• 제목/요약/키워드: Wet chemical analysis

검색결과 186건 처리시간 0.023초

재생골재 콘크리트의 화학안정성에 관한 실험적 연구 (An Experimental Study on the Chemical Soundness of Recycled Aggregate Concrete)

  • 김무한;김규용;박선규;이정율
    • 콘크리트학회논문집
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    • 제11권4호
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    • pp.13-20
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    • 1999
  • Recently, the study for practical construction application no recycled aggregate concrete is actively being proceeded, on the purpose of technical development for recycling on the construction waste concrete occurred at the time of destruction of building construction by the rapid increase of building wastes and exhaustion of natural aggregates. But, the durability of investigation with all sorts of fluidity and engineering property for application recycled aggregate concrete to practical construction must be done at the same time. Especially, because of the real condition for chemical attack of concrete construction by the acid rain, acidification of soil, deepening of air pollution and dirty water etc. being come to the fore a serious problem, the study on the chemical soundness of concrete durability must be accompanied. This study is composed as: I series: Analysis for chemical soundness of aggregates. II series: Analysis for chemical soundness of natural and recycled aggregate concrete against $Na_2$$SO_4$ solution in drying and wet curing condition ($at20~80^{\circ}C$).

$Al_2O_3-TiO_2$계 Nanocomposite 분체의 합성에 관한 연구 (A Study on the Preparation of $Al_2O_3-TiO_2$ Nanocomposite Powders)

  • 이홍림;이호순
    • 한국세라믹학회지
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    • 제30권2호
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    • pp.115-122
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    • 1993
  • Transparent Al2O3 and TiO2 clear sols prepared by hydrolysis and subsequent peptization were mixed into wet gel. EDS analysis for this gel showed that wet gel was extremely homogeneous in chemical composition. Calcination of the wet gel at 120$0^{\circ}C$ for 50 minutes resulted in Al2O3-TiO2 nanocomposite powders where TiO2 particles of 101~102 nanometer were dispersed in the Al2O3 matrix. Both powders were sintered for 4 hours in the temperature range over 1500~1$650^{\circ}C$ with and without 5wt% MgO sintering aid. Among these sintered bodies, nanocomposite powder compacts sintered at 1$650^{\circ}C$ for 4 hours with 5wt% MgO showed the most dense structure with the grain size under 5${\mu}{\textrm}{m}$ and highest relative density of 98.2%.

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자동차용 폐 삼원촉매로부터의 희귀금속 회수공정 기술 동향 (Recovery of Rare Earth Metal from Used Automotive Three-Way Catalyst)

  • 홍연기
    • 융복합기술연구소 논문집
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    • 제1권1호
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    • pp.13-17
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    • 2011
  • The car industry is one of the technological applications which more rare earth metals employes as three-way catalysts. Therefore, the recovery of rare earth metals from the used automotive three-way catalysts could be important source to obtain these metals. This work presents the analysis of market and demand for rare earth metal in automotive three-way catalyst and introduces the dry and the wet processes for the recovery of rare earth metals from used three-way catalyst. Finally, the alternative methods to conventional wet processes was simply suggested based on the economic and ecological point of view.

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Pore Distribution of Porous Silicon layer by Anodization Process

  • Lee, Ki-Yong;Chung, Won-Yong;Kim, Do-Hyun
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.494-496
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    • 1996
  • The purpose of this study is to investigate the effect of process conditions on pore distribution in porous silicon layer prepared by electrochemical reaction. Porous silicon layers formed on p-type silicon wafer show the network structure of fine porse whose diameters are less than 100${\AA}$. In n-type porous silicon, selective growth was found on the pore surface by wet etching process after PR patterning. And numerical method showed high current density on the pore tip. With this result we confirmed that pore formation has two steps. First step is the initial attack on the surface and second step is the directional growth on the pore tip.

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물리화학적 처리에 의한 일라이트 점토광물의 입도조절 및 분산특성 (Size Control and Dispersion Properties of Illite Clay by Physicochemical Treatment)

  • 임재원;정의경;서경원;이영석
    • 공업화학
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    • 제22권2호
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    • pp.133-137
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    • 2011
  • 본 연구에서는 다양한 용도로 사용되는 일라이트의 분산성 및 분산안정성을 향상시키고자, 습식 볼밀 분쇄법을 이용하여 일라이트의 입도를 저감하였다. 분쇄 시간에 따른 일라이트의 입도와 입도분포 및 분산특성의 변화를 고찰하였으며, 또한 여러 가지 pH조건에서 두 시간 동안 습식 볼밀 분쇄 처리하여 얻은 일라이트 분산용액의 분산성 및 분산안정성을 평가하였다. 일라이트의 입도분석 결과 분쇄시간의 증가에 따라 입자의 크기가 현저히 감소하였으며, 2 h의 분쇄시간을 기점으로 입도저감의 효과가 저하됨을 확인하였다. 또한, 입도분포분석 결과 분쇄시간의 증가에 따라 입자가 균일해지는 것을 확인하였다. X-선 회절분석 결과 분쇄에 의한 결정구조의 변화는 나타나지 않았으나 입도저감 또는 박리현상으로 인하여 특성 피크의 강도가 입도저감 시간의 증가에 따라 약해지는 것을 확인하였다. Zeta potential 분석 결과, 분쇄시간이 증가함에 따라서 분산성이 높아지는 것을 확인하였다. 분산 안정성 측정 결과 pH 2에서 분쇄처리한 일라이트의 분산안정성이 가장 낮았고 pH가 증가함에 따라서 표면 이온화도의 증가로 분산성 및 분산안정성이 향상되는 것을 확인하였다. 이러한 결과로부터 일라이트는 습식 볼밀 분쇄처리 시간을 증가시킬수록 입자 크기가 감소하고 표면 에너지 증가 및 입자간의 반발력 상승으로 분산성 및 분산안정성이 향상되는 것을 확인할 수 있었다.

다양한 시험생물종을 이용한 산업폐수 생태독성 평가 및 원인물질 탐색 (Ecotoxicity Test of Wastewater by a Battery of Bioassay and Toxicity Identification Evaluation)

  • 류태권;조재구;김경태;양창용;정기은;윤준헌;최경희
    • Environmental Analysis Health and Toxicology
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    • 제25권3호
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    • pp.207-214
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    • 2010
  • Toxicity identification and quantification are important factors to evaluate the effect of industrial effluent on the aquatic environment. In order to measure the potential and real toxicity of mixed chemicals in the effluents, the biological method (i.e., WET test) should be used as well as chemical analysis method. In this study, we conducted WET test for various kinds of industrial effluents using aquatic organisms such as water flea (Daphnia magna), algae (Pseudokirchneriella subcapitata), fish (Oryzias latipes, Danio rerio), and microorganism (Vibrio fisheri). In addition, we carried out chemical analysis and TIE (Toxicity Identification Evaluation) for effluents in order to identify the substances causing toxicity. Among the 30 kinds of wastewater, S13 showed the highest eco-toxicity and $Ca^{2+}$ and $Cl^-$ ion were suspected as major compounds causing toxicity for aquatic organisms. In order to confirm these suspected compounds, various confirmation procedures need to be carried out.

CFD모사 기법을 이용한 관내 혼화장치내 흐름 특성 평가 (Evaluation of Flow Characteristics within In-Line Mixer for Water Treatment using CFD Technique)

  • 박대진;박영오;박노석;김성수;왕창근
    • 상하수도학회지
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    • 제22권3호
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    • pp.351-358
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    • 2008
  • The modified in-line mixer which was suggested in this study for small water treatment facilities was evaluated on the performance of coagulation. For the objectives of this research, computational fluid dynamics(CFD) simulation was applied for analysis of flow characteristics within the modified in-line mixer. For verifying the results of CFD simulation, wet tests for the pilot plant were conducted. The wet test was to measure the actual coagulant dispersion distribution on the overall cross-section at a distance of 5.5D from the chemical injection point. From the results of CFD simulation and wet test, it was shown that the coagulant dispersion within the modified in-line mixer was occurred more uniformly than within the existing PDM(Pump diffusion Mixer). The results have confirmed the modified in-line mixer had several advantages compared with the existing PDM in terms of dispersion efficiency.

Calcium Phosphate Bone Cement Based on Wet Prepared Dicalcium Phosphate

  • Chang, Myung Chul
    • 한국세라믹학회지
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    • 제55권5호
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    • pp.480-491
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    • 2018
  • Calcium phosphates (CaP) were prepared by a wet chemical method. Micro-crystalline dicalcium phosphate (DCPD) was precipitated at $37^{\circ}C$ and pH 5.0 using $Ca(OH)_2$ and $H_3PO_4$. The precipitated DCPD solution was kept at $37^{\circ}C$ for 96 h. Artificial bone cement was composed of DCPD, $Ca(H_2PO_4)_2{\cdot}H_2O$ (MCPM), and $CaSO_4{\cdot}1/2H_2O$, $H_2O$ and aqueous poly-phosphoric acid solution. The wet prepared CaP powder was used as a matrix for the bone cement recipe. With the addition of aqueous poly-phosphoric acid, the cement hardening reaction was started and the CaP bone cement blocks were fabricated for the mechanical strength measurement. For the tested blocks, the mechanical strength was measured using a universal testing machine, and the microstructure phase analysis was done by field emission scanning electron microscopy and X-ray diffraction. The cement hardening reaction occurred through the decomposition and recrystallization of MCPM and $CaSO_4{\cdot}1/2H_2O$ added on the surface of the wet prepared CaP, and this resulted in grain growth in the bone cement block.

1994~1997년 중부지방에 내린 강수의 화학적 특성에 관한 연구 (A Study on Chemical Characterization of Precipitation in the Central Part of Korea from 1994 to 1997)

  • 조하만;최재천
    • 한국대기환경학회지
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    • 제14권6호
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    • pp.589-598
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    • 1998
  • This study was conducted to investigate the chemical characteristics of Precipitation at Seoul, Yangpyong, Hongchon and Inje in the central part of Korean peninsula during the period from March 1994 to November 1997. The precipitation samples were collected by automatic wet-only sampler. The samples were analyzed for major anions (SO42-, NO3-, Cl-, F-) and cations(NH4+, Ca2+, Mg+, Na+, K+), in addition to acidity and electrical conductivity. The analytical instrument for water soluble ionic components was ion chromatography. The volume - weighted mean PH were 4.73, 4.87, 4.89 and 4.81 at Seoul, Yangpyong, Hongchon and Inje, respectively. The sums of cation concentrations was slightly greater than the sums of anion concentrations. Also, the highest ion component was SO42- in anions and NH4+ in cations. The mean equivalent ratios of SO42- to NO3- were found by 2.96, 2.71, 2.43 and 2.25 at Seoul, Yangpyong, Hongchon and Inje, respectively. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables. It showed that major sources of pollutants in precipitation were from the anthropogenic in Seoul, the natural in Hongchon, and the anthropogenic and natural in Yangpyong and Inje.

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홍성 북동부 농촌 지역 지하수의 질산성 질소 오염과 수리지구화학적 특성 (Characterization of Nitrate Contamination and Hydrogeochemistry of Groundwater in an Agricultural Area of Northeastern Hongseong)

  • 기민규;고동찬;윤희성;김현수
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권3호
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    • pp.33-51
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    • 2013
  • Spatial and temporal characteristics of nitrate contamination and hydrogeochemical parameters were investigated for springs and surficial and bedrock groundwaters in northeastern part of Hongseong. Two field investigations were conducted at dry and wet seasons in 2011 for 120 sites including measurement of field parameters with chemical analyses of major dissolved constituents. Nitrate concentrations were at background levels in springs while 45% of bedrock groundwater and 49% of surficial groundwater exceeded the drinking water standard of nitrate (10 mg/L as $NO_3$-N). The difference in nitrate concentrations between surficial and bedrock groundwater was statistically insignificant. Cumulative frequency distribution of nitrate concentrations revealed two inflection points of 2 and 16 mg/L as $NO_3$-N. Correlation analysis of hydrogeochemical parameters showed that nitrate had higher correlations with Sr, Mg, Cl, Na, and Ca, in surficial groundwater in both dry and wet season. In contrast, nitrate had much weaker correlations with other hydrogeochemical parameters in bedrock groundwater compared to surficial groundwater and had significant correlations only in wet season. Temporally, nitrate and chloride concentrations decreased and dissolved oxygen (DO) increased from dry season to wet season, which indicates that increased recharge during the wet season affected groundwater quality. Aerobic conditions were predominant for both surficial and bedrock groundwater indicating low natural attenuation potential of nitrate in the aquifers of the study area.