• Title/Summary/Keyword: Yield grade

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The current status in the silicon crystal growth technology for solar cells (태양전지용 규소 결정 성장 기술 개발의 현황)

  • Lee, A-Young;Lee, Dong-Gue;Kim, Young-Kwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.2
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    • pp.47-53
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    • 2014
  • Three kinds of crystalline silicon have been used for the solar cell grade. First of all, single crystalline silicon is the main subject to enhance the production yield. Most of the efforts are focused on the control of the melt-crystal interface shape affected by the crystal-crucible rotation rate. The main subject in the multi-crystalline silicon ingot is the contamination control. Faster Ar gas flow above the melt surface will lower the carbon contamination in the crystal. And also, twin boundary electrically inactive is found to be more effective than grain boundary for the improvement of the MCLT. In the case of mono-like silicon material, propagation of the multi-crystalline silicon growing from the inner side crucible is the problem lowering the portion of the single crystalline part at the center of the ingot. Crystal growing apparatus giving higher cooling rate at the bottom and lower cooling rate at the side crucible was suggested as the optimum solution obtaining higher quality of the mono-like silicon ingot. Proper application of the seeds at the bottom of the crucible would be one of the solutions.

Preparation of Silicon Tetrachloride by Chlorination of Silicon (실리콘의 염소화반응에 의한 사염화규소 제조)

  • Park, Kyun Young;Lee, Mi Sun;Kim, Min Cheol;Lee, Chan Hee;Park, Hoey Kyung;Kang, Tae Won;Jeong, Hae Seong;Han, Kyoung Ah;Huh, Weon Hoe;You, Ji Cheol
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.407-410
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    • 2013
  • The chlorination of a metallurgical-grade silicon was carried out in a fluidized bed reactor, 25 mm in diameter. The flow rate of the chlorine admitted into the reactor was 0.2 L/min and that of the carrier nitrogen was 0.8~1.0 L/min. The reactor temperature was maintained at $450^{\circ}C$ and the temperature of the coolant at the $SiCl_4$ condenser was at $-5^{\circ}C$. The $SiCl_4$ yield increased with increasing the mole fraction of chlorine in the feed gas, exhibiting 28% at the mole fraction of 0.2. Further increase of the chlorine mole fraction was not attempted in a worry that the reactor might be failed due to the high exothermicity of the reaction. The production of $SiCl_4$ from silicon by fluidized bed chlorination was demonstrated on a laboratory scale, which is a stepping stone for future studies under more severe conditions toward industrial application.

Effect of Gypsum Application on Reducing Methane (CH4) Emission in a Reclaimed Coastal Paddy Soil (간척지 논 토양 개량제로서 석고처리가 메탄 배출량 저감에 미치는 영향)

  • Lim, Chang-Hyun;Kim, Sang-Yoon;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.30 no.3
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    • pp.243-251
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    • 2011
  • BACKGROUND: Gypsum($CaSO_4{\cdot}2H_2O$) is known as an ideal amendment to improve soil quality of the reclaimed coastal land. Since gypsum has very high concentration of electron acceptor like ${SO_4}^{2-}$, its application might be effective on reducing $CH_4$ emission during rice cultivation, but its effect has not been studied well. METHODS AND RESULTS: The effect of gypsum on $CH_4$ emission and rice growth characteristics was studied by pot test, which was packed by reclaimed paddy soils collected from Galsa, Hadong, Gyeongnam province. Chemical-grade gypsum was applied in two soils having EC 2.25 and 9.48 dS/m at rates of 0, 0.5, 1.0 and 2.0%(wt/wt). $CH_4$ emission was characterized a week interval by closed chamber method during rice cultivation. $CH_4$ emission rate was significantly decreased with increasing salt accumulation and gypsum application levels. With increasing gypsum application, dissolved ${SO_4}^{2-}$ concentration in the leachate water was significantly increased, which might have suppressed $CH_4$ production in soil. Total $CH_4$ flux was dramatically decreased with increasing gypsum application. In contrast, rice yield was increased with increasing gypsum application and then achieved maximum productivity at 1.0% gypsum application in two soils. CONCLUSION(s): Gypsum is a very good soil amendment to suppress $CH_4$ emission in reclaimed coastal paddy soils, and improve rice productivity and soil properties. The optimum application level of gypsum is assumed at ca. 1% to improve soil productivity with reducing effectively $CH_4$ emission during rice cultivation.

SHRIMP U-Pb Zircon Geochronology of the Guryong Group in Odesan Area, East Gyeonggi Massif, Korea: A new identification of Late Paleozoic Strata and Its Tectonic Implication (경기육괴 동부 오대산 지역의 구룡층군에 대한 SHRIMP U-Pb 저어콘 연대측정: 새로운 후기 고생대층의 인지와 지체구조적 의의)

  • Cho, Deung-Lyong
    • The Journal of the Petrological Society of Korea
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    • v.23 no.3
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    • pp.197-208
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    • 2014
  • Zircon separated from a biotite schist of the Guryong Group in Odesan area, eastern part of the Gyeonggi Massif in Korea were analysed for SHRIMP U-Pb ages. CL images display composite core-rim structures of the zircon, indicating an in-situ overgrowth of zircon through a high-grade metamorphism. The metamorphic zircon rims give a weighted mean age of $247{\pm}6Ma$. While the detrital zircon cores have zoning patterns and Th/U ratios indicative of a magmatic origin. Among 53 analyses from the cores, 46 data yield near concordant ages which are concentrated at $378{\pm}10Ma$ (n=9), $420{\pm}4Ma$ (n=6) and $1845{\pm}9Ma$ (n=18) with sporadic Neoproterozoic ($687{\pm}9Ma$) to late Archean ($2519{\pm}20Ma$) ages. The age data constraint sedimentation age of protolith of the Guryong Group, so far unknown, as late Paleozoic. The Guryong Group of this study is the first late Paleozoic strata reported from eastern Gyeonggi Massif, and its maximum depositional age (ca 378 Ma) is identical with those of the late Paleozoic strata in the southwestern Ogcheon Belt. The Triassic metamorphic age and abundant middle Paleozoic provenance (361~425 Ma) of the Guryong Group are similar with those reported from the Triassic collisional belt in central China. Thus this study indicates that the Odesan area would be an possible eastward extension of the Triassic collisional belt in central China.

Unstable Pathologic Vertebral Fractures in Multiple Myeloma : Propensity Score Matched Cohort Study between Reconstructive Surgery with Adjuvant Radiotherapy and Radiotherapy Alone

  • Park, Hyung-Youl;Kim, Young-Hoon;Ahn, Joo-Hyun;Ha, Kee-Yong;Kim, Sang-Il;Jung, Jae-Woong
    • Journal of Korean Neurosurgical Society
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    • v.65 no.2
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    • pp.287-296
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    • 2022
  • Objective : Although radiotherapy (RT) is recommended for multiple myeloma (MM) involving spine, the treatment of choice between reconstructive surgery with RT and RT alone for pathologic vertebral fractures (PVFs) associated with structural instability or neurologic compromises remains controversial. The purpose of this study was to evaluate the clinical efficacies of reconstructive surgery with adjuvant RT for treatment of MM with PVFs by comparing with matched cohorts treated with RT alone. Methods : Twenty-eight patients underwent reconstructive surgery followed by RT between 2008 and 2015 in a single institution, for management of PVFs associated with structural instability of the spine and/or neurologic compromises (group I). Twenty-eight patients were treated with RT alone (group II) after propensity score matching in a 1-to-1 format based on instability of the spine, as well as age and performance. Clinical outcomes including the overall survival rates, duration of independent ambulation, neurological status, and numeric rating scale (NRS) for back pain were compared. Results : Clinical and radiological features before treatment were similar in both groups. The median survival period was similar between the two groups. However, the mean duration of independent ambulation was significantly longer in group I (88.8 months; 95% confidence interval [CI], 66.0-111.5) than in group II (39.4 months; 95% CI, 25.2-53.6) (log rank test; p=0.022). Deterioration of Frankel grade (21.4% vs. 60.7%, p=0.024) and NRS for back pain (2.7±2.2 vs. 5.0±2.7, p=0.000) at the last follow-up were higher in the group II. Treatment-related complications were similar in both groups. Conclusion : In patients with unstable PVFs due to MM, reconstructive surgery may yield superior clinical outcomes compared with RT alone in maintaining independent ambulation and neurological status, as well as pain control despite similar median survival and complications.

Zircon U-Pb and Rare Earth Elements Analyses on Banded Gneiss in Euiam Gneiss Complex, Central Gyeonggi Massif: Consideration for the Timing of Depositional Event and Metamorphism of the Basement Rocks in the Gyeonggi Massif (경기육괴 중부 의암 편마암 복합체 호상편마암의 저어콘 U-Pb 연령과 미량원소: 경기육괴 기반암의 퇴적 시기와 변성작용에 대한 고찰)

  • Lee, Byung Choon;Cho, Deung-Lyong
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.215-233
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    • 2022
  • The zircon U-Pb and trace element analyses were performed for banded gneiss in the Euiam gneiss complex, central Gyeonggi Massif. An age of detrital zircon shows predominant age peaks at ca. 2500-2480 Ma with numerous ages ranging from Siderian to Rhyacian period. The youngest age peak of detrital zircon constrains the maximum deposition age of protolith of banded gneiss at ca. 2070 Ma. Meanwhile, the zircon rim yielded metamorphic age of ca. 1966 ± 39 Ma ~ 1918 ± 13 Ma. Based on the error range, degree of discordancy, and value of mean squared weighted deviation, we considered that the age of 1918 ± 13 Ma is the most reasonable age indicating the timing of metamorphism for banded gneiss. The zircon rims yield Ti-in-zircon crystallization temperature of 690-740℃. Therefore, we suggested that there was a high-grade metamorphic event in the Gyeonggi Massif at ca. 1918 Ma which is older than the metamorphic event that occurred in the Gyeonggi Massif during ca. 1880-1860 Ma.

Study of Hydrotreating and Hydrocracking Catalysts for Conversion of Waste Plastic Pyrolysis Oil to Naphtha (폐플라스틱 열분해유의 납사 전환을 위한 수첨처리 및 수첨분해 촉매연구)

  • Ki-Duk Kim;Eun Hee Kwon;Kwang Ho Kim;Suk Hyun Lim;Hai Hung Pham;Kang Seok Go;Sang Goo Jeon;Nam Sun Nho
    • Applied Chemistry for Engineering
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    • v.34 no.2
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    • pp.126-130
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    • 2023
  • In response to environmental demands, pyrolysis is one of the practical methods for obtaining reusable oils from waste plastics. However, the waste plastic pyrolysis oils (WPPO) are consumed as low-grade fuel oil due to their impurities. Thus, this study focused on the upgrading method to obtain naphtha catalytic cracking feedstocks from WPPO by the hydroprocessing, including hydrotreating and hydrocracking reaction. Especially, various transition metal sulfides supported catalysts were investigated as hydrotreating and hydrocracking catalysts. The catalytic performance was evaluated with a 250 ml-batch reactor at 370~400 ℃ and 6.0 MPa H2. Sulfur-, nitrogen-, and chlorine-compounds in WPPO were well eliminated with nickel-molybdenum/alumina catalysts. The NiMo/ZSM-5 catalyst has the highest naphtha yield.

Dietary effects of protected fat, glycerol, and soybean meal on performance, physiological parameters, carcass characteristics, and behavioral measurements of late-fattening Hanwoo steers under heat stress conditions

  • Jun Sik Woo;Gyeong Rim Ryu;Jeong Hoon Kim;Sun Sik Jang;Hong Gu Lee;Keun Kyu Park
    • Animal Bioscience
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    • v.37 no.7
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    • pp.1303-1315
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    • 2024
  • Objective: This study aimed to determine the effects of increasing energy and protein levels in diets by including protected fat (PF), glycerol (GL), and soybean meal (SBM) on growth performance, physiological parameters, carcass characteristics, and behavioral measurements of late-fattening Hanwoo steers under heat stress conditions. Methods: Thirty-six steers (initial body weight, 724.9±58.3 kg; age, 25.5±0.4 month) were assigned into control (total digestible nutrient [TDN] 76%, crude protein [CP] 15%), PF (TDN 83.6%, CP 15%), PF+GL (TDN 83.6%, CP 15%) and PF+GL+SBM (TDN 83.6%, CP 16.5%) by randomized complete block design for a total of 16 weeks with division of 4-week periods. The average temperature-humidity index was 87.0 (1st period; severe), 82.8 (2nd; moderate), 71.4 (3rd; comfort), and 68.1 (4th; comfort). Results: The dry matter intake (DMI) showed no treatments differences during the whole experiment. However, DMI in 1st and 2nd period decreased by approximately 30% and 10% compared to 4th period, respectively. Higher average daily gain and feed conversion ratio were noted for treatments compared to control at both 1st and 2nd period (p<0.05). There were no treatment effects on rectal temperature (RT), cortisol, and behaviors during the entire experiment. However, both RT and cortisol in 0, 1st and 2nd period were higher than those of 3rd and 4th period (p<0.05). Carcass yield and grade remained unaffected by increasing TDN and CP levels. Behavioral changes in the hot season (1st period) included reduced lying (43%), increased standing (48%), decreased walking (62%), and decreased eating (38%) (p<0.05), with an increase in drinking by 54%. Rumination during standing was 53% higher, while rumination during lying was about 33% lower compared to the post-hot season (3rd period) (p<0.05). Conclusion: Dietary supplementation of protected fat in late-fattening Hanwoo steers under heat stress had a positive effect on preventing a reduction in performance.

Effects of Concentrate Feeding Method and Slaughter Age on Growth Performance, Feed Intake and Carcass Characteristics of Hanwoo Steers (거세한우 배합사료 급여방법 및 출하월령이 발육, 사료섭취량 및 도체특성에 미치는 영향)

  • Cho, Young-Moo;Chang, Sun-Sik;Kim, Hyeong-Cheol;Kim, Tae-Il;Park, Byung-Ki;Paek, Bong-Hyun;Kim, Jin-Hyoung;Kwon, Eung-Gi
    • Journal of Animal Science and Technology
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    • v.51 no.1
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    • pp.53-60
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    • 2009
  • Thirty one Hanwoo steers were used in a completely randomized design experiment to see the effects of concentrate feeding method (group vs. individual feeding) and age at slaughter (26 vs. 28 months of age) on growth performance, feed intake and carcass characteristics. Steers were randomly assigned to one of four groups, G26 (group feeding slaughtered at 26 months of age), G28 (group feeding slaughtered at 28 months of age), I26 (individual feeding slaughtered at 26 months of age) or I28 (individual feeding slaughtered at 28 months of age). Amount of concentrate were restricted to 1.5% of BW for the growing period and 1.8% of BW for the early fattening period in both groups. For the late fattening period, concentrate were given ad libitum for G26 and G28, but were given up to 1.7% of BW for I26 and I28. Average daily gains were higher in individual feeding groups (I26 and I28) than those in group feeding groups (G26 and G28) for the early fattening period (p<0.05). ADGs were higher in group feeding groups than those in individual feeding groups (p<0.05). Concentrate intake in individual feeding groups tended to be higher compared to that in group feeding groups for the early fattening period, but tended to be higher in group feeding groups compared to that in individual feeding groups for the late fattening period. Feeding method or slaughter age had no significant effects on carcass characteristics, yield grade and quality grade. Shear force and tenderness of longissmus muscle were higher in groups slaughtered at 28 months of age than in groups slaughtered at 26 months of age (p<0.05). Feeding method or slaughter age had no effects on cooking loss, water holding capacity, juiciness, flavor, moisture, protein and fat of longissmus muscle.

Growth Efficiency, Carcass Quality Characteristics and Profitability of Finishing Pigs Slaughtered at 130 vs. 110Kg (110kg 대비 130kg에 도축된 비육돈의 성장효율, 도체 품질 특성 및 수익성)

  • 이철영;권오천;하덕민;신호원;이제룡;하영주;이진희;하승호;김원기;김광위;김두환
    • Journal of Animal Science and Technology
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    • v.48 no.4
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    • pp.493-502
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    • 2006
  • The slaughter weight (wt) is a most important economic factor in swine roduction. The present study was undertaken to determine if it is feasible to increase the slaughter wt of finishing pigs to 130kg without significantly affecting the growth efficiency and carcass quality. One hundred and sixty gilts and 160 barrows born from lean-type Yorkshire×Landrace (YL)-dam and Duroc (D)-sire lines, which are most widely used for terminal breeding for pork production in Gyeongsangnam-do, were randomly allocated into 16 pens under a 2 (sex)×2 (slaughter wt; 110 vs. 130kg) factorial arrangement of treatments. The animals were fed ad libitum a diet containing 3,200kcal DE/kg and 15.5% crude protein. After slaughter at the predetermined wt, yields of trimmed primal cuts and physicochemical characteristics of the longissimus dorsi muscle (LD) were measured or analyzed. Average daily gain was greater (P<0.01) in barrows than in gilts (0.86 vs. 0.79kg), but it was not different between the 110- and 130-kg slaughter wt groups (P>0.05). Backfat thickness was greater in the 130- vs. 110-kg group in both sexes (gilts: 21.6 vs. 17.6 mm, barrows: 25.1 vs. 20.8 mm). The yield percentage of belly was greater in barrows than in gilts (21.2 vs. 20.5%) and also in the 130-kg vs. 110-kg group (21.4 vs. 20.2%). Major physicochemical characteristics of LD including the color, percentage of 48-h drip loss, 24-h pH and percentages of crude protein and fat were not influenced by slaughter wt. Marginal profit of the 130-kg vs. 110-kg market pig was approximately 󰠏20,000 won/head, which resulted primarily from the heavy carcass weight of the former exceeding the upper limit of the A- or B-grade. However, if it had not been for the carcass weight limit of the current grading system, a 130-kg market pig would have had a potential marginal profit greater than 20,000 won. Results suggest that slaughter wt of lean-line finishing pigs can be increased to 130kg without significantly compromising the growth efficiency and carcass quality and accordingly, the upper weight limit of the ‘good-grade’ carcass needs to be increased or abolished to accommodate the larger market pigs.