• 제목/요약/키워드: Wetting behavior

검색결과 126건 처리시간 0.028초

Influence of flexural loading on chloride ingress in concrete subjected to cyclic drying-wetting condition

  • Ye, Hailong;Fu, Chuanqing;Jin, Nanguo;Jin, Xianyu
    • Computers and Concrete
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    • 제15권2호
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    • pp.183-198
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    • 2015
  • Chloride ingress implies a complex interaction between physical and chemical process, in which heat, moisture and chloride ions transport through concrete cover. Meanwhile, reinforced concrete structure itself undergoes evolution due to variation in temperature, relative humidity and creep effects, which can potentially change the deformation and trigger some micro-cracks in concrete. In addition, all of these process show time-dependent performance with complex interaction between structures and environments. In the present work, a time-dependent behavior of chloride transport in reinforced concrete beam subjected to flexural load is proposed based on the well-known section fiber model. The strain state varies because of stress redistribution caused by the interaction between environment and structure, mainly dominated by thermal stresses and shrinkage stress and creep. Finally, in order to clear the influence of strain state on the chloride diffusivity, experiment test were carried out and a power function used to describe this influence is proposed.

BRAZEABILITY AND MICROSTRUCTURE OF Ag-28Cu MICROJOINING FILLER PRODUCED BY HIGH ENERGY BALL MILLING

  • ASHUTOSH SHARMA;MYOUNG JIN CHAE;BYUNGMIN AHN
    • Archives of Metallurgy and Materials
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    • 제65권4호
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    • pp.1323-1327
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    • 2020
  • In this paper, we have studied the evolution of morphology and brazing behavior of Ag-28Cu alloy filler processed by high energy ball milling. The milling of the powder mixture was carried out for 40 h. The structural and morphological analyses were performed by the X-ray diffraction and scanning electron microscopy. The melting temperature of the braze filler was determined by differential thermal analysis. The filler wetting properties were assessed from the spread area ratio measurements on various Ti substrates. The results indicate that the ball milling can effectively depress the filler melting point and enhance the brazeability. The milled powder mixture showed Ag(Cu) solid solution with a crystallite size of 174-68 nm after 40 h. It was shown that the high energy ball milling can be a potential method to develop low temperature brazing fillers for advanced microjoining applications.

폴리에스테르/락톤 폴리올과 HDI-Biuret에 의한 폴리우레탄 도료의 제조 및 경화거동 (Preparation and Curing Behavior of Polyurethane Coatings by Polyester/Lactone Polyol and HDI-biuret)

  • 최용호;김대원;황규현;박홍수;김태옥
    • 폴리머
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    • 제24권1호
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    • pp.72-81
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    • 2000
  • 벤조산 폴리에스테르/락톤 폴리올의 합성은 디올로서 폴리카프로락톤 0201, 트리올로서 트리메틸올프로판, 2염기산으로서 아디프산 및 1염기산으로 벤조산을 사용하였다. 폴리이소시아네이트 프리폴리머는 HDI-biuret형인 Desmodur N-100을 사용하였다. 벤조산 폴리에스테르/락톤 폴리올, 폴리이소시아네이트, 안료, 습윤분산제 및 플로우개량제 등을 블렌드하여 2성분계 폴리우레탄 도료를 제조하였다. 제조된 폴리우레탄 도료로서 도막시편을 제작하여 각종 도막 물성시험을 행한 결과 KS 규격에서 제시한 기준치와 비교하여 내마모성, 촉진내후성, 황변도는 우수하게, 굴곡성, 내충격성, 60$^{\circ}$ 경민광택도, 접착력, 내유성, 명도지수차는 양호하게, 경도는 다소 나쁘게 나타났다. 따라서 디올로서 폴리카프로락톤 0201을 도입한 후 내유성, 굴곡성, 내충격성의 장점이 나타남을 확인하였다. 또한 벤조산 함량변화에 따른 고화 및 경화거동을 살펴 본 결과, 고화에 따른 건조시간은 2~4시간으로, 경화에 따른 가사시간은 20~37시간으로 각각 나타나, 도막표면의 고화 및 경화상태가 양호함을 보여주었다.

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불포화토의 열·탄소성 거동 분석을 위한 Barcelona Basic Model 소개 (Introduction of Barcelona Basic Model for Analysis of the Thermo-Elasto-Plastic Behavior of Unsaturated Soils)

  • 이창수;윤석;이재원;김건영
    • 터널과지하공간
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    • 제29권1호
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    • pp.38-51
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    • 2019
  • Barcelona Basic Model(BBM)은 응력의 변화에 따른 부피변화뿐만 아니라 흡입력의 변화에 따른 팽윤거동을 설명할 수 있으며, 흡입력 변화에 따른 점착력과 선행압밀응력의 변화와 온도변화에 따른 선행압밀응력의 변화를 고려할 수 있다. 따라서, 고준위방사성폐기물 처분시스템에서 공학적방벽재로 고려되고 있는 벤토나이트 완충재의 열-수리-역학적 복합거동을 예측 및 분석하는 것에 많이 활용되고 있다. 그러나 우리나라의 암반 및 지반 공학자들에게 잘 알려져 있지 않기 때문에 BBM을 소개하고자 한다. BBM은 불포화 토질의 역학적 거동을 모사하기 위해 Modified Cam Clay(MCC) 모델을 확장하여 만들어 졌기 때문에 본 고에서는 먼저 MCC 모델을 간략하게 소개하고, 열-탄소성 모델인 BBM을 상세히 소개하였다.

불포화 사질토의 거동예측을 위한 구성식 개발 (Development of Constitutive Model for the Prediction of Behaviour of Unsaturated Granular Soil)

  • 송창섭;장병욱
    • 한국지반공학회지:지반
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    • 제11권3호
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    • pp.43-54
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    • 1995
  • 실트질 모래를 재료로 삼축압축시험기를 개조하고, 삼축셀에 고압공기투과판을 부착하여 축변환기법에 의해 흡인력과 순평균응력을 조절하면서 등력압축시험과 전단시험을 행하여, 불포화 상태에 따른 토질정수의 변화를 규명하였으며, 함수상태의 변화에 따라 응력, 체적변화 등의 거동특성을 검토하였다. 실험의 결과에서 규명된 불포화토의 특성을 바탕으로, 불포화토의 응력성분을 고려하고, 수정 Cam -Clay 모델을 경계조건으로 하는 불포화토의 거동예측을 위한 구성식을 개발하고, 실트질 모래에 대한 실내실험의 자료로부터 구한 관측치와 예측치를 비교하여 이의 타당성을 검증하였다.

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이트리아 안정화 지르코니아 바인더에 의한 열전지 전기화학적 특성 (Electrochemical Properties of Yttria Stabilized Zirconia Binder for Thermal Batteries)

  • 김지연
    • 한국전기전자재료학회논문지
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    • 제30권5호
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    • pp.331-337
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    • 2017
  • Thermal batteries, reserve power source, is activated by melting of molten salt at the temperature range of $350{\sim}550^{\circ}C$. To immobile the molten state electrolyte when the thermal battery is activated, the binder must be added in electrolyte. Usually, molten salts include 30~40 wt% of MgO binder to ensure electrical insulation as well as safety. However, the conventional MgO binder tends to increase ionic conductive resistance and thus the inclusion of the binder increases the total impedance of the battery. This paper mainly focused on the study of yttria stabilized zirconia (YSZ) as an alternative binder for molten salt. The chemical stability between the molten salt and YSZ is measured by XRD and DSC. And the sufficient path for ionic conduction on molten salt could be confirmed by the enhanced wetting behavior and the enlarged pore size of YSZ. The electrochemical properties were analyzed using single cell tests so that it showed the outstanding performance than that using MgO binder.

유역 공간 강우 산정방법에 따른 VfloTM 분포형 강우-유출 모형의 매개변수 평가 - 금호강 동촌 유역을 대상으로 - (Parameter Estimation of VfloTM Distributed Rainfall-Runoff Model by Areal Rainfall Calculation Methods - For Dongchon Watershed of Geumho River -)

  • 김시수;정충길;박종윤;정성원;김성준
    • 한국농공학회논문집
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    • 제55권1호
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    • pp.9-15
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    • 2013
  • This study is to evaluate the parameter behavior of VfloTM distributed rainfall-runoff model by applying 3 kinds of rainfall interpolation methods viz. Inverse Distance Weighting (IDW), Kriging (KRI), and Thiessen network (THI). For the 1,544 $km^2$ Dongcheon watershed of Nakdong river, the model was calibrated using 4 storm events in 2007 and 2009, and validated using 2 storm events in 2010. The model was calibrated with Nash-Sutcliffe model efficiency of 0.97 for IDW, 0.94 for KRI, and 0.95 for THI respectively. For the sensitive parameters, the saturated hydraulic conductivity ($K_{sat}$) for IDW, KRI, and THI were 0.33, 0.31, and 0.43 cm/hr, and the soil suction head at the wetting front (${\Psi}_f$) were 4.10, 3.96, and 5.19 cm $H_2O$ respectively. These parameters affected the infiltration process by the spatial distribution of antecedent moisture condition before a storm.

솔-젤 법을 이용한 Pb(Zr, Ti)$O_3$ 박막의 성장 및 전기적 특성에 관한 연구 (Growth and electrical properties of Pb(Zr, Ti)$O_3$ thin films by sol-gel method)

  • 김봉주;전성진;이재찬;유지범
    • 한국진공학회지
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    • 제8권4A호
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    • pp.425-431
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    • 1999
  • $Pb(Zr_{0.52}, Ti_{0.48})O_3$ (PZT) thick films as an actuating material with conducting oxides, $(La_{0.5}Sr_{0.5}) CoO_3$ (LSCO), have been fabricated by sol-gel method for Optical Micro-Electro-Mechanical System (MEMS) devices, in which PZT/LSCO/SiO2 structures were used. In order to improve the adhesion to LSCO solution in order to enhance the wetting behavior of a water-based LSCO precursor solution and further to improve the adhesion between LSCO and $SiO_2$ layers. PZT films were made using 1-3 propanediol based precursor solution which has a high viscosity and a boiling point appropriate for thick film fabrication. In the precursor solution, Ti-propoxied and Zr-propoxied are partially substituted with acetylacetone to achieve the solution stability while maintaining reactivity. Crack free PZT films (0.8~1$\mu\textrm{m}$) have been successfully fabricated at crystallization temperatures above $700^{\circ}C$. Dielectric constants and dielectric losses of the PZT films were 900~1200and 2~5%, respectively. Piezoelectric constant $d_{33}$ of the PZT films constrained by a substrate were 200pm/V at 100kV/cm.

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층상구조를 가진 증발식 열교환기 습채널의 표면 젖음도 해석 (Analysis on Wetting Behavior of A Lamellar Type Wet Channels in An Evaporative Heat Exchanger)

  • 오동욱;박재범;송찬호
    • 설비공학논문집
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    • 제28권7호
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    • pp.283-287
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    • 2016
  • One of the most important factors for determining the thermal performance of an evaporative cooling system is the wettability of the evaporative heat exchanger surface. Evaporation of a widely spread water film on the heat exchanger surface promotes heat transfer between the "dry" air and "wet" air passages. Hydrophilic coating is generally applied on the heat exchanger surfaces to increase the wettability of the heat exchanger surface and the COP of the evaporative cooling system. In this paper, a simple lamellar patterned structure is suggested to maximize the spreading of a water film on the vertically oriented walls. The capillary height of the lamellar structured grooves is analyzed through a theoretical model, and the results are compared with the numerical analysis through a finite element analysis tool, SE-FIT. A good agreement between the theoretical model and the numerical analysis can be observed as long as the channel depth is comparable to or larger than the channel width of the lamellar structure.

니켈기 초내열합금의 고온연성거동에 관한 연구 (A Study on Hot Ductility Behavior of Ni-based Superalloys)

  • 이청래;엄상호;김성욱;최철;이창희
    • Journal of Welding and Joining
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    • 제22권2호
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    • pp.59-68
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    • 2004
  • Plasma transferred arc welding (PTAW) has been taken into consideration for repairing Ni-based superalloy components used gas turbine blades. Various cracks has been generally reported to be found in the base metal heat affected zone(HAZ) along grain boundary. Thus, hot cracking susceptibility of Ni-based superalloys was evaluated according to heat treatments. Hot ductility test was conducted on specimens with solution treated at 112$0^{\circ}C$ for 2 hours and aging treated at 845$^{\circ}C$ for 24hours after solution treatment. The results of the hot ductility test appeared that solution treated specimens were the highest ductility recovery rate among three conditions. The loss of ductility at high temperature in Ni-based superalloy was mainly controlled by the degree of pain boundary wetting due to constitutional liquation of MC carbide precipitates. Meanwhile, the highest ductility recovery rate in solution-treated alloys seems to be lack of M23C6, which can be dissolved during heating and then result in the local enrichment of Cr in the vicinity of the grain boundary.