• Journal of the Korean Chemical Society
• /
• v.47 no.3
• /
• pp.220-228
• /
• 2003

This study was to examine the thermodynamic features of polyelecrolytic adsorption of polyamidoamine-epichlorohydrin(PAE) in a papermaking wet-end. The PAE adsorption experiments were conducted in a stirred jar containing an aqueous fibrous suspension and evaluated in terms of Langmuir and Freundlich parameters. The electrokinetic property of a stock was examined by measuring the zeta potential of each colloidal suspension. The polyelectrolytic PCD titration was employed to determine the adsorbed amounts of PAE polymer. The zeta potential of a stock, being varied significantly depending upon the addition of PAE polymer, showed initially a sharp increase and later an exponential decay as a function of time . The PAE adsorption exhibited a pseudo-Langmuir adsorption behavior at$20^{\circ}C$ , whereas its Freundlich power(v) increased in a proportional way at an elevated temperature. The train numbers calculated on the basis of adsorption thermodynamics were 7 to 8. The length of the extended loop of PAE was calculated as 215 nm at $20^{\circ}C$ and increased at a rate of 9% at every $10^{\circ}C$ rise in temperature. The PAE adsorption was proven to be an exothermic physisorption with the estimated adsorption enthalpy of -27 to -29 kJ/mol.

• Journal of Korean Society of Environmental Engineers
• /
• v.37 no.12
• /
• pp.705-711
• /
• 2015

Degradation of 2,6-Dichlorophenol (DCP) using liquid ferrate(VI) synthesized by wet oxidation method has been studied. Several parameters such as pH (acid, base and neutral), DCP initial concentration, ferrate dosage, and temperature have been examined to determine the optimal experimental conditions. The ferrate(VI) has useful properties such as strong oxidizing power and selectivity and generates a non-toxic end product, Fe(III). Ferrate ion reduced rapidly to Fe(III) and oxygen in acidic and neutral conditions. The experimental results showed the higher DCP degradation efficiency in the neutral condition than in the acidic and basic conditions. The oxidation of DCP strongly depended on the dosage of ferrate added to the reactor and DCP initial concentration. With increasing of ferrate dosage the degradation efficiency of DCP increased, while the degradation efficiency of DCP decreased with increasing of DCP initial concentration. The effect of temperature has been tested at 4 different levels (10, 25, 35, and $50^{\circ}C$). The optimal temperature was obtained in $25^{\circ}C$ and degradation efficiency decreased as the temperature increased in the range from $25^{\circ}C$ to $50^{\circ}C$. The DCP degradation pathways were studied and proposed based on the intermediate products identified by GC/MS analysis.

• Journal of Environmental Impact Assessment
• /
• v.25 no.4
• /
• pp.248-260
• /
• 2016

This study was aimed to assess the effect of diverse pollutants control measures suggested in the Chuso basin and its upstream of So-oak stream watershed where are the most concerned areas on the control of algal bloom occurring in Daecheong Reservoir. The control measures were classified as watershed measures and in-reservoir measures, and their effects were simulated using a two-dimensional hydrodynamic and water quality model. The watershed measures were made up of 1) point sources control, non-point sources control, and their combinations. The in-reservoir measures were supposed to treat sediment at Chuso basin and to install a phosphorus elimination plant (PEP) at the end of So-oak stream. The results showed that the effect of each measure was influenced by the hydrological condition of the year. In wet year, as the contribution of non-point sources increased, the non-point source control measures (NPS1~NPS4) showed more effective compared to other measures, while, the PEP system to eliminate phosphorus from So-oak stream showed better performance in dry year. In particular, the scenario of NPS1, in which all livestock manures were collected and treated but only chemical fertilizers (NPS1) were used for agriculture fields, showed the best performance for the control of algal bloom in Chuso basin among the watershed measures.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2001.04a
• /
• pp.80-80
• /
• 2001

제지 공정의 효율적인 운영을 위한 수단으로 보류 및 탈수성의 분석은 매우 중요한 작 업 이 다. 보류 및 탈수 특성 을 평 가하기 위 하여 SR(Shopper-Riegler), CSF(Canadian S Standard Freeness tester) 그리고 원형 수초지기 등의 비난류 상태의 자연탈수 특성 평가 장치와 동적 조건의 감압식 탈수성 분석기 등이 사용되고 있다. 하지만 이것들은 제지 공정 에 보다 더 근접한 탈수 및 보류 특성을 평가하기에는 부족한 점이 있다. 특히 wet-end 첨 가제들의 효능을 보다 정확히 분석하는 것이 불가능하다. 이런 이유로 난류 발생과 감압 탈 수 둥을 유도한 탈수 특성 평가 장치 개발의 필요성이 커지고 있다. R RDA - HSF(Retention Drainage Analyzer- Handsheet Former)는 지료조성, 감압탈수 및 습지의 성형이 자동화되어 보류도와 탈수성, 종이지합 및 강도를 종합 평가 할 수 있는 새 로운 실험실용 초지기이다. 보다 현장에 가까운 초지 조건을 구현하기 위해서 지료의 농도 를 높이고 진공 탈수를 실시함에 따라 기존의 탈수성 분석기나 보류도 측정기의 단점을 보 완하게 되 었다. 본 연 구에 서 는 Canadian Standard Freeness test와 Dynamic Drainage Jar test 및 원 형 수초지기를 활용한 기존의 탈수성, 보류도 분석 결과와 RDA-HSF를 비교하여, 자연 탈수를 이용하는 기존의 탈수 및 보류 설비에 비해 현장 공정을 보다 현실적으로 재현할 수 있는 감압 탈수 초지 설비로서 RDA-HSF의 활용 가능성을 분석하였다. RDA-HSF를 활용한 실험실적 분석을 통해 현장의 상황올 유사하게 재현함에 따라 공정 운영 인자의 변화에 따른 제품의 품질 및 생산효율을 예측할 수 있게 된 바, 보다 효율적 인 공정 관리가 가능할 것으로 기대된다. 안료 입자의 경우 피인쇄체의 표면 공극을 채우고, 비히클의 경우 미세한 공극속으로 침투되어 경화됨으로써 피인쇄체가 지니고 있는 공극량을 감소시커 게 될 것이다. 그리고 피인쇄체의 각종 형태의 공극으로 침투된 잉크의 양에 반비례적으로 피인쇄체의 표변에 잉크가 잔류하게 될 것이다. 따라서 본 연구에서는 여러가지 안료를 사용하여 각각 다른 공극 특성을 지니는 도공지를 제조한 후 이들이 가지는 공극 특성과 잉크의 잔류 거동에 대해 고찰해 보고자 하였다.여 표면 유효층 일부만 오버레이시키며I 주조 및 단조가 불가능한 재료까지도 표면부에 오버레이 시킴으로 서 부품 및 설비의 제조에 있어 재료비의 절감과 제품의 수명이 획기적으로 개선될 수 있다. 그리고 최근에는 도금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다. within minimum time from beginning of the shutdown.및 12.36%, $101{\sim}200$일의 경우 12.78% 및 12.44%, 201일 이상의 경우 13.17% 및 11.30%로 201일 이상의 유기의 경우에만 대조구와 삭제 구간에 유의적인(p<0.05) 차이를 나타내었다.는 담수(淡水)에서 10%o의 해수(海水)로 이주된지 14일(日) 이후에 신장(腎臟)에서 수축된 것으로 나타났다. 30%o의 해수(海水)에 적응(適應)된 틸라피아의 평균 신사구체(腎絲球體)의 면적은 담수(淡水)에 적응된 개체의 면적보다 유의성있게 나타났다. 해수(海水)에 적응(適應

• Journal of fish pathology
• /
• v.9 no.2
• /
• pp.113-118
• /
• 1996

During a study to document more fully the parasitic ciliates of Korean freshwater fishes, we found numerous small ciliates in the gills and skin of crucian carp, Carassius carassius. Cursory examination indicated that the ciliate were very similar with Chilodonella sp. In this study, we described the morphometrics of this ciliate in detail and compared with other species of Chilodonella in the world. Numerous small ciliates were observed in the body surface, fins and gills of infected fish and excessive mucus production were seen in those fish. Sometimes ulcer was observed in the body of moribund fish. From the scrutinized observation of the parasite, it was identified as Chilodonella hexasticha. The parasite was dorsoventrally flattened body, without a notch in the posterior margin, and it measured 30-$45{\mu}m$ long and 15-$30{\mu}m$ wide. In number of kineties, the right band ciliature was 3-5 and the left band ciliature was 3-5. The right ventral ciliary band shaped arch and was longer than the left, straight band. It had a single oval macronucleus, 8-$15{\mu}m$ in diameter, a single micronucleus, 2-$4{\mu}m$ in diameter. The cytopharynx was reinforced by 10-16 conspicuous nematodesmata, which shaped like a tube and curved at its inner end. Two contractile vacuoles, one anteriorly at right and the second posteriorly at left were observed in wet mounts. This parasite reproduced by a simple division at $22{\pm}1^{\circ}C$.

• Resources Recycling
• /
• v.16 no.5
• /
• pp.71-76
• /
• 2007

The mixed plastic waste generated from households after hand-picking and/or mechanical sorting processes amounts to 1,750,000 ton in 2006, and most of these waste are finally end up with landfill and/or incineration due to the lacks of separation technologies and economical reasons. The mixed plastic wastes can not be used as raw materials for chemical and/or thermal recycling processes because of their high content of PVC(upto 4.0 wt.%). In the present research, gravity separation system has been developed to remove PVC from the mixed plastic waste and to recover the PO-type plastics. This system mainly consists of air classification, magnetic separation, one-step crushing, feeding system at fixed rate and wet-type gravity separation system. The gravity system based on centrifugal separation has been developed at capacity of 0.5 ton/h and it consists of mixing, precleaning, separation, dewatering, recovery system and wastewater treatment system, etc. The main objective of this process is to achieve high separation efficiency of polyolefins with less than 0.3 wt.% PVC content and less than 10% moisture content in the final products. In addition, a crushing unit of with 8 rotor system is also developed to improve the crushing efficiency of soft-type plastics. The system with a capacity of 1.0 ton/h is developed and operational results are presented.

• ALGAE
• /
• v.32 no.1
• /
• pp.57-66
• /
• 2017

The red alga Gracilaria vermiculophylla, a species native to the waters of Korea and Japan, has invaded marine coastal areas of Europe and the Americas, thriving in conditions that differ from those of its native habitat. In recent years, G. vermiculophylla has been discovered in the Long Island Sound (LIS) estuary growing alongside the native congener Gracilaria tikvahiae. The goal of this study was to determine whether the two strains of G. vermiculophylla from different regions of the world have evolved genetic differences (i.e., ecotypic differentiation) or if the physiological performance of the strains simply reflects phenotypic plasticity. Two strains of G. vermiculophylla (isolated in Korea and LIS) and a strain of the LIS native G. tikvahiae were grown for four weeks under temperatures ranging from 20 to $34^{\circ}C$ using a temperature gradient table (all other environmental conditions were kept constant). At the end of each week, wet weight of each sample was recorded, and thalli were reduced to the original stocking density of $1gL^{-1}$ (excess biomass was preserved for tissue carbon and nitrogen analysis). Generally, the growth rates of Korean G. vermiculophylla > LIS G. vermiculophylla > G. tikvahiae. After one week of growth G. tikvahiae grew 9.1, 12.0, 9.4, and 0.2% $d^{-1}$, at temperatures of 20, 24, 29, and $34^{\circ}C$, respectively, while G. vermiculophylla (LIS) grew 6.6, 6.2, 5.7, and 3.6% $d^{-1}$. G. vermiculophylla (Korea) grew 15.4, 22.9, 23.2, and 10.1% $d^{-1}$, much higher than the two strains currently inhabiting the LIS. On average, the LIS G. vermiculophylla strain contained 4-5% DW N, while the Korean strain and G. tikvahiae had more modest levels of 2-3% N DW. However, tissue N content declined as temperature increased in LIS and Korean G. vermiculophylla. The non-native haplotype may have evolved genetic differences resulting in lower growth capacity while concentrating significantly more nitrogen, giving the non-native a competitive advantage.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2000.04a
• /
• pp.48-48
• /
• 2000

효율적인 wet-end시스템의 적용으로 중성 초지시스템의 이점을 최대한 구현하고 이에 따른 초지계의 안정성 및 원가절감 등을 얻기 위해서는 중성 초지 시스템에서 사용되는 사 이즈제 및 사이징 공정에 대한 연구가 매우 중요하다. 현재 중성 사이즈제로는 AKD와 A ASA가 가장 널리 사용되고 있는데, 유럽에서는 주로 AKD가 쓰이고 있으며, 미국에서는 A ASA가 50%정도 사용되고 있다 .. AKD에 비해서 ASA는 사이즈도의 발현이 매우 빨라 사이 즈 프레스에서 사이즈도가 발현되므로 사이즈 프레스에서의 픽엽 조절 및 지절감소에 유리 한 장점을 가지고 있다. 하지만 ASA는 AKD에 비해 반웅성 높아 습부에서의 가수분해되어 초지 조업성을 악화시키는 문제점을 지니고 있다. 이러한 문제를 극복하기 위해서는 ASA 유화액의 정착성을 개선시키기 위한 연구가 시급히 요청되고 있으며 여기에는 ASA의 유화 에 사용되는 양성전분의 최적화가 가장 핵심적인 기술로 평가된다. 현재 ASA용 유화제로는 양성전분이 가장 많이 사용되고 있다. ASA 에멀션 제조에 있 어서 양성전분의 역할은 음전하를 가지고 있는 ASA 입자에 홉착되여 양전하를 부여함으로 써 콜로이드 업자의 안정성을 부여할 뿐만 아니라 섬유와의 정전기적 인력을 유도하여 정착 을 증진시키는 효과를 나타낸다. ASA 유화용으로 쓰이는 양성전분 중에서는 감자전분이 가 장 효과적인 것으로 알려져 있으며 옥수수나 타피오카 둥도 쓰이고 있다. 그러나 국내의 경 우 감자전분은 옥수수전분보다 가격이 비싸다는 단점이 있으므로 저렴한 옥수수 전분을 이 용하여 ASA 유화용 변성전분의 개발이 국내 제지산업의 경쟁력 강화를 위해 시급히 요망 되고 있다. 본 연구의 목표는 옥수수 전분을 이용한 ASA용 유화안정제를 개발하고 그 효과를 극대 화시킬 수 있는 적용기술을 확립하는데 있다. 옥수수전분을 이용한 ASA 유화용 변성전분은 외국에서 소개된 바가 있기는 하지만 사이즈도 발현이 감자전분의 절반 수준으로 효과적이 지 못한 것이 문제점으로 지적된 바 있다. A ASA 유화용 전분으로는 감자전분과 옥수수전분으로 제조된 외국산 기존 제품과 본 연 구를 통해 개발된 옥수수 전분을 이용하였다. 먼저 실험실적으로 최적의 ASA 에멸션의 유 화가 가능하도록 유화조건을 설정하여 유화액의 입도가 1µm 정도가 되도록 하였다. 이들 A ASA 사이즈제를 Hw. Sw-BKP로 조성된 지료에 투입하여 수초한 후 Hercules 사이즈도 측정기를 이용하여 수초지의 사이즈도를 측정하였다. 또 사이정 효과를 극대화시키기 위한 방안을 모색하기 위해 ASA 에말션의 입도, 제타전위, 탁도 등의 평가를 병행 실시하였다. 실험 결과 기존의 방법으로 유화한 경우 수입감자양성전분이 가장 높은 사이즈도를 보였 다. 그러나, 적절한 전분변성법과 유화조건을 개선함으로써 옥수수전분을 이용하여 수입 감 자전분이나 수입 옥수수전분보다 더 우수한 ASA 사이정 효과를 나타내는 양성전분이 개발 될 수 있음을 확인하였다.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.27 no.2
• /
• pp.57-66
• /
• 2019

This study carried out on-site investigation and precision monitoring to prepare proper design and operation technical guidelines for the use of bio gas in organic waste resources (fertilizing urine, food waste, food waste, food waste, etc.). According to the government's mid- and long-term policy on bio gasification, the expansion of waste resources is actively being pushed forward. However, facilities that use the biogas produced for urban gas and transportation are still under-efficient. Precision monitoring was carried out for biogasification facilities of organic waste resources in seven locations nationwide. When the results of precision monitoring were summarized with the four-season average, the efficiency analysis of each organic waste resource showed that the organic breakdown rate was 66.3% on average on VS basis. Analysis of biogas characteristics before and after pretreatment revealed that the $H_2S$ average of the entire facility was measured at 949.7 ppm using iron salts and desulfurization (dry, wet) and that the quality refining facility shearing and rear end was 29.0 ppm and 0.3 ppm. The methane content was found to be reduced by 65.6% at the rear of the fire tank, 63.5% at the back and 97.5% at the rear.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.37 no.4
• /
• pp.233-242
• /
• 2019

ZHD (Zenith Hydrostatic Delay) model is important parameter in estimating of GNSS (Global Navigation Satellite System) PWV (Precipitable Water Vapor) along with weighted mean temperature. The ZWD (Zenith Wet Delay) is tend to accumulate the ZHD error, so that biases from ZHD will be affected on the precision of GNSS PWV. In this paper, we compared the accuracy of GNSS PWV with radiosonde PWV using three ZHD models, such as Saastamoinen, Hopfield, and Black. Also, we adopted the KWMT (Korean Weighted Mean Temperature) model and the mean temperature which was observed by radiosonde on the retrieval processing of GNSS PWV. To this end, GNSS observation data during one year were processed to produce PWVs from a total of 5 GNSS permanent stations in Korea, and the GNSS PWVs were compared with radiosonde PWVs for the evaluating of biases. The PWV biases using mean temperature estimated by the KWMT model are smaller than radiosonde mean temperature. Also, we could confirm the result that the Saastamoinen ZHD which is most used in the GNSS meteorology is not valid in South Korea, because it cannot be exclude the possibility of biases by latitude or height of GNSS station.