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An Investigation of Treatment Effects of Limestone and Steel Refining Slag for Stabilization of Arsenic and Heavy Metal in the Farmland Soils nearby Abandoned Metal Mine (폐금속 광산 주변 비소 및 중금속 오염농경지의 안정화 처리를 위한 석회석과 제강슬래그의 처리효과 검토)

  • Yun, Sung-Wook;Kang, Sin-Il;Jin, Hae-Geun;Kim, Ha-Jin;Lim, Young-Cheol;Yi, Ji-Min;Yu, Chan
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.734-744
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    • 2011
  • A soil stabilization method is an effective and practical remediation alternative for arsenic (As) and heavy metal contaminated farmland soils nearby abandoned metal mine in Korea. This method is a technique whereby amendments are incorporated and mixed with a contaminated soil. Toxic metal bind to the amendments, which reduce their mobility in soil, so the successful stabilization of multi-element contaminated soil depends on the combination of critical elements in the soil and the type of amendments. The objective of this study is to investigate the treatment effects and applicability of limestone (LS) and steel refining slag (SRS) as the amendment for farmland soil contaminated with As and heavy metals, and a lab-column test was conducted for achieving this purpose. The result showed that soil treated with LS and SRS maintained pH buffer capacity and, as a result, the heavy metal leaching concentration was quite low below the water quality standard compared to untreated soil which leachate exceeding the water quality standard was observed, however, the arsenic concentration rather increased with increasing mixture ratio of SRS. This was believed to be related to phosphorus (P) contained in SRS, and dominancy in the competitive adsorption relation between As and P binding strongly to iron might be different according to soil characteristic. We suggested that LS is a effective amendment for reducing heavy metals in soil, and SRS should be used after investigating its applicability based on the adsorption selectivity of arsenic and phosphorus in selected soil.

Recommendation of the Amount of Nitrogen Top Dressing based on Soil Nitrate Nitrogen Content for Leaf Perilla (Perilla frutescens) under the Plastic Film House (토양 질산태질소 함량에 따른 시설 잎들깨 질소 웃거름시비량 추천)

  • Kang, Seong-Soo;Lee, Ju-Young;Sung, Jwa-Kyung;Gong, Hyo-Young;Jung, Hyung-Jin;Park, Chang-Hwan;Yun, Yeo-Uk;Kim, Myung-Sook;Kim, Yoo-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1112-1117
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    • 2011
  • This study was conducted to recommend nitrogen (N) top dressing based on soil nitrate content for leaf perilla under forcing culture in Gumsan-gun and Milyang-si. Experimental design was the randomized complete block design for five N fertilization levels and conventional fertilization. Dry weight, nitrogen uptake, and the node number of leaf perilla were measured and soil nitrate contents were analyzed monthly. The amount of nitrogen uptake for growth of a node with two leaves was $2.2kg\;10a^{-1}$ for Gumsan site and $3.5kg\;10a^{-1}$ for Milyang site. Lower level of soil nitrate N concentration for standard N fertilization was determined as $10mg\;kg^{-1}$ for both sites. Soil depth, bulk density, utilization rate of soil nitrate N, and the amount of N uptake for growth of a node with two leaves were considered for calculation of upper level of soil nitrate N concentration. The upper levels of soil nitrate N concentration for no N fertilization were determined as $30mg\;kg^{-1}$ for Gumsan site and as $40mg\;kg^{-1}$ for Milyang site. Consequently the recommendation equations for the N top dressing were Y=-0.157X+4.71 for Gumsan site and Y=-0.1667X+6.6667 for Milyang site.

Chinese Cabbage Growth Effected by Black Vinyl Mulching and Organic Fertilizer Application in Spring Season (유기질비료 시용시 흑색비닐 멀칭이 봄 배추 생육에 미치는 영향)

  • Yun, Hong-Bae;Lee, Jong-Sik;Lee, Ye-Jin;Kim, Rog-Young;Song, Yo-Sung;Han, Seung-Gap;Lee, Yong-Bok
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1107-1111
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    • 2011
  • Organic fertilizers application has become a popular alternatives to reduce the dependence on chemical fertilizer in Korean farming systems. In this study, we evaluated the nitrogen (N) use efficiency and growth performance of Chinese cabbage grown by black vinyl mulching after application of organic and chemical fertilizers compared with no-mulching. The treatments included chemical fertilizer alone as control (NPK, N-$P_2O_5-K_2O$ : $320-78-198kg\;ha^{-1}$), organic fertilizer alone (OF100), 70% organic fertilizer and 30% chemical fertilizer (OF70+N30), and 30% organic fertilizer and 70% chemical fertilizer (OF30+N70), which were all applied in the no-mulching plots and in plots with black vinyl mulching. Daily means soil temperature was $2^{\circ}C$ higher in the black vinyl mulched treatments throughout the 54 days compared with no-mulched treatments. OF100 with black vinyl mulching gave highest soil inorganic N content. Also, Chines cabbage yield increased 46% by black vinyl mulched compared with no-mulching in OF100 treatment. Without mulching, N use efficiency was, 44, 26, 29, and 27% in NPK, OF100, OF70+N30, and OF30+N70, respectively. However, black vinyl mulching much more effectively increased N use efficiencies by 56, 55, 51, and 39% in the same treatments in the order as mentioned above. Conclusively, combined organic and chemical fertilizers application with black vinyl mulching could be good practical technique to reduce a amount of used nitrogen because of its greater ability to enhance N use efficiency.

Prevalence of Pathogenic Bacteria in Livestock Manure Compost and Organic Fertilizer (가축분퇴비와 유기질비료에서 병원성박테리아의 분포도 분석)

  • Jung, Kyu-Seok;Heu, Sung-Gi;Roh, Eun-Jung;Lee, Dong-Hwan;Yun, Jong-Chul;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.824-829
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    • 2011
  • In recent years, there has been an increasing public concern about fecal contamination of water, air and agricultural produce by pathogens residing in organic fertilizers such as manure, compost and agricultural by-products. Efforts are now being made to control or eliminate the pathogen populations at on-farm level. Development of efficient on-farm strategies to mitigate the potential risk posed by the pathogens requires data about how the pathogens prevail in livestock manure composts and organic fertilizers. Microbiological analysis of livestock manure composts and organic fertilizers obtained from 32 and 28 companies, respectively, were conducted to determine the total aerobic bacteria count, coliforms, Escherichia coli count and the prevalence of Staphylococcus aureus, Bacillus cereus, Salmonella spp., Escherichia coli O157:H7, Listeria monocytogenes, and Cronobacter sakazakii. The total aerobic bacteria counts in the livestock manure composts and organic fertilizers were in the range of 7 to $9log\;CFU\;g^{-1}$ and 4 to $6log\;CFU\;g^{-1}$, respectively. In the livestock manure composts, coliforms and E. coli were detected in samples obtained from 4 and 2 companies, respectively, in the range of 2 to $5log\;CFU\;g^{-1}$ and $2log\;CFU\;g^{-1}$. In the organic fertilizers, coliforms and E. coli were detected in samples obtained from 4 and 1 companies, respectively, in the range of 1 to $3log\;CFU\;g^{-1}$ and $2log\;CFU\;g^{-1}$. In 3 out 32 compost samples, B. cereus was detected, while other pathogens were not detected. In 28 organic fertilizers, no pathogens were detected. The complete composting process can result in the elimination of pathogens in livestock manure compost and organic fertilizer. The results of this study could help to formulate microbiological guidelines for the use of compost in environmental-friendly agriculture. This research provides information regarding microbiological quality of livestock manure compost and organic fertilizer.

Stress Day Index to Predict Soybean Yield Response by Subsurface Drainage in Poorly Drained Sloping Paddy Fields (배수불량 경사지 논에서 배수개선에 따른 콩의 수분스트레스 반응해석)

  • Jung, Ki-Yuol;Yun, Eul-Soo;Park, Chang-Young;Hwang, Jae-Bok;Choi, Young-Dae;Park, Ki-Do
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.702-708
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    • 2011
  • There are considerable areas of wet paddy fields in Korea that requires improvement of its drainage system. In poorly drained sloping paddy fields, upland crops can be damaged by either rainfall or capillary rise of the water table caused by percolating water beneath the upper fields during summertime rainy season. The purpose of this study is to evaluate excess water stress of soybean yield by drainage systems. Four drainage methods namely open ditch, vinyl barrier, pipe drainage and tube bundle were installed within 1-m position at the lower edge of the upper paddy fields. Stress Day Index (SDI) approach was developed to quantify the the cumulative effect of stress imposed on a soybean yield throughout the growing season. SDI was determined from a stress day factor (SD) and a crop susceptibility factor (CS). The stress day factor is a measure degree and duration of stress of the ($SEW_{30}$). The crop susceptibility factor (CS) depends of a given excess water on crop stage. The results showed that SDI used to represent the moisture stress index was most low on the pipe drainage 64.75 compared with the open ditch 355.4, vinyl barrier 271.55 and tube bundle 171.55. Soybean grain yield increased continuously with the rate of 3% in Vinyl Barrier, 32% in Pipe Drainage and 16% in Tube Bundle.

Evaluation of Drainage Improvement Effect Using Geostatistical Analysis in Poorly Drained Sloping Paddy Soil (경사지 배수불량 논에서 배수개선 효과의 지구통계적 기법을 이용한 평가)

  • Jung, Ki-Yuol;Yun, Eul-Soo;Park, Ki-Do;Park, Chang-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.804-811
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    • 2010
  • The lower portion of sloping paddy fields normally contains excessive moisture and the higher water table caused by the inflow of ground water from the upper part of the field resulting in non-uniform water content distribution. Four drainage methods namely Open Ditch, Vinyl Barrier, Pipe Drainage and Tube Bundle for multiple land use were installed within 1-m position from the lower edge of the upper embankment of sloping alluvial paddy fields. Knowledge of the spatial variability of soil water properties is of primary importance for management of agricultural lands. This study was conducted to evaluate the effect of drainage in the soil on spatial variability of soil water content using the geostatistical analysis. The soil water content was collected by a TDR (Time Domain Reflectometry) sensor after the installation of subsurface drainage on regular square grid of 80 m at 20 m paddy field located at Oesan-ri, Buk-myeon, Changwon-si in alluvial slopping paddy fields ($35^{\circ}22^{\prime}$ N, $128^{\circ}35^{\prime}$). In order to obtain the most accurate field information, the sampling grid was divided 3 m by 3 m unit mesh by four drainage types. The results showed that spatial variance of soil water content by subsurface drainage was reduced, though yield of soybean showed the same trends. Value of "sill" of soil water content with semivariogram was 9.7 in Pipe Drainage, 86.2 in Open Ditch, and 66.8 in Vinyl Barrier and 15.7 in Tube Bundle.

Effluent Characteristics of Nonpoint Source Pollutant Loads at Paddy Fields during Cropping Period (영농기 광역논으로부터 비점오염물질 유출 특성)

  • Han, Kuk-Heon;Kim, Jin-Ho;Yoon, Kwang-Sik;Cho, Jae-Young;Kim, Won-Il;Yun, Sun-Gang;Lee, Jeong-Taek
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.18-24
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    • 2007
  • Paddy fields are apparently nonpoint source pollution and influence water environment. In order to improve water quality in rivers or lakes, to low nutrient load from paddy fields are required. To establish comprehensive plan to control agricultural non-point source pollution, it is imperative to get a quantitative evaluation on pollutants and pollution load from paddy fields. A field monitoring study was carried out to investigate the water balance and losses of nutrients from fields in Sumjin river basin. The size of paddy fields was 115 ha and the fields were irrigated from a pumping station. The observed total nitrogen loads from paddy fields were larger than those of the unit loads determined by Ministry of Environment data (MOE). It is because the nitrogen fertilization level at the studied field was higher than the recommended rate and the high irrigation and subsequent drainage amount. On the contrary, total phosphorus loads were less than those addressed by MOE since phosphorus fertilization level was lower than that of standard level. Therefore, it was found that fertilization, irrigation, and drainage management are key factors to determine nutrient losses from paddy fields. When the runoff losses of nutrients were compared to applied chemical fertilizer, it was found that 42 to 60% of nitrogen lost via runoff while runoff losses of phosphorus account for 1.3 to 7.6% of the total applied amount during the entire year.

Influences of Chinese Cabbage Growth and Soil Salinity to Alternative Irrigation Waters (대체관개 용수에 의한 배추생육 및 토양 염류도에 미치는 영향)

  • Shin, Joung-Du;Park, Sang-Won;Kim, Won-Il;Lee, Jong-Sik;Yun, Sun-Gang;Eom, Ki-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.25-30
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    • 2007
  • Objective of this experiment was to investigate the growth effects of Chinese cabbage and soil salinity to alternative irrigation waters for drought periods. The treatments were consisted of the discharge water from industrial wastewater treatment plant (DIWT), the discharge water from municipal wastewater treatment plant (DMWT) and ground water as the control. For the chemical compositions of alternative water, it appeared that concentrations of the $Ni^+$ and SAR values in DIWT were over the reuse criteria of other countries for irrigation, but CODcr concentration in DMWT was higher than the reuse criteria for agricultural irrigation. According to classification of water by $EC_i$ value, DIWT and DMWT are ranged from 0.7 to $2.0dS\;m^{-1}$, slight salinity. Average harvest indexes were 0.64 for DIWT and 0.63 for DMWT as compared to 0.61 of the control regardless of irrigation periods. SAR value in soil was increased with prolonging the irrigation periods at head forming stage, but not much difference except for 30 days of irrigation period at harvesting time for DIWT. However, it was not much difference along with irrigation periods through the growth stages for DMWT as compared with the groundwater. At harvesting time, average $EC_e$ for the soil irrigated with alternative agricultural waters was $0.017dS\;m^{-1}$ for its DIMT and $0.036dS\;m^{-1}$ for its DMWT as compared to $0.013dS\;m^{-1}$ of its groundwater as the control. For $NH_4-N$ concentrations, it observed that there were no differences among the treatments with different irrigation periods at head forming stage in soil after irrigation. Also, $NO_3-N$ concentration in soil was increased up to 20 days after irrigation, and then decreased at 30 days after irrigation with DMWT at head forming stage. The $Ni^+$ concentration in upper layer soil (0-15 cm) irrigated with DIWT was increased with prolonging the irrigation period at head forming stage, but it was dramatically decreased and almost constant in all the treatments at harvesting time. Therefore, it might be concluded that there was potentially safe to irrigate the discharge water from municipal wastewater treatment plant for 20 days after transplanting to drought periods with cultivating the Chinese cabbage.

A Study on the Oxy-Combustion of the Coal in Drop Tube Furnace (Drop Tube Furnace에서 석탄의 순산소 연소 특성)

  • Roh, Seon Ah;Yun, Jin Han;Lee, Jung Kyu;Keel, Sang In;Min, Tai Jin;Kim, Sang-Bok;Park, In-Yong;Han, Bangwoo;Kim, Jin-Tae
    • Clean Technology
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    • v.27 no.4
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    • pp.367-371
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    • 2021
  • The oxy-combustion system is one of the carbon recovery and storage technologies (CCS: Carbon capture & storage) that performs coal combustion using pure oxygen and recirculated flue gas. This is a technology that facilitates storage of carbon dioxide by generating an exhaust gas consisting of only carbon dioxide without a process of separating carbon dioxide and nitrogen when coal is burned using pure oxygen and recirculated flue gas mixture instead of a conventional air combustion system that produces carbon dioxide and nitrogen mixed exhaust gas. In this study, the characteristics of generated NO and SO2 as atmospheric pollutants during oxy-combustion were examined using O2/CO2 mixed simulation gas. The reaction temperature was varied from 900 ℃ to 1200 ℃ and oxygen partial pressure was varied from 30% to 50%. The results showed that NO and SO2 concentrations in flue gas increased as the oxygen concentration and the reaction temperature in the furnace increased. The partial pressure of CO2 in flue gas also increased as the oxygen concentration and the reaction temperature in the furnace increased. As a results of comparing NO production of 30% O2/CO2 oxy-combustion with air combustion, NO in flue gas increased with reaction temperature in both experiments and NO of oxy-combustion was 40 ~ 80 ppm lower than that of air combustion.

A Study on Under Keel Clearance of Gadeok Channel for the Safety Passage of Mega Container Ship (초대형 컨테이너선의 가덕수로 안전운항을 위한 선저여유수심 연구)

  • Ryu, Won;Kong, Suk-Young;Lee, Yun-Sok
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.6
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    • pp.789-797
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    • 2021
  • The worldwide sizes of container ships are rapidly increasing. The container ship size in 2005, which was about 9,200 TEU has increased to 24,000 TEU in recent times. In addition to the increase in the sizes of the container ships, the arrivals/departures of large container vessels to/from Korea have also increased. Hence, the necessity for reviewing safe passage of such vessels is emphasized. In the present study, a 24,000 TEU container vessel was used as a model ship to calculate the under-keel clearance (UKC) at Gadeok Channel through which vessels must pass to arrive at Busan New Port, in accordance with the Korean Port and Fishing Port Design Standards and Commentary. In addition, the maximum allowable speed that meets UKC standards was calculated using various squat formulas, whose results were then compared with the current speed limit standards. The analysis results show that Busan New Port requires 10% marginal water depth, and the squat that meets this requirement is 0.95 m. Gadeok Channel requires 15% marginal water depth, and the squat that meets this requirement is 1.78 m; in this case, the maximum allowable speed is calculated as 15 kts. Busan New Port has set the speed limit as 12 kts, which is higher than the calculated 11 kts. Thus, speed limit reconsideration is required in terms of safety. However, the set speed limit for Gadeok Channel is 12 kts, which is lower than the calculated 15 kts. Thus, additional considerations may be provided to increase the speed limits for smooth navigational passage of vessels. The present study, however, is constrained by the fact that it reflects only a limited number of elements in the UKC and allowable speed calculations; therefore, more accurate UKC and safe speed values can be suggested based on extended studies to this research.