• 대한화학회지
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• 제36권6호
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• pp.818-823
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• 1992

Y, Er, Yb, Ba 및 Cu를 각각 포함하는 유기금속 화합물인 2-Ethylhexanoate 화합물을 합성하였다. 합성된 유기금속화합물들은 모두 공통용매에 녹아 균일혼합물을 형성하였으며 이들을 원료물질로 하여 고온초전도체 $YBa_2Cu_3O_{7-\delta}(Y_{123})$, $ErBa_2Cu_3O_{7-\delta}(Er_{123})$ 및 $YbBa_2Cu_3O_{7-\delta}(Yb_{123})$를 제조하였다. X-선 회절분석결과 이들은 단일상이 아니었으며 $YBa_2Cu_4O_8(Y_{124})$를 포함한 약간씩의 불순물상을 포함하고 있었고, 이것은 자화율 측정에서도 확인되었다. Ceramic method로 제조한 시료에 비하여 임계온도가 대체로 높았으며, 부피반자성자화율은 큰 변화가 없는 것으로 판단된다.

• 한국세라믹학회지
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• 제35권1호
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• pp.79-87
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• 1998

Melt spun YbBa2Cu3Agx(x=0, 5, 12, 16 and 53) precursor alloy ribbons were oxidized at 263-330$^{\circ}C$ and treated at 820$^{\circ}C$, 855$^{\circ}C$ and 885$^{\circ}C$ under 1.0 atm oxygen pressure. In the ribbons treated at 820$^{\circ}C$, 855$^{\circ}C$and 885$^{\circ}C$ 1-2-4 phase (YbBa2Cu4O8) and 1-2-3 phase (YbBa2Cu3O{{{{ OMICRON _7-$\delta$ }})were formed respectively. The shape of 1-2-4 phase was distorted or ellipsoid. The 2-4-7 and 1-2-3 phases tooked the shape of bar. All the ribbons showed zero critical current density Jc at 77K in zero magnetic field. By considering the shape and the highest critical temperature (among the three phases) of the 1-2-3 phase we tried to increase the critical current density of the ribbons treated at 885$^{\circ}C$ by press deformation. About tenribbons were stacked and coupled by press deformation and then treated at 885$^{\circ}C$ These 1-2-3 phase did not show any texture in any of the ribbons. However they exhibited weak texture in the multilayered specimens. Among the multilayered specimens YbBa2Cu3Ag16 exhibited a Jc of 180 A/cm2 Among the above ribbons YbBa2Cu3Ag16 ribbon has the optimum composition to produce textured superconducting oxide with improved Jc by press deformation. Onset critical temperatures Ton of the multilayered YbBa2Cu3Agx(x=5, 12, 16 and 53) were measured as 88-90 K.

• E2M - 전기 전자와 첨단 소재
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• 제9권4호
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• pp.404-409
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• 1996

The structural and electric properties of $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$(x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) have been investigated by using XRD(X-ray diffraction), TMA(thennomechanical analysis), NMR(nuclear magnetic resonance) analysis and four probe method. $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$ samples were prepared by conventional solid-state reaction method using $Y_{2}$O$_{3}$, BaCO$_{3}$, CuO and YbF$_{3}$ power. TMA and high temperature XRD results shows that orthorhombic to tetragonal phase transition occurs in the unfluorinated 1-2-3 sample while the phase change is not observed in the fluorinated 1-2-3 samples. Superconducting transition temperature(T$_{c}$) increases with increasing YbF$_{3}$ content ; T$_{c}$, of the sample reaching maximum of 102K for x=0.3, and then decreases with further increasing YbF$_{3}$ content. The structural analysis and T$_{c}$ results shows that the fluorine doping stabilize the orthorhombic phase, together with the increase in T$_{c}$.}$ c/.TEX> c/.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1992년도 추계학술발표강연 및 논문개요집
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• pp.16-16
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• 1992

We have studied the effect of platinum addition on the supercon ducting properties of YB $a_2$C $u_3$$O_{7-x}$ (123) compound and elucidated the mechanism of fine dispersion of $Y_2$BaCu $O_{5}$(211) particles in YB $a_2$C $u_3$$O_{7-x}$ superconductor prepared by melting method from the metallurgical point of view. In this study, BaCu $O_2$ and CuO-rich phase unreacted during the peritecitc reaction markedly decreased by the 211 powder addition. The 211 particle of Pt-fee sintered samples exhibited 8~10$\mu$m in size, but in 1wt%Pt-added sample, 211 particles were finely dispersed in 123 matrix and the size of 211 particle was about 1~2$\mu$m. And, the critical temperature( $T_{c. zero}$) of Pt doped samples was 91.5K and the transport critical current density ( $J_{c}$) of Pt-doped samples was much more than 10$^4$A/$\textrm{cm}^2$. The high $J_{c}$ and fine dispersion of 211 particles of Pt doped YB $a_2$C $u_3$$O_{7-x}$ superconductor are attributed to $Ba_4$CuP $t_2$ $O_{8}$ compounds formed during the partial melting, which were considered als nucleation sites of 211 particles, rather than Pt inself.han Pt inself.

• 한국재료학회지
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• 제7권10호
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• pp.919-925
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• 1997

초기 혼합분말을 다르게 사용함으로써 다른 반응경로를 따라 성장된 일방향 집합조직 YB $a_{2}$BaCu $O_{5}$(Y211)형상과 분포가 초기 혼합분말이 달라짐에 따라 상당히 다르게 형성되었다. 여러 반응경로 중에서 $Y_{2}$ $O_{3}$+Y123$\longrightarrow$ $Y_{1.6}$Ba/ sub 2.2/ $O_{y}$와 ( $Y_{2}$ $O_{3}$BaCu $O_{2}$)+Y123$\longrightarrow$ $Y_{1.6}$B $a_{2.3}$C $u_{3.3}$ $O_{y}$반응에 의하여 용융공정된 경우 일방향 집합조직 Y 123 결정 성장이 잘 일어났으며, 특히 Y123의 포정반응 온도 이하의 낮은 온도에서도 결정성장이 일어났다. 또한 Y211입자 미세화가 다른 반응에 의한 용융공정보다 잘 일어났다. 이와같은 서로 다른 반응과정에 의하여 용융공정된 미세구조의 차이점들을 $Y_{2}$ $O_{3}$-BaO-CuO 3원계 상평형도를 이용하여 설명하였다.다.다.다.다.다.다.

• Progress in Superconductivity
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• 제3권1호
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• pp.1-4
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• 2001

Interface-engineered junctions with $YbBa_2$$Cu_3$$O_{7}$ as the counter electrode were demonstrated. The junctions exhibited excellent Josephson characteristics with a Josephson critical current ($I_{c}$) ranging from 0.1 mA to 8 mA and a magnetic field modulation of the $I_{c}$ exceeding 80% at 4.2 K while maintaining complete c-axis orientation of the counter-electrode layer. The$ 1\sigma$ spreads in $I_{c}$ for junctions with an average $I_{c}$ of 1-2 mA were 5-8% for 16 junctions within a chip, and 9.3% for a 100-junction array. Our dI/dV measurements suggest that a theoretical approach taking into account both a highly transparent barrier and the proximity effect is required to fully understand the Junction characteristics.ristics.

• 한국초전도ㆍ저온공학회논문지
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• 제6권3호
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• pp.16-20
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• 2004

YB $a_2$C $u_3$$O_{7-x}$ (YBCO) films were deposited on (100) SrTi $O_3$ single crystal substrates by a metal organic chemical vapor deposition (MOCVD) system of hot-wall type using single liquid source. Under the condition of the mole ratio of Y(tmhd)$_3$:Ba(tmhd)$_2$:Cu(tmhd)$_2$= 1:2.1:2.9. the deposition pressure of 10 Torr. the MO source line speed of 15 cm/min. the Ar/ $O_2$ flow rate of 800/800 sccm. YBCO films were prepared at the deposition temperatures of 780∼89$0^{\circ}C$. In case of the YBCO films with 2.2 ${\mu}{\textrm}{m}$ thickness deposited for 6 minutes at 86$0^{\circ}C$. XRD pattern showed complete c-axis growth and SEM morphology showed dense and crack-free surface. The atomic ratios of Ba/Y and Cu/Ba in the film were 1.92 and 1.56. respectively. The deposition rate of the film was as high as 0.37 ${\mu}{\textrm}{m}$/min. The critical temperature ( $T_{c.zero}$) of the film was 87K. The critical current of the film was 104 A/cm-width. and the critical current density was 0.47 MA/$\textrm{cm}^2$. For the thinner film of 1.3 ${\mu}{\textrm}{m}$ thickness. the critical current density of 0.62 MA/$\textrm{cm}^2$ was obtained.d.

• 한국재료학회지
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• 제5권7호
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• pp.880-887
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• 1995

융체방사법으로 제작한 YB $a_2$C $u_3$A $g_{15}$과 YbB $a_2$C $u_3$A $g_{x}$(x=5, 16 and 53) 예비 합금 리본(precursor alloy ribbon)을 263~322$^{\circ}C$에서 산화시키고, 산소 1기압 온도 872~89$0^{\circ}C$에서 열처리하였다. 또한 약 10개의 리본을 층으로 쌓아 프레스로 압축.접착시켜 다층 시편(multilayered specimen)을 제작하였다. 이 다충 시편도 위의 리본과 같은 조건에서 열처리하였다. YB $a_2$C $u_3$ $O_{7-{\delta}}$ 혹은 YbB $a_2$C $u_3$ $O_{7-{\delta}}$상이 모든 리본과 모든 다층 시편에서 형성되었다. 이 1-2-3상들은 모든 리본에서 집합조직(texture)을 나타내지 않았으나, 다층 시편들에서는 약간의 집합조직을 나타내었다. 모든 리본은 0 자장 77K에서 임계 전류 밀도 $J_{c}$가 0을 나타내었다. 다층 시편 중에서 YB $a_2$C $u_3$A $g_{15}$과 YbB $a_2$C $u_3$A $g_{16}$시편이 각각 260, 180A/$\textrm{cm}^2$의 임계 전류 밀도를 나타내었다. 여러 리본들 중에서 YB $a_2$C $u_3$A $g_{15}$ 과 YbB $a_2$C $u_3$A $g_{16}$ 리본이, 프레스 변형으로 집합조직을 가지게 함으로써 향상된 $J_{c}$를 가진 초전도 산화물을 만들 수 있는 적절한 조성을 가지고 있다. 다층 YB $a_2$C $u_3$A $g_{15}$ 시편의 개시 임계 온도 ( $T_{on}$ )는 92K 이었으며, 다층 YbB $a_2$C $u_3$A $g_{x}$(x=5, 16 and 53)의 $T_{on}$ 은 88~90K이었다.

• 한국지구과학회지
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• 제27권1호
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• pp.49-60
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• 2006

본 연구는 나주지역 하상퇴적물에 대한 지구화학적 특성 연구이다. 이를 위해 1차 수계를 대상으로 139개의 하상퇴적물 시료를 채취하였다. 채취된 시료는 실험실에서 자연 건조시켰으며, XRF, ICP-AES, NAA를 이용하여 화학분석을 실시하였다. 기반암에 따른 지구화학적 특성을 알아보기 위하여, 화강암질편마암 지역, 편암류 지역, 화강암류 지역, 사질암 지역, 응회암 지역, 안산암 지역, 유문암 지역으로 분류하였다. 나주지역 하상퇴적물의 지질집단별 주성분원소 평균함량은 $SiO_2\;58.37{\sim}66.06wt.%,\;Al_2O_3\;13.98{\sim}18.41wt.%,\;Fe_2O_3\;4.09{\sim}6.10wt.%,\;CaO\;0.54{\sim}1.33wt.%,\;MgO\;0.86{\sim}1.34wt.%,\;K_2O\;2.38{\sim}4.01wt.%,\;Na_2O\;0.90{\sim}1.32wt.%,\;TiO_2\;0.82{\sim}1.03wt.%,\;MnO\;0.09{\sim}0.15wt.%,\;P_2O_5\;0.11{\sim}0.18wt.%$이다. 주성분원소의 평균함량 비교에서 $Al_2O_3$와 $K_2O$는 화강암질편마암 지역에서, $Fe_2O_3,\;CaO,\;P_2O_5$는 응회암 지역에서, MgO와 $TiO_2$는 안산암 지역에서, $Na_2O$는 유문암 지역에서 높고, $SiO_2$와 MnO 함량은 사질암 지역에서 약간 높다. 미량성분 및 희토류원소의 지질집단별 평균함량은 $Ba\;1278{\sim}1469ppm,\;Be\;1.1{\sim}1.5ppm,\;Cu\;18{\sim}25ppm,\;Nb\;25{\sim}37ppm,\;Ni\;16{\sim}25ppm,\;Pb\;21{\sim}28ppm,\;Sr\;83{\sim}155ppm,\;V\;64{\sim}98ppm,\;Zr\;83{\sim}146ppm,\;Li\;32{\sim}45ppm,\;Co\;7.2{\sim}12.7ppm,\;Cr\;37{\sim}76ppm,\;Cs\;4.8{\sim}9.1ppm,\;Hf\;7.5{\sim}25ppm,\;Rb\;88{\sim}178ppm,\;Sc\;7.7{\sim}12.6ppm,\;Zn\;83{\sim}143ppm,\;Pa\;11.3{\sim}37ppm,\;Ce\;69{\sim}206ppm,\;Eu\;1.1{\sim}1.5ppm,\;Yb\;1.8{\sim}4.4ppm$이다. Pb, Li, Cs, Hf, Rb, Sb, Pa, Ce, Eu, Yb 평균함량은 화강암질편마암 지역에서, Ba, Co, Cr 평균함량은 편암류 지역에서, Nb, Ni, Zr 평균함량은 사질암 지역에서, Sr 평균함량은 응회암 지역에서 높고, Be, Cu, V, Sc, Zn 평균함량은 안산암 지역에서 다른 지질집단에서 보다 높다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.620-623
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• 2001

The peculiarities of using Self-propagating High-temperature Synthesis (SHS) and solid state phase synthesis for production of high temperature superconductor materials are discussed. Oxide superconductors with general formula $ReBa_2$$Cu_3$$O_{7-x}$ (Re= Y, Yb, Sm, Nd) have been made with using barium oxide initial powder instead of traditional barium carbonate. X-ray powder diffraction showed a single phase orthorhombic perovskite structure was produced in all reactions. Phenomena observed during the grinding of the reactant mixture are presented. Mechano-chemical activation - as a pretreatment of the reactant mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product.