• Title/Summary/Keyword: Wet chemical analysis

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Characteristic Study for Methyl-mercaptain Removal by an Essential Oil (식물추출물을 이용한 메틸멀캡탄 제거 특성 연구)

  • Park, Young-Gyu
    • KSBB Journal
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    • v.22 no.3
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    • pp.151-156
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    • 2007
  • Increasing public concerns over odors and air regulations necessitates the remediation of a wide range of odorous compounds for industrial purpose. Currently, wet scrubbing technique by neutralization using essential oils is utilized to treat methyl mercaptan odor. The chemical analysis is performed to analyze the composition of an essential oil by GC-MS. The objective of this study is to clarify the possibility of the neutralization of odors sprayed in the fixed bed and determine the removal efficiencies in the misty aerosol by different input odor concentration. It is found that methyl mercaptan is significantly removed in the wet scrubber, and their removal efficiency of methyl mercaptan is obtained by 98%.

A Study on Thermal Oxidation of 3C-SiC Thin-films Grown on Si(100) Wafer (Si(100) 기판 위에 성장된 3C-SiC 박막의 열산화에 관한 연구)

  • Chung, Yun-Sik;Ryu, Ji-Goo;Chung, Su-Young;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.407-410
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    • 2002
  • Thermal oxidations of 3C-SiC thin-films grown on Si(100) by APCVD(atmospheric pressure chemical vapor deposition) were carried out. The oxidations of 3C-SiC were performed at $1100^{\circ}C$ for 1~6 hr in wet and dry $O_2$ ambient, respectively. Ellipsometry was used to determine the thickness and index of refraction of oxide films. The oxide thickness vs. the oxidation time follows the general relationship used for the thermal oxidation of Si. The surface roughness was analyzed by using AFM(atomic force microscopy). The surface roughness of oxidized 3C-SiC was rougher than before oxidation. The thermal oxide was found to be $SiO_2$ by XPS(X-ray photoelectron spectroscopy) analysis. Auger analysis showed them to be homogeneous with near stoichiometric composition.

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Development of a 1 MHz Megasonic for a Bare Wafer Cleaning (Bare Wafer 세정용 1 MHz 급 메가소닉 개발)

  • Hyunse Kim;Euisu Lim
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.2
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    • pp.17-23
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    • 2023
  • In semiconductor manufacturing processes, a cleaning process is important that can remove sub-micron particles. Conventional wet cleaning methods using chemical have limits in removing nano-particles. Thus, physical forces of a mechanical vibration up to 1 MHz frequency, was tried to aid in detaching them from the substrates. In this article, we developed a 1 MHz quartz megasonic for a bare wafer cleaning using finite element analysis. At first, a 1 MHz megasonic prototype was manufactured. Using the results, a main product which can improve a particle removal performance, was analyzed and designed. The maximum impedance frequency was 992 kHz, which agreed well with the experimental value of 986 kHz (0.6% error). Acoustic pressure distributions were measured, and the result showed that maximum / average was 400.0~432.4%, and standard deviation / average was 46.4~47.3%. Finally, submicron particles were deposited and cleaned for the assessment of the system performance. As a result, the particle removal efficiency (PRE) was proved to be 92% with 11 W power. Reflecting these results, the developed product might be used in the semiconductor cleaning process.

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Fabrication and Characterization of an Antistiction Layer by PECVD (plasma enhanced chemical vapor deposition) for Metal Stamps (PECVD를 이용한 금속 스탬프용 점착방지막 형성과 특성 평가)

  • Cha, Nam-Goo;Park, Chang-Hwa;Cho, Min-Soo;Kim, Kyu-Chae;Park, Jin-Goo;Jeong, Jun-Ho;Lee, Eung-Sug
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.225-230
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    • 2006
  • Nanoimprint lithography (NIL) is a novel method of fabricating nanometer scale patterns. It is a simple process with low cost, high throughput and resolution. NIL creates patterns by mechanical deformation of an imprint resist and physical contact process. The imprint resist is typically a monomer or polymer formulation that is cured by heat or UV light during the imprinting process. Stiction between the resist and the stamp is resulted from this physical contact process. Stiction issue is more important in the stamps including narrow pattern size and wide area. Therefore, the antistiction layer coating is very effective to prevent this problem and ensure successful NIL. In this paper, an antistiction layer was deposited and characterized by PECVD (plasma enhanced chemical vapor deposition) method for metal stamps. Deposition rates of an antistiction layer on Si and Ni substrates were in proportion to deposited time and 3.4 nm/min and 2.5 nm/min, respectively. A 50 nm thick antistiction layer showed 90% relative transmittance at 365 nm wavelength. Contact angle result showed good hydrophobicity over 105 degree. $CF_2$ and $CF_3$ peaks were founded in ATR-FTIR analysis. The thicknesses and the contact angle of a 50 nm thick antistiction film were slightly changed during chemical resistance test using acetone and sulfuric acid. To evaluate the deposited antistiction layer, a 50 nm thick film was coated on a stainless steel stamp made by wet etching process. A PMMA substrate was successfully imprinting without pattern degradations by the stainless steel stamp with an antistiction layer. The test result shows that antistiction layer coating is very effective for NIL.

A Study on Technology Transfer of Bokto Seeding Method for Crop Production - Based on Theory of Asian and Pacific Center for Transfer of Technology(APCTT) - (복토직파재배기술의 수용과 기술 확산에 관한 연구 - 아시아태평양기술이전센터(APCTT) 이론을 중심으로 -)

  • Ahn, D.H.;Park, K.H.;Kang, Y.K.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.10 no.1
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    • pp.29-41
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    • 2008
  • This research was conducted to develop a technology transfer and farmer's extension of newly released technology of Bokto seeding method for crop and vegetable production based on the theory of Asian and Pacific Center for Transfer of Technology(APCTT). This technology has recently transferred to not only Korea but also other countries like North Korea, China, Japan, Taiwan, Russia and Africa(Cameroon, Sudan and South Africa) since 2005. It has known as a highly reduction of production cost in terms of labors, chemical fertilizer and pesticides as well as environmental friendly due to a deep and side banded placement of chemical fertilizer at basal application. In addition this technology was proven to a precision farming on sowing depth and mechanism of chemical application method and also highly resistant against disasters like typhoon, flooding, low temperature, drought and lodging due to silicate application. It has improved a constraints such as a poor seedling establishment, weed occurrence, lodging, low yield and poor grain and eating quality in the previous direct seeding methods but still have a problem in occurrence of weedy rice and ununiformed operation of wet or flooded soil condition. Also this technology has a limit in marketing and A/S system. Based on a theory of APCTT evaluation and analysis this technology may be more concentrated on establishment of a special cooperation team among researcher and scientists, extension workers, industry sections and governmental sectors in order to rapidly transfer this technology to farmer's field. Also there will be needed to operate a web site for this newly released technology to inform and exchange an idea, experiences and newly improved information. A feed back system might be operated in this technology as well to improve a technology under way on users' operation. Also user's manual will be internationally released and provided for farmer's instruction and training at field site.

Interpretation of Analytical Data of Ion Components in Precipitation, Seoul (서울 地域 降水中 이온成分 分析資料의 解析)

  • 강공언;이주희;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.3
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    • pp.323-332
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    • 1996
  • Precipitation samples were collected by the wet-only sampling method at Seoul from September 1993 to June 1995. Sample were analysed for the anions $(NO_3^-, NO_2^-, SO_4^{2-}, Cl^-, and F^-)$ and cations $(Na^+, K^+, Ca^{2+}, Mg^{2+}, and NH_4^+)$ in addition to pH and electric conductivity. In order to establish the chemical analysis data of high quality, the assurance checks for analytical data of precipitation were performed by considering the ion balance and by comparing the measured conductivity with the calculated conductivity. As we applied the various assurance checking methods by the ion balance used until recently to a data set measured in this study, the f value expressed as $\Sigma C/\Sigma A$ was found to be not appropriate for the data screening. Also, the scattering plot between cations and anions in each sample was found to show the general tendency of ion balance but was proved to not quantitate the standard of data screening at a data set of samples of various concentration levels. The h value defined as (A-C)/C for C $\geq$ A and (A-C)/A for C < A was used to check the ion balance. However, the standard of data screening by h value must very in response to total ion concentration of samples. In this study, the quality assurance of chemical analysis data was checked by considering both the ion balance of evaluating by h value and the conductivity balance. Further the quality control was achieved by these quality assurance methods. As the result, 67 samples among total 77 were obtained as valid. As the central tendency value for a statistical summary in the analytical parametr of samples, the volume-weighted mean value was found to represent more the general chemistry of precipitation rather than the arithmetic mean. The volume-weighted mean pH was 5.0 and 25% of samples was less than this mean. The concentrations of sufate and nitrate in precipitation were 90.4 ueq/L and 32.4 ueq/L which made up 59% and 21% of all anions. The raion of $SO_4^{2-}/(NO_3^- + NO_2^-)$ in precipitation was 2.7, which indicates that the contributions of $H_2SO_4$ and $HNO_3$ to the acidity of precipitation are 70% and 30%, respectively.

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X-Ray Fluorescence Analysis of Iron and Titanium in Iron Ores by Dilution Parameter Method (희석 파라미터법에 의한 철광석 중 철과 티탄의 X-선 형광분석)

  • Young Sang Kim;Lee Chong Wook
    • Journal of the Korean Chemical Society
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    • v.25 no.3
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    • pp.183-189
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    • 1981
  • Iron and titanium, the major constituents in iron ores, were X-ray spectrometrically determined by using the dilution parameter method. A standard and samples possessing a similar composition were diluted with the diluent $ZrO_2$ to their proper respective ratios. After measuring the intensity of the fluorescent X-ray, the dilution parameter was calculated from the following equation. $Pa=\frac{\frac{I_{as}}{(I_{as})_d}}{D-1}{^{-1}}$The dilution parameters were used to correct the difference between the matrix effect of the standard and that of the sample. The content of the major constituents was calculated, without using any standard calibration curves, from the following equation;$W_a=W_a^*{\cdot}{\frac{I_as}{I_{as}^*}{\cdot}\frac{P_a^*}{P_a}$where asterisks indicate the standard. The results agreed with those of the wet analysis within 2% of relative error, and the precision of the experiment was also tolerably good.

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Anti-ulcerogenic activity of virgin coconut oil contribute to the stomach health of humankind

  • Selverajah, Malarvili;Zakaria, Zainul Amiruddin;Long, Kamariah;Ahmad, Zuraini;Yaacob, Azhar;Somchit, Muhammad Nazrul
    • CELLMED
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    • v.6 no.2
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    • pp.11.1-11.7
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    • 2016
  • The aimed of the presence study was to determine the antiulcer potential of virgin coconut oil (VCO), either extracted by wet process (VCOA) or fermentation process (VCOB), and to compare their effectiveness against the copra oil (CO) using the HCl/ethanol-induced gastric ulcer model. Earlier, the oils underwent chemical analysis to determine the free fatty acids composition, physicochemical properties and anti-oxidant capability. In the antiulcer study, rats (n=6) were pre-treated orally for 7 consecutive days with distilled water (vehicle), 100 mg/kg ranitidine (positive group) or the respective oils (10, 50, and 100% concentration). One hour after the last test solutions administration on Day 7th, the animals were subjected to the gastric ulcer assay. Macroscopic and microscopic analyses were performed on the collected rat's stomachs. From the results obtained, the chemical analysis revealed i) the presence of high content of lauric acid followed by myristic acid and palmitic acid in all oils and; ii) the significant (*p< 0.05) different in anisidine- and peroxide-value, percentage of free fatty acid, total phenolic content and total antioxidant activity among the oils. The animal study demonstrated that all oil possess significant (*p< 0.05) antiulcer activity with VCOB being the most effective oil followed by VCOA and CO. The macroscopic observations were supported by the microscopic findings. Interestingly, all oils were more effective than 100 mg/kg ranitidine (reference drug). In conclusion, coconut oils exert remarkable antiulcer activity depending on their methods of extraction, possibly via the modulation of its antioxidant and anti-inflammatory activity.

Geochemical and Geophysical Characteristics of Shallow Gases in the Deep Sea Sediments, Southwestern Ulleung Basin (울릉분지 남서부 심해저 퇴적층에 분포하는 천부 가스의 지화학 및 지구물리 특성)

  • 김일수;이영주;유동근;류병재
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.149-157
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    • 2003
  • Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.

A Study on the Properties of Mortar using Wet-type Waste Sludge according to Heating Temperature (가열온도별 습식방식 폐슬러지를 활용한 모르타르의 특성에 관한 연구)

  • Kang, Suk-Pyo;Cho, Ku-Young;Lee, Jun;Kim, Chang-Oh
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.111-119
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    • 2011
  • Recently, urban redevelopment programs and expansion of social infrastructure have caused massive amounts of construction waste in construction fields, and the mounds of it keep increasing every year. The disposal of construction waste is emerging as a national and social issue and the recycled powder generated by the treatment process of waste concrete is all being abolished or buried. Therefore, the purpose of this study is to utilize waste sludge generated by the wet-type treatment process of waste concrete as materials(binder, filler) for cement composite. This study evaluates physical and mechanical properties of mortar using recycled powder according to heating temperature, contents and applications. As a result of the chemical analysis, recycled powder is composed mainly of CaO and $SiO_2$, and that it is even lower in the content of CaO than OPC. The charateristics of mortar using recycled powder, according to drying and heating temperature, shows that as the heating temperature increases, flow decreases. Also, compressive strength and porosity of mortar using recycled powder was superior when heating temperature was $600^{\circ}C$. Thus, it is revealed that an effective development of recycled powder is possible since the binder by cement composite recovers a hydraulic property during heating at $600^{\circ}C$.

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