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Magnetic Properties of $Nd_{x}Fe_{77}B_{23-x}(4 Melt-Spun Alloys ($Nd_{x}Fe_{77}B_{23-x}(4 급속응고 합금의 자기특성)

  • 박우식;김윤배;김희태;조용수;김창석;박만장
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.34-37
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    • 1995
  • $Nd_{x}Fe_{77}B_{23-x}(x=4,\;6,\;8,\;11,\;13)$ alloys were prepared by rapid quenching technique. They were crystallized at higher than $650^{\circ}C$ and subsequently the magnetic properties were investigated The melt-spun alloy of x=8 consisted of nearly single metastable compound $Nd_{2}Fe_{23}B_{3}$ and showed the soft magnetic property. In $8{\leq}x{\leq}13$ alloys, the coercivities were increased according to the increase of Nd content but the remanences decreased. In $4{\leq}x{\leq}6$ alloys, the coercivities and the remanences were increased by lowering Nd content. In x=4 alloy, the ratio of soft to hard magnetic phase was 70:30 and the energy product was $96kJ/m^{3}(12MG.Oe)$.

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Synthesis and Superconductivity in $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ System ($(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ 계의 합성 및 초전도 특성)

  • Lee, H.K.;Bae, S.M.
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.128-132
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    • 2009
  • Polycrystalline samples of $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$($ 0{\leq}x{\leq}1.25$) have been synthesized by a solid-state reaction route. The X-ray diffraction data revealed that the Nd solubility limit can be placed between x=0.5 and x=0.75. The superconducting transition temperature decreased with increasing Nd content, confirming that Nd entered the lattice. Room-temperature thermoelectric power measurements showed that all the samples are in the underdoped state and the partial substitution of Nd for Gd resulted in a decrease in the carrier density on the superconducting layers.

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HDDR Characteristics and Magnetic Properties of Nd15(Fe1-xCox)77B8(x=0-0.6) Alloys

  • Kwon, H.W.
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.127-131
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    • 2002
  • HDDR characteristics and magnetic properties of $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys were investigated. The effect of applying magnetic field during the recombination step on the anisotropic nature of the HDDR-treated material was also examined. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$ phase in the Nd-Fe-B alloys with high Co-substitution alloy had remarkably enhanced phase stability. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution could be HDDR-treated successfully by only using high pressure hydrogen. However, these alloys had no appreciable coercivity. The poor coercivity of the HDDR-treated $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution was attributed to the $Nd{(Fe,Co)}_2$ phase in the alloys. The magnetic filed applied during the recombination step had little effect on the anisotropic nature of the HDDR-treated powder.

Effects of Ni Addition on the Microstructures and Magnetic Properties of Fe70-xPd30Nix High-Temperature Ferromagnetic Shape Memory Alloys

  • Lin, Chien-Feng;Yang, Jin-Bin
    • Journal of Magnetics
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    • v.17 no.2
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    • pp.86-95
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    • 2012
  • This study investigated the effects of adding a third alloying element, Ni, to create $Fe_{70-x}Pd_{30}Ni_x$ (x = 2, 4, 6, 8 at.% Ni) ferromagnetic shape memory alloys (FSMAs). The Ni replaced a portion of the Fe. The $Fe_{70-x}Pd_{30}Ni_x$ alloys were homogenized through hot and cold forging to gain a ~38% reduction in thickness, next they were solution-treated (ST) with annealing recrystallization at $1100^{\circ}C$ for 8 h and quenched in ice brine, and then aged at $500^{\circ}C$ for 100 h. Investigation of the microstructures and magnetostriction indicated that the greater Ni amount in the $Fe_{70-x}Pd_{30}Ni_x$ alloys reduced saturation magnetostriction at room temperature (RT). It was also observed that it was more difficult to generate annealed recrystallization. However, with greater Ni addition into the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys, the $L1_0+L1_m$ twin phase decomposition into stoichiometric $L1_0+L1_m+{\alpha}_{bct}$ structures was suppressed after the $500^{\circ}C$/100 h aging treatment. The result was that the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys maintained a high magnetostriction and magnetostrictive susceptibility (${\Delta}{\lambda}{_\parallel}{^s}/{\Delta}H$) after the alloys were aged at $500^{\circ}C$ for 100 h. This magnetic property of the $Fe_{70-x}Pd_{30}Ni_x$ (x = 6, 8 at.% Ni) alloys make it suitable for application in a high temperature (T > $500^{\circ}C$) and high frequency environments.

Theoretical Studies on the Structure and Aromaticity of 1H-Indene and Mono-sila-1H-Indene (1H-Indene과 Mono-sila-1H-Indene의 구조와 방향족성에 대한 이론적 연구)

  • Ghiasi, Reza;Monnajemi, Majid
    • Journal of the Korean Chemical Society
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    • v.50 no.4
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    • pp.281-290
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    • 2006
  • The electronic structure and properties of the 1H-indene and mono-sila-1H-indene series have been investigated using basis set of 6-31G(d, p) and hybrid density functional theory. Basic measures of aromatic character derived from structure, molecular orbitals, a variety of magnetic criteria (magnetic isotropic and anisotropic susceptibilities) are considered. Energetic criteria suggest that In(Si7) enjoy conspicuous stabilization. However, by magnetic susceptibility isotropic this system are among the least aromatic of the family: Within their isomer series, In(Si4) is the most aromatic using this criteria. Natural bond orbital (NBO) analysis method was performed for the investigation of the relative stability and the nature of the 8-9 bonds in 1H-indene and mono-sila-1H-indene compounds. The results explained that how the p character of natural atomic hybrid orbital on X8 and X9 (central bond) is increased by the substitution of the C8 and C9 by Si. Actually, the results suggested that in these compounds, the X8-X9 bond lengths are closely controlled by the p character of these hybrid orbitals and also by the nature of C-Si bonds. The magnitude of the molecular stabilization energy associated to delocalization from X8-X9 and to * X8-X9 bond orbital were also quantitatively determined. Molecular orbital (MO) analysis further reveal that all structure has three delocalized MOs and two delocalized MOs and therefore exhibit the aromaticity.

A Study on Optimization of Physical Properties of Acrylic Pressure Sensitive Adhesives (아크릴 점착제의 최적물성에 관한 연구)

  • Byeon, Sang-Hoon;Kim, Jung-Hyun
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.678-685
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    • 1992
  • The effects of functional monomers on the pressure sensitive adhesive proporties were studied. Acrylic acid and other monomers were copolymerized by radical solution polymerization and their properties were measured. The desirability function methodology was applied to obtain optimum pressure sensitive adhesive properties. Acrylic acid showed more effective than acrylamide on peel strength increase. On the other hand acrylamide showed more effective than acrylic acid on tack decrease. The optimum monomer ratio of the acrylic pressure sensitive adhesive recipe containing n-butylacrylate 81.7 mole%, acrylic acid 8.0 mole%, acrylamide 2.1 mole% and vinylacetate 8.2 mole% was obtained to result from the statistical analysis with the desirability function methodology. The estimated regression equation of desirability function(D) is as follows: $D=.857+.072X_1-.114X_2-.027X_3-.126X_1{^2}-.046X_1{\cdot}X_2-.063X_1{\cdot}X_3-.152X_2{^2}+.027X2{\cdot}X_3-.120X_3{^2}$ $X_1$:coded acylic acid, $X_2$:coded acylamide, $X_3$:coded vinylacetate

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Simulataneous X-ray Diffraction Measurements of the Antiferroelectric-ferroelectric Phase Transition of PLZT under Electric Field (전장하에서 PLZTd의 반강유전-강유전 상전이의 동시적 X-선 회절 측정)

  • 고태경;조동수;강현구
    • Journal of the Korean Ceramic Society
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    • v.33 no.11
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    • pp.1292-1300
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    • 1996
  • In-site X-ray diffraction measurements under electric field up to 20kV/ cm were carried out on PLZT (x/70/30) with x=7.5, 8.0, 8.5, and 10.5 All of PLZT belonged to cubic phases. At x=7.5, 8.0 and 8.5 PLZT behaved as an antiferroelectric under low electric fields up to 4-8 kV/cm. PLZT became ferroelectric at the higher electric fields. The high-temperature measurements on the dielectric constants of PLZT with x=7.5, 8.0 and 8.5 showed that they were similar to relaxor ferroelectrics and underwent a diffuse phase transition from antiferroelectrics to paraelectrics at 50-7$0^{\circ}C$. Their P-E hysteresis curves confirmed that they were antifer-roelectrics. The broad distribution of Curie points suggests that there is a significant disorder of cations and vacances in the crystal structure of those PLZT due to La-substitution. The variation of the lattice strain of PLZT(10.5/70/30) with electic field was very small and did not show any hysteresis confirming that it was paraelectric. The degree of the electric-induced strain variation decreased as La doping increased. In PLZT(7.5/70/30) the intensity of 110 reflection changes sensitively by applying electric field. Some domains with polarization parallel to [110] appeared to be developed in the field-induced ferroelectric phase of the PLZT.

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Design and Fabrication of the Frequency Multiplier for S-band Transponder (S-대역 트랜스폰더용 주파수 체배기 설계 및 제작)

  • Kim, Byung-Soo;Ko, Bong-Jin
    • Journal of Advanced Navigation Technology
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    • v.10 no.4
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    • pp.348-355
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    • 2006
  • In this paper, frequency multipliers used S-band transponder of the KOMPSAT 3 are designed and fabricated. In the transponder, 108 times multiplier which generate 1st LO signal(2008.8MHz) is comprised of the X9 frequency multiplier, 1st X2 multiplier, 2nd X2 multiplier and the last stage of the X3 frequency multiplier. As results, output power of 8.17 dBm at 2008.8MHz, the harmonic suppression of -56.67dBc, the bandwidth of 14MHz were measured.

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Glass Forming Ability and Mechanical Properties of (Fe79C11B8Si2)100-XCrX (X = 0-8) Amorphous Ribbons ((Fe79C11B8Si2)100-XCrX (X = 0-8) 조성 비정질 리본의 크롬 함량에 따른 비정질 형성능, 기계적 특성 평가)

  • Moon, Jae-Won;Park, Ji-Sung;Yi, Seong-Hoon
    • Journal of Korea Foundry Society
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    • v.36 no.1
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    • pp.18-23
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    • 2016
  • Iron based amorphous ribbons with the nominal compositions of $(Fe_{79}C_{11}B_8Si_2)_{100-X}Cr_X$ (X = 0,2,4,6,8 at%) have been developed as reinforcements that can be applied to the concrete materials. Mechanical properties and glass forming ability of the ribbons can be enhanced by the optimum amounts of Cr additions that can also improve corrosion properties of the ribbons. Vein patterns typical of the fractured surface morphology of amorphous alloys have been observed on the surfaces of ribbons after tensile tests. It is inferred from the EDS analysis results of vein patterns that carbon segregations occur within the narrow shear band regions.

Acquisition of Monochromatic X-ray Using Multilayer Mirror (다층박막 거울을 이용한 단색 엑스선 획득)

  • Chon, Kwon-Su
    • Journal of radiological science and technology
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    • v.33 no.3
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    • pp.179-184
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    • 2010
  • A hard X-ray microscope system for obtaining images of nano-spatial resolution has been widely studied and requires monochromatic X-ray. A multilayer mirror of 84% reflectivity was designed to acquire tungsten characteristic X-ray of 8.4 keV from the white beam generated from an X-ray tube, and the C/W multilayer mirror of $50{\times}50\;mm$ size and 5.65 nm d-spacing was fabricated by the ion-beam sputtering system. The C/W multilayer had a uniformity of 99.5%, and the structure of the multilayer mirror was verified by a TEM image. The obtainable x-ray reflectivity for the C/W multilayer mirror at 8.4 keV was estimated from measuring the X-ray reflectivity using the copper characteristic X-ray of 8.05 keV. Monochromatic X-ray of 8.4 keV was generated by combining a X-ray tube, and the reflectivity and monochromaticity were 77.1% and 0.21 keV, respectively. Monochromatic X-ray generated from the combination of an X-ray tube and an C/W multilayer mirror has enough potential to use X-ray source for hard X-ray microscope system of laboratory size. If the C/W multilayer mirror of d-spacing of a few nanometers can be fabricated, monochromatic X-ray corresponded to 17.5 keV, molybdenum characteristic X-ray, can be obtained and applied to mammography in the medical application.