• Title/Summary/Keyword: YBa$_2$Cu$_3$O$_y$

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Analysis of orientation distribution in polycrystalline YB$a_2$C${u_3}{O_7}$-X by electron channeling patterns (ECP 법을 이용한 YB$a_2$C${u_3}{O_7}$-X의 결정방위 분포해석)

  • Gang, Hwang-Jin
    • Korean Journal of Materials Research
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    • v.3 no.4
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    • pp.336-343
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    • 1993
  • The standard map for polyerystalline $YBa_2Cu_3O_7$-X was construeted and indexed from pressed tape sintered bulk and compressed bulk samples were drawn by the [001-110-110] stereographie quadrant map and by the ECPs from individual grains of the speeimens. The relationship between the (001) texture development and critical current density (Jc) for various samples was discussed. An (001) orintation was preferred in the pressed tape thickness was decreased. and in the compressed bulk as the compression strain was increaesed.The (001) orientation made a signifieant in crease on Jc. We conclded that an ECP technique was very useful for the analysis of the orientation distribution in small-sized $YBa_2Cu_3O_7$-X specimens such as superonducting tapes or thin films.

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Study on the preparation of BaPbO3 Additive for Improvement of YBCO Superconductor (YBCO 초전도체 특성 향상을 위한 첨가제 $BaPbO_3$ 제작에 관한 연구)

  • Cho, Yong-Joon;Soh, Dea-Wha;Park, Seong-Bum;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.55-58
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    • 2003
  • [ $YBa_2Cu_3Ox$ ](YBCO) oxide superconductor was prepared by sol-gel method to improve its superconducting properties, and it was made to be a fine powder, which has the same property of solid state reacted powder. $BaPbO_3$ was synthesized with $BaCO_3$, BaO, PbO, and $PbO_2$ and analyzed by XRD. YBCO superconductor was prepared by use of sol-gelled YBCO powder and additive $BaPbO_3$ and its critical temperature and transition temperature were shown as 91.9 K, 3.7 K respectively in case 20 wt.% $BaPbO_3$ was added to pure sol-gelled YBCO powder.

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Angle-dependent modulation of the critical current of YBa$_2Cu_3O_7$ step-edge Josephson junctions on SrTiO$_3$ substrate (SrTio$_3$ 기판 위에 제작된 YBa$_2Cu_3O_7$ 계단형 모서리 조셉슨 접합의 각도에 따른 임계전류 특성)

  • Hwang, Yun-Seok;Moon, Sun-Kyung;Lee, Soon-Gul;Kim, Jin-Tae
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.83-86
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    • 1999
  • We have fabricated $_2Cu_3O_7$ step-edge junctions with different step orientations and studied their transition properties. Steps with different orientations were prepared on the substrate. Josephson junctions were made on a single substrate with step orientations ranging from 0$^{\circ}$ to 165$^{\circ}$ at 15$^{\circ}$ interval. We measured current-voltage characteristics, the critical current, and the superconducting transition temperature as a function of the angle. The critical current showed a modulation that has a maximum near 0$^{\circ}$ or 90$^{\circ}$ and a minimum near 45$^{\circ}$ and 135$^{\circ}$. We believe that the critical current modulation with the step orientation could be associated with the symmetry of high T$_c$ superconductor.

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Properties of $YBa_2{Cu_3}O_{7-X}$ superconducting thin films prepared by visible light pulsed laser (기사광선 펄스 레이저에 의해 제작된 $YBa_2{Cu_3}O_{7-X}$초전도체 박막의 특성)

  • 신현용
    • Electrical & Electronic Materials
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    • v.7 no.4
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    • pp.289-293
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    • 1994
  • Thin films of YB $a_{2}$C $u_{3}$$O_{7-x}$ supercondYB $a_{2}$C $u_{3}$$O_{7-x}$uctor were prepared on (100) SrTi $O_{3}$ substrates by pulsed laser deposition using visible light laser. Q-switched Nd:YAG(532 nm, 30 ns) pulsed laser was used for deposition. The effects of substrate temperature and oxygen pressure during deposition on films were studied. Critical current density of 2.93*10$^{6}$ A/c $m^{2}$ at 77K and Tc(zero)=91.7K were obtained from the film prepared with Tsub=745.deg. C and $P_{02}$=200 mTorr. XRD analysis showed that the grown film has c-axis normal orientation to the substrate surface and has single phase. Surface morphology of the film has been improved by interfering the plume ejected from YB $a_{2}$C $u_{3}$$O_{7-x}$ target.arget.t.

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Electronic Structure Study of the Formal Oxidation States of Lead and Copper in $Pb_2Sr_2ACu_3O_8$ (A=Ln, Ln+Sr, or Ln+Ca) and Their Possible Changes upon Oxidation

  • 강대복
    • Bulletin of the Korean Chemical Society
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    • v.17 no.4
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    • pp.324-330
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    • 1996
  • We examined the formal oxidation states of Pb and Cu in the Pb2CuO4 slab of Pb2Sr2ACu3O8(A=Y1-xCaxor Nd1-xSrx) and their possible changes by oxygen incorporation in the Cu layer of the slab by performing tight-binding band electronic structure calculations on the Pb2CuO4+δ slab. Our results show that the most likely oxidation state of Pb is +2 and that of Cu is +1 for the Pb2CuO4 slab prior to oxidation. With small δ values, the oxygen incorporation occurs by the formation of such chain fragments as in YBa2Cu3O7-y along the a+b axis. The four-coordinate Cu atoms in the chain fragments are in the +3 oxidation states. For values of δ larger than 0.5, however, an additional oxygen (Oad) goes to the site along the b axis to form short Pb-Oad distances oxidizing Pb2+ to Pb4+. This change in the Pb oxidation state leads to the suppression of superconductivity due to the decrease of holes in the CuO2 layer.

Resistance distribution in large area thin film type SFCLS (박막형 대면적 초전도 한류소자에서의 저항 분포)

  • 김혜림;최효상;현옥배
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.1
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    • pp.89-93
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    • 2002
  • We investigated the resistance distribution n 4"diameter SFCLS. $YBa_2CU_3O_7$ films coated in-situ with a gold layer were patterned into 3 mm wide 142 cm long meander lines by Photolithography. The limiters were tested with simulated fault currents. The resistance was uniform all over the film except at the edge. At lower source voltages, CFCLs did not quench simultaneously and the resistance distribution was less uniform. Compared with 2" diameter SFCLS 4" SFCLS had similar values and time dependence of resistivity at similar electric fields The resistance distribution was more uniform in 4" SFCLS. The area at the edge where the distribution was not uniform was around 3 mm wide in SFCLs of both sizes. The experimental results were quantitatively explained with a heat transfer concept.