• 공업화학
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• 제2권1호
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• pp.1-11
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• 1991

1980년대 발전된 크세논-129 핵자기 공명분광법은 제올라이트나 활성탄 또는 알루미나와 같은 다공성 물질에 크세논 기체를 흡착시킨 후에 기 기체중에 존재하는 천연동위원소 $^{129}Xe$의 핵자기 공명신호의 화학적이동(chemical shift)이나 선폭(linewidth)으로 부터 그 물질의 물리화학적 특성을 분석하는 방법이다. 현재까지 이 방법은 주로 제올라이트 촉매를 제조하거나 반응시키는 경우에 있어서 담지된 금속 물질의 위치와 화학변화 및 담체 자체의 성질변화 등을 감지하는데 있어서 탁월한 것으로 알려져 있으며, 최근에는 이 방법이 활성탄과 실리카, 알루미나와 같은 비정형 물질에도 효과적으로 적용될 수 있다는 것이 발표되었다. 여기서는, 이 크세논-129 핵자기 공명 분광법의 원리와 실험방법 및 불균일계 촉매연구 분야에서 이 방법의 이용에 대한 최근의 연구결과들을 요약하여 소개한다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
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• pp.220-222
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• 2005

We can classify two cases in a way to observe an atom of gas state or a molecule using the laser. First case is way to use dispersion phenomenon like Rayleigh scattering, Thomson scattering, Mie scattering, Raman Scattering. And Second case is a way to use change phenomenon like a LAS (Laser Absorption Spectroscopy), LIF (Laser Induced Fluorescent). In this paper, we have measured the meta-stable density and the distribution by using a LAS method in Xe discharge lamp. The laser absorption spectroscopy (LAS) is useful to investigate the behavior of such species. The xenon atoms in the $1S_4$ and $1S_5$ generate excited $Xe^*$(147nm) and $Xe_{2}^*$(173nm) dimers in Xe plasma. It is found that the intensity of VUV 147nm emission is proportional to that of the IR 828nm emission, and the VUV 173nm emission is roughly proportional to that of the IR 823nm emission. The laser is used CW laser that consist of AlGaAs semiconductor and energy level is used 823.16nm wavelength. We measured signal of monochrometer from the lamp center while will change a discharge electric current by 6mA in 3mA and calculated meta-stable state density of a xenon atom through a measured value.

• Current Optics and Photonics
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• 제4권6호
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• pp.466-471
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• 2020

We analyze the transverse nuclear magnetizations of 129Xe and 131Xe in a vapor cell containing natural Xe, 87Rb, and buffer gases. Th e Xe atoms are polarized th rough spin-exch ange optical pumping (SEOP) with Rb atoms under low-magnetic-field conditions. From the free-induction-decay (FID) signal, we measure the nuclear magnetization of the Xe atoms in the Xe-Rb vapor cell. Furthermore, we measure the dependence of the gyromagnetic ratio on the magnetization of 129Xe and 131Xe by examining the amplitude of the FID signal of each isotope, and we evaluate the relationship between the magnetic field gradient and transverse relaxation rate for both of the 129Xe and 131Xe isotopes.

• 대한전자공학회논문지
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• 제13권5호
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• pp.17-23
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• 1976

고속열중성자로에서 정상 운전중인 원자로를 운전정지하였다가 재가동할 때 가장 문제가 되는 것은 핵분열 생성물인 Xe135의 독소작용이다. 이것은 Xe135가 원자로 출력에 영향을 주는 열중성자에 대한 흡수단면적이 크고 그의 반감기가 길기 때문이다. 그러므로 원자로의 일시적 운전정지가 요구될 때 이의 재가시에는 반듯이 이 독소를 능과할 수 있는 충분한 초과반응도를 가해 주던지, Xe135가 붕괴되어 그의 농도가 줄어든 이후에야 원자로의 재가동이 가능하게 된다. 위와 같은 문제는 사실상 원자로 운전시 안전성 뿐만 아니라 경제성에도 큰 영향을 주고 있다. 본 논문에서는 이 점을 고려하여 Pontoyagin의 최대원리를 이용하여 운전정지를 최적화시키므로서 언제든지 원자로를 전출력으로 재가동할 수 있도록 운전정지 방법을 개선하였다. 그러나 제어과정에서나 그 이후에도 X, 농도는 제어된 허용치를 넘지 않고 최소시간 이내에 모든 제어를 끝내도록 하였다. The buildup of fission product, i.e. Xe-135 poisoning, is a prime factor in restarting a nuclear reactor from the shutdown, which was under normal operation in the high flux thermal reactor, It is caused by the high absorption crosssection of Xe-135 to thermal neutrons and its long half life, from which the thermal power is affected. It is then possible to restart a nuclear reactor after the sufficient excess reactivity to override this poisoning must be inserted, or its concentration is decreased sufficiently when its temporary shutdown is required. As ratter of fact, these have an important influence not only on reactor safety but also on economic aspect in operation. Considering these points in this study, the shutdown process was cptimized using the Pontryagin's maximum principle so that the shutdown mirth[d was improved as to restart the reactor to its fulpower at any time, but the xenon concentration did not excess the constrained allowable value during and after shutdown, at the same time all the control actions were completed within minimum time from beginning of the shutdown.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.515-517
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• 2004

The laser absorption spectroscopy has been used for measuresurement of the xenon atoms in the resonant $1S_4$ and metastable $1S_5$ states in coplanar AC PDP. For the purpose of improving VUV luminous efficiency and optimization of PDP cells, it is important to study behavior of excited Xe atoms in a micro-discharge cell of a coplanar AC-PDP. We measured the xenon excited density of $1S_5$ and $1S_4$ state under mixture gas of Ne-Xe(10%) with gas pressure of 350 Torr and sustaining gap distance of 150 um.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 광주전남지부
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• pp.43-47
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• 2006

In this paper, parameters of electron temperature and density for the mercury-free lighting-source were measured to diagnosis and analyze in Xe based inductively coupled plasma (ICP). As results at several dependences of 20~100mTorr Xenon pressure, the brightness of discharge tube was higher (4,900 $cd/m^2$) than other conditions when Xe pressure was 20mTorr and RF power was 200W. In that case, the electron temperature and density were 3.58eV and $3.56{\times}10^{12}cm^2$, respectively. The key parameters of Xe based ICP depended on Xe pressure more than RF power that could be verified. A high electron temperature and low electron density with a suitable Xe pressure are indispensible parameters for Xe based ICP lighting-source.

• Journal of Information Display
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• 제11권4호
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• pp.149-153
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• 2010

To improve the luminescence characteristics of high-efficiency alternating-current plasma display panels (AC-PDPs), we developed a new hoof-type electrode structure, and we studied the spatiotemporal behavior of the density of the excited Xenon atom in the $1s_5$ metastable state via laser absorption spectroscopy. Using this structure, the maximum density of the excited Xenon atom per cell was improved by 2.4 times that when the conventional electrode structure was used.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.511-514
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• 2012

A continuous flow hyperpolarized (HP) $^{129}Xe$ NMR spectroscopy was employed for the first time to investigate $TiO_2$ nanotubes (Ti-NTs) synthesized from commercial nanoparticles with different reaction times. A single peak attributing to channels for Ti-NTs was observed for variable temperature HP $^{129}Xe$ NMR spectra. It was also noted that there is alteration in value for heat of adsorption, ${\Delta}H$ from $12.6{\pm}1.3$ to $16.4{\pm}0.4kJ/mol$ and variation in chemical shift of the xenon adsorbed in channels, ${\delta}_s$ from $120{\pm}2\sim135{\pm}9ppm$ which were closely correlated to channel length and it was shown that P25-24 Ti-NTs with longest channel is most favorite Ti-NTs for Xe adsorption.

• 조명전기설비학회논문지
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• 제22권8호
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• pp.104-108
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• 2008

플라즈마 현상의 정량적 이해를 위해서는 원자나 분자기체가 가지고 있는 정확한 전자충돌단면적과 그 전자수송 계수의 값을 필요로 한다. 본 연구에서 사용하고 있는 Kr과 Xe 원자기체는 PDP와 무전각램프 등 다양한 산업 응용분야에 이용되고 있다. 따라서 2항 근사 볼츠만 해석에 의해 기체압력 1[torr]의 조건에 $0.001{\sim}500$[Td]의 광범위한 E/N에서 순수 Kr과 Xe 원자기체의 전자이동속도 W, 종 횡축확산계수 $ND_L$과 $ND_T$, 전리계수 $\alpha$/N의 전자수송 계수를 계산하고 물성 해석하였다.

• Nuclear Engineering and Technology
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• 제48권3호
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• pp.758-764
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• 2016

Specimens of stainless steel reactor internals were irradiated with 240 keV protons and 6 MeV Xe ions at room temperature. Nanoindentation constant stiffness measurement tests were carried out to study the hardness variations. An irradiation hardening effect was observed in proton- and Xe-irradiated specimens and more irradiation damage causes a larger hardness increment. The Nix-Gao model was used to extract the bulk-equivalent hardness of irradiation-damaged region and critical indentation depth. A different hardening level under H and Xe irradiation was obtained and the discrepancies of displacement damage rate and ion species may be the probable reasons. It was observed that the hardness of Xe-irradiated specimens saturate at about 2 displacement/atom (dpa), whereas in the case of proton irradiation, the saturation hardness may be more than 7 dpa. This discrepancy may be due to the different damage distributions.