• Journal of the Korean Wood Science and Technology
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• v.41 no.4
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• pp.358-373
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• 2013

In this study, both mild acid and alkali treatments with 1.0 wt% and 2.0 wt% of $H_2SO_4$ and NaOH solution were applied to evaluate the effects on chemical compositions of wood biomass. Yellow poplar (Liriodendron tulipifera L.) and larch (Larix kaempferi C.) were chosen due to major species planted in Korea. Chemical treatments of biomass were carried out by being soaked in either acid or alkali solution with 1:20 ratio for 72 hours at ambient temperature. Afterward, lignin, 5 major reduced sugars, ash contents and elemental composition were determined. To statistically understand the relationship between samples and chemical treatments, the Tukey test, simple linear regression model and ANOVA analysis were introduced using a statistical software R. As results from both wet chemistry and statistical analysis, yellow poplar was more affected on the lignin and xylose contents by acid treatments under these experimental conditions. Meanwhile, larch was more affected on the composition of galactose and lignin by alkali treatments. A series of results in this study would show that equivalent chemical treatment makes a change the chemical composition of each species.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.12
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• pp.804-815
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• 2019

Due to the depletion and environmental problems of fossil fuel, biomass has arisen as an alternative energy source. Biomass is a renewable and carbon-neutral source. However, it is moister and has lower energy density. Therefore, biomass needs thermal chemical conversion processes like gasification, and it does not only produce a flammable gas, called 'syngas', which consists of CO, H2, and CH4, but also some unwanted byproducts such as tars and some particulates. These contaminants are condensed and foul in pipelines, combustion chamber and turbine, causing a deterioration in efficiency. Thus this work attempted to find a method to remove tars and particles from syngas with a filter which adopts a pre-coating technology for preventing blockage of the filter medium. Hydrated limestone powder and activated carbon(wood char) powder were used as the pre-coat materials. The removal efficiency of the tars was 86 % and 80 % with activated carbon(wood char) coating and hydrated limestone coating, respectively.

• Journal of Energy Engineering
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• v.19 no.4
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• pp.215-220
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• 2010

Hydrogen is a clean and efficient energy source and is expected to take an important role in future energy demand. A possibly good route to produce hydrogen is by using biomass and organic wastes as a source through thermo-chemical conversion technology. In this study, pyrolysis of wood Pellet(Oregon pine) has been carried out in batch type fixed-bed reactor in $N_2$ atmosphere during 20 minutes to determine the optimum hydrogen generating conditions. At the influence of temperature, hydrogen yield was increased with increasing temperature. For the influence of Steam/Biomass Ratio(SBR), hydrogen yield was increased by steam addition at low temperature condition. However, effect of steam addition was insignificant over at SBR = 1. The hydrogen yield was increased with increasing SBR at high temperature condition. From result of $H_2$/CO and $H_2/CH_4$ ratio, dominant reaction was steam reforming in this experimental condition. The optimum condition for hydrogen production was determined as follows: $H_2$ yield = 38.3 vol.% (56.01 L/min kg) at $900^{\circ}C$, SBR=3.

• Clean Technology
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• v.27 no.4
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• pp.325-331
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• 2021

In this study, bio-carbons were produced by activation process from unused biomass (Grade 3 wood pellet and spent coffee grounds) to determine the removal performance of formaldehyde and acetaldehyde. The activation experiments were conducted in a fixed bed reactor using CO₂ as an activation agent. The temperature of the activation reactor and input of CO₂ were 900 ℃ and 1 L min^-1 for all the experiments. The maximum BET surface area of about 788 m² g^-1 was obtained for bio-carbon produced from Grade 1 wood pellet, whereas about 544 m² g^-1 was achieved with bio-carbon produced from spent coffee grounds. In all the experiments, the bio-carbons produced were mainly found to have micro-porous nature. A lower ash amount in raw material was favored for the high surface area of bio-carbons. In the removal test of formaldehyde and acetaldehyde, the bio-carbon produced from spent coffee grounds showed excellent adsorption performance compared with woody biomass (Grade 1 wood pellet and Grade 3 wood pellet). In addition, the comparative experiment of commercial impregnated activated carbon and bio-carbon produced from spent coffee grounds was conducted. In terms of formaldehyde removal performance, the commercial impregnated bio-carbon was excellent, while bio-carbon produced from spent coffee grounds was excellent in acetaldehyde removal.

• Journal of Korean Society of Forest Science
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• v.82 no.2
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• pp.188-194
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• 1993

A natural Quercus variabilis forest and a Populus alba${\times}$P. glandulosa plantation in Mt. Mohu area were studied to investigate aboveground biomass and net production. A $20m{\times}30m$ quadrat was set up in each stand, and 10 sample trees each of Quercus variabilis and Populus alba ${\times}$ P. glandulosa were cut for dimension analysis. There was little difference in accuracy among three biomass regression models of logWt=A+BlogD, $logWt=A+BlogD^2H$, and logWt=A+BlogD+ClogH, where Wt. D, and H were dry weight, DBH, and height, respectively. Aboveground total biomass of Quercus variabilis stand was 31,275kg/ha, and that of Populus alba ${\times}$ P. glandulosa was 55,581kg/ha. In both of Quercus variabilis stand and Populus alba ${\times}$ P. glandulosa stand, the proportion of each tree component to abovegound total biomass was high in order of stem wood, branches, stem bark, and leaves. Quercus variabilis stand was higher in the proportion of stem bark, branches and leaves than Populus alba ${\times}$ P. glandulosa stand, while the former was lower in that of stem wood than the latter. Aboveground total net production of Quercus variabilis stand was 4,267kg/ha/yr., and that of Populus alba ${\times}$ P. glandulosa stand was 3,903kg/ha/yr. The proportion of each tree component to aboveground total net production of Quercus variabilis stand was high in order of leaves, stem wood, branches, and stem bark. That of Populus alba ${\times}$ P. glandulosa stand was high in order of stem wood, leaves, branches, and stem bark. Net assimilation rate and efficiency of leaf to produce stem of Quercus variabilis stand were 2.121 and 0.840, respectively. Those of Populus alba ${\times}$ P. glandulosa stand were 3.376 and 2.085, respectively. Though Populus alba${\times}$P. glandulosa stand was lower in aboveground total net production than Quercus variabilis stand, the former was higher in aboveground total biomass than the latter. The reason was that Populus alba${\times}$P. glandulosa stand was higher in net production of stem wood of accumulation organs than Quercus variablis stand.

• Journal of Ecology and Environment
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• v.37 no.4
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• pp.177-184
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• 2014

This study was conducted to develop allometric equations and to determine the stem density and biomass expansion factor (BEF) for the estimation of the aboveground and belowground biomass of Cryptomeria japonica in Jeju Island, Korea. A total of 18 trees were harvested from the 40-year-old C. japonica stands in Hannam experimental forest, Jeju Island. The mean biomass of the C. japonica was $50.4Mg\;ha^{-1}$ in stem wood, $23.1Mg\;ha^{-1}$ in root, $9.6Mg\;ha^{-1}$ in branch, $4.6Mg\;ha^{-1}$ in needle and $4.3Mg\;ha^{-1}$ in stem bark. The diameter at breast height (DBH) was selected as independent variable for the development of allometric equations. To evaluate the performance of these equations, coefficient of determination ($R^2$) and root mean square error (RMSE) were used and results of the evaluation showed that $R^2$ ranged from 71% (root biomass equation) to 96% (aboveground biomass equation) and the RMSE ranged from 0.10 (aboveground biomass equation) to 0.33 (root biomass equation). The mean stem density of C. japonica was $0.37g\;cm^{-3}$ and the mean aboveground BEF was $1.28g\;g^{-1}$. Furthermore, the ratio of the root biomass to aboveground biomass was 0.32.

• 한국생물공학회:학술대회논문집
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• 2000.04a
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• pp.227-230
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• 2000

Batch cultivations of Anaerobiospirillum succiniciproducens have been systematically studied for the economical production of succinic acid from wood hydrolysate with corn steep liquor(CSL) as a nitrogen source. CSL was found to be an alternative complex nitrogen source for A. succiniciproducens when glucose and wood hydrolysate were used as carbon sources. Compared with polypeptone and/or yeast extract, CSL had similar effects on fermentation performance such as succinic acid yield and a ratio of succinic acid to acetic acid in the fermentation of wood hydrolysate as well as glucose. This means that succinic acid can be produced more economically from wood hydrolysate and CSL than relatively expensive carbon and nitrogen sources. Besides its low cost, the alternative medium served as a green technology for succinic acid production because it gives a net-zero effect on global warming.

• Journal of the Korean Wood Science and Technology
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• v.37 no.2
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• pp.155-163
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• 2009

This study examined the thermal stability of PLA-WF bio-composites. Wood flour (WF)-filled PLA bio-composites were reinforced with the flame retardants, Melamine pyrophosphate (MPP), resorcinol bis (diphenyl phosphate) (RDP) and zinc borate (ZB). The flame retardant was compounded with PLA and natural biodegradable filler. The thermal properties of the biodegradable polymer and bio-composites reinforced with the flame retardant were measured and analyzed by DSC, DMA and TGA. The results showed that the flame retardant-reinforced biodegradable bio-composite exhibited improved thermal properties.

• Journal of Korea Society of Waste Management
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• v.35 no.7
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• pp.640-646
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• 2018

Biomass-fired power plants produce electricity and heat by burning biomass in a boiler. However, one of the most serious problems faced by these plants is severe corrosion. In biomass boilers, corrosion comes from burnt fuels containing alkali, chlorine, and other corrosive substances, causing boiler tube failures, leakages, and shorter lifetimes. To mitigate the problem, various approaches implying the use of additives have been proposed; for example, ammonium sulfate is added to convert the alkali chlorides (mainly KCl) into the less corrosive alkali sulfates. Among these approaches, the high temperature corrosion prevention technology based on ammonium sulfate has few power plants being applied to domestic power plants. This study presents the results obtained during the co-combustion of wood chips and waste in a circulating fluidized bed boiler. The aim was to investigate the characteristics of pollution load in domestic biomass power plants with ammonium sulfate injection. By injecting the ammonium sulfate, the KCl content decreased from 68.9 to 5 ppm and the NOx were reduced by 18.5 ppm, but $SO_2$ and HCl were increased by 93.3 and 68 ppm, respectively.

• Clean Technology
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• v.26 no.4
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• pp.239-250
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• 2020

Biomass is an abundant renewable energy resource that can replace fossil fuels for the reduction of greenhouse gas (GHG). Indonesia has a large number of cheap biomass feedstocks, such as reforestation (waste wood) and palm residues (empty fruit bunch or EFB). In general, raw biomass contains more than 20% moisture and lacks calorific value, energy density, grindability, and combustion efficiency. Those properties are not acceptable fuel attributes as the conditions currently stand. Recently, torrefaction facilities, especially in European countries, have been built to upgrade raw biomass to solid fuel with high quality. In Korea, there is no significant market for torrefied solid fuel (co-firing) made of biomass residues, and only the wood pellet market presently thrives (~ 2 million ton yr-1). However, increasing demand for an upgraded solid fuel exists. In Indonesia, torrefied woody residues as co-firing fuel are economically feasible under the governmental promotion of renewable energy such as in feed-in-tariff (FIT). EFB, one of the chief palm residues, could replace coal in cement kiln when the emission trading system (ETS) and clean development mechanism (CDM) system are implemented. However, technical issues such as slagging (alkali metal) and corrosion (chlorine) should be addressed to utilize torrefied EFB at a pulverized coal boiler.