• 제목/요약/키워드: Y2O3

검색결과 33,206건 처리시간 0.068초

세라믹 Package 봉착용 유리의 결정화에 관한 연구 (Crystallization of Solder Glasses for Ceramic Package)

  • 손명모;박희찬;이헌수;강원호
    • 한국재료학회지
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    • 제1권4호
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    • pp.206-213
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    • 1991
  • PbO 77-80wt%, ZnO 4.5-6wt%, $B_2O_3$ 7.5-8.5wt%, $TiO_2$ 3-7wt%, $P_2O_5$ 0.5-2wt%의 조성을 갖는 IC Package봉착용 저융점($400-460^{\circ}C$) 결정화유리 frit를 제조하였다. DTA-TMA, X-선 회절분석, SEM 등을 이용하여 봉착용 유리의 결정화 특성을 연구하였다. $TiO_2$ 함량이 3wt% 함유시료는 $420-440^{\circ}C$에서 $2PbO{\cdot}ZnO{\cdot}B_2O_3$의 결정이 균일성장하였다. $TiO_2$ 함량이 4wt% 첨가된 시료는 $420-440^{\circ}C$에서 $2PbO{\cdot}ZnO{\cdot}B_2O_3와\;PbTiO_3$ 결정이 섞여서 혼합결정을 이루고 있었다. 또한 $TiO_2$ 5wt% 첨가된 시료는 $440-460^{\circ}C$에서 perovskite $PbTiO_3$ 결정만 석출되었다.

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$Al_2O_3+Y_2O_3를 첨가한 {\beta}-SiC-TiB_2$ 복합체의 특성 (Properties of the $\beta-SiC-TiB_2$ Composites with $Al_2O_3+Y_2O_3$ additives)

  • 임승혁;신용덕;주진영;윤세원;송준태
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권7호
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    • pp.394-399
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    • 2000
  • The mechanical and electrical properties of pressed and annealed $\beta-SiC-TiB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of $Al_2O_3+Y_2O_3$. Phase analysis of composites by XRD revealed $\alpha$-SiC(6H), TiB2, and (Al5Y3O12). Reaction between Al2O3 and $Y_2O_3$ formed YAG but the relative density decreased with increasing $Al_2O_3+Y_2O_3$ contents. The Flexural strength showed the value of 458.9 MPa for composites added with 4 wt% $Al_2O_3+Y_2O_3$ additives at room temperatures. Owing to crack deflection and crack bridging, the fracture toughness showed 6.2, 6.0 and 6.6 MPa.m1/2 for composites added with 4, 8 and 12 wt% Al2O3+Y2O3 additives respectively at room temperature. The resistance temperature coefficient showed the value of $3.6\times10^{-3},\; 2.9\times10^{-3}\; and\; 3.0\times10^{-3} /^{\circ}C$$^{\circ}C$ for composite added with 4, 8 and 12 wt% $Al_2O_3+Y_2O_3$additives respectively at room temperature. The electrical resistivity of the composites was all positive temperature coefficient resistance(PTCR) in the temperature range of $25^{\circ}C\; to\; 700^{\circ}$.

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$YBa_2Cu_3O_{7-}\delta$, $Y_2BaCuO_5$ 및 Ba-Cu-O계 화합물의 수분과의 반응에 의한 열방출에 관한 연구 (Heat Liberation in the Reaction of $YBa_2Cu_3O_{7-}\delta$, $Y_2BaCuO_5$, and Binary Compounds in the Ba-Cu-O System with Water)

  • 김배연
    • 한국세라믹학회지
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    • 제32권1호
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    • pp.83-89
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    • 1995
  • YBa2Cu3O7-$\delta$, Y2BaCuO5, and binary compounds in the Ba-Cu-O system with the nominal composition of Ba2CuO3, BaCuO2, Ba3Cu4O7, Ba3Cu5O8 were synthesized to investigate the heat evolutions and crystalline phases in the hydration reaction of orthorhombic YBa2Cu3O7-$\delta$ phase. The observed crystalline phases were YBa2Cu3O7-$\delta$, Y2BaCuO5, and BaCuO2, or Ba2Cu3O5+x, and some amount of noncrystalline phase in the Ba-Cu system comounds. In contact with distilled water, YBa2Cu3O7-$\delta$ and Y2BaCuO5 did not have considerable heat liberation, but in the binary compounds of the Ba-Cu-O system, the amount of total heat liberation was increased with respect to the Cu content. It might be that the reaction of high temperature superconductor YBa2Cu3O7-$\delta$ with water and/or moisture originated from the unusual oxidation state of Cu ion and the presence of amorphous Ba-Cu oxide compound. The degradation of high Tc superconductor by moisture and water could be controlled by restricting the heterogeneous distribution of Tc comlposition and the formation of second phase, such as stable Y2BaCuO5, and the resulting unstable Ba-Cu oxide compound.

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구형 SiO2@Y2O3: Eu 코어-쉘 복합체 형광체 합성 및 특성 (Synthesis and Characterization of Spherical SiO2@Y2O3 : Eu Core-Shell Composite Phosphors)

  • 송우석;양희선
    • 한국세라믹학회지
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    • 제48권5호
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    • pp.447-453
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    • 2011
  • The monodisperse spherical $SiO_2$ particles were overcoated with $Y_2O_3:Eu^{3+}$ phosphor layers via a Pechini sol-gel process and the resulting $SiO_2@Y_2O_3:Eu^{3+}$ core-shell phosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and luminescent property of core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL). The spherical, nonagglomerated $SiO_2$ particles prepared by a Stober method exhibited a relatively narrow size distribution in the range of 260-300 nm. The thickness of phosphor shell layer in the core-shell particles can be facilely controlled by varying the coating number of $Y_2O_3:Eu^{3+}$ phosphors. The core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors showed a strong red emission, which was dominated by the $^5D_0-^7F_2$ transition (610 nm) of $Eu^{3+}$ ion under the ultraviolet excitation (263 nm). The PL emission properties of $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were also compared with pure $Y_2O_3:Eu^{3+}$ nanophosphors.

$Al_{2}O_{3}+Y_{2}O_{3}$를 첨가한 $\beta$-SiC-$ZrB_2$ 복합체의 특성 (Properties of the $\beta$-SiC-$ZrB_2$ Composites with $Al_{2}O_{3}+Y_{2}O_{3}$ additives)

  • 신용덕;주진영
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.853-855
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    • 1998
  • The electrical resistivity and mechanical properties of the hot-pressed and annealed ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of $Al_{2}O_{3}+Y_{2}O_{3}$(6:4wt%). In this microstructures. no reactions were observed between $\beta$-SiC and $ZrB_2$, and the relative density is over 97.6% of the theoretical density. Phase analysis of composites by XRD revealed mostly of a $\alpha$-SiC(6H, 4H), $ZrB_2$ and weakly $\beta$-SiC(15R) phase. The fracture toughness decreased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents and showed the highest for composite added with 4wt% $Al_{2}O_{3}+Y_{2}O_{3}$ additives. The electrical resistivity increased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents because of the increasing tendency of pore formation according to amount of liquid forming additives $Al_{2}O_{3}+Y_{2}O_{3}$. The electrical resistivity of composites is all positive temperature coefficient resistance(PTCR) against temperature up to $700^{\circ}C$.

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$Al_2O_3+Y_2O_3 첨가량에 따른 {\beta}-SiC-ZrB_2$계 전도성 복합체의 특성 (The Properties of $\beta-SiC-ZrB_2$ Electroconductive Ceramic Composites with $Al_2O_3+Y_2O_3$Contents)

  • 신용덕;주진영;황철
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권9호
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    • pp.516-522
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    • 2000
  • The mechanical and electrical properties of the hot-pressed and annealed $\beta-SiC-ZrB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of$Al_2O_3+Y_2O_3$ Phase analysis of composites by XRD revealed $\alpha-SiC(6H) ZrB_2\; and YAG(Al_5Y_3O_{12})$ The relative density of composites were increased with increased Al2O3+Y2O3 contents. The Flexural strength showed the highest value of 390.6MPa for composites added with 20wt% Al2O3+Y2O3 additives at room temperature. Owing to crack deflection crack bridging phase transition and YAG of fracture toughness mechanism the fracture toughness showed the highest value of 6.3MPa.m1/2 for composites added with 24wt% Al2O3+Y2O3 additives at room temperature. The resistance temperature coefficient showed the value of$ 2.46\times10^{-3}\;, 2.47\times10^{-3},\; 2.52\times10^{-3}/^{\circ}C$ for composite added with 16, 20, 24wt% Al2O3+Y2O3 additives respectively. The electrical resistivity of the composites was all positive temperature coefficient resistance(PTCR) in the temperature range of $256{\circ}C\; to\; 900^{\circ}C$.

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조합화학을 이용한 CaO-Y2O3-Al2O3계의 Tb활성 형광체의 합성 및 검색 (Combinatorial Synthesis and Screening of the Tb-activated Phosphors in the System CaO-Y2O3-Al2O3)

  • 윤호신;김창해;강윤찬;유승곤;박희동
    • 한국재료학회지
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    • 제13권12호
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    • pp.785-790
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    • 2003
  • We have synthesized some phosphors in the system $CaO-Y_2$$O_3$-$Al_2$$O_3$by combinatorial polymerized-complex method. Composition and synthetic temperature of phosphors in the library was screened from the emission intensities of individual samples under VUV excitation. In $Tb^{ 3+}$-activated $CaO-Y_2$$O_3$-$Al_2$$O_3$, green phosphors showing good intensity were found to be X$O_3$$O_{7}$, CaYA1O$_4$, YA1O$_3$, $Y_3$$Al_{5}$$O_{12}$, $Y_4$$A1_2$$O_{9}$ .

4성분 Li2O-B2O3-Al2O3-SiO2 유리들의 구조로부터 굴절률과 경도 연구 (Studies of Refractive Index and Hardness from the structures in Quarternary Li2O-B2O3-Al2O3-SiO2 Glasses)

  • 문성준
    • 한국안광학회지
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    • 제7권2호
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    • pp.27-31
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    • 2002
  • 4성분 $Li_2O-B_2O_3-Al_2O_3-SiO_2$ 유리들을 $R({\equiv}Li_2Omole%/B_2O_3mole%)$$K({\equiv}(Al_2O_3mole%+SiO_2mole%/B_2O_3mole%)$에 의해 제작하여 유리들의 구조를 굴절률 (refractive index)과 Vicker's 경도(hardness)의 변화를 측정하여 분석하였다. 먼저, 굴절률의 증가는 유리 내부구조의 분극률을 증가시키는 $Li^+$ 양이온 수의 증가에 우선적으로 의존하여 증가하였으며, 적은 양의 리튬 산화물($Li_2O$)이 첨가된 영역에서는 굴절률은 리튬 이온 양에 의존하며, 많은 양의 리튬 산화물이 첨가된 영역에서는 큰 몰 부피를 갖고 하나의 비가교 산소를 갖는 $BO_3{^-}$ 단위들의 형성으로 유리 구조 내의 몰 부피 증가로 유리들의 굴절률의 증가가 둔화되었다. 그리고 알루미늄 산화물($Al_2O_3$)과 규소 산화물($SiO_2$)의 증가에 따라 굴절률의 감소는 $Al_2O_3$$SiO_2$에 의해 형성되어진 $AlO_4$ 단위들과 $SiO_4{^-}$ 단위들이 붕소 산화물($B_2O_3$)에 의해 형성되어진 $BO_4$단위들보다 몰 부피의 증가로 감소되어졌다. 또한, 경도의 증가는 유리 망목구조에 형성되어지는 $BO_4$ 단위 수에 의존하였으며, 경도의 감소는 유리 망목구조를 개방화시키는 $BO_3{^-}$ 단위 수에 의존하여 감소함을 알 수 있었다.

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CaO-Al$_2$O$_3$-SiO$_2$계 슬래그와 스피넬의 반응에 미치는 스피넬중의 MgO함유량의 영향 (Effects of MgO content of Spinel on the Reaction of Spinel with CaO-Al$_2$O$_3$-SiO$_2$ Slag)

  • 조문규;홍기곤
    • 한국세라믹학회지
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    • 제36권4호
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    • pp.410-416
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    • 1999
  • The reactivity of three kinds of spinels which CaO-Al2O3-SiO2 slag was investigated in terms of mineral phases and microstructures. New crystal products were not formed by reaction of 12CaO.7Al2O3 in the slag with spinels and free MgO components was preferenctially dissolved into slag for MgO-rich spinel and stoichiometric spinel. Meanwhile mineral phase was changed from 12CaO.7Al2O3 to CaO.Al2O3 to CaO.2Al2O3 finally to CaO.6Al2O3 having high melting point for Al2O3 -rich spinel. The Fe-oxide component of the slag was taken up by only stoichiometric spinel grains within the spinel clinker and the trapped amount of Fe-oxide was independent of MgO content of MgO in spinel clinker the more th resistance to slag corrosion but the less resistance to slag penetration.

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