• Korean Journal of Crystallography
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• v.9 no.1
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• pp.11-14
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• 1998

The synthesis and characterization of [Cu(L)](NCS)2 (1) (L:2,5,9,12-Tetramethyl-1,4,8,11-tetraazacyclotetradecane) are described. Crystal structure of 1 crystallizes in the monoclinic system, space group P21/a, a=7.622(2)Å, b=17.645(2) Å, c=8.223(3) Å, β=109.99(2)˚ Z=2. Least-squares refinement of 1 led to a R(Rw) factor of 0.087 (0.158) for 1535 observed reflections of F0>40(F0). The complex 1 has a square planar geometry with average Cu-N (secondary amines) bond distance of 2.030(4)Å. The axially disposed thiocyanate anions are not coordinated with Cu-N distances of 2.842(7) Å.

• Korean Journal of Crystallography
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• v.6 no.2
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• pp.93-97
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• 1995

Re(≡NC6H5)(PPh3)2CI3, I, reacted with, 1,2-bis(diphenylphosphino)ethane (DPPE) to give fac-Re(≡NC6H5)(DPPE)CI3, II. The product has been characterized by 1H-NMR, elemental analysis, and X-ray crystallography. II Crystalizes in the monoclinic space group Pc, with cell parameters a=11.083(3)Å, b=10.930(1)Å, c=14.081(2)Å, β=108.37(2)°, Z=2. Least-squares refinement of the structure led to a R(wR2)factor of 0.0254(0.0607) for 2888 unique reflections of I>2σ(I) and for 352 variables.

• Korean Journal of Crystallography
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• v.7 no.2
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• pp.113-119
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• 1996

Reaction of Re(O)(PPh3)2Cl3,I, with 2,3,4,5,6-pentafluoroaniline (C6F5NH2), produced Re(NC6F5)(PPh3)2Cl3, II. The product has been characterized by 1H-NMR, elemental analysis, and X-ray diffraction. II crystallizes in the orthorhombic system, space group Pna21 with cell parameters a=18.763Å, b=14.737(2)Å, c=16.707(3)Å, Z=4. Least-square refinement of the structure led to an R(wR2)factor of 0.0455(0.1148) for 3319 unique reflections of I > 2σ(I) and for 174 variables.

• Journal of Electrical Engineering and Technology
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• v.9 no.2
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• pp.589-599
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• 2014

On the basis of the traditional ZSI (Z-source inverter), this paper presents a ESL-${\Gamma}$-ZSI, which uses a unique ${\Gamma}$-shaped impedance network and an extended SL network for boosting its output voltage in addition to their usual voltage-buck behavior. The inverter can increase the boost factor through adjusting shoot-through duty ratio and increasing the number of inductors. Capacitor voltage stress of ESL-${\Gamma}$-ZSI is a constant when 1>D>0, and ESL-${\Gamma}$-ZSI has small inductor current stress. The working principle of ESL-${\Gamma}$-ZSI and comparison with the classical ZSI and SL- ZSI are analyzed in detail. The power loss comparison between ESL-${\Gamma}$-ZSI and Cuk converter is analyzed detailedly. Simulation and experimental results are given to demonstrate the operation features of the inverter.

• Journal of the Korean Magnetics Society
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• v.4 no.1
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• pp.1-6
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• 1994

The magnetization dynamics was investigated by solving possible origins of overdamped susceptibility observed in ultra-soft magnetic amorphous thin films. The experimental high frequency spectrum and computational spectrum calculated from Gilbert's equation of motion were compared in order to find proper damping factor $\alpha{\approx}20$ and demagnetizing coefficients $D_{x}{\approx}D_{y}{\approx}D_{z}{\approx}0$ for ultra-soft magnetic films. A magnetization vortex mode was, then, proposed to explain the origin of the reversible susceptibility and other anomalies of the ultra-soft magnetic heterogeneous thin films. In this mode it is suggested that there occur, within the nanoscale structural features of the ultra-soft films, incoherent rotational spin motions that are highly damped by the energy transfer from short wavelength spin wave modes and local defect structure mode interactions.

• Journal of Distribution Science
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• v.19 no.6
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• pp.51-64
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• 2021

Purpose: A restaurant is a business of the physical distribution of food and beverages which includes intercultural interaction. This research paper aims to examine the influence of Japanese taste as a product advantage, determining service quality factor in the restaurant business, the e-CRM that involves technology, social media campaigns to reach the target market of young people, and customer satisfaction on customer loyalty in Sushi Tei restaurant. This study also intends to find direct and indirect influence between the variables. Research design, data and methodology: Quantitative research was conducted using a survey method by distributing 100 questionnaires to Sushi Tei customers in Jakarta, consisting of Gen Z and Millennials. Samples were taken at each outlet in the Jakarta area on weekend and weekdays by purposive sampling. Data was generated by path analysis Results: The results showed that Japanese taste, service quality, and e-CRM significantly influence customer satisfaction and customer loyalty. However, social media campaigns failed to influence customer loyalty. As a result, customer satisfaction has a significant influence on customer loyalty within Sushi Tei restaurant. Conclusion: The study also proposed significant implications to develop and maintain a relationship with the customer to gain satisfaction and loyalty in the food and beverage industry.

• Bulletin of the Korean Chemical Society
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• v.17 no.4
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• pp.353-357
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• 1996

Second-order rate constants have been measured spectrophotometrically for the reaction of 2,4-dinitrophenyl X-substituted benzenesulfonates with Z-substituted phenoxides in absolute ethanol at 25.0±0.1 ℃. The nucleophilic substitution reaction gives both S-O bond and C-O bond cleavage products. The extent of S-O bond cleavage increases significantly with increasing electron withdrawing ability of the sulfonyl substitutent X, while that of the C-O bond cleavage is independent on the electronic effect of the substituent. On the contratry, the effect of the substituent Z in the nucleophilic phenoxide is more significant for the C-O bond cleavage than for the S-O bond cleavage. Aminolyses of 2,4-dinitrophenyl benzenesulfonate (1) with various 1°, 2° and 3°amines have revealed that steric effect is little important. The extent of S-O bond cleavage increases with increasing the basicity of the amines, but decreases with increasing the basicity of the nucleophilic aryloxides, indicating that the HSAB principle is not always operative. Besides, reactant and solvent polarizability effect has also been found to be an important factor in some cases but not always to influence the reaction site.

• The Journal of Korean Academic Society of Nursing Education
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• v.28 no.3
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• pp.305-316
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• 2022

Purpose: The purpose of this study was to construct a structural equation model of organizational commitment in hospital nurses based on a job demands-resources model and to confirm the moderating effect(s) according to the nurses' generation. Methods: The model was constructed of the exogenous variables of social support, emotional intelligence, emotional labor, and job conflict and the endogenous variables of burnout, job engagement, and organizational commitment. The participants were 560 hospital nurses working in 3 general hospitals. Data were collected from August 1 to September 30, 2021, and analyzed using SPSS Window 23.0 and IBM AMOS 23.0. Results: The strongest factor directly influencing hospital nurses' organizational commitment was social support. In a multiple group analysis, nurses' generation had a partial moderating effect. In a generation-specific analysis, the Z generation group was higher than the X and Y generation groups in the variables of emotional labor and burnout related to organizational commitment. Conclusion: Based on the findings of this study, to improve hospital nurses' organizational commitment, social support is needed as an important management strategy. At the organizational level, we need to develop ways to improve organizational commitment by reducing the emotional labor and burnout of Generation Z.

• Journal of Korean Port Research
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• v.6 no.2
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• pp.43-64
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• 1992

This study discusses the interacting with deep water waves approaching from deep water based on the linear wave theory and steep sloping sea bottom floor by the numerical procedure. The results of particular interest are particle velocity and acceleration in x, y, z direction wave height amplification factor reflection coefficient and dimensionless pressure distribution on the steep sloping bottom with respect to the various incident wave angle. The wave loads relative to various bottom slopes, incident wave angles and wave periods on submerged breakwater and pipe are represented in comparison with mild sloping bottom the wave load parameters on the steep sloping bottom seemed to be influenced by variation of incident wave angle. In general the particle velocities and accelerations in x, y, z directions on the steep sloping bottom represented larger value or about two than those on the mild sloping bottom according to incident wave angle. However, the wave height amplification factors did not show distinct difference, but the slight variation with respect to the various incident angle showed on mild sloping bottom. The reflection coefficient increased with respect to increase of the incident angle on the steep sloping bottom the results also indicate that the very steep sloping beach produces a rather substantial amount of reflection as we expected. No significant variation of wave pressure was shown on the steep sloping bottom but it represented a certain amount of variation on the mild sloping bottom according to the various incident wave angle. The analysis at the OTEC site also showed similar results.

• Journal of ILASS-Korea
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• v.27 no.1
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• pp.1-10
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• 2022

In this study, an experimental investigation on the effects of the pressure ratio on the wall-impingement spray characteristics of nitrogen gas using a compressed natural gas (CNG) injector was conducted. The transient development of the impingement spray was recorded by a high speed camera with Z-type Schlieren visualization method. The spray behavior under various pressure ratio conditions were analyzed. The experimental results showed that the pressure ratio has positive effect on the development of spray wall-impingement. The effects of the above factor were evaluated in a constant volume chamber at atmospheric conditions. The data from test showed that, with the increase of the pressure ratio, the spray tip penetration (STP) quickly increases before the impingement and gradually increases after the impingement. Additionally, the spray velocity first increases and then sharply decreases on regardless of the injection pressure level. As the spray spreading angle increases, spray area and volume increases rapidly with the increase in STP at the beginning of injection, and finally entered a stable range, has a great correlation with the increase of pressure ratios.