• Journal of the Korean Magnetics Society
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• v.18 no.1
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• pp.19-23
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• 2008

The mixed ferrite $V_xFe_{3-x}O_4$(x=0.0, 0.15, 0.5, 1.0) thin films were prepared by sol-gel method. Their crystallographic and magnetic hyperfine properties have been studied using X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS) and conversion electron $M\"{o}ssbauer$ spectroscopy(CEMS). The crystal structure is found to be cubic spinel throughout the series($x{\leq}1.0$), and the lattice parameter $a_0$ increases linearly with increasing V content. XRD, XSP and CEMS indicate that $V^{3+}$ substitution for $Fe^{3+}$ in B-site is superior to $V^{2+}$ substitution for $Fe^{2+}$ in B-site. It is noticeable that both quadrupole shift and hyperfine field decreases with increasing V composition, suggesting the change of local symmetry and accompanying line-broadening. The line-broadening on CEMS spectra can be explained by the distribution of magnetic hyperfine fields.

• Journal of the Korean Magnetics Society
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• v.12 no.5
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• pp.179-183
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• 2002

Fe-Si-C alloy system has been made by mechancial alloying process. The structural and magnetic properties were analysed as a function of processing times. The structural properties were investigated by X-ray diffraction and EXAFS experiments. The magnetic properties were measured by vibrating sample magnetometer and M ssbauer spectroscopy. As processing time increases, Si and C atoms diffuse into a ${\alpha}$-Fe structure and then bcc solid solution is formed after 12 hours of the processing time. The magnetization and the hyper fine field decreased steeply up to 4 hours and then it changed slowly. After 12 hours of the processing time, it almost saturated. These results were agreed with the structural variation.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.4
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• pp.660-666
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• 1998

We discussed structure, energy state, characteristics of thermal stability, and electrochemical properties of Li-GFICs, Li-PCICs, and Li-AGICs during the intercalation process. According to X-ray diffraction patterns, we observed phase of stage 2 mainly from Li-GFICs, while stage 1 phase as well as stage 2 from Li-PCICs. For the structure of Li-AGICs, stage 1 phase was dominant, but it was not possible to obtain pure stage 1 compound probably due to structural characteristics of artificial graphite. We measured energy state of the compounds to stage stability, and revealed that Li-AGICs and Li-GFICs were in more stable state than Li-PCICs. Therefore, those two compounds could be excellent candidate for energy reserve material. From the study of thermal degradation, Li-GFICs showed strong exothermic reaction at around 300 and $400^{\circ}C$. In the study of thermal stability of Li-AGIC at various temperatures, we observed that lithium was not completely deintercalated and high stage was maintained even at high temperature. In the case of charge, discharge, and electrochemical studies, Li-GFICs showed the best results.

• Journal of the Korean Chemical Society
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• v.31 no.6
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• pp.491-497
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• 1987

$ThO_2-Tm_2O_3$ (TDT) solid solutions containing 1,3,5,8,10, and 15 mol% $Tm_2O_3$ were synthesized from spectroscopically pure $ThO_2$ and $Tm_2O_3$ polycrystalline powders. The TDT solid solutions were indentified to the fluorite structure by the X-ray powder technique. The values of the lattice parameter were decreased with increasing amount of $Tm_2O_3$ incorporated. But, there was no linearity for the samples containing 8, 10, and 15 mol% $Tm_2O_3$. It was concluded that these samples became incomplete solid solutions. From the intensity analyses of X-ray diffraction patterns, the residual factor was found below 0.13 even for the 15 mol% TDT system. lt was confirmed from the DTA and TGA analyses that any phase transitions did not occur under the experimental condition executed. Comparing the pycnometric density with the lattice parameter obtained from XRD, it was suggested that the predominant defect model be an oxygen vacancy.

• Journal of Sensor Science and Technology
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• v.7 no.6
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• pp.386-393
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• 1998

We have carried out the measurements of complex dielectric constants with impedance/gain-phase analyzer using capacitor method and the experiments of high temperature X-ray powder diffraction with X-ray diffractometer using ${\theta}-2{\theta}$ scan method for the KTP single crystal which has the premium nonlinear optical properties. From the results of high temperature X-ray powder diffraction experiments, we have found that KTP does not undergo structural phase transition below $900^{\circ}C$. It is clear that KTP undergoes structural phase transition around $900^{\circ}C$ and belongs to orthorhombic above $900^{\circ}C$ still. However, we have applied phenomenological relation of dielectric relaxation to the results of complex dielectric measurement and have found that relaxation mechanism of KTP well satisfies the Cole-Cole relation over the temperature range from $-78^{\circ}C$ to $200^{\circ}C$. And also the relaxation time well satisfies the Vogel-Fulcher relation. It is regarded that the hopping and thermally activated diffusion mechanism may control the conduction behavior of KTP above $200^{\circ}C$.

• Journal of the Korean Chemical Society
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• v.55 no.1
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• pp.38-45
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• 2011

The complexation behavior of the $\alpha$-ketostabilized phosphorus ylides $Ph_3P$=CHC(O) $C_6H_4-X$ (X=Br, Ph) towards the transition metal ions mercury (II) and Silver (I) was investigated. The mercury(II) complex {$HgX_2$ [Y]} 2 ($Y_1$=4-bromo benzoyl methylene triphenyl phosphorane; X=Cl(1), Br(2), I(3), $Y_2$=4-phenyl benzoyl methylene triphenyl phosphorane; X=Cl(4), Br(5), I(6)) have been prepared from the reaction of $Y_1$ and $Y_2$ with $HgX_2$ (X=Cl, Br, I) respectively. Silver complexes [$Ag(Y_2)_2]$ X(X=$BF_4$(7), OTf(8)) of the $\alpha$-keto-stabilized phosphorus ylides ($Y_2$) were obtained by reacting this ylide with AgX (X=$BF_4$, OTf) in $Me_2CO$. The crystal structure of complexes (1) and (4) was discussed. These reactions led to binuclear complexes C-coordination of ylide and trans-like structure of complexes $[Y_1HgCl_2]_2$. $CHCl_3$ (1) and $[Y_2HgCl_2]_2$ (4) is demonstrated by single crystal X-ray analyses. Not only all of complexes have been studied by IR, $^1H$ and $^{31}P$ NMR spectroscopy, but also complexes 1-3 have been characterized by $^{13}$CNMR.

• Journal of the Korean Chemical Society
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• v.33 no.5
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• pp.445-451
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• 1989

A series of solid solutions with formula $Er_{1-x}Sr_xFeO_{3-y}, where x is from 0.0 to 1.0, has been synthesized by heating at $1200^{\circ}C$ for 24 hours. X-ray diffraction shows these samples to be orthorhombically distorted perovskites for compositions up to x = 0. 6 and apparantly simple cubic perovskite structures from $0.8{\leq}x{\leq}1.0$. Lattice volumes are increased with the introduction of Sr. The mixed valence state of two kinds of Fe ion in these ferrite systems is analyzed by the Mohr salt titration method. Mossbauer spectra measured at room temperature for x = 0.0 and 0.5 compositions shows hyperfine splitting for iron (III) due to magnetic ordering and indicates that these samples contain octahedrally and tetrahedrally coordinated iron sites. Electrical conductivity measurements indicate that conduction in these samples apparantly occurs over the octahedral sites by a hopping mechanism.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.165-165
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• 2012

비정질의 Tantalum-indium-zinc oxide (TIZO) 박막 트랜지스터는 RF-sputtering 방법으로 증착되었으며 소결된 단일 타겟을 사용하였다. 증착당시 반응 가스는 알곤과 산소를 95 : 5로 섞어 반응성 스퍼터링을 진행하였으며, 1 mtorr에서 5 mtorr까지 다양한 공정압력에서 증착한 이 후 Furnace system을 통하여 $350^{\circ}C$의 온도로 1시간 동안 후열처리 공정을 진행하였다. 비정질 TIZO 박막을 활성 층으로 사용하여 제작한 박막 트랜지스터는 공정압력이 낮아짐에 따라 높은 이동도와 낮은 subthrehsold gate swing 보였다. 이러한 현상의 원인을 규명하고자 물리적, 전기적, 광학적 분석을 통하여 공정압력의 변화가 박막 트랜지스터 구동에 미치는 영향을 해석하였다. 우선 공정압력에 따른 TIZO 박막의 Ta, In, Zn, O 각각의 조성을 분석하기 위하여 Rutherford back scattering (RBS) 분석을 실시하였다. 또한 X-선 회절(X-ray diffraction)분석을 통해 열처리된 TIZO 박막은 공정압력에 따라 물리적 구조의 변화를 일으키지 않으며 모든 박막은 비정질상을 보이는 것을 확인하였다. 3.3eV의 광학적 밴드 갭은 기존에 보고되었던 비정질 산화물 반도체(InGaZnO, HfInZnO 등)와도 유사한 밴드갭을 가지고 있음을 확인하였다. 또한, spectroscopic ellipsometry (SE)분석을 통하여 전도대 이하 밴드 갭 내에 존재하는 결함상태 및 전도대에서 결함상태까지의 에너지 준위 그리고 공정압력에 따라 결함의 양과 발생되는 에너지 준위가 변화하는 현상을 관측하였다. 박막을 제조 할 때의 공정압력은 박막 내의 결함의 양 및 발생되는 에너지 준위의 변화를 야기하고 변화된 결함의 양과 발생된 에너지 준위에 따라 박막트랜지스터의 전기적 특성을 변화시킨다는 결과를 도출하였다.

• Composites Research
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• v.29 no.4
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• pp.151-155
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• 2016

Graphene has been a valuable candidate for use as electrodes for supercapacitors. In order to improve the surface area of graphene, three-dimensional graphene was synthesized on porous Ni nanostructure using thermal chemical vapor deposition and microwave plasma chemical vapor deposition. The structural and chemical characterization of synthesized graphene was performed by scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It was confirmed that three-dimensional and high-crystalline multilayer graphene onto various substrates was synthesized successfully.

• Journal of the Korean Magnetics Society
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• v.22 no.1
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• pp.15-18
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• 2012

The olivine structured $LiFe_{0.9}Mn_{0.1}PO_4$ material was prepared by solid state method, and was analyzed by x-ray diffractometer (XRD), superconducting quantum interference devices (SQUID) and Mossbauer spectroscopy. The crystal structure of $LiFe_{0.9}Mn_{0.1}PO_4$ was determined to be orthorhombic (space group: Pnma) by Rietveld refinement method. The value of N$\acute{e}$el temperature ($T_N$) for $LiFe_{0.9}Mn_{0.1}PO_4$ was determined 50 K. The temperature dependence of the magnetization curves showed magnetic phase transition from paramagnetic to antiferromagnetic at $T_N$ by SQUID measurement. M$\ddot{o}$ssbauer spectra of $LiFe_{0.9}Mn_{0.1}PO_4$ showed 2 absorption lines at temperatures above $T_N$ and showed asymmetric 8 absorption lines at temperatures below $T_N$. These spectra occurred due to the magnetic dipole and electric quardrupole interaction caused by strong crystalline field at asymmetric $FeO_6$ octahedral sites.