• Title/Summary/Keyword: Yellowing

Search Result 260, Processing Time 0.067 seconds

Yellowing of Chemical Pulp by Glucuronoxylan

  • Kim, Young-Seok;Yoon, Byung-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.38 no.3 s.116
    • /
    • pp.23-28
    • /
    • 2006
  • Xylan in hemicellulose has been reported as one of the reasons of the yellowing of chemical pulp and paper. But little relevant information is available in literature. In this study, we examined into the influence that glucuronoxylan or glucomannan and metallic ion($Cu^{2+},\;Fe^{2+},\;Fe^{3+},\;Mn^{2+}$) residued in pulp get each or when mixed at yellowing. Filter paper was treated with each metallic ion, glucuronoxylan and the mixture of glucuronoxylan and metal ions, and brightness and CIE $L^*a^*b^*$ was measured after accelerated aging. As the results of measurements, the filter paper processed by 10% glucuronoxylan was dropped $2{\sim}3%$ on the brightness after accelerated aging for 24 hours. Also, the filter paper treated with glucuronoxylan and $Fe^{2+}$ was dropped 7% on the brightness.

Preparation of Yacht Sail Using High Tenacity Polyester and Its Performance Evaluation (폴리에스터 고강력사를 이용한 요트용 세일의 제조 및 성능분석)

  • Son, Hyun-Sik;Sim, Seung-Bum;Min, Mun-Hong
    • Textile Coloration and Finishing
    • /
    • v.24 no.1
    • /
    • pp.54-61
    • /
    • 2012
  • This study surveyed the preparation of 8oz coated fabric and the physical property of the coated fabric according to the treated condition for the sail yacht. And the coated fabrics were compared with the performance of overseas products for verification. Physical properties of the coated fabric treated with non-yellowing functional polyurethane resin were examined according to the treatment condition such as compression and ageing treatments. Finally, yellowing fastness to light for 60 hours was assessed. Considering the compression condition after coating, good physical property was obtained at $6kgf/cm^2$. Also, the performance of yellowing fastness was similar to performance of overseas goods.

Preparation and Physical Properties of Epoxy with Improved Yellowing Resistance for the Preservation of Stone Cultural Heritage (석조 문화재 보존용 저황변 Epoxy의 제조 및 물성 연구)

  • Lee, Seungyeon;Oh, Seungjun;Wi, Koangchul
    • Conservation Science in Museum
    • /
    • v.26
    • /
    • pp.1-12
    • /
    • 2021
  • The bisphenol A epoxy resin currently used for the conservation of stone cultural heritage items is known to suffer from yellowing discoloration. In order to mitigate this yellowing and explore the availability of more diverse materials for the conservation of stone cultural heritage items, a hydrogenated Bisphenol A-based epoxy resin was prepared and compared with the epoxy resin currently used in the conservation treatment of stone cultural heritage items. The newly prepared epoxy resin showed improved physical properties relative to the existing materials, especially in terms of tensile strength, adhesion, and machinability, while the yellowing discoloration was reduced by a factor of roughly five to eight. The results suggest that epoxy resin could be used as a stable material for the conservation treatment of stone cultural heritage items, most of which are located outdoors.

An Aplication Effect of UV-Absorbent on The Indigo Dyed Products (인디고 염색제품에 대한 자외선흡수제의 응용효과)

  • 차옥선;양진숙
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.23 no.6
    • /
    • pp.909-918
    • /
    • 1999
  • The indigo-dyed blue denim garments are favored not only by young people but also by almost everyone of life, In the early years they were casually worn on most occasions but became universal recently. Such denim garments are treated with various process to give it optimal softness and color contrast of blue and white. The processess can generate photoyellowing and thus the yellowing may damage their appearance and quality. So this study is to find the solutions to reduce the photoyellowing problem. For this prupose sample denim were treated with cellulase fluorescent brightener UV absorbent etc. The results were as follows; The yellowing would be more accelerated by fluorescent brightening. Since the yellowing was reduced by 90% In particular the application of the UV absorbent before using of the fluorescent brightener was most effective. The optimal concentration was 0.5% (o.w.f) and the benzophenone compounds were found most effective for the indigo denim. And reduction effect of yellowing by UV absorbent was lowered with repeated laundering but metal compound treatment on fabric made a removal of UV absorbent by laundering prevented.

  • PDF

DISCOLORATION OF CANNED BOILED OYSTER (굴 통조림의 변색과 그 방지)

  • LEE Kang-Ho;CHOE Wi-Kyung;PYEUN Jae-Hyeung;KIM Mu-Nam
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.9 no.2
    • /
    • pp.111-119
    • /
    • 1976
  • Discoloration of canned boiled oyster namely greening, yellowing and browning often occur separately or associatively in the storage of the product. Greening is mainly caused by the appearance of chlorophyll and its derivatives on the surface around the digestive diverticula of the oyster and yellowing by dispersion of carotenoid. Browning reactions by sugar amino condensation or enzymatic action, tyrosinase, also cause an undesirable color development. In this paper, the stability and the changes in distributional or partitional ratio of chlorophyll and carotenoid pigment of meat vs viscera in raw and canned oyster during six month storage in order to measure the dispersion rate of both pigments between meat and viscera, and to evaluate the feasibility of discoloration of oyster meat. The development of brownish pigment and the toss of free tyrosine in oyster were also determined to compare the readiness of color development. In addition the influence of processing and storage conditions to the dispersion rate and the tendency of discoloration, and finally the effect of inhibitor were discussed. The results showed that greening or yellowing was initiated by the dispersion of chlorophyll or carotenoids from viscera to the meat of oyster, and the dispersion rate of carotenoid was much higher than the chlorophyll's, so that, yellowing appeared a leading reaction of discoloration. The dispersion rate was obviously fastened by raising the temperature in the process of sterilization and storage. Consequently, the low temperature storage could largely retard the occurance of yellowing or greening of oyster meat. The pH control of canned oyster did not seem to affect the dispersion of pigment but significantly did on the stability of the piqments. Browning by the reaction of sugar-amino condensation and enzymatic oxidation of tyrosine was positively detected in canned oyster meat. The development of brownish color was influenced rather by the storage temperature than the heating process. Addition of sodium sulfite in can or treating the boiled oyster with sulfite solution prior to filling seemed possibly inhibit the color development particularly in cold-storaged oyster meat.

  • PDF

Yellowing Inhibition of Bagasse Chemimechanical Pulp

  • Andulkhani Ali;Mirshokraie Seyed Ahmad;Latibari Ahmad Jahan;Enayati Ali Akbar
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2006.06b
    • /
    • pp.337-347
    • /
    • 2006
  • Papers made from unbleached and bleached bagasse chemimechanical pulp were chemically modified by acetylation. The effects of irradiation on unbleached and bleached also reduced papers of bagasse chemimechanical pulp before and after acetylation were investigated in this study. Chemimechanical pulp was prepared from bagasse and then bleached with hydrogen peroxide. Unbleached and hydrogen bleached pulps were reduced by Sodium borohydride in different procedures. Paper sheets were prepared from pulps and then acetylated using a technical grade of acetic anhydride. Accelerated photo-aging was run on the samples using fluorescent lamps to verify photo-stability of paper sheets before and after pretreatments. Brightness reversion (as Post-color number) and other optical properties of the paper sheets were measured. Efficient inhibition of photo-yellowing of papers made from bagasse CMP was achieved by acetylation. The acetylated unbleached CMP was noticeably photo-bleached during irradiation. Sodium borohydride reduction followed by acetylation had the same effect as acetylation alone at the same degree of reaction time and reductive treatment did not affect the yellowing rate to any great extent. The pre-reduced, acetylated unbleached papers were, however, not brightened during irradiation. Calculation done by Kubelka-Munk equation showed that reductive treatment had little effect in reducing the photo-yellowing of paper made from CMP pulp; a small stabilization effect was observed in the case of bleached CMP, while unbleached CMP was slightly more prone to discolor in the later phase of photo-reversion. The improved stability towards light may was closely related to the decrease in the phenolic hydroxyl content as a result of blocking by acetyl groups during treatment with acetic anhydride. The results support the hypothesis that phenolic hydroxyl has an important role in the process of photo-reversion of high-yield pulps. The results obtained in this study demonstrate that the acetylation of paper manufactured from peroxide bleached Bagasse CMP significantly retards light-induced discoloration. The inhibition of yellowing is connected with a decrease in the phenolic hydroxyl content of both unbleached and peroxide bleached papers.

  • PDF

Phytoplasma Associated with Yellowing Disease of Washingtonia sp. in Kuwait

  • Al-Awadhi, Husain A.;Montasser, Magdy S.;Suleman, Patrice;Hanif, Asma M.
    • The Plant Pathology Journal
    • /
    • v.17 no.6
    • /
    • pp.329-335
    • /
    • 2001
  • Yellowing disease of palms caused by phytoplasma is spreading in the Arabian Gulf region. Surveys were conducted to determine the occurrence of the disease. Electron and fluorescence microscopy, and polymerase chain reaction (PCR) techniques were used to detect the phytoplasma associated with the yellowing disease of ornamental palm Washingtonia sp. grown in Kuwait. An accumulation of phytoplasmal DNA was observed by fluorescence microscopy in phloem tissues of diseased palms. Electron microscopy showed that phytoplasma cells were primarily confined to the phloemsieve elements of tissue samples collected from infected mature palms in the field. The pathogen was identified on the basis of molecular analysis using universal and specific nested primers in PCR amplifications. Prokaryotic 16S rDNA gene was detected in amplified PCR products. Nested PCR resulted in DNA amplification of 1.2 kbp fragment. This is the first report of a phytoplasmal rDNA gene identified from the putative causal pathogen of yellows in ornamental palms in the Arabian Gulf region.

  • PDF

A Study on the Development and Physical Properties of Low Yellowing Epoxy for Ceramic Preservation (도자기 복원용 저황변 Epoxy 수지의 개발 및 물성에 대한 연구)

  • Kim, Woo Hyun;Cheong, Da Som;Bae, Jin Soo;Jee, Joo Yeon;Wi, Koang Chul
    • Journal of Conservation Science
    • /
    • v.30 no.2
    • /
    • pp.181-187
    • /
    • 2014
  • AThe studies on ceramic preservation have been conducted widely in various institutions such as national/ public museums and research labs as well as the excavation institutions and university museums. Although there are some differences in preservation methodologies and materials used across the institutions, the variation is minimal. Specifically, epoxy resin is mostly used for ceramic restoration for its high cohesiveness, low contraction and high strength although there are some variations in for Ceramic Preservation. The synthetic resin type used according to the type of damage in the ceramic. However, the yellowing or the change of color across the time after the restoration is the weakness of epoxy resin. In this study, we aim to develop a material which minimizes this yellowing of epoxy resin while enhancing its cohesiveness and strength as well as other physical properties. We made the new material to have similar properties with those used widely for the ceramic restoration, such as EPO-TEK301$^{(R)}$, L30$^{(R)}$, XTR-311$^{(R)}$ through comparative experiments. The cohesiveness of the newly developed resin was improved to 2.51(MPa), which is similar level of XTR-311$^{(R)}$ of the 2.30(MPa) but about 2x higher than the other resins EPO-TEK301$^{(R)}$, L30$^{(R)}$ (1.21 and 1.81 (MPa), respectively). Especially, the experiment on yellowing shows that the existing resins show the range of color change at 10~25(${\Delta}E^*ab$), but the new low yellowing epoxy resin has the color change value at 8.3 (${\Delta}E^*ab$), the value lowering the yellowing effect to 1 to 3 times of the existing epoxy resin, thereby solving the issue of generating sense of differences due to change of color or yellowing.

Soil Physiochemical Properties in Leaf-yellowing Black Locust (Robinia Pseudo-acacia L.) Stands (아까시나무 황화현상 발생임분의 토양 이화학적 특성)

  • Lee, Seung-Woo;Byun, Jae-Kyoung;Ji, Dong-Hun;Kwon, Young-Dae
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.42 no.6
    • /
    • pp.409-414
    • /
    • 2009
  • In 1970's Black locust(Robinia pseudoacacia) had been widely planted Korea as an important forest greening species for erosion control afforestation. Since 2000, however, the tree's leaf-yellowing symptom has often been observed at a limited region and then spreaded out over the country in 2006. This study was conducted to study soil physiochemical properties of black locust stands with and without the leaf-yellowing symptom in Osan, Gyeonggi province. Most of soils in sampling sites were mostly slightly eroded, dry, and moderately dry. Available soil depth(16cm) and total soil depth(26cm) in leaf-yellowing (LY) site were significantly lower than in non leaf-yellowing (Non-LY) site's soil depths which were 30cm and 56cm, respectively. And solid phase proportion and bulk density in soils were lower in LY site than in non-LY site soils, while soil liquid phase proportion was also low. It could reflect that LY site soils might have a lower air and moisture movement in the rhizosphere of black locust stand compared with non-LY site soils. Soil acidity in both sites was very strong acid, soil pH (4.42) of LY site was slightly lower than non-LY site's (pH 4.54). Content of available phosphorous, exchangeable $Ca^{2+}$ and $Mg^{2+}$ and percent base saturation were less than LY site. These results indicated that soil physiochemical condition in LY site, more deteriorated than non-LY site, should adversely affect the retention and supply capacity of soil nutrients and moisture. Therefore the black locust may be more sensitive to other environmental stresses.