• 제목/요약/키워드: Whiskers

검색결과 159건 처리시간 0.029초

차세대 원자력 시스템용 탄화규소계 세라믹스의 제조와 이온조사 특성 평가 (Fabrication and Ion Irradiation Characteristics of SiC-Based Ceramics for Advanced Nuclear Energy Systems)

  • 김원주;강석민;박경환;;류우석;박지연
    • 한국세라믹학회지
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    • 제42권8호
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    • pp.575-581
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    • 2005
  • SiC-based ceramics are considered as candidate materials for the advanced nuclear energy systems such as the generation IV reactors and the fusion reactors due to their excellent high-temperature strength and irradiation resistance. The advanced nuclear energy systems and their main components adopting ceramic composites were briefly reviewed. A novel fabrication method of $SiC_f/SiC$ composites by introducing SiC whiskers was also described. In addition, the charged-particle irradiation ($Si^{2+}$ and $H^{+}$ ion) into CVD SiC was carried out to simulate the severe environments of the advanced nuclear reactors. SiC whiskers grown in the fiber preform increased the matrix infiltration rate by more than $60\%$ compared to the conventional CVI process. The highly crystalline and pure SiC showed little degradation in hardness and elastic modulus up to a damage level of 10 dpa at $1000^{\circ}C$.

A study of noblemen's grooming styles of facial hair in portraits in the Joseon Dynasty

  • Kim, Yang-Soon;Cho, Hyun-Ju
    • 복식문화연구
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    • 제21권4호
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    • pp.596-605
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    • 2013
  • The purpose of this study is to classify and recreate the grooming styles of facial hair sported by noblemen during the Joseon Dynasty. Using existent portraits painted during this period as corroborative materials, this study has identified the traditional grooming styles of facial hair sought by noblemen in this age. This study has utilized 30 facial hair styles found in the portraits of noblemen inherited from the Joseon Dynasty, which take up the majority of the portraits currently remaining in Korea. To recreate grooming styles of facial hair, this study has divided facial hair into three types according to its location: beards, moustaches and whiskers. Based on the analysis of these divided grooming styles, this study has recreated grooming styles of facial hair by using artificial modelling heads, artificial hair, artificial glue, scissors, and a comb. The grooming styles of facial hair recreated by this study are closest to those that noblemen sought and did wear during the Joseon Dynasty. The results of this study are as follows. First, they groomed their moustaches in the 八 shape. Next, they wore their beards in the shape of an inverted triangle. Finally, they also grew and groomed whiskers. Though there are individual differences in the location, length, and volume of facial hair, noblemen in the Joseon Dynasty generally sought to wear their facial hair neat and long. Little research has been done to recreate and present noblemen's grooming styles of facial hair focusing on portraits. Thus, the findings of this study are expected to be utilized as basic materials for the education and research of grooming styles of facial hair according to ages. They can also be used as basic materials for recreating facial hair in historical dramas.

Microstructural Investigations of $Al_2O_3$ Scale Formed on FeCrAl Steel during High Temperature Oxidation in $SO_2$

  • Homa, M.;Zurek, Z.;Morgiel, B.;Zieba, P.;Wojewoda, J.
    • Corrosion Science and Technology
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    • 제7권3호
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    • pp.139-144
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    • 2008
  • The results of microstructure observations of the $Al_2O_3$ scale formed on a Fe-Cr-Al steel during high temperature oxidation in the $SO_2$ atmosphere are presented. Morphology of the scale has been studied by SEM and TEM techniques. Phase and chemical compositions have been studied by EDX and XRD techniques. The alumina oxide is a primary component of the scale. TEM observations showed that the scale was multilayer. The entire surface of the scale is covered with "whiskers", which look like very thin platelets and have random orientation. The cross section of a sample shows, that the "whiskers" are approximately $2{\mu}m$ high, however the compact scale layer on which they reside is $0.2{\mu}m$ thick. The scale layer was composed mainly of small equiaxial grains and a residual amount of small columnar grains. EDX analysis of the scale surface showed that the any sulfides were found in the formed outer and thin inner scale layer. A phase analysis of the scale formed revealed that it is composed mainly of the $\theta-Al_2O_3$ phase and a residual amount of $\alpha-Al_2O_3$.

다성분 산화물 요업체의 고온 물라이트화 반응 정량분석 (Quantitative Analysis of High-Temperature Mullitization from a Multicomponent Oxide System)

  • 신현호;김철수;김창욱;장순남;성완;장동환;강석원;최석홍
    • 한국세라믹학회지
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    • 제35권1호
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    • pp.5-10
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    • 1998
  • Mullitization in a multicomponent oxide system(alumina-kaolin-quartz-feldspar-talc) was studied as a function of sintering temperature from 1200 to 1500$^{\circ}C$ based upon a quantitative X-ray diffraction analysis. In the present study mullite grew as wiskers and its formation reaction showed characteristic there stages as follows In the first stage(1255-1295$^{\circ}C$) an appreciable mullitization(nucleation) occurred while corun-dum dissolution into glass (increasing glass content ) limited the rate of the reaction. At 1295-1335$^{\circ}C$ (second state) the reaction was significantly enhanced with a considerable glass consumption and with no appreciable change in corundum content. Finally (above 1335$^{\circ}C$) the reaction rate was attenuated re-markably with an apparent decrease in glass consumption rate. The impingement of mullite whiskers by oth-er whiskers and crystals was speculated to cause mullite growth in thickness direction with a slow growth rate resulting in the diminished reaction rate in the final stage.

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배향된 $\beta-Si_3N_4$ Whisker를 함유하는 $Si_3N_4$ 복합체의 기계적 특성에 미치는 소결조제와 소결온도의 영향 (Effect of Sintering Additives and Sintering Temperature on Mechanical Properties of the $Si_3N_4$ Composites Containing Aligned $\beta-Si_3N_4$ Whisker)

  • 김창원;최명제;박찬;박동수
    • 한국세라믹학회지
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    • 제37권1호
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    • pp.21-25
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    • 2000
  • Gas pressure sintered silicon nitride based composites with 5 wt% $\beta$-Si3N4 whiskers were prepared, and the variations depending on sintering additives and sintering temperature were studied. Sintering additives were 6 wt% Y2O3-1 wt% MgO(6Y1M), 6 wt%Y2O3-1 wt% Al2O3(6Y1A), 6 wt% Y2O3-1 wt% SiO2(6Y1S), and whiskers were unidirectionally oriented by a modified tape casting technique. Samples were fully densified by gas pressure sintering at 2148 K and 2273 K. As the sintering temperature increased, the size of large elongated grains was increased. Three point flexural strength of 6Y1M and 6Y1M samples was higher than that of 6Y1S sample, and the strength decreased as the sintering temperature increased. The indentation crack length became shorter for the sample sintered at higher temperature, and the difference between the cracks length parallel to and normal to the direction of whisker alignment was decreased. In case of cracks 45$^{\circ}$off the whisker alignment direction, the crack length anisotropy disappeared.

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Mechanical properties and assessment of a hybrid ultra-high-performance engineered cementitious composite using calcium carbonate whiskers and polyethylene fibers

  • Wu, Li-Shan;Yu, Zhi-Hui;Zhang, Cong;Bangi, Toshiyuki
    • Computers and Concrete
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    • 제30권5호
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    • pp.339-355
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    • 2022
  • The high cost of ultra-high-performance engineered cementitious composite (UHP-ECC) is currently a crucial issue, especially in terms of the polyethylene (PE) fibers use. In this paper, cheap calcium carbonate whiskers (CW) were evaluated on the feasibility of hybrid with PE fibers. Diverse combinations of PE fibers and CW were employed to investigate the multi-scale enhancement on the UHP-ECC performance. A probabilistic-based UHP-ECC tensile strain reliability analysis approach was utilized, which was in general agreement with the experimental results. Furthermore, a multi-dimensional integrated representation was conducted for the comprehensive assessment of UHP-ECC. Results illustrated that CW improved the compressive strength and energy dissipation capacity of UHP-ECC owing to the microscopic strengthening mechanism. CW and PE fiber further promoted the saturated cracking of composite by multi-scale crack arresting effect. In particular, PE1.75-CW0.5 specimen possessed the best overall performance. The ultimate cracking width of PE1.75-CW0.5 group had 98 ㎛, which was 46.18% lower compared to PE2-CW0 group, the 28d compressive strength were slightly improved, the tensile strain capacity was comparable to that of PE2-CW0 group. The results above demonstrated that combinations of PE fiber and CW could significantly enhance the comprehensive performance of UHP-ECC, which was beneficial for large-scale engineering applications.

첨가제 $Al_2O_3$ 및 SiC Whisker가 $Si_3N_3$ 결합 SiC 소결체 특성에 미치는 영향 (Effect of Al2O3 and SiC Whisker on Sintering and Mechanical Properties of Si3N3 Bonded SiC)

  • 백용혁;신종윤;정종인;권양호
    • 한국세라믹학회지
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    • 제29권11호
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    • pp.837-842
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    • 1992
  • SiC and Si mixtures dispersed by 0.5~10.0 wt% of Al2O3 and reinforced by SiC whisker were sintered to Si3N4 bonded SiC bodies at 140$0^{\circ}C$ in a N2 gas atmosphere, and the nitridation and mechanical properties of sintered bodies were investigated. From these observation, it is concluded that relative density and bending strength increased with the rising of nitridation and the highest nitridation ratio was obtained for a specimen having 1.5 wt% Al2O3. On the other hand, the amount of $\beta$-Si3N4 in the specimens containing Al2O3 more than 5.0 wt% was increased abruptly and the best in fracture toughness was sintered for a composits having 30 wt% SiC whiskers.

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Sintering Phenomena and Thermodynamic Analysis in the SiC Whisker-Reinforced Mullite Matrix Ceramic Composites During RF Plasma Sintering

  • Park, Youngsoo;:Michael J. MeNallan
    • The Korean Journal of Ceramics
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    • 제2권4호
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    • pp.231-237
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    • 1996
  • Mullite ceramics can be sintered by rf plasma sintering to densities as high as 97% compared to the theoretical density of the mullite, while SiC whisker-reinforced mullite matrix ceramic composites were not sintered by plasma sintering. Decomposition of mullite occurs in a superficial regins at the outside surface of the specimen by volatilization of SiO at elevated temperature by plasma. SiC whiskers were destroyed, and the matrix was converted to alumina from SiC-whisker reinforced mullite matrix ceramic composites during the plasma sintering. Accelerated volatilization from the SiC whisker in the mullite prevents sintering. The volatile species are mainly SiC and CO gas species. The effects of plasma on mullite and SiC-whisker reinforced mullite matrix composites are interpreted by thermodynamic simulation of the volatile species in the plasma environment. The thermodynamic results show that the decomposition will not occur during hot pressing.

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Dielectric Properties of Amorphous and Composite Alkoxi-derived Alumina Thin Films

  • N., Korobova;Soh, Dea-Wha
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.772-775
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    • 2003
  • The development of new improved type of dielectric materials on the conception of multiphase structure has been carried out in this paper. Metal alkoxides solutions were used for application of thin film by electrophoretic deposition technique. We succeeded in preparation of amorphous and composite dielectric films from Al alkoxides. Specific features of the preparation technique were considered. Microstructure of the films was examined as well as their dielectric properties. TEM analyses reveals that films deposited from aging sols and heat-treated at temperatures as low as $400^{\circ}C$ contain small whiskers of ${\delta}-Al_2O_3$.

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