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Silver nanowires and nanodendrites synthesized by plasma discharge in solution for the catalytic oxygen reduction in alkaline media

  • Kim, Hoe-Geun;Song, Myeon-Gyu;Kim, Dong-U;Lee, Sang-Yul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.62-62
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    • 2018
  • Pt is still considered as one of the most active electrocatalysts for ORR in alkaline fuel cells. However, the high cost and scarcity of Pt hamper the widespread commercialization of fuel cells. As a strong candidate for the replacement of Pt catalyst, silver (Ag) has been extensively studied due to its high activity, abundance, and low cost. Ag is more stable than Pt in the pH range of 8~14 as the equilibrium potential of Ag/Ag+ being ${\approx}200mV$ higher than that of Pt/PtO. However, Ag is the overall catalytic activity of Ag for oxygen reduction reaction(ORR) is still not comparable to Pt catalyst since the surface Ag atoms are approximately 10 times less active than Pt atoms. Therefore, further enhancement in the ORR activity of Ag catalysts is necessary to be competitive with current cutting-edge Pt-based catalysts. We demonstrate the architectural design of Ag catalysts, synthesized using plasma discharge in liquid phase, for enhanced ORR kinetics in alkaline media. An attractive feature of this work is that the plasma status controlled via electric-field could form the Ag nanowires or dendrites without any chemical agents. The plasma reactor was made of a Teflon vessel with an inner diameter of 80 mm and a height of 80 mm, where a pair of tungsten(W) electrodes with a diameter of 2 mm was placed horizontally. The stock solutions were made by dissolving the 5-mM AgNO3 in DI water. For the synthesis of Agnanowires, the electricfield of 3.6kVcm-1 in a 200-ml AgNO3 aqueous solution was applied across the electrodes using a bipolar pulsed power supply(Kurita, Seisakusyo Co. Ltd). The repetition rate and pulse width were fixed at 30kHz and 2.0 us, respectively. The plasma discharge was carried out for a fixed reaction time of 60 min. In case of Ag nanodendrites, the electric field of 32kVcm-1 in a 200-ml AgNO3 aqueous solution was applied and other conditions were identical to the plasma discharge in water in terms of electrode configuration, repetition rate and discharge time. Using SEM and STEM, morphology of Ag nanowires and dendrites were investigated. With 3.6 kV/cm, Ag nanowire was obtained, while Ag dendrite was constructed with 32 kV/cm. The average diameter and legth of Ag nanowireses were 50 nm and 3.5 um, and thoes values of Ag dendrites were 40 nm and 3.0 um. As a results of XPS analysis, the surface defects in the Ag nanowires facilitated O2 incorporation into the surface region via the interaction between the oxygen and the electron cloud of the adjacent Ag atoms. The catalytic activity of Ag for oxygen reduction reaction(ORR) showed that the catalytic ORR activity of Ag nanowires are much better than Ag nanodendrites, and electron transfer number of Ag nanowires is similar to that of Pt (${\approx}4$).

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CFD Analysis on the Heat Transfer Performance with Various Obstacles in Air Channel of Air-Type PV/Thermal Module (공기식 태양광/열 시스템 공기채널 내 여러 저항체 설치에 따른 전열성능에 관한 CFD 해석)

  • Choi, Hwi-Ung;Fatkhur, Rokhman;Kim, Young-Bok;Yoon, Jung-In;Son, Chang-Hyo;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.38 no.2
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    • pp.33-43
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    • 2018
  • PV/Thermal module is the combined system, which consist of a photovoltaic module and solar thermal collector that can obtain electrical power and thermal energy simultaneously. Thus the power generation can be increase by decreasing the temperature of photovoltaic module and thermal energy retrieved from module also can be used for heating system. In this study, Heat transfer performance of air type PV/Thermal module was confirmed with various bottom obstacles that can be installed easily to real photovoltaic module by CFD (computational fluid dynamics) analysis. Eight type obstacles were investigated according to the shape and arrangement. As a result, nusselt number represent heat transfer performance was increased about 86% compare with the basic type PV/Tthermal module that has no obstacle and triangle type obstacle had higher value than other types. But pressure drop was also increased with increment of heat transfer enhancement. Thus the performance factor considering both heat transfer and pressure drop was confirmed and V-fin type obstacle arranged in a row for Reynolds number below 9,600 and protrusion type obstacle arranged in zigzag for Reynolds number above 14,400 were shown higher performance factor than other types. From these results, V-fin type obstacle arranged in row and protrusion type obstacle arranged in zigzag were considered as a proper type for applying to real PV/thermal module according to operating condition. But the heat transfer performance can be changed by the geometric conditions of obstacle such as height, width, length and arrangement. Thus, it could also confirmed that the optimal condition and arrangement of this obstacle need to be found in further study.

Inspection System for The Metal Mask (Metal Mask 검사시스템)

  • 최경진;이용현;박종국
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.40 no.2
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    • pp.1-9
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    • 2003
  • We develop an experimental system to inspect a metal mask and, in this paper, introduce its inspection algorithm. This system is composed of an ASC(Area Scan Camera) and a belt type xy-table. The whole area of the metal mask is divided into several inspection blocks. The area of each block is equal to FOV(Field of View). For each block, the camera image is compared to the reference image. The reference image is made by gerber file. The rotation angle of the metal mask is calculated through the linear equation that is substituted two end points of horizontal boundary of a specific hole in a camera image. To calculate the position error caused by the belt type xy-table, HT(Hough-Transform) using distances among the holes in two images is used. The center of the reference image is moved as much as the calculated Position error to be coincided with the camera image. The information of holes in each image, such as centroid, size, width and height, are calculated through labeling. Whether a holes is mado correctly by laser machine or not, is judged by comparing the centroid and the size of hole in each image. Finally, we build the experimental system and apply this algorithm.

Structural Capacity Evaluation of System Scaffolding using X-Type Advanced Guardrail (교차가새형 선행 안전난간을 적용한 시스템비계의 구조 성능 평가)

  • Park, J.D.;Lee, H.S.;Shin, W.S.;Kwon, Y.J.;Park, S.E.;Yang, S.S.;Jung, K.
    • Journal of the Korean Society of Safety
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    • v.35 no.5
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    • pp.49-58
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    • 2020
  • In domestic construction sites, when installing steel pipe scaffolding and system scaffolding, the guardrails are installed after the installation of the work platforms. This conventional guardrail system (CGS) is always exposed to the risk of falls because the safety railing is installed later. In order to prevent fall disasters during erecting and dismantling scaffolds, it is necessary to introduce the advanced guardrail system (AGS) which installs railings in advance of climbing onto a work platform. For the introduction of the AGS, the structural performance of the system scaffolding applying the CGS and the AGS was compared and evaluated. The structural analysis of the system scaffold (height: 31 m and width: 27.4 m) with AGS confirmed that structural safety was ensured because the maximum stress of each element of the system scaffolding satisfies the allowable stress of each element. As a result of performance comparison of CGS and AGS for each element, the combined stress ratio of vertical posts in AGS was 6.4% lower than that of CGS. In addition, in the case of ledger and transom, the combined stress ratios of AGS and CGS were almost the same. The compression test of the assembled system scaffolding (three-storied, 1 bay) showed that the AGS had better performance than the CGS by 9.7% (8.91 kN). The cross bracing exceeds the limit on slenderness ratio of codes for structural steel design. But the safety factor for the compressive load of the cross bracing was evaluated as meeting the design criteria by securing 3 or more. In actual experiments, it was confirmed that brace buckling did not occur even though the overall scaffold was buckled. Therefore, in the case of temporary structures, it was proposed to revise the standards for limiting on slenderness ratio of secondary or auxiliary elements to recommendations. This study can be used as basic data for the introduction of AGS for installing guardrails in advance at domestic construction sites.

A Study on Growth and Physiological Characteristic for Families in Open-pollinated Progeny Test Forest of Pinus koraiensis in Kapyung Site (가평지역(加平地域) 잣나무 풍매차대검정림(風媒差代儉定林)의 가계별(家系別) 생장(生長)과 생리적(生理的) 특성(特性)에 관한 연구(硏究))

  • Chung, Dong-Jun;Shin, Man Yong;Jang, Yong-Seok;Chon, Sang-Keun
    • Journal of Korean Society of Forest Science
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    • v.90 no.1
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    • pp.124-132
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    • 2001
  • This study was conducted to reveal the relationship between physiological characteristics and growth by family for open-pollinated progeny stand of Korean white pine in Gapyung site. Average growth performance of total 25 families for 18 years old progeny stand in this study site showed 5.9m in mean height, 8.9cm in mean DBH, $12.0m^2$ in basal area per hectare and $46.5m^3$ in volume per hectare, respectively. By the analysis result of growth performance for all 25 families, family No. 20 showed the most excellent growth and middle in family No. 10. On the other hand, family No. 3 represented the worst growth among the 25 families. The change of seasonal photosynthesis rate by increasing luminous intensity was the same tendency as the growth pattern of all 25 families and showed the same results in all four seasons. In the seasonal analysis, the photosynthesis rate was increased as the season has changed from winter to summer. Chlorophyll contents was also increased from winter to summer. Especially, family No. 20 which is the best in growth performance has more chlorophyll contents than the others. In addition, family No. 20 was also better than other families in the weight of assimilation tissue(g), length of needle(cm), width of needle(cm), and number of Stoma. However, in water utilization rate, family No. 3 which is the worst in the growth performance showed the best result that is reverse tendency compared with the photosynthesis rate. The changes of water utilization rate represented to be increased as the season has changed from winter to summer.

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Experimental Study on Loading Capacity of SY Corrugated Steel Form for RC Beam and Girder (SY 비탈형 보거푸집의 내하성능에 관한 실험적 연구)

  • Bae, Kyu-Woong;Boo, Yoon-Seob;Hwhang, Yoon-Koog;Shin, Sang-Min
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.32-39
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    • 2021
  • Recently, necessities of steel form for reinforced concrete beam and girder have been emphasized in building structures for the reduction of the construction period and the labor cost. SY Beam was developed for the these purposes and is roll-formed using thin steel plate. On this research, we tried to evaluate and verify the performance and behavior of SY Beam under construction loading stage as like pouring in situ concrete. For the standard shape of SY beam, structural modelling with various steel thicknesses has carried out using MIDAS GEN program. From results of modelling, the width and height of SY Beam were determined 600mm and 400mm respectively. For 3 SY Beams, the loading experiment was performed to measure vertical and horizontal displacement under stacking sand, concrete block, and bundle of rebar. As a result, the vertical deflection showed a tendency to decrease as the thickness increased. In the horizontal displacement, the trend according to the thickness was not clearly observed. From the evaluation on the loading experiment, it is considered that the SY Beam can secure both workability and structural safety. In particular, the SY Beam(1.2mm) hardly generates horizontal displacement, so it has excellent load-bearing capacity. So, we judged that the SY Beam with 1.2mm steel plate has excellent performance and consider to be immediately commercially available.

Quantitative image processing analysis for handwriting legibility evaluation (글씨쓰기 명료도 평가의 정량적 영상처리 분석)

  • Kim, Eun-Bin;Lee, Cho-Hee;Kim, Eun-Young;Lee, OnSeok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.158-165
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    • 2019
  • Although evaluation of writing disabilities identification and timely intervention are required, clinicians adopt a manual scoring method and there is a possibility of error due to subjective evaluation. In this study, the size ratio and position of letters are digitized and quantified through image processing of offline handwritten characters. We tried to evaluate objectively and accurately the performance of writing through comparison with existing methods. From November 12th to 16th, 2018, 20 adults without neurological injury were selected. They used a pencil to follow the 10 words, 2 sentence stimuli after keeping the usual habit, and we collected the writing test data. The results showed that the height of the word was 1.2 times larger than the width and it tilted to the lower left. The spacing interval was 9mm on average. In the Paired T test, a high correlation was showed between our system and existing methods in the word and sentence 2. This demonstrated the possibility as a testing tool. This study evaluated objectively and precisely writing performance of offline handwritten characters through image processing and provided preliminary data for performance standards. In the future, it can be suggested as a basic data on writing diagnosis of various ages.

The effect of starvation on the characteristics of morphometric measurement and body-sectioned shape in Far Eastern catfish (Silurus asotus) (메기(Silurus asotus) 기아 시 외부형태 및 체 절단면 변화)

  • Park, In-Seok;Goo, In Bon;Gil, Hyun Woo
    • Korean Journal of Environmental Biology
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    • v.39 no.1
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    • pp.55-67
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    • 2021
  • A 210-day experiment was conducted to examine the effects of starvation on survival, external morphometric traits, and sectioned morphometric traits in Far Eastern catfish(Silurus asotus). The survival rate decreased to 92.2±0.47% in the fed group and to 74.4±2.59% in the starved group. Eight dimensions of Ls, DALPO/Ls, DADOP/Ls, ED/Ls, CH/Ls, BDAA/Ls, BDMA/Ls, and BWAA/Ls showed significant differences (p<0.05), and 16 other dimensions of DALAD/Ls, DPDPL/Ls, HPLAA/Ls, HALAV/Ls, HALOP/Ls, DAUPO/Ls, DADAV/Ls, DADAA/Ls, Max BL/Ls, Man BL/Ls, LD/Ls, HWOP/Ls, DAUF/HL, DAUS/HL, IW/HL, and DAUE/HL were not significantly different among the initial, fed, and starved groups (p>0.05). The fed group showed higher total height (THX), wider width (WX), and larger area (AX) than those of the starved group in each body section. This research provides information on the morphometric traits and body sections of starved Far Eastern catfish. These results can be used as a basic guide to indicate nutritional status and assist in aquaculture methods for Far Eastern catfish. Moreover, the methods used in this study were considered helpful because the survey analysis method can be used to investigate information on the nutritional status of other fish species.

Evaluation of Lateral Flow in Soft Ground under Embankment (성토하부 연약지반의 측방유동 평가)

  • Hong, Won-Pyo;Cho, Sam-Deok;Lee, Jae-Ho;Lee, Kwang-Wu
    • Journal of the Korean Geotechnical Society
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    • v.22 no.10
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    • pp.93-100
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    • 2006
  • The lateral soil movement in soft grounds undergoing improvement with application of vertical drains is analyzed on the basis of monitoring data at three fields, in which fifty six monitoring sites are located. Based on the investigations, the criterions are suggested to predict the lateral soil movement. In order to predict the lateral soil movement in the improved soft grounds by using the dimensionless parameter R suggested by Marche & Chapuis (1974), it is desirable that the maximum lateral displacement in the soft ground below the toe of embankment should be applied to calculate R instead of the lateral displacement at the toe of embankment. The lateral soil movement may increase rapidly, if the safety factor of slope is less than 1.4 in case of high ratio of H/B (Thickness of soft ground/Embankment width) such as 1.15 or is less than 1.2 in case of low ratio of H/B such as 0.05. Also, the graph suggested by Tschebotarioff (1973), which illustrates the relationship between the maximum height of embankments and the undrained shear strength of soft grounds, can be applied to the evaluation for the possibility of the lateral soil movement due to embankments on soft grounds.

Evaluation of Surface Temperature Variation and Heat Exchange Rate of Concrete Road Pavement with Buried Circulating Water Piping (열매체 순환수 배관이 매설된 콘크리트 도로 포장체의 표면 온도 변화와 방열량 평가)

  • Byonghu Sohn;Yongki Kim
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.19 no.3
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    • pp.1-13
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    • 2023
  • Hydronic heated road pavement (HHP) systems have been well established and documented to provide road safety in winter season over the past two decades. However, most of the systems run on asphalt, only a few are tested with concrete, and there rarely is a comparison between those two common road materials in their performance. The aim of this study is to investigate the thermal performance of the concrete HHP systems, including surface temperature variations of experimental pavements in winter season. For preliminary study a small-scale experimental system was installed to evaluate the heat transfer characteristics of the concrete HHP in the test field. The system consists of 3 concrete slabs made of 1 m in width, 1 m in length, and 0.25 m in height. In these slabs, circulating water piping was embedded with different pipe depths of 0.08 m (Case A), 0.12 m (Case B), and 0.20 m (Case C) and same horizontal space of 0.16 m. Heating performance in winter season was tested with different inlet temperatures of 25℃, 30℃, 35℃ and 40℃ during the entire measurement period. Overall, the surface temperature of the concrete HHPs remained above 3℃ in all experimental conditions applied in this study. The results of the surface temperature measurement with respect to the pipe depth showed that Case B was the highest among the three cases. However, the closer the circulating water pipe was to the pavement surface, the greater the heat exchange rate. This results is considered that the heat is continuously accumulated inside the pavements and then the temperature inside the pavements increases, while the amount of heat dissipation decreases as the temperature difference between the inlet and outlet of circulating water decreases. In this preliminary test the applicability of the concrete HHP on road deicing was confirmed. Finally, the results can be used as a basis for studying the effects of various variables on road pavements through numerical analysis and for conducting large-scale empirical experiments.