• Textile Coloration and Finishing
• /
• v.23 no.1
• /
• pp.51-59
• /
• 2011

Calcium alginate fiber were prepared by wet spinning of various conditions, including different concentrations of sodium alginate solution and $CaCl_2$ concentrations for coagulating the fiber through an absorption of calcium ion. The absorption of calcium ion during the coagulating step lead to solidify the fibers by the replacement of sodium ion with calcium ion to produce some crosslinking. The concentration of calcium ion in the calcium alginate fiber seems to be well related to the mechanical and physical property of the fiber, such as fiber strength moisture regain, and degree of swelling. The tensile strength of calcium alginate fiber was increased along with the increasing amount of sodium alginate solution. According to EDS analysis, 7 wt% $CaCl_2$ coagulation bath resulted in more calcium ion in the fiber compared to 3 wt% $CaCl_2$ coagulation bath. The decomposition temperature of calcium alginate fiber was $199^{\circ}C$, which $14^{\circ}C$ higher than that of sodium alginate.

• Textile Coloration and Finishing
• /
• v.15 no.3
• /
• pp.146-153
• /
• 2003

This article describes the metal ions adsorption of chitosan fibers. The chitosan fibers were manufactured by wet spinning using 2% acetic acid as solvent, 10% aqueous sodium hydroxide as non solvent, and 4%chitosan solution as a solvent. The adsorption characteristics of chitosan fibers towards 100ppm solutions of various metal ions such as Cu(II), Cd(II), Cr(III), Hg(II) were examined at different pH value by ICP-Atomic Emission Spectrometer. The adhesiveness of metallic ions to the chitosan fiber were increased with the increase of pH and the decrease of denier. On the other hand, from pH4, chitosan fiber that is immersed in metal ion aqueous solution of Cu(II) and Cd(II) became homogeneous solution because is dissolved. The adhesiveness of metallic ions to chitosan fiber were found to increased in a sequence of Hg(II)> Cr(III)> Cu(II)> Cd(II). The antimicrobial characteristics of the chitosan fiber by adhered metal ions, virgin chitosan fiber, and cotton fiber were evaluated. The antimicrobial activity of the fibers were increased with the decrease of denier.

• Composites Research
• /
• v.35 no.2
• /
• pp.115-119
• /
• 2022

The performance of carbon fiber is important for the production of these high-quality polymer composite materials such as CFRP (Carbon Fiber Reinforced Plastic). For this purpose, it is essential to use an optimized spinning process for improving the mechanical, physical, and structural properties of the precursor fiber, which greatly affects the properties of the carbon fiber, and the use of a suitable precursor polymer. In this study, the content of MAA (Methacrylic Acid), MAA injection time, and concentration of AIBN (2,2'-Azobis(2-methylpropionitrile)) were set as parameters for the polymer synthesis process, and Poly(AN-co-MAA) (poly(acrylonitrile-co-methacrylic acid)) was polymerized by solution polymerization. Poly(AN-co-MAA) with a molecular weight of 305,138 g/mol and an MAA ratio of 4.2% was dissolved in DMF (N,N-dimethylformamide) at a concentration of 16.0 wt%, and then a precursor fiber was prepared through dry-jet-wet spinning. The precursor fiber had a tensile strength of ~1.06 GPa and a tensile modulus of ~22.01 GPa, and no voids and structural defects were observed on the fiber.

• International Journal of Industrial Entomology and Biomaterials
• /
• v.20 no.2
• /
• pp.99-105
• /
• 2010

In this paper, the regenerated silk fibroins were dissolved in LiBr aqueous solution with different dissolution temperature and time, and the effects of the dissolution condition on the regeneration yield, molecular weight, wet spinnability, and electrospinnability of regenerated silk fibroin were investigated. The regeneration yield, molecular weight distribution, and wet spinnability of regenerated silk fibroin were nearly affected by the dissolution temperature and time. However, the electrospinning performance of silk fibroin was influenced by the dissolution condition implying the electrospinning of silk fibroin is more sensitive process than the wet spinning in the range tested in this study. While $25^{\circ}C$ of dissolution temperature resulted in a good electrospinnability of regenerated silk fibroin, the electrospinnability was slightly deteriorated when silk fibroin was dissolved at $60^{\circ}C$ for 6 hours. Also, though the fiber diameters of electrospun silk fibroin produced by the dissolution at $25^{\circ}C$ for 6 hours and 24 hours were 443 and 451 nm, respectively, that at $60^{\circ}C$ for 5 min was reduced to 411 nm. The fiber diameter was more decreased to 393 nm when the dissolution time increased up to 6 hours at $60^{\circ}C$.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.39 no.6
• /
• pp.877-884
• /
• 2015

Polytrimethylene Terephthalate (PTT) is an eco-fiber with good elastic properties; however, it requires more detailed studies related to spinnability according to blending of various kinds of fibers. The evolution of spinning technology was focused on improved productivity with good quality; in addition, air vortex spinning was recently invented and applied on the spinning factory as the facility with good productivity and quality. More detail spinning technology according to the blending of various kinds of fibers on the air vortex spinning system is required to obtain good quality yarns for high emotional fabrics. In this paper, the physical properties of air vortex, compact and ring staple yarns using PTT/wool/modal blend fibers were investigated with yarn structure to promote high functional PTT that includes fabrics for high emotional garments. Unevenness of air vortex yarns was higher than those of compact and ring yarns; in addition, imperfections were greater than those of compact and ring yarns, which was attributed to a fascinated vortex yarn structure. Tenacity and breaking strain of air vortex yarns were lower than those of compact and ring yarns, caused by higher unevenness and more imperfections of air vortex yarns compared to compact and ring yarns. Vortex yarns showed the highest initial modulus and ring yarns showed the lowest ones which results in a stiff tactile feeling of air vortex yarns in regards to the initial modulus of yarns. Dry and wet thermal shrinkages of air vortex yarns were lower than ring yarns. Good shape retention of vortex yarns was estimated due to low thermal shrinkage.

• Textile Coloration and Finishing
• /
• v.33 no.4
• /
• pp.302-308
• /
• 2021

Air filters are being used in countless places from industrial sites to everyday life. The spread of the COVID-19 virus, which started in 2019, is disrupting people's daily lives, and the importance of air filters as a basic means to prevent the spread of these diseases is further highlighted. In this study, the purpose was to develop another type of air filter media with excellent barrier properties that can replace PP meltblown nonwoven fabrics widely used commercially due to its excellent electrostatic properties, differential pressure and filtration efficiency. Therefore, wet-laid nonwoven for air filters were manufactured using plexi-filaments formed through flash spinning and having various fiber diameter from hundreds of nanometers to tens of micrometers, and its applicability as an air-filter media was investigated compared to the meltblown nonwoven. As a result of the performance evaluation, it was found that the filtration efficiency and barrier performance at 0.3㎛ was superior to that of the meltblown nonwoven of the same weight, although the differential pressure was high due to morphological properties of the plexi-filament.

• Carbon letters
• /
• v.12 no.1
• /
• pp.26-30
• /
• 2011

For polyacrylonitrile (PAN) based carbon fiber (CF) process, we developed a lab scale wet spinning line and a continuous tailor-made stabilization system with ten columns for controlling temperature profile. PAN precursor was spun with a different spinning rate. PAN spun fibers were stabilized with a total duration of 45 to 110 min at a given temperature profile. Furthermore, a stabilization temperature profile was varied with the last column temperature from 230 to $275^{\circ}C$. Stabilized fibers were carbonized in nitrogen atmosphere at $1200^{\circ}C$ in a furnace. Morphologies of spun and CFs were observed using optical and scanning electron microscopy, respectively. Tensile properties of resulting CFs were measured. The results revealed that process conditions such as spinning rate, stabilization time, and temperature profile affect microstructure and tensile properties of CFs significantly.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1995.10a
• /
• pp.5-9
• /
• 1995

In the dry-jet-wet-spinning process of a hollow fiber membrane, the polymer solution is pumped into a coaxial tube, jet spinneret. The threadline emerging from the spinneret is stabilized by an internal coagulating medium(liquid or gas) as it emerges from the jet orifice. The nascent hollow thread is further stabilized in a quench bath as shown in Fig. 1. In this scheme, three mechanism of formatiota(temperature gradient, solvent evaporation, and solvent-nonsotvent exchange) can be combined. The changes which promote stabilization often play a dominant role in determining the ultimate fiber wall structure as well. Hence, in pratice, hollow fiber stabilization and development of membrane structure are commonly inseparable. However, fiber dimension(the inside diameter and wall thickness of the hollow fiber) is mainly a rheological problem and is determined by dope pumping rate, spinneret diatance from the coagulation bath, inner coagulant flow rate, and fiber draw-rate. Besides rheological phenomena play a prominent part in the final properties of the hollow fiber.

• Composites Research
• /
• v.29 no.4
• /
• pp.145-150
• /
• 2016

Polyvinylidene fluoride (PVDF) as a representative polymer with the piezoelectric property has been studied since the 1960s. Crystalline structure of poly(vinylidene fluoride) polymer is composed of five different crystal structure of the polymer as a semi-crystalline. Among the various crystal structures, ${\beta}-type$ crystal exhibits a piezoelectricity because the permanent dipoles are aligned in one direction. Generally ${\beta}-form$ crystal structure can be obtained through the transformation of the ${\alpha}-form$ crystal structure by the stretching and it can increase the amount through the after treatment as poling process after stretching. ${\beta}-form$ crystal structure the PVDF fibers produced by wet spinning is formed through a diffusion mechanism of a polar solvent in the coagulation bath. However, it has a disadvantage that the diffusion path of the solvent remains as pores in the fiber because the fiber solidification occurs simultaneously with the diffusion of the polar solvent. These pores play a role in reducing effect of poling process owing to effect of disturbances acting on the polarization by the electric field. In this work, the drying method using the microwave was introduced to remove more effectively the residual solvent and the pore within PVDF fibers produced through wet-spinning process and piezoelectric PVDF fibers was produced by transformation of the remaining ${\alpha}$ form crystal structure into ${\beta}-crystal$ structure through the stretching process.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.43 no.4
• /
• pp.281-290
• /
• 2007

This study was aimed not only to develop the gill net and trap made of biodegradable monofilaments in order to prevent a ghost fishing and to protect marine ecosystem, but also to analyze their spinning process and physical properties. Results showed that the spinning speed of biodegradable polybutylene succinate(PBS) monofilament was estimated to be approximately 100m/min when spinning temperature and cooling water temperature were adjusted at $180^{\circ}C$ and $3^{\circ}C$, respectively. The breaking loads of PBS monofilaments were estimated to be $35.3kg/mm^2$ at ${\phi}0.2mm$, $46.5kg/mm^2$ at ${\phi}0.3mm$, and $49.7kg/mm^2$ at ${\phi}0.4mm$ in the dry condition, respectively. However, its breaking loads in the wet condition were reduced by 2.4-5.5%, compared to those in the dry condition. The knotted strength of PBS monofilament at ${\phi}0.2mm$ was estimated to be 98.6% of PE in the dry condition. The breaking load of PBS monofilament at ${\phi}0.3mm$ was evaluated to be 81.8% of PA, and its softness showed 3 times less than that of PA in the wet condition. The breaking load of PBS monofilament at ${\phi}0.4mm$ was 95.3% of PA, and its softness showed 1.6 times less than that of PA in the wet state. However, the load elastic elongations of two kinds of monofilaments were estimated to be 1% higher than that of PA.