• 한국군사과학기술학회지
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• 제14권6호
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• pp.1186-1191
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• 2011

Composition which was used as a white smoke grenade consists of Aluminium(Al), Hexachloroethane(HCE) and Zinc Oxide(ZnO), etc. there is a possibility of misfire due to long term storage and there are very few reports on the mechanism behind misfire. In this study, an experimental method known as accelerated degradation testing is used to investigate the chemical mechanism resulting in misfire. The mechanism of chemical change during long term storage was analyzed with XRD and FT-IR. Analysis results suggest that a part of HCE consisting of the white smoke grenade disappeared and the other part was combined into $ZnCl_2$, $AlCl_3$, as a recycled intermediate product under closed system.

• 한국군사과학기술학회지
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• 제14권5호
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• pp.888-896
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• 2011

A white smoke hand grenade, KM8 is used to make smoke screen in order to provide visual field interceptions or signals. The grenade fails when its time to emit smoke is longer than the specified emission time so that the smoke concentration becomes lighter. This paper considered failure in smoke emission time, and evaluated its storage lifetime. The main objective of this paper is to modify the present specification limits of smoke emission time for the efficient process control in manufacturing, through analyzing effect of its specification change on the storage lifetime, based on the lifetime evaluation results. Accelerated degradation test was performed and then failure in smoke emission time was reproduced from the test. And estimated storage lifetimes from the accelerated test results was compared to evaluated lifetimes of grenades using the ASRP data. Past process testing results of the grenade in manufacturing were analyzed in this paper. Then, each storage lifetime for the specifications, ${\pm}3$ and ${\pm}5$ in seconds, extended from the current specification in manufacturing were estimated using the past testing results, and compared to one another.