• Fibers and Polymers
• /
• v.5 no.1
• /
• pp.52-58
• /
• 2004

Previous investigation results revealed that after the Low Temperature Plasma (LTP) treatment, the hydrophilicity of wool fiber was improved significantly. Such improvement enhances the wool dyeing and finishing processes which might be due to the changes of the wool surface to a more reactive one. In this paper, wool fibers were treated with LTP with different gases, namely, oxygen, nitrogen and gas mixture (25 % hydrogen/75 % nitrogen). Investigations showed that chemical composition of wool fiber surface varied differently with the different plasma gas used. The surface chemical composition of the different LTP-treated wool fibers was evaluated with different characterization methods, namely FTIR-ATR, XPS and saturated adsorption value. The experimental results were thoroughly discussed.

• Science of Emotion and Sensibility
• /
• v.5 no.3
• /
• pp.53-59
• /
• 2002

The surface fibers on the fabric is one of decisive factors which affects human sensory evaluation as well as heat and moisture transfer characteristics. In this study the length and distribution of surface fibers that are extruded from the fabric surface of the wool/wool blend fabrics (14 wool fabrics and 10 wool blend fabrics) and its contribution to subjective sensory evaluation were investigated. In order to quantify the length and distribution of surface fibers, image analysis and wavelet transform technique were introduced. Instant warm-cool feeling of touch, Q$\_$max/, and contact area were also measured and related to the quantified surface fibers. To figure out the effect of surface characteristics on sensory evaluation, human sensory responses to three adjectives which represent surface characteristics and warm-cool feeling of touch were obtained and analyzed. The relationship between the quantified surface fibers assessed by wavelet energy and both warm-cool reeling of touch, Qmax, and human sensory response were discussed.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.20 no.5
• /
• pp.728-737
• /
• 1996

The purpose of this study is to investigate the change of the chemical properties of wool treated with six kinds of alkali (NaOH, Naac03, NH40H, NH2CH3CH30H, TMAH and BTMAH) with or without CTAB. Content of bound fatty acid liberated from wool surface, elemental composition and allw6rden time were measured to compare the surface modification of untreated and alkali treated wool. Also, the chemical degradation of the fiber was investigated by measuring cystine contents and urea-hydrogensulfite solubility. The result were as follows: 1. By the alkali treatment of wool, the covalently bound fatty acid of the epicuticle was removed and the allworden time was shortened, and in the case of wool treated with TMAH, BTMAH, the allw6rden sacs were formed unevenly and rarely. Also, cystine contents and urea-hydrogensulfite solubility were decreased by alkali treatment on wool. 2. The modification of epicuticle and the chemical degradation of wool were occurred due to alkaline hydrolysis in the order of TMAH, BTMAH > NaOH, Na3c03> NH2CH3CHaOH, NH40H. 3. As a treating time increased, the modification of epicuticle and chemical degradation of wool were accelerated. By the addition of CTAB to the alkali solution, the modification of epicuticle was increase, and the cystine contents and urea-hydrogensulfite solubility were reduced than that of wool teated with alkli without CTAB due to reduction of negative charge on the wool surface by the adhesion of CTAB.

• Textile Coloration and Finishing
• /
• v.17 no.6 s.85
• /
• pp.51-59
• /
• 2005

To manufacture hightech easycare wool, there are several methods which use strong oxidising agent or the resin treatment, however, neither are environmentally friendly methods. Moreover it may deteriorate the handle. The aim of this study is to manufacture the hightech easycare wool using the modified Fenton method which can be formed by hydrogen peroxide and ferric sulfate and enzyme treatment. The method was pretreated by ferric sulfate on the wool surface and then the surface of wool scale was selectively removed by ferric ion catalyst. Subsequently the Enchiron which is one of the proteolytic enzymes was treated on the wool surface. The treated wool had the result of having optimum weight loss and excellent whiteness and good handle. Therefore implications of these results suggest that this method using the modified Fenton method and enzyme treatment may be one way of manufacturing the hightech easycare wool.

• Fibers and Polymers
• /
• v.2 no.1
• /
• pp.152-156
• /
• 2001

Three different silicone polymer systems, such as aminofunctional, epoxyfunctional, and hydrophilic epoxyfunctional silicone polymers, were applied onto plasma pretreated wool fabric to improve the dimensional properties. The results showed that the plasma pretreatment modified the cuticle surface of the wool fiber and increased the reactivity of wool fabric toward silicone polymers. Felting shrinkage of plasma and silicone treated wool fabric was decreased with different level depending on the applied polymer system. Fabric tear strength and hand were adversely affected by plasma treatment, but these properties were favorably restored on polymer application. Therefore, it has been concluded that the combination of plasma and silicone treatments can achieve the improved dimensional stability, and better performance properties of wool fabric. The surface smoothness appearances of treated fabrics were measured using a new evaluation system, which showed good correspondence with the results of KES-FB4 surface tester.

• Textile Coloration and Finishing
• /
• v.9 no.6
• /
• pp.87-95
• /
• 1997

Wool samples were treated by potassium tert-Butoxide(t-BuOK) in anhydrous tert-butanol to remove the bound surface lipid-layer, and the weight loss behaviors in protease solution and dyeabilities of the samples were studies. The C/N ratio of the surface of the t-BuOK-treated wool was shown to be 4.3 from XPS analysis. From SEM pictures any remarkable change in the shape of surface curticle during the proteasw treatment was not observed regardless of prior t-BuOK treatment. Dyeing rate and equilibrium adsorption of Orange II, a typical levelling type acid dye, on wool were not changed by protease or t-BuOK treatment, but those of Milling Cyanine 5R, a typical milling type acid dye, on wool were greatly enhanced by t-BuOK treatment in spite that, from alkali and urea-bisulfite solubilities, no damage on the inner part of wool fiber was expected by t-BuOK treatment.

• Computers and Concrete
• /
• v.11 no.2
• /
• pp.93-104
• /
• 2013

The use of rock wool waste, an industrial by-product, in cement-based composites has positive effects on the environment because it reduces the problems associated rock wool disposal. The experiments in this study tested cement-based composites using various rock wool waste contents (10, 20, 30 and 40% by weight of cement) as a partial replacement for Portland cement in mortars. The pozzolanic strength activity test, flow test, compressive strength test, dry shrinkage test, absorption test, initial surface absorption test and scanning electron microscope observations were conducted to evaluate the properties of cement-based composites. Test results demonstrate that the pozzolanic strength activity index for rock wool waste specimens is 103% after 91 days. The inclusion of rock wool waste in cement-based composites decreases its dry shrinkage and initial surface absorption, and increases its compressive strength. These improved properties are the result of the dense structure achieved by the filling effect and pozzolanic reactions of the rock wool waste. The addition of 30% and 10% rock wool wastes to cement is the optimal amount based on the results of compressive strength and initial surface absorption for a w/cm of 0.35 and 0.55, respectively. Therefore, it is feasible to utilize rock wool waste as a partial replacement of cement in cement-based composites.

• Proceedings of the Korean Fiber Society Conference
• /
• 2003.10a
• /
• pp.96-96
• /
• 2003

In this article modification of wool fibers and fabrics by pulse corona discharge and enzymes, in particular purified keratinase with a single component has been carried out to improve their surface properties. The shrinkproofing, tensile strength, weight loss, and the primary hand values calculated from the mechanical properties of the dual treated wool fabrics were investigated. In addition, the surface morphology of wool fiber was observed under the dry and wet conditions using an environmental SEM, ESEM.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.27 no.9_10
• /
• pp.1134-1143
• /
• 2003

The purpose of this study is to investigate surface color change and effects of mordants on the K/S values of silk and wool fabrics dyed with Lac extract, according to the mordanting methods and conditions such as temperature, concentration and time of the mordanting bath. The results were as follow; 1 K/S values of the silk and wool fabrics according to the temperature of the mordanting bath were shown a slight decline beyond 40$^{\circ}C$. 2. Surface color of the silk changed from red to reddish purple and that of the wool showed red tone when mordanted with Aluminum postassium sulfate, Copper acetate and Copper (II) sulfate regardless of the mordanting conditions. 3. The light and dry cleaning fastness of silk and wool fabrics dyed with Lac extract according to the mordanting methods were very good.

• Textile Coloration and Finishing
• /
• v.13 no.4
• /
• pp.227-233
• /
• 2001

Wool fabrics were pre-treated with corona prior to treating with enzyme for shrinkage resistance. Commercial protease and cellulase were used for degradation of wool and the treatment conditions such as enzyme amount, treating time, and assistant chemicals. Friction coefficient and zeta-potential were measured to certificate an effect of treatment condition on the handle of wool fabric. Corona pretreatment make the wool fabric soft, which result in the decrease of friction coefficient and zeta-potential. Scale removal of wool surface was observed by scanning electron microscope. Amino acid analysis shows the effectiveness of enzyme, and corona pretreatment does not cause severe internal damage.