• Title/Summary/Keyword: Yb

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Fabrication of $Er^{3+}/Yb_3$ co-doped Soda-lime Glass Thin Films using Radio Frequency Magnetron Sputtering Method and Optical Property Characterization (RF 마그네트론 스퍼터에 의해 제조된 $Er^{3+}/Yb_3$ 도핑된 소다 라임 유리 박막의 제조 및 광학적 특성평가)

  • 임종모;김미옥;이병택;문종하;김진혁
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.42-43
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    • 2002
  • 고상 소결법으로 715iO$_2$+11$Na_2$O+10CaO+3Er$_2$O$_3$+5Yb$_2$O$_3$(all wt%) 조성의 스퍼터용 유리 타겟을 제조하여, RF 마그네트론 스퍼터에 의해 희토류 원소가 첨가된 광증폭기용 다성분계 sodium calcium silicate 유리박막을 제조하였다. 최적의 공정조건을 얻기 위해 RF-power, 공정압력, 기판온도를 변화시키면서 박막을 제조하여 RF-power 150W, 공정압력 4mtorr, 기판온도 50$0^{\circ}C$, 타겟-기판 거리 6cm에서 타겟의 손상이 심하지 않으면서, 1.4$mu extrm{m}$/h의 최고 증착율을 가지는 양질의 박막을 제조하였다. (중략)

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Fabrication of $SrZrO-3$-based Proton Conductors and Their Characterization

  • Yoo, Kwang-Soo;Byun, Douck-Young
    • The Korean Journal of Ceramics
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    • v.7 no.2
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    • pp.93-96
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    • 2001
  • The Y- or Yb-doped SrZrO$_3$ proton conductors were fabricated using the powders prepared by the self-propagating high-temperature synthesis (SHS). The electrical conductivity was evaluated from an a.c. impedance measurements. The conductivity of SrZr$_{0.92}$Yb$_{0.08}$O$_{3-\delta}$ was 1.8$\times$10$^{-3}$ Scm$^{-1}$ at $900^{\circ}C$ in dry air atmosphere and its activation energy was 0.50 eV. The conductivity in wet air was larger, compared with the dry air, and the activaton energy of SrZr$_{0.92}$Yb$_{0.08}$O$_{3-\delta}$ in wet air was 0.40 eV.

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Electrical Conductivity of Ytterbium Sesquioxide ($Yb_2O_3$) ($Yb_2O_3$의 전기 전도도)

  • 강영환;최재시;윤기현
    • Journal of the Korean Ceramic Society
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    • v.18 no.1
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    • pp.23-26
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    • 1981
  • The electrical conductivity of highly pure polycrystalline $Yb_2O_3$ has been measured from 650 to 105$0^{\circ}C$ under oxygen pressure range of $10^{-5}$ to 102 torr. The conductivity dependence of oxygen pressure in the temperature region from 750 to 105$0^{\circ}C$ is approximated by $\sigma$ $\alpha$ $Po_2^{1/5.3}$. This shows that the conduction mechanism is associated with doubly ionized metal vacancies. Fairly low activation energy and the lack of oxygen pressure dependence are found over the temperature range of 650 to 75$0^{\circ}C$. The conduction mechanism can be explaned by not metal vacancies, but hopping oxygen ions in the oxide.

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Thermal Effect of a Diode Side-Pumped Yb:YAG Laser Using a Diffusive Reflector (난반사체를 이용한 다이오드 횡여기 Yb:YAG 레이저의 열유도 효과 연구)

  • 이성만;김선국;윤미정;문희종;김현수;고도경;차병헌;이종민
    • Proceedings of the Optical Society of Korea Conference
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    • 2001.02a
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    • pp.46-47
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    • 2001
  • 난반사체를 이용한 다이오드 횡여기 Yb:YAG 레이저에서 레이저 결정의 반경과 레이저 결정의 도핑 농도 등을 매개변수로 하여 이들 매개변수의 변화가 열초점거리에 미치는 영향을 분석해 보았다. 이 때 결정의 굴절률은 1.826, 결정의 투과율은 90%, 결정의 길이는 10mm로 하였으며, 냉각수의 굴절률은 1.33, 냉각튜브의 두께는 1.5 mm로 하였다. 또 렌즈를 통과한 황선의 divergence는 5도, 난반사 공동체의 반사율은 95.7%로 계산하였다. 다이오드의 전체 출력은 600 W이다. 펌프헤드의 구조도를 그림1에 보였다. (중략)

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Microstructure and Mechanical Properties of Mg-Zn-Y-Yb Alloys Produced by Consolidation of Rapidly Solidified Ribbons

  • Sakamoto, Yoshihito;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1045-1047
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    • 2006
  • Fabrication of $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy has been performed through the consolidation of rapidly solidified ribbons. The $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy exhibited excellent mechanical properties, high tensile yield strength of 530 MPa, and large elongation of 3 %. Microstructure of the alloy was characterized by equiaxed fine grains that consist of -Mg, long period ordered (LPO) structure phase, and $Mg_5RE$-type cubic compound. The strengthening of the alloys may be due to fine grains with LPO structure phase and $Mg_5RE$-type compound.

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Analysis of Broad-Range DNA Fragments with Yttrium Oxide or Ytterbium Oxide Nanoparticle/Polymer Sieving Matrix Using High-Performance Capillary Electrophoresis

  • Kwon, Hae-Myun;Kim, Yong-Seong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.297-301
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    • 2009
  • We have developed the yttrium oxide (YNP) or ytterbium oxide (YbNP) nanoparticle/polymer matrices for the size-dependent separation of DNA ranging from 100 bp to 9,000 bp. High separation efficiency (> $10^6$ plates/m) and the baseline resolution for various DNA standards (100 bp, 500 bp, and 1 kbp DNA ladder) were obtained in 10 min with these matrices. The effects of concentrations of both polyethylene oxide (PEO) and nanoparticles were investigated and the highest performance was obtained at 0.02% PEO with 0.02% YNP or YbNP. Similar sieving power for both YNP and YbNP matrices was observed probably due to the similar sizes of nanoparticles, resulting in the formation of comparable sieving networks for DNA separation. For the reduction of electrosmotic flow, either dynamic or permanent coating of the capillary inner wall was compared and it turned out that PEO was superior to polyvinylpyrrolidone (PVP) or polyacrylamide (PAA) for better separation efficiency.

Cooling Geometry Dependent Operation Properties in a Diode End-Pumped Monolithic Yb:YAG Laser

  • Moon, Hee-Jong;Lim, Changhwan
    • Journal of the Optical Society of Korea
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    • v.20 no.5
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    • pp.593-600
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    • 2016
  • Operation properties, such as output power, beam radius, and crystal temperature rise were investigated in a diode-pumped edge-cooled monolithic Yb:YAG laser with ~ 4 W pumping level. The output power showed saturation behavior because of severe temperature rise and poor spatial overlapping between pump beam and lasing mode. Face cooling geometry by using a sapphire plate was also investigated. No apparent saturation behavior in output power was observed due to the reduced temperature rise, which could be attributed to efficient heat removal through the crystal-sapphire interface.

Solvent Effect on Relative Gibbs Free Energy and Structural Property of $Eu^{3+}\;to\;Yb^{3+}$ Ion Mutation: A Monte Carlo Simulation Study

  • Kim, Hak Seong
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.877-882
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    • 2001
  • The solvent effects on the relative free energies of Eu3+ to Yb3+ ion mutation in solution have been investigated using a Monte Carlo simulation of statistical perturbation theory (SPT). Our results agree well with available data that were obtained by others. Particularly, the results of water (SPC/E) solvent are almost identical with experimental data. For the present Eu3+ and Yb3+ ions, the relative free energies of solvation vs. Born’s function of bulk solvents decrease with increasing Born’s function of bulk solvents. There is also good agreement between the calculated structural properties in this study and the published works obtained by computer simulation and experimental work.

Near IR Spectroscopic Studies on the Interaction between Acetamide and Lu$(dpm)_3$ in Carbon Tetrachloride

  • 최영상;김홍순;유정아;이상원;박정희;윤창주
    • Bulletin of the Korean Chemical Society
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    • v.17 no.6
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    • pp.511-514
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    • 1996
  • The interactions between Ln(dpm)3 [Ln3+=Eu3+, Yb3+, Pr3+, Sm3+, Tb3+and Ho3+; dpm=tris 2,2,6,6-tetramethylheptane-3,5-dionate] and acetamide in CCl4 solution were investigated using near IR absorption spectroscopy. From the measured 2 νC=O+ amide Ⅲ combination band of acetamide in the region of 2130-2180 nm(4695-4587 cm-1), it was found that acetamide is coordinating through its carbonyl oxygen atom to Ln(dpm)3[C=O…Ln(dpm)3)] and forms only 1 : 1 stoichiometric Ln(dpm)3- acetamide complex. The ΔHo values for the formation of Ln(dpm)3-acetamide obtained from the temperature studies are -39.1, -28.4, -25.5, -24.7, -21.1 and -17.7 kJ mol-1 for Eu(dpm)3, Yb(dpm)3, Pr(dpm)3, Sm(dpm)3, Tb(dpm)3 and Ho(dpm)3, respectively, which are larger than those of the hydrogen bond between amide and various hydrogen acceptors. Except Eu(dpm)3 and Yb(dpm)3, -ΔHovalue increases as the ionic size increases.