• Journal of the Korean Geotechnical Society
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• v.28 no.6
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• pp.53-61
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• 2012

The purpose of this study is to understand the mechanism of cementation of soil induced by bacteria. In order to understand the mechanism of cementation of soft soils treated with bacteria, six types of specimens(Not treated, Normal concentration bacteria treatment, High concentration bacteria treatment, Supernatant high concentration bacteria treatment, Double high concentration bacteria treatment, and 25% Specimen high concentration bacteria treatment) were made. Scanning Electron Microscope (SEM), EDX and X-ray diffraction (XRD) analyses were performed on the soft silt and loose sand specimens. Compared with the normal bacteria concentration treated specimen, a clearer cementation between particles was observed in the 25% specimen high bacteria concentration treated specimen. On the basis of the preliminary results, it appears that microbial cementation can occur in the soft soil.

• Analytical Science and Technology
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• v.21 no.3
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• pp.229-236
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• 2008

$C/TiO_2$ composites were prepared with surface modified MWCNT sequentially after HCl treatment and TNB as titanium source. There is a single crystal structure which is anatase in all of the samples from the data of XRD. The SEM microphotographs of $C/TiO_2$ composites show that the $TiO_2$ particles were well mixed with the CNT. There are C, O and Al with strong Ti peaks in all samples from EDX results, and it also shows that the sample CT has much more amount of C and Ti content than that of sample HCT. Finally, the photocatalytic activities for the $C/TiO_2$ composites have more effective than that of pristine $TiO_2$.

• Applied Chemistry for Engineering
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• v.18 no.1
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• pp.48-53
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• 2007

Pulverization characteristics of H-kenyaite in vibration mill and exfoliation property in epoxy of pulverized H-kenyaite was investigated by using XRD, SEM, TEM. and particle size analyzer. Pulverization was conducted for 0.5~5 h. The particle morphology of sample pulverized for 1 h preserved plate-shape. However, this plate-shape disappeared in the sample pulverized for 3 h. The XRD pattern of sample pulverized for 1 h showed the characteristic peak of H-kenyaite. However, the peak disappeared in samples pulverized above 3 h, indicating severe destruction of H-kenyaite structure. TEM analysis for the kenyaite/epoxy nanocomposites exhibited only gallery expansion of 3~5 nm in non-pulverized sample, but dramatical large expansion of 5~10 nm in the samples pulverized during 1 h. This results confirm that the pulverization of wide plates composed of H-kenyaite particle have largely affect on the formation of an exfoliated kenyaite-polymer nanocomposite.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.11b
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• pp.18-30
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• 2002

이암 및 셰일은 점토를 함유하고 있어 풍화작용을 받을 경우 공학적 성질이 급격히 변화하여 강도 저하, 내구성저하현상 및 토사와 유사한 거동을 보이는 등 토목공사에 위험한 요소가 되고 있다. 풍화된 시료엔 대한 실험용 시료 가공이 어렵고 적용 가능한 실험법이 적어 공학적 특성이나 거동을 정량적으로 파악하는 기법이 다른 암종에 비해 극히 제한된다. 현재까지 강도측정과 같은 일반적인 물성의 단순측정보다는 내구성을 분석하는 슬레이킹 내구성 시험 (Slake durability test), Modified Jar test, 팽창율 측정시험 (Swelling test) 등의 정량화 시험법이 주로 사용되고 있으며 국내 현장에서도 적용을 권장할 수 있다. 이러한 실험치의 해석에서 단일 실험치 (예: 팽창율)만으로 지질공학적 특성을 파악하는 경우 잘못된 판단을 할 수도 있으므로, X선 회절분석시험 (XRD: X-Ray Diffraction Test), TG-DTA분석, 주사전자현미경 (SEM: Scanning Electron Microscope) 이미지 분석, 투수계수 측정실험 등도 함께 수행하여 실험결과를 종합적으로 해석하는 것이 바람직하다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.167-167
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• 2010

Ge-Sb-Se계 칼코게나이드 유리의 Melting 조건변화에 따른 특성변화를 연구하였다. Glass melting 조건(homogenization-temperature, homogenization-time, annealing) 에 따라 제작된 칼코게나이드 유리 bulk를 FT-IR, XRD, SEM 등의 분석장비를 이용하여 특성을 분석하였다. Homogenization temperature가 높을수록 석영관 급냉 시 발생되는 mechanical stress와 내부응력차로 인해 칼코게나이드 유리 깨짐현상이 증가하였으며 조성비와 melting 조건에 따라 XRD분석에서 확인되지 않는 미소결정이 SEM 분석결과 관찰되었다. 본 연구를 통해 칼코게나이드 유리의 melting 조건에 따른 경향성을 확인할 수 있었다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.5
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• pp.1760-1767
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• 2010

FAT compounds photocatalysts were prepared with $TiOSO_4{\cdot}xH_2O$ (TOS) by a sol-gel method. The samples were characterized by scanning electron microscopy (SEM), BET specific surface area, X-ray diffraction analysis (XRD) and energy dispersive X-ray spectroscopy (EDX). The SEM results showed that ferric compounds and titanium dioxide were fixed onto the AC surfaces. The XRD results showed that Fe-AC/$TiO_2$ composites mostly contained anatase phase. EDX showed the presence of C, O, and Ti with Fe peaks in all samples. The photocatalytic activities were evaluated by the photocatalytic oxidation of methylene blue (MB) solution, via compare photodegradation of MB solution under visible light and UV light separately. Fe-AC/$TiO_2$ composites had an excellent photocatalytic under strong visible light irradiation. A small amount of Fe ions in AC/$TiO_2$ particles could obviously enhance their photocatalytic activity.

• Analytical Science and Technology
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• v.18 no.4
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• pp.355-361
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• 2005

The objective of this paper is to compare the surface features of two kinds of activated caron fiber (ACF) treated with potassium and the variation of their properties by phosphoric acid pre-treatment. X-ray diffraction (XRD) patterns indicate that activated carbon fiber containing potassium species show better performance for metal and metal salts by pre-treatment with phosphoric acid. In order to present the causes of the differences in surface properties and specific surface area after the samples were treated with phosphoric acid, pore structure and surface morphology were investigated by adsorption analysis and SEM. For the chemical composition microanalysis for potassium leading of the activated carbon fibers pre-treated with phosphoric acid, samples were analyzed by EDX. Finally, the type and quality of oxygen groups were determined from the method proposed by Boehm.

• Journal of Energy Engineering
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• v.20 no.4
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• pp.309-317
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• 2011

The effect of physical properties of coal fuels and carbon particle on performance of DCFC (Direct Carbon Fuel Cell) was investigated. Shenhua and Adaro were selected as coal fuel and carbon particle was used for comparing with coal. The Ultimate, proximate, SEM, XRD, and BET analysis of samples were conducted. The component of char was more important than that of raw coal because the operating temperature of reactor is higher than devolatilization region of coal. The surface area and volume of pores affected significantly the performance of the system than content of fixed carbon or char rates. The performance of DCFC with carbon particle was in proportional to working temperature.

• Journal of the Korea Institute of Building Construction
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• v.23 no.6
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• pp.693-702
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• 2023

This research explores the potential application of Liquid Red Mud(LRM), a byproduct of industrial processes, in the construction sector. We neutralized LRM(pH 10-12) using nitric acid, aiming to understand its viability in construction applications. The study involved substituting LRM(pH 7-8) in mortar formulations, varying by cement type. We assessed the properties of these mixtures by measuring flow, setting time, and compressive strength. Additionally, X-ray Diffraction(XRD) and Scanning Electron Microscopy(SEM) analyses were conducted to examine the chemical properties. Results indicated a reduction in flow value for LRM and LN(neutralized LRM) compared to the control (Plain ) across different cement types. The setting times(initial and final) for LRM and LN were notably shorter than Plain. In compressive strength tests, LRM replaced with slag cement showed enhanced initial strength, though long-term strength gains were marginal across different cement types. SEM analysis revealed distinct voids in Plain and LN, with LRM exhibiting a fibrous microstructure. XRD patterns in SN(slag neutralized) resembled those in OR(original red mud) and ON(original neutralized), with a notable peak at a 2θ value of 22°. The study concludes that unneutralized LRM, when substituted for slag cement in mortar, yields superior initial strength compared to its neutralized counterpart.

• Journal of the Korea Institute of Building Construction
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• v.23 no.3
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• pp.231-240
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• 2023

In this research, our goal was to explore the potential use of cement mortar augmented with liquid red mud. To facilitate this, we neutralized liquid red mud(LR) - exhibiting a pH of 10-12 - using sulfuric acid to yield sulfuric acid neutralized red mud(SR). We then evaluated the flow, setting time, and compressive strength of the cement mortar combined with liquid red mud, while also performing a thorough examination of its chemical properties through X-ray diffraction(XRD) and scanning electron microscopy(SEM). The flow tests indicated a decrease in flow values for both MS-LR and MS-SR in comparison to the Plain. Analogously, the setting time for MS-LR and MS-SR was found to be abbreviated when juxtaposed with the Plain. With regards to compressive strength, MS-LR demonstrated a surge in strength at the 1-day mark, while MS-SR displayed a diminution at the 1-day and 3-day timepoints compared to the Plain. XRD analysis illustrated that after 28 days, the XRD patterns of Plain and MS-SR bore significant resemblance, though a new peak was detected in MS-LR. SEM imagery highlighted that the microstructures of Plain and MS-SR were alike, but MS-LR manifested a distinct microstructure, characterized by a finely fibrous formation. Based on these observations, we infer that the replacement of cement mortar with liquid red mud neutralized with sulfuric acid contributes to a noticeable enhancement in strength, thereby verifying its suitability for this application.