• Title/Summary/Keyword: XCO

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Petrogenesis of the Skarn at the Dielette, Cotentin, France (디엘레트지역(地域) 스카른의 암석학적(岩石學的) 성인연구(成因硏究))

  • Chang, Ho Wan
    • Economic and Environmental Geology
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    • v.18 no.2
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    • pp.139-150
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    • 1985
  • Skarn at the Dielette formed largely in calc-silicate hornfels at the contact with the Flamanville granite. The skarn consists mainly of garnet and pyroxene, and less frequently vesuvianite. Traversing toward calc-silicate hornfels wall rock from a central zone of the skarn, the general sequence of formation of mineral assemblages is: (1) dark brown garnet (2) pale brown garnet-vesuvianite-pyroxene, and (3) pyroxene-prehnite-scapolite-wollastonite envelopes (designated as transition zone) developed between skarn and calc-silicate hornfels. The central zone of the skarn consists mainly of dark brown garnets (garnet I) that contain little or no pyroxene. The pale brown garnet (garnet II) is associated with pyroxene and vesuvianite. The sequence of these garnets results from the zonal growth outward. There is an abrupt discontinuity in composition between garnet I formed in early stage and garnet II in late stage, while each garnet shows relatively uniform composition. At the zone in contact with the granite, the iron contents of garnets decrease toward the marginal zone of the skarn, from an average value of 36 mole % andradite in garnet I to 18 mole % andradite in garnet II. At the zone distant from the granite, the andradite component decreases from 28 mole % in garnet 1 to 19 mole % in garnet II. The variation of the iron contents of pyroxenes is also similar to that of garnets. The sharp discontinuity in composition of garnets and pyroxenes suggests that the skarn of study area was formed by infiltration metasomatic process. The results of the analyses of mineral assemblages of the transition zone by chemical potential diagrams suggest that the transition zone was made by the diffusion of the elements Ca, K and Fe from the skarn to the calc-silicate hornfels contact zone. The estimated temperatures and $Xco_2$ for the formation of the transition zone show $300^{\circ}C$$440^{\circ}C$ and $0.07{\pm}0.05<Xco_2<0.02{\pm}0.01$ at 1 Kb respectively.

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Characteristics of Satellite-Based CO/CO2, CO/NO2 Ratio in South Korea and China (한국과 중국의 도시별 위성기반 CO/CO2, CO/NO2 비율 특성)

  • Jieun Yu;Jaemin Kim;Jin Ah Jang;Jeong-Ah Yu;Seung-Yeon Kim;Yun Gon Lee
    • Korean Journal of Remote Sensing
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    • v.39 no.2
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    • pp.129-142
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    • 2023
  • This study analyzed the ratio of carbon monoxide (CO) and carbon dioxide (CO2), CO and nitrogen dioxide (NO2) for cities and regionsin Korea and China using column-averaged carbon dioxide dry-air mole fraction (XCO2) of the Orbiting Carbon Observatory-2/3, CO and NO2 vertical column density (named XCO, XNO2 in thisstudy) of TROPOspheric monitoring instrument from April 2018 to April 2022, and presented the relationship between socioeconomic indicators (population, number of vehicles, Gross Regional Domestic Product) and ratio, and differences in characteristics between Korea and China. First, CO2 and CO were analyzed after calculating ΔXCO2 and ΔXCO removing the background value and trend line due to the difference in atmospheric residence time of three gaseous substances (CO2, CO, and NO2). Comparing the three values by regions, ΔXCO and ΔXCO2 were relatively higher in China and XNO2 were higher in Korea and the ratio of both values (ΔXCO/ΔXCO2, ΔXCO/XNO2) was higher in China than in Korea. ΔXCO/ΔXCO2, ΔXCO/XNO2 and socioeconomic indicators have a positive correlation suggesting that the concentration of air pollutants and greenhouse gases is higher as the city is large and the economic activity is active. Regarding the differences in the ratio characteristics of Korea and China, the relationship between ΔXCO and ΔXCO2 showed a negative correlation in Korea and a positive correlation in China. When the relationship between ΔXCO and XNO2 was examined for summer and winter, the change of ΔXCO by season was not significant in Korea, whereasthe change of ΔXCO and XNO2 by season waslarge in China resulting in the relationship between two countries appeared differently. These results suggest that seasonal variability and national emission characteristics should be considered in the process of analyzing the ratio of greenhouse gases to air pollutants.

Skarn-Ore Associations and Phase Equilibria in the Yeonhwa-Keodo Mines, Korea (태백산광화대(太白山鑛化帶) 연화(蓮花)-거도광산(巨道鑛山)에 있어서의 스카른과 광석광물(鑛石鑛物)의 수반관계(隨伴關係) 및 상평형(相平衡))

  • Yun, Suckew
    • Economic and Environmental Geology
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    • v.16 no.1
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    • pp.1-10
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    • 1983
  • The Yeonhwa (I, II) and Keodo mines, neighboring in the middle part of the Taebaegsan mineral belt, contain three distinct classes of skarn deposits: the zinc-lead skarn at Yeonhwa (I, II), the iron skarn at Keodo south (Jangsan orebodies), and the copper skarn at Keodo north (78 orebodies). The present study characterizes the three classes of skarn deposits mainly in terms of skarn/ore associations examined from chemical compositional point of view, and applies existing quantitative phase diagrams to some pertinent mineral assemblages in these mines. At Yeonhwa I the Wolam I orebody shows a vertical variation in skarn minerals ranging from clinopyroxene/garnet zone on the lower levels through clinopyroxene (without garnet) zone on the intermediate levels, and finally to rhodochrosite veins on the upper levels and surface. Ore minerals, sphalerite and galena, associate most closely with the intermediate clinopyroxene zone. At Keodo, the Jangsan iron skarn hosted in quartz monzodiolite as a typical endoskarn, shows a skarn zoning, from center of orebody to outer side, magnetite zone, magnetite/garnet zone, garnet clinopyroxene zone, and clinopyroxene/epidote/plagioclase zone. The 78 copper skarn in the Hwajeol limestone indicates a zoning, from quartz porphyry side toward limestone side, orthoclase/epidote zone, epidote/clinopyroxene zone, and clinopyroxene/garnet zone; chalcopyrite and other copper sulfides tend to be in clinopyroxene/garnet zone. Mioroprobe analyses of clinopyroxenes and garnets from the various skarn zones mentioned above revealed that the Yeonhwa zinc/lead skarns are characterized by johansenitic clinopyroxene (Hd 25-78, Jo 15-23) and manganoan andraditic garnet (Ad 13-97, Sp 1-24), whereas the Jangsan iron skarn at Keodo by Mn-poor diopsidic clinopyroxene (Di 78-93, Jo 0.2-1.0) and Mn-poor grossularitic grandite (Gr 65-77, Sp 0.5-1.0). The 78 copper skarn at Keodo is characterized by Mn-poor diopsidic-salite (Di 66-91, Jo 0.2-1.1) and Mn-poor andraditic grandite(Ad 40-74, Sp 0.5-1.1). The compositional charateristics of iron, copper, and zinc-lead skarns in the Yeonhwa-Keodo mines are in good correlations with those of the foreign counterparts. Compiling a $T-XCO_2$ phase diagram for the Jangsan endoskarns, a potential upper limit of temperature of the main stage of skarn formation is estimated to be about $530^{\circ}C$, and a lower limit to be $400^{\circ}C$ or below assuming $XCO_2=0.05$ at P total=1kb. Applying a published log $fS_2$-log $fo_2$ diagram to the Keodo 78 and Yeonhwa exoskarns, it is revealed that copper sulfides and zinc-lead sulfides do not co-exist stably below log $fS_2=-4$ and log $fO_2=-23$ at $T=400^{\circ}C$ and ${\times}CO=1$ atm.

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Magnetic and Microwave Absorbing Properties of M-type Ba-ferrite($BaFe_{12-2X}Ti_XCo_XO_{19}$)with Planar Magnetic Anisortropy (면내 자기이방성을 갖는 M-type Ba-ferrite($BaFe_{12-2X}Ti_XCo_XO_{19}$)의 자기적특성 및 전파흡수특성)

  • 조한신;김성수
    • Resources Recycling
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    • v.7 no.4
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    • pp.22-26
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    • 1998
  • The purpose of this experimenL is to investigate the magnetic anisotropy and microwave absorbing properties in M-type Bat territe (${BaFe}_{12-2X}{A}_{X}{Me}_{X}{O}_{19}$), where $Fe_{3+}$ is substituted by $Ti_{4+}$ in A site and $Co_{2+}$ in Me site. The saturation magnetization (Ms) is linearly decreased with the substitution rate(x) and the coerciviLy (He) is rapidly decreased in accordance with the reduction in t the magnetocrystalline anisotropy For the specimen with x=0.8 and thickness of 2 mm, the reflection loss calculated from the n material constants is less than -10 dB (90% absorption) in the frequency range of 10~16 GHz. The absorption loss is pre이.ctcd t to be more than 20 dElern in the frequency range of 12-16 GHz. The results demonstrate that the Ti-Co substituted M-type Ba-ferrite can be effectively used as a microwave absorber at high frequency range.

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The Effects of Virtual Reality Games in Posture Correction Exercise on the Posture and Balance of Patients with Forward Head Posture

  • Son, Ho-Hee
    • Journal of the Korean Society of Physical Medicine
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    • v.15 no.2
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    • pp.11-21
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    • 2020
  • PURPOSE: This study examined the effects of posture improvement exercise using virtual reality programs on the posture and balance of patients with forward head postures. METHODS: Thirty men and women in their 20 s, who had a forward head posture, were divided randomly into a group with posture correction exercise and a group with posture correction exercise combined with virtual reality programs. The posture correction exercise was composed of squats, XCO training, and chin-tuck exercise. In contrast, exercise with virtual reality games involved the Hot Squat, Climbey, and Baskhead programs while wearing a headset. Both groups performed the exercises 15 min a day, three times per week, for four weeks. The balance ability, distance between the acromion and earlobe, and neck joint range of motion were assessed before and after the exercises. RESULTS: Both groups showed significant reductions in the distance between the acromion and the earlobe, along with significant improvements in the range of joint motion. The group that performed the virtual reality exercises showed a significant increase in the limit of stability. Both groups showed a significant decrease in the sway length. In contrast, the group given the virtual reality exercises showed a significant reduction in the sway speed while standing with their eyes closed. CONCLUSION: Exercise applying virtual reality programs can be used in clinical and home programs to correct the postures of individuals with a forward head posture because they can trigger interest in inducing active participation.

Crystal Chemistry and Paragenesis of Calc-silicate Minerals from Meta-sedimentary Rocks in Chuncheon Area: (I) Occurrence, Mineralogy, and Paragenesis (춘천 지역의 변성 퇴적암류에서 산출되는 석회 규산염 광물의 결정 화학과 생성: (I) 투각섬석의 산출상, 광물상 및 생성 관계)

  • 노진환;조현구;최진범
    • Journal of the Mineralogical Society of Korea
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    • v.8 no.2
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    • pp.57-72
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    • 1995
  • 춘천 지역 선캠브리아기의 구봉산층군 내의 백운석질 대리암에는 광역변성작용의 산물로서 조립질의 투각섬석이 주된 규산염 광물상을 이루며 산출된다. 이들은 배태 층준과 원암의 조성에 따라 두 가지 유형으로 구분된다. : (1) 투각섬석(흑회색)+방해석+백운석+활석, (2)투각섬석(백색)+금운모+백운석+방해석+K-장석, 백색의 투각섬석이 흑회색형보다 상대적으로 높은 Al과 알칼리 함유도를 보이지만, 전반적으로 모두 Mg-단종에 가까운 화학 조성을 갖는다. 투각섬석들이 격자 구조상의 결함 구조를 갖지 않는데 비해서, 금운모는 1M 구조형을 이루고 저면 격자 간격상에 녹니석 단위의 빈번한 개재에 의한 격자상의 구조적 결함이 흔히 관찰된다.방해석-백운석 지온계에 대한 연구와 TWEEQU 프로그램을 이용한 상평형도 작성을 통해서, 투각섬석들은 500~$600^{\circ}C$의 온도 범위, 8kb 정도의 압력 및 Xco2=0.2~0.5 조건에서 생성된 것으로 해석하였다. 이 지역의 투각섬석은 위와 같은 조건에서 지속적으로 평형 상태가 유지되고 상안정도가 증대되므로서, (1) 투휘석을 수반하지 않고, (2) 격자 구조상의 결합을 갖지 않는, (3) 자형의 큰 결정을 이루게 된 것으로 해석된다.

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Carbon and Cobalt Diffusion in Liquid Phase Sintering of WC-Co with Gradient Composition

  • Park, Dong-Kyu;Kim, Ki-Won;Jung, Woo-Hyun
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.635-636
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    • 2006
  • In this study, the diffusion behaviors of C and Co in liquid phase sintering of WC-Co system were investigated whether these two components diffused in the same direction in case of having opposite gradient each other with not being $\eta$ phase. The green compacts with controlled compositions in not being of $\eta$ phase and gradient composition which one is WC-5Co-1.2%C, the other is WC-XCo-0.2%C (where X = 5, 10, 15, 20, 25) were sintered at $1350^{\circ}C$ and $1400^{\circ}C$ and then the diffusion behaviors of C and Co were investigated by analyses of compositional change, also determined for microstructure and microhardness. Also, same testing was carried out on the specimens with dual layers sintered in upright and reverse positions to evaluate the effect of gravity on the diffusion in liquid Co. From the results of this study, we can find the fact that the direction of diffusion for C and Co in WC-Co system during liquid phase sintering was different and the effect of gravity for the liquid was insignificant. Also other physical properties were changed on the diffusion of elements.

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The Effect of Asymmetric Lower-Extremity Muscle Force of Elementary Students on Dynamic Balance during Walking (하지 근력의 좌우 비대칭성이 초등학생의 보행 동적안정성에 미치는 영향)

  • Kim, Gun-Soo;Chae, Woen-Sik;Yoon, Chang-Jin;Lee, Haeng-Seob;Kang, Nyeon-Ju;Kim, Dong-Soo
    • Korean Journal of Applied Biomechanics
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    • v.21 no.3
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    • pp.309-315
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    • 2011
  • The purpose of this study was to evaluate the effect of asymmetric muscle force in lower extremity on dynamic balance during walking. Sixteen elementary students(age: 12.3${\pm}$0.7 yrs, height: 149.4${\pm}$9.7 cm, weight 40.6${\pm}$7.8 kg) who have no musculoskeletal disorder were recruited as the subjects. Temporal parameters, M-L inclination angle of XCoM-CoP, M-L and A-P CoP, loading rate, and decay rate were determined for each trial. For each dependent variable, a independent-sample t-test was performed to test if significant difference existed between each conditions(p<.05). The displacement of antero-posterior COP during RTO-LHC1 in SG was siginificantly smaller than corresponding value in AG. In contrast, the displacement of medio-lateral COP during RTO-LHC1 in SG was greater than those of AG. It seems that imbalance of muscle force may result in increasing the medio-lateral stance in order to minimize the instability. We found that the asymmetric muscle force in the lower extremity may be a reason for the awkward control of impact force.

A Study on Flame Structure and NO Emission in FIR- and FGR-applied Methane-air Counterflow Diffusion Flames (FIR과 FGR 기법이 적용된 메탄-공기 대향류 확산화염에서 화염구조와 NO 배출 연구)

  • Park, Jeong;Kwon, Oh Boong;Kim, Sewon;Lee, Changyeop;Keel, Sang-In;Yun, Jin-Han;Lim, In Gweon
    • Journal of the Korean Society of Combustion
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    • v.21 no.1
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    • pp.38-45
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    • 2016
  • Flame characteristics and NO emission behavior in $CH_4$/air-air premixed counterflow flames with applying FIR and FGR with $CO_2$ and $H_2O$ were investigated numerically by varying the ratios of FIR and FGR as well as global strain rate. Chemical effects of added $CO_2$ and $H_2O$ via FIR and FGR were analyzed through comparing flame characteristics and NO behaviors from real species($CO_2$ and $H_2O$) with those from their artificial species($XCO_2$ and $XH_2O$) which have the same thermochemical, radiative, and transport properties to those for the real species. The results showed that flame temperature and NO emission with FIR varied much more sensitively than that with FGR. Those varied little irrespective of adding $CO_2$, $H_2O$, and their artificial species to the fuel stream via FIR. However, Those were varied complicatedly by chemical effects of added $CO_2$ and $H_2O$ via FGR. Detailed analyses for them were made and discussed.

Stable Isotope and Fluid Inclusion Studies of the Manjang Copper Mine, South Korea (만장동광산(萬藏銅鑛山)에 대(對)한 유체포유물(流體包有物) 및 안정동위원소분석(安定同位元素分析) 연구(硏究))

  • Kim, Kyu Han;Shin, Jeung Sook
    • Economic and Environmental Geology
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    • v.20 no.3
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    • pp.169-177
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    • 1987
  • The Manjang copper magnetite-fluorite orebodies are imbedded within the limestone beds of the Hwajonri Formation. The ore deposits are characterized by magnetite-fluorite bearing skarn orebody in the west orebody and copper sulfide veins of the central and main orebodies. This study includes fluid inclusion geothermometry, salinity analysis, stable isotope analysis, and application of phase rule to mineral associations in skarn ore. Ore minerals are closely associated with the skarn silicates such as garnet, wollastonite and epidote. Magnetite and fluorite are remarkable in the west orebody whereas chalcopyrite is dominate in the central and main orebodies where pyrite and pyrrhotite also appear as sulfide gangues. Homogenization temperature and salinity of fluid inclusions are measured ranging between $240^{\circ}C$ and $350^{\circ}C$, 6.3~12.9 wt. percent in quartz and $220^{\circ}C$ and $350^{\circ}C$, 8.5~9.9wt. percent in fluorite, respectively. This indicates that the filling temperature and salinity are higher in quartz than in fluorite with the tendency of both to be linearly decreased suggesting an attribution of meteoric water to the mineralization. $T-fo_2$ diagram in the Ca-Fe-Si system at 1 kb and $Xco_2$=0.02 shows that the mineral assemblages with decreasing temperature are andradite-hedenbergite-calcite, hedenbergite-andradite-quartz, magnetite-andradite-quartz, and magnetite-quartz-calcite, indicating that magnetite crystallizes mostly late skarn stage at lower temperature. According to the carbon and oxygen isotopic values of the host limestone and calcite in ores, the sourec of carbon might be mixture of host limestone and deep seated carbons. Sulfur isotope data imply that ore fluids be relatively homogeneous in sulfur isotopic composition, mainly derived from igneous source.

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