• Nuclear Engineering and Technology
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• v.52 no.1
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• pp.148-154
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• 2020

The radiation induced segregation of Cr at grain boundaries (GBs) in Ferritic/Martensitic steels was modeled assuming vacancy and interstitialcy diffusion mechanisms. In particular, the dependence of segregation on temperature and grain boundary misorientation angle was analyzed. It is found that Cr enriches at grain boundaries at low temperatures primarily through the interstitialcy mechanism while depletes at high temperatures predominantly through the vacancy mechanism. There is a crossover from Cr enrichment to depletion at an intermediate temperature where the Cr:Fe vacancy and interstitialcy diffusion coefficient ratios intersect. The bell-shape Cr enrichment response is attributed to the decreasing void sinks inside the grains as temperature rises. It is also shown that low angle grain boundaries (LAGBs) and special Σ coincidence-site lattice (CSL) grain boundaries exhibit suppressed radiation induced segregation (RIS) response while high angle grain boundaries (HAGBs) have high RIS segregation. This different behavior is attributed to the variations in dislocation density at different grain boundaries.

• Journal of the Korean Wood Science and Technology
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• v.25 no.2
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• pp.27-32
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• 1997

This study was carried out to find the relationship between anatomical characters and compression strength parallel to grain of Pinus densiflora S. et. Z., the representative conifer species in Korea. The results were as follows ; 1. The compression strength parallel to grain increased with the increase of tracheid length and wall thickness. The strength, however, decreased with the increase of height of uniseriate ray and microfibril angle. 2. The major factors affecting compression strength parallel to grain in heartwood were radial diameter of latewood tracheid and wall thickness of earlywood tracheid but length and tangential diameter of latewood tracheid were the important factors in sapwood.

• Korean Journal of Materials Research
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• v.32 no.4
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• pp.181-185
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• 2022

In this study, phase-pure titanium dioxide TiO₂ ceramics are sintered using standard high-temperature solid-state reaction technique at different temperatures (1,000, 1,100, 1,200, 1,300, 1,400 ℃). The effect of sintering temperature on the densification and impedance properties of TiO₂ ceramics is investigated. The bulk density and average grain size increase with the increase of sintering temperature. Impedance spectroscopy analysis (complex impedance Z^* and complex modulus M^*), performed in a broad frequency range from 100 Hz to 10 MHz, indicates that the TiO₂ ceramics are dielectrically heterogeneous, consisting of grains and grain boundaries. The complex impedance Z^* -plane indicates the resistance of grains of the TiO₂ ceramics increases with increasing sintering temperature, while that of grain boundaries develops in the opposing direction. The complex modulus M^*-plane shows a grain capacitance that seems to be independent of the sintering temperature, while that of the grain boundaries decreases with increasing sintering temperature. These results suggest that different sintering temperatures have effects on the microstructure, leading to changes in the impedance properties of TiO₂ ceramics.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1996.10a
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• pp.139-146
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• 1996

The torsion tests in the range of 900~1100$^{\circ}C$ and 5.0X10-2~5.0X100/sec were performed to study the high temperasture deformation behavior kinetics of 304 stainless steels. The flow curves and microstructures exhibited the characteristic of dynamic recrystallization(DRX). The relationship between the critical strain($\varepsilon$c) for the initiation of dynamic recrystallization and the peak strain($\varepsilon$p) could be expressed as $\varepsilon$c=0.73$\varepsilon$p. The dependence of the flow stress on temperature(T) and stain rate($\varepsilon$) was expressed by hyperbolic sine law, $\varepsilon$=2.75X1014 (sinh 0.076$\sigma$)5.26 exp(-379.55kJ/mol). Under the Zener-Hollomon parameter, Z value of 1013 order, it was found that the grain size was 20${\mu}$m. The relationship between the grain size, dDRX and Z parameter was expressed as dDRX =139.48-7.33 log Z.

• Advances in materials Research
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• v.5 no.2
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• pp.93-105
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• 2016

KNN-based ceramics modified with small amounts of $Bi_4Zr_3O_{12}$ (BiZ) has been synthesized using high-throughput experimentation (HTE). The results from X-ray diffraction show that for samples with base composition $(K_{0.5}Na_{0.5})NbO_3$ (KNN), the phase present changes from orthorhombic to pseudo-cubic with more than 0.2 mol% BiZ addition; for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.9}Ta_{0.1})O_3$ (KNNLT), the phase present changes from a mixture of orthorhombic and tetragonal symmetry to pseudo-cubic with more than 0.4 mol % while for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.86}Ta_{0.1}Sb_{0.04})O_3$ (KNNLST), the phase present is tetragonal with <0.3 mol% BiZ addition and transforms to pseudo-cubic with more dopant addition. The microstructures of the samples show that addition of BiZ decreases the average grain size and increases the volume of pores at the grain boundaries. The values of dielectric constant for KNN and KNNLT compositions increase slightly with BiZ addition while that for KNNLST decreases gradually with BiZ addition. The dielectric loss values are between 0.02 and 0.04 for KNNLT and KNNLST compositions while they are ~ 0.05 for KNN samples. The resistivity values increases with BiZ addition and values in the range of $10^{10}{\Omega}cm$ and $10^{12}{\Omega}cm$ are obtained. The piezoelectric charge coefficient ($d{^*}_{33}$) is highest for KNNLST samples and decreases gradually from ~400 pm/V to ~100 pm/V with BiZ addition.

• Journal of the Korean Wood Science and Technology
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• v.21 no.3
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• pp.45-52
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• 1993

Surveyed results on the slope of grain and the twist of sawn lumber of Pinus koraiensis, Larix leptolepis, and Pinus densiflora were summarized as follows: 1. The slope of grain of Pinus koraiensis has a Z-grain in the stem axis. The slope of grain was found to be the lowest at near to the pith and then constantly increased. At the height of 0.2m from the base of stem. a cross section of 35 annual rings was found to have a repeatedly increasing and decreasing slope of grain and then constantly decreased. At the height of 1.2m to 7.2m from the base of stem, the slope of grain increased conspicuously until the 10th annual ring, after which it increased near to the bark with repeatedly increasing and decreasing trends. 2. Pinus densiflora has a S-grain in the stem axis. The lowest slope of grain was found at near to the pith, and the highest in the 10 to 35 annual rings from the pith. 3. Larix leptolepis has a S-grain. At the height of 3.2m from the base of stem, the big fluctuation of the slope of grain was found without any particular trend. 4. The slope of grain and the twist between natural and reforested timber of Pinus koraiensis were found to be almost the same trend in viewpoint of the annual ring. The maximum slope of grain of imported Siberian timber of Pinus koraiensis was found at the 10 annual rings, which was quite similar to that of native species in Korea, but the big difference of the twist was found at 140 annual rings. 5. The twist was little at the mature wood of reforested Pinus koraiensis and Siberians and the duplicated part of mature and juvenile woods of those. On the contrary, the twist was great at the duplicated part of mature and juvenile woods of Pinus koraiensis. 6. The twist of Larix leptolepis showed the S-direction which coincided with that of slope of grain. The twist was greatest at the part of juvenile wood and little at the duplicated part of mature and juvenile woods, and little difference of twist was found between mature and juvenile woods. 7. Siberian larix having a minimum slope of grain showed the lowest twist, and the twist at the duplicated part of mature and juvenile woods showed a middle level of both mature and juvenile woods' portions.

• Geomechanics and Engineering
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• v.2 no.4
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• pp.303-319
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• 2010

The effect of grain crushing on the deformation of sand in 1D compression and 1D creep at high stresses was investigated theoretically and experimentally. An approach was proposed to formulate the process of grain crushing in sand in accordance with the laws of fracture mechanics and energy conservation. With this approach, the relation between the void ratio and the amount of grains crushed in 1D compression was derived. Laboratory test data were used to verify this derived relation. In addition, it was observed that there are similarities in evolution of grain size distribution in 1D compression and 1D creep tests. This implies that the changes in microstructure in sand under 1D compression and 1D creep are comparable.

• Bulletin of the Korean Chemical Society
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• v.8 no.4
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• pp.235-237
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• 1987

(7Z, 11E)-7, 11-Hexadecadien-1-yl acetate(1), the sex pheromone of the female Angoumois grain moth, Sitotroga cerealella, was synthesized via the acetylenic intermediate, (11E)-11-hexadecen-7-yn-ol THP ether(2). The acetylenic compound was prepared from 7-octyn-1-ol THP ether(4) and (3E)-1-bromo-3-octene(3). The (E)-homoallylic bromide 3 was synthesized by the Julia olefin synthesis of 1-cyclopropylpentan-1-ol(6).

• Geomechanics and Engineering
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• v.13 no.6
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• pp.947-961
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• 2017

An innovative spiral variable-section capillary model is established for piping critical hydraulic gradient of cohesion-less soils causing water/mud inrush in tunnels. The relationship between the actual winding seepage channel and grain-size distribution, porosity, and permeability is established in the model. Soils are classified into coarse particles and fine particles according to the grain-size distribution. The piping critical hydraulic gradient is obtained by analyzing starting modes of fine particles and solving corresponding moment equilibrium equations. Gravities, drag forces, uplift forces and frictions are analyzed in moment equilibrium equations. The influence of drag force and uplift force on incipient motion is generally expounded based on the mechanical analysis. Two cases are studied with the innovative capillary model. The critical hydraulic gradient of each kind of sandy gravels with a bimodal grain-size-distribution is obtained in case one, and results have a good agreement with previous experimental observations. The relationships between the content of fine particles and the critical hydraulic gradient of seepage failure are analyzed in case two, and the changing tendency of the critical hydraulic gradient is accordant with results of experiments.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.11
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• pp.949-955
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• 2009

In this study, we investigated the effects of Cr dopant (1.0 at% $Cr_2O_3$ sintered at $1000^{\circ}C$ for 1 h in air) on the bulk trap (i.e. defect) and interface state levels of ZnO using dielectric functions ($Z^*$, $M^*$, $Y^*$, $\varepsilon^*$, and $tan{\delta}$), admittance spectroscopy (AS), and impedance-modulus spectroscopy (IS & MS). For the identification of the bulk trap levels, we examine the zero-biased admittance spectroscopy and dielectric functions as a function of frequency and temperature. Impedance and electric modulus spectroscopy is a powerful technique to characterize grain boundaries of electronic ceramic materials as well. As a result, three kinds of bulk defect trap levels were found below the conduction band edge of ZnO in 1.0 at% Cr-doped ZnO (Cr-ZnO) as 0.11 eV, 0.21 eV, and 0.31 eV. The overlapped defect levels ($Zn^{..}_i$ and $V^{\cdot}_0$) in admittance spectra were successfully separated by the combination of dielectric function such as $M^*$, $\varepsilon^*$, and $tan{\delta}$. In Cr-ZnO, the interfacial state level was about 1.17 eV by IS and MS. Also we measured the resistance ($R_{gb}$) and capacitance ($C_{gb}$) of grain boundaries with temperature using impedance-modulus spectroscopy. It have discussed about the stability and homogeneity of grain boundaries using distribution parameter ($\alpha$) simulated with the Z"-logf plots with temperature.