• Title/Summary/Keyword: Wet-reduction process

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Numerical Study on Optimization of the SCR Process Design in Horizontal HRSG for NOx Reduction (수평형 폐열회수보일러 배기탈질 SCR시스템의 최적설계를 위한 수치해석적 연구)

  • Kim, Kyeongsook;Lee, Kyeongok
    • Journal of Environmental Science International
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    • v.22 no.11
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    • pp.1481-1498
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    • 2013
  • The SCR (selective catalytic reduction) system is highly-effective technique for NOx reduction from exhaust gases. In this study, the effects of the direction and size of nozzle and the ammonia injection concentration on the performance of SCR system are analyzed by using the computational fluid dynamics method. When the nozzle is arranged in zigzaged direction which is normal to exhausted gas flow, it is shown that the uniformity of gas flow and the NH3/NO molar ratio is improved remarkably. With the change of the ammonia injection concentration from 0.2 vol%(wet) to 1.0 vol%(wet), the uniformity of gas flow shows a good results. As the size of nozzle diameter changes from 6 mm to 12 mm, the uniformity of gas flow is maintained well. It is shown that the uniformity of the $NH_3/NO$ molar ratio becomes better with decreasing the ammonia injection concentration and the size of nozzle diameter.

The Preparation and Growth Mechanism of the Recovered Bi2Te3 Particles with Respect to Surfactants (회수된 Bi2Te3의 계면활성제에 따른 합성 및 성장 거동)

  • So, Hyeongsub;Song, Eunpil;Choa, Yong-Ho;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.141-146
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    • 2017
  • $Bi_2Te_3$ powders are recovered by wet chemical reduction for waste n-type thermoelectric chips, and the recovered particles with different morphologies are prepared using various surfactants such as cetyltrimethylammonium bromide (CTAB), sodium dodecylbenzenesulfonate (SDBS), and ethylenediaminetetraacetic acid (EDTA). When citric acid is added as the surfactant, the shape of the aggregated particles shows no distinctive features. On the other hand, rod-shaped particles are formed in the sample with CTAB, and sheet-like particles are synthesized with the addition of SDBS. Further, particles with a tripod shape are observed when EDTA is added as the surfactant. The growth mechanism of the particle shapes depending on the surfactant is investigated, with a focus on the nucleation and growth phenomena. These results help to elucidate the intrinsic formation mechanism of the rod, plate, and tripod structures of the $Bi_2Te_3$ recovered by the wet reduction process.

Preparation and Characterization of Monodispersed and Nano-sized Cu Powders

  • Kim, Tea-Wan;Lee, Hyang-Mi;Kim, Yong-Yee;Hwang, Kyu-Hong;Park, Hong-Chae;Yoon, Seog-Young
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.464-465
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    • 2006
  • Monodispersed and nano-sized Cu powders were synthesized from copper sulfate pentahydrate $(CuSO_4{\cdot}5H_2O)$ inside a nonionic polymer matrix by using wet chemical reduction process. The sucrose was used as a nonionic polymer network source. The influences of a nonionic polymer matrix on the particle size of the prepared Cu powders were characterized by means of X-ray diffraction), scanning electron microscopy), and particle size analysis). The smallen Cu powders with size of approximately 100 nm was obtained with adding of 0.04M sucrose at reaction temperature of $60\;^{\circ}C$. The particle size of the Cu powders prepared by the reduction inside polymer network was strongly dependent of the sucrose content and reaction temperature.

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The Evaluation of the Application of Modified Wood Powder Spacers to Liner Board Mill Trials (개질처리된 목질계 스페이서의 산업용지 생산현장 적용평가)

  • Seo, Yung Bum;Yoon, Doh-Hyun;Sung, Yong Joo;Gwon, Wan-Oh;Kim, Jin-doo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.98-103
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    • 2015
  • The reduction of the energy consumption in papermaking process become more important issue because of the regulation of green house gas (GHG) emission. Since more than half of energy for papermaking process is consumed during drying process, the increase of the drying efficiency would be very important solution for saving energy and reduction of GHG emission. The improvement of drying efficiency could be very difficult for the liner board mill because the liner board are usually made of recycled paper, OCC (old corrugated container). The short fiber and fines originated the OCC lead to compact sheet structure and delay the water flow out during wet pressing process and drying process. The application of lignocellulose spacer could provide more loose wet sheet structure and result in the higher drainage rate and the improved drying efficiency. In this study, the effects of the application of lignocellulose spacer to the liner board mill were evaluated based on the mill trial. In order to overcome the common disadvantage of the spacer, the loss of strength properties, the spacer was pretreated with amphoteric polyelectrolyte during mill trial. The results showed the application of pretreated spacer improved the drying efficiency by reducing steam consumption. And the loss in the strength properties by the spacer could be supplemented by the pretreatment.

Experimental Study on Reduction of Particulate Matter and Sulfur Dioxide Using Wet Electrostatic Precipitator (습식전기집진기를 활용한 입자상 물질 및 황산화물 저감 성능에 관한 실험적 연구)

  • Kim, Jong-Lib;Oh, Won-Chul;Lee, Won-Ju;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.6
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    • pp.898-904
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    • 2021
  • This experimental study aims to investigate the use of a wet electrostatic precipitator as a post-treatment device to satisfy the strict emission regulations for sulfur oxides and particulate matter (PM). The inlet/outlet of a wet electrostatic precipitator was installed in a funnel using a marine four-stroke diesel engine (STX-MAN B&W) consuming marine heavy fuel oil (HFO) with a sulfur content of about 2.1%. Measurements were then obtained at the outlet of the wet electrostatic precipitator; an optical measuring instrument (OPA-102), and the weight concentration measurement method (Method 5 Isokinetic Train) were used for the PM measurements and the Fourier transform infrared (FT-IR; DX-4000) approach was used for the sulfur oxide measurements. The experimenst were conducted by varying the engine load from 50%, to 75% and 100%; it was noted that the PM reduction efficiency was a high at about 94 to 98% under all load conditions. Additionally, during the process of lowering the exhaust gas temperature in the quenching zone of the wet electrostatic precipitator, the sulfur dioxide (SO2) values reduced because of the cleaning water, and the reduction rate was confirmed to be 55% to 81% depending on the engine load.

Vertically Standing Graphene on Glass Substrate by PECVD

  • Ma, Yifei;Hwang, Wontae;Jang, Haegyu;Chae, Heeyeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.232.2-232.2
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    • 2014
  • Since its discovery in 2004, graphene, a sp2-hybridized 2-Dimension carbon material, has drawn enormous attention. A variety of approaches have been attempted, such as epitaxial growth from silicon carbide, chemical reduction of graphene oxide and CVD. Among these approaches, the CVD process takes great attention due to its guarantee of high quality and large scale with high yield on various transition metals. After synthesis of graphene on metal substrate, the subsequent transfer process is needed to transfer graphene onto various target substrates, such as bubbling transfer, renewable epoxy transfer and wet etching transfer. However, those transfer processes are hard to control and inevitably induce defects to graphene film. Especially for wet etching transfer, the metal substrate is totally etched away, which is horrendous resources wasting, time consuming, and unsuitable for industry production. Thus, our group develops one-step process to directly grow graphene on glass substrate in plasma enhanced chemical vapor deposition (PECVD). Copper foil is used as catalyst to enhance the growth of graphene, as well as a temperature shield to provide relatively low temperature to glass substrate. The effect of growth time is reported that longer growth time will provide lower sheet resistance and higher VSG flakes. The VSG with conductivity of $800{\Omega}/sq$ and thickness of 270 nm grown on glass substrate can be obtained under 12 min growing time. The morphology is clearly showed by SEM image and Raman spectra that VSG film is composed of base layer of amorphous carbon and vertically arranged graphene flakes.

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NiAl/Y Coating Process for Corrosion Resistance of Wet-seal area in MCFC (MCFC용 wet-seal부의 내식성 향상을 위한 NiAl/Y 피복 공정에 관한 연구)

  • Choe, Jae-Ung;Gang, Seong-Gun;Song, Sang-Bin;Hwang, Eung-Rim
    • Korean Journal of Materials Research
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    • v.11 no.8
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    • pp.666-670
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    • 2001
  • To improve the corrosion resistance of separator wet-seal area which is the barrier of commercialization of molten carbonate fuel cell(MCFC), Ni/Y/Al coating layer was fabricated by Ni electroplating and Y, Al e-beam PVD on AISI 316L stainless steel. NiAlY alloy coating layer was formed by heat treatment in reduction atmosphere at $800^{\circ}C$ for 5hr. Immersion test in molten carbonate salt at $650^{\circ}C$ was performed on as- received AISI 316L stainless steel and NiAlY coated specimen. According to cross sectional SEM/EDS observations, corrosion resistance of separator wet-seal area was improved by formation of dense oxide layers of Al and Y.

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Study on the Measurement of Emission Spectrum and Reaction Mechanism of OH Radical in the Nitrogen Corona Discharge System for Removal of $NO_x$ in Flue Gas (배연가스의 $NO_x$제거용 코로나 방전장치에서 OH 발광 스펙트럼 측정 및 관련 반응 연구)

  • Park, Chul-Woung;Hahn, Jae-Won;Shin, Dong-Nam
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.27-38
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    • 1999
  • We constructed a wire-cylinder type pulsed corona discharge system for $NO_x$ removal, which was operated in room temperature. A emission spectrometer was built with a boxcar averager and monochrometer equipped with photo-multiplier tube detector. The sensitivity of the emission spectrometer was greatly improved by synchronizing the emission spectrometer with pulsed corona discharge system using a triggered spark-gap switch. $N_2$ spectrum($c^3{\Pi}_u{\rightarrow}X^1{\Sigma}_g{^+}$) was measured in the range of 300 - 450 nm and oxidizing OH radical emission($A^2{\Sigma}^+{\rightarrow}X^2{\Pi}$) was measured in case $N_2$ was supplied with water bubbling. As wet gas composition of inlet $N_2$ supplied in the discharge system increased, the intensity of OH emission was increased and saturated at wet gas composition 50%. We also investigated additive effect of $C_2H_4,\;H_2O,\;H_2O_2$ on the intensity of OR emission and $NO/NO_2/NO_x$ reduction and analysed the related reaction mechanism in corona discharge process. $H_2O_2$ additive increased the intensity of OH emission and $NO/NO_x$ reduction.

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Implementation of an Intelligent Video Detection System using Deep Learning in the Manufacturing Process of Tungsten Hexafluoride (딥러닝을 이용한 육불화텅스텐(WF6) 제조 공정의 지능형 영상 감지 시스템 구현)

  • Son, Seung-Yong;Kim, Young Mok;Choi, Doo-Hyun
    • Korean Journal of Materials Research
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    • v.31 no.12
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    • pp.719-726
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    • 2021
  • Through the process of chemical vapor deposition, Tungsten Hexafluoride (WF6) is widely used by the semiconductor industry to form tungsten films. Tungsten Hexafluoride (WF6) is produced through manufacturing processes such as pulverization, wet smelting, calcination and reduction of tungsten ores. The manufacturing process of Tungsten Hexafluoride (WF6) is required thorough quality control to improve productivity. In this paper, a real-time detection system for oxidation defects that occur in the manufacturing process of Tungsten Hexafluoride (WF6) is proposed. The proposed system is implemented by applying YOLOv5 based on Convolutional Neural Network (CNN); it is expected to enable more stable management than existing management, which relies on skilled workers. The implementation method of the proposed system and the results of performance comparison are presented to prove the feasibility of the method for improving the efficiency of the WF6 manufacturing process in this paper. The proposed system applying YOLOv5s, which is the most suitable material in the actual production environment, demonstrates high accuracy (mAP@0.5 99.4 %) and real-time detection speed (FPS 46).

Debiasing Technique for Numerical Weather Prediction using Artificial Neural Network

  • Kang, Boo-Sik;Ko, Ick-Hwan
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.51-56
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    • 2006
  • Biases embedded in numerical weather precipitation forecasts by the RDAPS model was determined, quantified and corrected. The ultimate objective is to eventually enhance the reliability of reservoir operation by Korean Water Resources Corporation (KOWACO), which is based on precipitation-driven forecasts of stream flow. Statistical post-processing, so called MOS (Model Output Statistics) was applied to RDAPS to improve their performance. The Artificial Neural Nwetwork (ANN) model was applied for 4 cases of 'Probability of Precipitation (PoP) for wet and dry season' and 'Quantitative Precipitation Forecasts (QPF) for wet and dry season'. The reduction on the large systematic bias was especially remarkable. The performance of both networks may be improved by retraining, probably every month. In addition, it is expected that performance of the networks will improve once atmospheric profile data are incorporated in the analysis. The key to the optimal performance of ANN is to have a large data set relevant to the predictand variable. The more complex the process to be modeled by the ANN, the larger the data set needs to be.

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