyanide was the most active. However, further research is required on the simultaneous removal of heavy metals such as chrome and zinc.

Development of Sleeve Parts for Continuous Hot Zinc Plating Roll Applied to Wear-Resistant Alloy Cast Steel

  • Park, Dong-Hwan;Hong, Jin-Tae;Kwon, Hyuk-Hong
    • 한국생산제조학회지
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    • 제26권4호
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    • pp.357-364
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    • 2017
  • Metal casting is a process in which molten metal or liquid metal is poured into a mold made of sand, metal, or ceramic. The mold contains a cavity of the desired shape to form geometrically complex parts. The casting process is used to create complex shapes that are difficult to make using conventional manufacturing practices. For the optimal casting process design of sleeve parts, various analyses were performed in this study using commercial finite element analysis software. The simulation was focused on the behaviors of molten metal during the mold filling and solidification stages for the precision and sand casting products. This study developed high-life sleeve parts for the sink roll of continuous hot-dip galvanizing equipment by applying a wear-resistant alloy casting process.

A study on zinc phosphate conversion coatings on Mg alloys

  • Phuong, Nguyen Van;Lee, Kyuhwan;Chang, Doyon;Kim, Man;Lee, Sangyeoul;Moon, Sungmo
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 추계총회 및 학술대회 논문집
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    • pp.17-17
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    • 2012
  • Magnesium alloys exhibit many attractive properties such as low density, high strength/weight ratio, high thermal conductivity, very good electromagnetic features and good recyclability. However, most commercial magnesium alloys require protective coatings because of their poor corrosion resistance. Attempts have been made to improve the corrosion resistance of the Mg alloys by surface treatments, such as chemical conversion coatings, anodizing, plating and metal coatings, are commonly applied to magnesium alloys in order to increase the corrosion resistance. Among them, chemical conversion coatings are regarded as one of the most effective and cheapest ways to prevent corrosion resistance. In this study, zinc phosphate conversion coatings on various Mg alloys have been developed by selecting proper phosphating bath composition and concentration and by optimizing phosphating time, temperature. Morphology, coatings composition, corrosion resistance, adhesion and its formation and growth mechanism of the zinc phosphate conversion coatings were studied. Results have shown some attractive properties such as simplicity in operation, significantly increased corrosion protective property. However, adhesions between coatings and substrate and also between coatings and paint are still not satisfied. Resolving the problems and understanding the mechanism of phosphating process are targets of our study.

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36개월간 국내 옥외폭로시험에 따른 아연도강의 부식거동 (Corrosion Behavior of Galvanized Steels with Outdoor Exposure Test in Korea for 36 Months)

  • 김기태;김영식
    • Corrosion Science and Technology
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    • 제17권5호
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    • pp.231-241
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    • 2018
  • Atmospheric corrosion is generally an electrochemical degradation process of metal. It can be caused by various corrosion factors of atmospheric component, weather, and air pollutants. Moisture, particles of sea salts, and sulfur dioxide are major factors in atmospheric corrosion. Galvanizing coating is one of the most efficient ways to protect iron from corrosion by zinc plating on the surface of the iron. Galvanized steels are being widely used in automobiles, building structures, roofing, and other industrial structures due to their high corrosion resistance compared to bare iron. Atmospheric corrosion of galvanized steel has shown complex corrosion behavior depending on coating process, coating thickness, atmospheric environment, and air pollutants. In addition, different types and kinds of corrosion products can be produced depending on the environment. Lifespan of galvanized steels is also affected by the environment. Therefore, the objective of this study was to determine the corrosion behavior of galvanized steel under atmospheric corrosion at six locations in Korea. When the exposure time was increased, content of zinc from GA surface decreased while contents of iron and oxygen tended to increase. On the other hand, content of iron was constant even after 36 months of exposure of GI.

자동차용 판재 성형시 드로우비드 공정인자별 인출특성에 대한 연구 (Effect of drawbead process parameters on the drawing characteristics of sheet metals for automotive parts)

  • 김원태;이동활;강우순;서만석;문영훈
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2003년도 추계학술대회논문집
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    • pp.140-143
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    • 2003
  • The drawbead is an important part in sheet metal forming for automotive part and its effect is affected by various process parameters. Therefore in this study, drawbead friction test was performed at various process parameters - panels (cold rolled and galvanized sheet steel), lubricants (having three different viscosities), bead materials(steel, iron) and surface treatment of bead (Cr plating). Circular shape bead has been used for the test. The results show that friction and drawing characteristics were mainly influenced by the nature of zinc coating, viscosity of lubricants, surface treatment of a bead and hardness of coated layer.

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핫프레스포밍 공정에서 내산화 코팅처리가 TWB 용접부 특성에 미치는 영향 (The Effect of Mechanical Property of Tailor Welding Blank and Hot Press Forming Process by the Different Anti-oxidation Coating Treatment on Boron-steel Sheet)

  • 김상권;임옥동;이재훈
    • 열처리공학회지
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    • 제25권6호
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    • pp.283-291
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    • 2012
  • In order to increase the anti-oxidation property during the tailor welding blanked hot press forming process for a high strength boron steel sheet, we performed a different coating method on the boron-steel sheet such as 87% Al - 13% Si and Fe - 8.87 Zn dipping plating procedure. However, during laser welding process, the Al-Si coated steel sheet has showed a low tensile strength and about half value of elongation than the original boron-steel sheet. Aluminum and silicon, elements of coating layer were diffused into the boron-steel matrix and have shown a low strength result than non-coated specimen. On the other hand, Zinc-coated boron-steel has expectedly showed a excellent tensile strength and micro-harness value in the welded area like original boron-steel.

아연도금강판의 품질향상을 위한 도금욕 내부 유동제어 연구 (Flow Control Inside a Molten Zn Pot for Improving Surface Quality of Zinc Plated Strips)

  • 최재호;고민석;김석;이상준
    • 대한기계학회논문집B
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    • 제25권10호
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    • pp.1392-1399
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    • 2001
  • The flow fields inside a molten Zn pot of continuous hot-chip galvanizing process were investigated experimentally. With varying several parameters including the strip speed Vs, flow rate Q of induction heater. scrapper location and baffle configuration, instantaneous velocity fields were measured using a PIV velocity field measurement technique. Inside the strip region, counter-clockwise rotating flow is dominant. The general flow pattern inside the strip region is nearly not influenced by the strip speed Vs, flow rate Q and the scrapper location. In the exit region, the flow separated from the moving strip due to the existence of a stabilizing roll ascends to the free surface, for the cases of no scrapper and scrapper detached form the roll. On the other hand, the ascending flow to the free surface is decreased, as the flow rate Q of induction heater increases. By installing a baffle around the uprising strip, the flow moving up to the stabilizing roll decreases. In addition, B-type baffle is better than A-type baffle in reducing speed of flow around the stabilizing rolls. However, the flow ascended to the free surface is largely influenced by changing the flow rate Q, and the scrapper location, irrespective of the baffle type.