• 상하수도학회지
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• 제27권6호
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• pp.743-750
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• 2013

In this study, the carbonized aggregate of light weight and high mechanical strength using sewage sludge was evaluated with changing carbonation variables of temperature, detention time and feed condition. Porosity and mechanical strength was simultaneously increased according to increase of carbonization temperature unexpectedly. Carbonization detention time above 1 hour nearly affect on the porosity, but mainly on mechanical strength of the carbonized aggregate in case of clay addition. On $900^{\circ}C$, porosity and mechanical strength was increased rapidly, but above $1000^{\circ}C$, porosity began to decrease. Clay addition was very effective on increase of mechanical strength following much loss in porosity. The carbonized aggregate manufactured at $900^{\circ}C$ adding 30 % clay in sewage sludge was higher a little in porosity and 3 times in mechanical strength than those at $700^{\circ}C$ not adding clay. Consequently, in manufacturing the carbonized aggregate having simultaneously high porosity and mechanical strength, it is desirable to have operational condition of $900{\sim}1000^{\circ}C$ temperature and 1 hour time, and clay addition within 30 % for further higher mechanical strength.

• 한국지하수토양환경학회지:지하수토양환경
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• 제20권4호
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• pp.66-72
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• 2015

The aim of this study was to enhance of the Discfilter process (maximum treatment capacity - 500 ton/day) removal efficiency for small-scale wastewater reclamation under various influent wastewater conditions (with / without coagulation process, coagulant content and temperature). The result of chemical resistance test for fiber filter in the Discfilter that weight loss was obtained with 0.535% under pH 3, 0.092% under pH 9 and 0.028% under 10% NaClO. The removal efficiency test of Discfilter process on the with / without coagulation process showed that with coagulation process condition was occurred COD_Mn of 42.26 ± 0.61, BOD₅ of 88.72 ± 0.44, T-P of 84.67 ± 0.72 and SS of 90.58 ± 0.61. The removal efficiency of Discfilter process on the coagulant content (4.5, 5.0 and 5.0 mL/min) and temperature (< 10℃, 10℃~ 20℃ and > 20℃) conditions were increased as coagulant content and temperature increased. This study demonstrated the potential application of Discfilter process for small-scale wastewater reclamation.

• 자원리싸이클링
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• 제16권3호
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• pp.12-18
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• 2007

수산물 처리과정중에서 다량으로 발생하는 폐굴껍질을 흡착제로 활용하는 방안을 모색하고자 이의 물성을 분석하였다. 폐기되는 굴껍질의 조성은 대부분 $CaCO_3$인 것으로 나타났으며 온도를 증가시키면서 굴껍질을 열분해를 시키면 온도에 따라 수분과 $CO_2$에 의한 분해가 일어나 약 46%의 무게 감량을 보인다. pH가 증가할수록 흡착되는 불소 이온의 양은 크게 감소했다. 또한 산성 불소 폐수가 흡착 반응의 평형에 도달하였을 경우 굴껍질에서 용해된 ${CO_2}^{3-}$의해 중화되는 경향이 관찰되었다.

• 플랜트 저널
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• 제4권2호
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• pp.60-65
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• 2008

As the operating conditions in a supercritical oxidation reactor are set in high temperature with high pressure causing a reactor suffering from the harsh circumstances. It means the reactor adopts itself with Fe-Cr alloy in acidic atmosphere with low pH value and Ni alloy in basic atmosphere with high pH value due to its superior corrosion resistance. The study, whose target waster water is pertinent to the latter part, has selected Ni alloy such as ostenite type stainless steel 304 and 316, superstainless steel AL6XN, Inconel 625, MAT 21, and titanium Gr. 5 in order to measure corrosion resistance against those samples under the same conditions of temperature and pressure applied for a supercritical oxidation reactor. The result shows the identifiable difference in corrosion resistance by observing the surface states through a scanning probe microscope as well as measuring the weight loss through making the samples above deposited in wastewater for two-week and four-week stay. The purpose of this corrosion experiment is to identify the most corrosion-resistant material among sample species pre-selected according to pH concentration of wastewater in pursue of applying for a reactor exposed to the extreme corrosion environment. It is because such a reactor made of a verified material enables to safeguard a stable operation under the supercritical wastewater processing facility.

• 대한화학회지
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• 제58권1호
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• pp.25-32
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• 2014

Corrosion inhibition of 304 stainless steel (SS) in 1 M HCl by aqueous extract of coriander seeds was studied using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Values of inhibition efficiency obtained are dependent upon the concentration of extract and temperature. Generally, inhibition was found to increase with inhibitor concentration, but decrease with temperature. Physical adsorption mechanism has been proposed for the inhibition with Langmuir adsorption isotherm obeyed. Values of activation energy of the inhibited corrosion reaction of 304 SS are greater than the value obtained for the blank. Thermodynamic consideration reveals that adsorption of aqueous extract of coriander seeds 304 SS surface is spontaneous.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.122-131
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• 2001

Pakistan being the 6$^{th}$ largest sugar producer has over 75 sugar mills with annual production capacity of about 2.4 million tons during 1996-97. The contribution of Sindh with 27 sugar mills is recorded over 50% of the total sugar production. The majority of the mills in Pakistan use the Defecation-Remelt-Phosphitation (DRP; 24 mills), Defecation-Remelt-Carbonation (DRC; 21 mills) and Defecation-Remelt Carbonation and Sulphitation (DRCS; 11 mills) process. Seven of the 75 sugar mills in Pakistan also produce industrial alcohol from molasses, a by- product of sugar manufacturing process. These sugar industries also produce fly ash, which have been found to contain unburned carbon and reach as far as four-kilo meter area with the wind direction, threatening the community health of people living around, besides posing other aesthetic problems. The untreated wastewater, in many cases, finds its way to open surface drains causing serious threat to livestock, flora and fauna. One study showed that fly ash emitted from the chimneys contain particle size ranging from 38 ${\mu}{\textrm}{m}$ to 1000 ${\mu}{\textrm}{m}$. About 50 per cent of each fly ash samples were above 300 ${\mu}{\textrm}{m}$ in size and were mostly unburned Carbon particles, which produced 85% weight loss on burning in air atmosphere at 1000${\mu}{\textrm}{m}$. This fly ash (mostly carbon) was the main cause of many health and aesthetic problems in the sugar mill vicinity. The environmental challenge for the local sugar mills is associated with liquid waste gaseous emission and solid waste. This paper discusses various waste recycling technologies and practices in sugar industries of Pakistan. The application of EM technology and Biogas technology has proved very successful in reusing the sugar industry wastewater and mud, which otherwise were going waste.

• 상하수도학회지
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• 제29권2호
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• pp.203-209
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• 2015

The purpose of this study is to estimate the applicability of a stable anaerobic digester using a separator membrane to the preprocessing thickening process. The results of the experiments showed about a 47.16% weight loss rate for the sludge under anaerobic condition, and about 41.17% under intermittent aeration condition. The concentrations of rejection water were $SCOD_{Cr}$ 25 mg/L, T-N 16.6 mg/L, and T-P 1.4 mg/L on the average under the intermittent aeration condition, which were lower than the concentrations of rejection water under an anaerobic condition. As for the factors affecting the reduction of the flux, correlation analyses of TTF, MLSS, $SCOD_{Cr}$, and $EPS_{Protein}$, $EPS_{Polysacchride}$ resulted in -0.97, -0.95, -0.84 and -0.86, -0.95, respectively, which showed that TTF had the highest correlation to the reduction of the flux. In addition, it was concluded that MLSS, $SCOD_{Cr}$ and $EPS_{Protein}$, $EPS_{Polysacchride}$ also have close correlations. The results are considered to show that, in the case of the process using a tubular membrane in the preprocessing process of an anaerobic digester, an intermittent aeration condition of the thickener considering the contamination of the membrane and load of rejection water is appropriate for the stable preprocessing process.

• 한국염색가공학회지
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• 제8권6호
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• pp.27-32
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• 1996

This research is to investigate the reaction kinetics by air-lift bioreactor using calcium hydroxide, the neutralization agent and immobilization media, for removing ethylene glycol remained after chemical pretreatment. It was found that the optimum hydraulic retention time was obtained as 24.2hours at the optimum F/M ratio of 1.32kg-$TCOD_{Mn}$/day.kg-MLVSS, and then, infiuent $TCOD_{Mn}$ and MLVSS concentration were 3,290mg/l and 2,472mg/l, respectively. During the steady state, the kinetics constants such as maximum specific substrate removal rate, half saturation velocity coefficient, yield coefficient and endogenous respiration coefficient were estimated in the base of $TCOD_{Mn}$ as substrate concentration. And they were 1.47day$^{-1}$, 3.95mg/l, 0.391 and 0.092day$^{-1}$, respectively. And also, the oxgen use coefficients for cell synthesis, a', and energy of maintenance, b', were obtained as 0.4kg-O$_{2}$/kg-$TCOD_{Mn}$ and 0.056day$^{-1}$, at the steady state by the experimental result of oxygen uptake rate.

• 한국염색가공학회지
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• 제19권3호
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• pp.1-5
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• 2007

The advantage of enzyme scouring over alkali scouring is that the enzymatic process can be carried in a neutral pH, resulting in less damage on the fibers and a drastic reduction of wastewater. Since the pH of scouring bath is neutral, dyeing can be carried in the same bath. Four different types of scouring and dyeing in a single-bath were performed in this work: continuous scouring and dyeing in one-bath I and II, simultaneous scouring and dyeing in one-bath I and II. The difference between process I and II is the existence of an after-treatment process in the scouring. Dyeing was performed with three major colors(red, blue, yellow) and black to investigate the dye-ability. The absorbency of scoured and dyed fabrics was measured using gravimetric absorbency testing system. The fabric weight loss was measured after the treatment. Although the color depth for the three major colored fabrics treated in a single-bath was lower than the fabric scoured and dyed separately, the fabrics dyed with black did not show much difference. In addition, the absorbency of fabric treated in a single-bath was higher than the fabric treated separately.

• KSBB Journal
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• 제8권2호
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• pp.156-163
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• 1993

Polyester 감량폐수의 주성분인 EG,TPA분해균을 분리하여 각각 Pseudomonas sp.로 동정하여 Pseudomonas sp. EAW, Pseudomonas sp. TS2로 명명하였다. 이 두 균주의 최적 배양조건은 pH 7.5, 온도 $35^{\circ}C$ 및 질소원은 ${(NH_4)}_2SO_4$ 이며, Strain EAW의 경우 niacin과 biotin, Strain TS2의 경우 $Na_2MoO_4{\cdot}2H_2O$와 thiamine이 각 균주의 성장과 분해율에 약간씩 영향을 미치는 것으로 나타났다. Strain EAW는 접종량의 증가에 따라서 성장 및 EG의 분해시간이 현저히 감소하였으나 Strain TS2의 경우는 접종량이 증가하여도 성장 및 분해율이 큰 차이가 없었다. 또한 rich-medium에 계대배양한 각 균을 EG, T TPA액체배지에 접종하였을 때 계대배양의 회수가 증가함에 따라 Strain EAW가 Strain TS2보다 성장 및 분해율이 현저히 감소하였다. 실제 폐수에서 균들의 성장 및 분해율이 분리용 배지의 경우 보다는 약간 감소하였으며 EG, TPA 는 배양 48hr 후 $COD_{Mn}\;and\;COD_{Cr}$의 제거율은 89% 와 93%로 각각 나타났다. 회분배양시 EG,TPA의 초기농도가 25g/L 이상에서는 각 균주의 비성장속도가 감소하였다.