• Journal of Korean Society of Environmental Engineers
• /
• v.33 no.8
• /
• pp.606-616
• /
• 2011

The objectives of this study were to evaluate the applicability of adsorption models for adsorption properties of adsorbents. For this study, adsorption experiment of $NO_3^-$ ion using anion exchange resin has been investigated under adsorption equilibrium and kinetic in bach process. Adsorption equilibrium experiment were carried out that two conditions is change of adsorbate concentration and change of adsorbent weight. Experiment results have been analyzed by adsorption isotherm models, energy models and kinetic models. Under the condition of change of adsorbate concentration was best described by Sips and Redlich-Perterson isotherm models. However case of change of adsorbent weight was described by Langmuir isotherm models. It seems reasonable to assume that isotherm model was dominated by multiple mechanism according to experiment condition.

• Journal of Biomedical Engineering Research
• /
• v.28 no.5
• /
• pp.609-617
• /
• 2007

In this paper, a new rehabilitation training system was developed to improve equilibrium sense of the elderly by combining virtual reality technology with a fixed exercise bicycle. In order to evaluate the effectiveness of the training system, the elderly participated as test subject in the investigation of the influence of different the parameters on postural balance control. We measured three different running modes of virtual bicycle system with two successive sets. The parameters measured were running time, velocity, the weight movement, the degree of the deviation from the road, and the variables about the center of pressure. The repeated training, our results showed that the running capability of the elderly improve compared. In addition, it was found out that the ability of postural control and the equilibrium sense was improved with the presentation of the visual feedback information of the distribution of weight. From the results of this experiment, we showed that our newly developed system might be useful in the diagnosis of equilibrium sense or in the improvement of the sense of sight and, somatic, and vestibular sense of the elderly in the field of rehabilitation training.

• Journal of the Institute of Electronics Engineers of Korea SC
• /
• v.42 no.6
• /
• pp.57-66
• /
• 2005

In this paper, a new rehabilitation training system was developed to improve equilibrium sense by combining virtual reality technology with a fixed exercise bicycle. The subjects consisted of two groups. A group of young people, was compared against a group of elderly. We measured three different running modes of virtual bicycle system with two successive sets. The parameters measured were running time, velocity, the weight movement, the degree of the deviation from the road, and the variables about the center of pressure. The repeated training, our results showed that the running capability of the elderly improve compared. In addition, it was found out that the ability of postural control and the equilibrium sense was improved with the presentation of the visual feedback information of the distribution of weight. From the results of this experiment, we showed that our newly developed system might be useful in the diagnosis of equilibrium sense or in the improvement of the sense of sight and, somatic, and vestibular sense of the elderly in the field of rehabilitation training.

• Journal of Environmental Health Sciences
• /
• v.29 no.3
• /
• pp.50-58
• /
• 2003

Removal of heavy metal ions (Cd$^{2+}$, Cr$^{3+}$, Cu$^{2+}$, Pb$^{2+}$) by several chitosans was studied and the molecular weight of chitosan was investigated in order to examine the effect of autoclaving. Chitosan were divided into 3 groups (A type, controlled chitosan; B type, autoclaved for 15 min; C type, autoclaved for 60 min). The heavy metal removal capacity and rate of B type chitosan were higher than those of A type and B type chitosan. The molecular weight of chitosan was decreased by the increase of autoclaving time. Therefore, the heavy metal capacity was not well correlated to the molecular weight. Freundlich and Langmuir isotherm was determined from the experimental results of equilibrium adsorption for individual heavy metal ions on chitosan. Langmuir isotherm was well fitted to this experimental data. The heavy metal removal capacity of B type chitosan was in the order of Pb$^{2+}$ > Cu$^{2+}$ > Cd$^{2+}$> Cr$^{3+}$.3+/.$.3+/.

• Environmental Analysis Health and Toxicology
• /
• v.22 no.4
• /
• pp.299-304
• /
• 2007

This paper was studied to investigate the equilibrium state between organochlorine pesticides (OCPs) concentration of air and soil, and to know whether soil is a secondary pollution source of OCPs in air or not. The OCPs concentration of air ($C_{air}$) and soil ($C_{soil}$) is not related to molecular weight, vapor pressure ($P_L$) and octanol-air partition coefficient ($K_{oa}$). The slope of the regression line between soil-air partition coefficient ($K_{sa}$) and scavenging coefficient ($C_{soil}/C_{air}$) was 0.2952, which the OCPs concentration between air and soil did not reached to the equilibrium state. The soil/air fugacity quotients ($f_{soil}/f_{air}$) of p, p'-DDT/DDD/DDE and ${\beta}-HCH\;(0.30{\sim}0.67$), which is smaller than 1, means the deposit of OCPs from air to soil. However, $f_{soil}/f_{air}$ of heptachlor, heptachlor epoxide, ${\alpha}/{\gamma}-chlordane$, trans-nonachlor, endosulfan sulfate and ${\alpha}/{\gamma}-HCH\;(1.90{\sim}73.25)$, which is greater than 1, means that soil is secondary pollution source of OCPs in air.

• Geomechanics and Engineering
• /
• v.8 no.4
• /
• pp.523-540
• /
• 2015

Based on limit equilibrium principles, this study presents a theoretical derivation of a new analytical formulation for estimating magnitude and lateral earth pressure distribution on a retaining wall subjected to seismic loads. The proposed solution accounts for failure wedge inclination, unit weight and friction angle of backfill soil, wall roughness, and horizontal and vertical seismic ground accelerations. The current analysis predicts a nonlinear lateral earth pressure variation along the wall with and without seismic loads. A parametric study is conducted to examine the influence of various parameters on lateral earth pressure distribution. Findings reveal that lateral earth pressure increases with the increase of horizontal ground acceleration while it decreases with the increase of vertical ground acceleration. Compared to classical theory, the position of resultant lateral earth force is located at a higher distance from wall base which in turn has a direct impact on wall stability and economy. A numerical example is presented to illustrate the computations of lateral earth pressure distribution based on the suggested analytical method.

• Korea-Australia Rheology Journal
• /
• v.14 no.1
• /
• pp.17-23
• /
• 2002

A novel and simple method using a cylindrical penetrometer is being developed for the measurement of yield stress. The principle of this technique is based on the measurement of the static equilibrium of a falling penetrometer in a yield stress fluid. The yield stress is simply determined by a balance of forces acting on the penetrometer. The yield stress of Carbopol gels and $TiO_2$ suspensions has been measured using this method. The results are in reasonable agreement with the values from conventional methods. The effects of the dimensions and weight of the penetrometer have been examined. The long-term behaviour was also observed. No measurable creep was seen and equilibrium was found to be very quickly established. The cylindrical penetrometer technique promises to be a simple, quick and reliable static method for the measurement of yield stress.

• The Journal of Korea Robotics Society
• /
• v.9 no.4
• /
• pp.250-257
• /
• 2014

In this paper, a new mobile robot, so called a rollerbot, is presented, which has single body and rugby-ball shaped roller wheel. A rollerbot has single point contact on ground and low energy consumption in motion because of the reduced friction. By changing center of mass using a balancing weight, a rollerbot is able to get steering force. The vertical position of mass center of the rollerbot in this paper is designed to lie inside radius of the roller wheel, so that to have stable equilibrium position. Thus, the posture and the steering control of the rollerbot can be easily done by changing the center of mass. Kinematics of the rollerbot is derived by transformation of differential motion in this paper.

• Biotechnology and Bioprocess Engineering:BBE
• /
• v.7 no.6
• /
• pp.367-370
• /
• 2002

Candida cylindracea lipase was immobilized by adsorption on acid washed glass beads. It was observed that protein loading of the support depends on the size of the particle, with smaller particle containing higher amount of protein per unit weight. Initial reaction rate linearly varied up to enzyme concentration of 17.25 U/mL. Amount of free fatty acids produced was linearly proportional up to the enzyme loading of 1650 $\mu$g/g of bead. Achievement of chemical equilibrium took longer time in the case of less protein loading. Degree of hydrolysis was found to decrease in second and third consecutive batch operations on repeated use of immobilized lipase.

• Korean Membrane Journal
• /
• v.1 no.1
• /
• pp.8-24
• /
• 1999

free volume in polymers is defined as the difference of the specific volume and the volume which is not available for the particular molecular motion which is responsible or the process that is considered . Relations between free volume and viscosity free volume and diffusion coefficient are pre-sented both in the case of simple low molecular weight liquids and in the case of polymers. Molecular models and free volume models are reminded starting from the equilibrium state equation of Simha and Somcynski. The non equilibrium situations of specific volume of glass polymers below Tg are shown introducing different relaxation volume equations which involve different material's parameters and con-cept of the fictitious temperature. The diffusivity equations of Vrentas and Duda are introduced both for the glassy and rubbery states. The possibility of introducing time relaxation functions is also suggested. The importance of finding experimental evidences of the free volume is stressed. highlights of the free volume measurement methods are given in particular as to dilatometry photocromy fluorescence electron spin resonance small angle X-ray scattering positron annihilation spectroscopy.