• Bulletin of the Korean Chemical Society
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• 제16권2호
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• pp.169-180
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• 1995

A topological theory is introduced to extend Tsenoglou's theory to polymer blends having temporary and permanent networks composed of multicomponent polymers which have miscible and flexible chains. The topological theory may estimate the values of free elastic energy, the molecular weight between entanglements, and the equilibrium shear moduli, and it may establish more correctly the topological relations among these physical quantities. Through such introduction of the topological theory, there can be topologically analyzed the mixing law for the rubbery plateau modulus of a fluid polymer blend, and there can be considered the topological relationship to the equilibrium modulus of an interpenetrating polymer network containing trapped entanglements and dangling segments. The theoretically predictive values are compared and show good agreement with the experimental data for several miscible polymer blends.

• Korean Chemical Engineering Research
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• 제55권2호
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• pp.230-236
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• 2017

약 303 K로부터 약 343 K의 온도 범위와 약 50 bar까지의 압력 범위에서 poly(ethylene glycol) dimethyl ether(PEGDME)에 녹는 이산화탄소($CO_2$)의 용해도를 측정하였다. 가변부피 투시창이 장착된 고압용 상평형 장치를 사용하여 온도를 변화시키면서 여러 가지 조성을 갖는 $CO_2+PEGDME$ 혼합물의 기포점 압력을 측정함으로써 PEGDME에서의 고압 $CO_2$의 용해도를 결정하였다. PEGDME의 분자량이 $CO_2$ 용해도에 미치는 영향을 관찰하기 위하여, 두 가지 종류의 분자량을 가진 PEGDME 시료에 대한 $CO_2$ 용해도를 비교하였다. 압력이 증가함에 따라 PEGDME에 대한 $CO_2$ 용해도는 증가하였으며 온도가 증가함에 따라 용해도는 감소하였다. 같은 온도와 압력에서 비교할 때, 분자량이 더 큰 PEGDME는 질량분율과 몰랄농도 기준으로 더 작은 $CO_2$ 용해도를 주었으나, 몰분율 기준으로는 더 큰 $CO_2$ 용해도를 주었다.

• 폴리머
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• 제24권2호
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• pp.182-193
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• 2000

폴리알킬렌테레프탈레이트 (PAT)의 고리 올리고머의 몰 고리화 정수(molar cyclization equilibrium constants)를 회전 이성 상태 (rotational isomeric state) (RIS) 모델에 의해Monte Carlo 모사로부터 얻었다. Jacobson-Stockmayer 이론과 이를 보완한 Flory, Suter, 그리고 Mutter의 방법으로는 각 PAT의 고리 올리고머의 함량과 분포를 잘 설명할 수 없었다. RIS모델을 이용한 직접 계산법으로는 반응거리를 ${\gamma}$=0.5 < ${\gamma}^{2}$> $^{1/2}$로 잡아준 경우에 모든 PAT에 대해서 실험치에 가까운 고리 올리고머의 분포를 얻었다. 또한 각 PAT의 입체형태의 변화에 따른 몰고리화 정수의 변화를 고찰하기 위하여 PAT 반복단위 중의 통계적 가중치 rl과 필를 변화시키면서 각 PAT의 몰 고리화 정수를 구하였다. 여러 반응거리와 ${\gamma}$=0.5 < ${\gamma}^{2}$> $^{1/2}$로 설정한 경우에 ${\sigma}_{1}$과 ${\sigma}_{2}$의 변화에 모든 PAT의 평형 고리 올리고머의 함량이 약간 변하기는 하나 그 분포는 그대로유지되었다. 각 PAT의 몰 고리화 정수는 주어진 입체배열에 의해서 일차적으로 결정이 되며 입체형태의 변화에 의해서도 다소 영향을 받는다는 것을 알았다.

• Ocean and Polar Research
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• 제42권1호
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• pp.77-88
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• 2020

This paper presents the coordinate systems used for trawl doors modeling, and provides matrix equations of connection between these systems. The projections of the forces acting on the door into axes of various coordinate systems were obtained, which were used in the door equilibrium equations. Six equilibrium conditions for the door as a solid were obtained: formulas that allow for the door area in plan to be determined; its weight in water; its mass; three moment equations for determining the position of the warp and backstrops fastening points to the door with triangular and quadrangular backstrop arrangements. It was found that the moment equilibrium equations of trawl doors are generally incompatible, which was not found by any of the authors who have previously conducted research into trawl doors. Using the Kronecker-Capelli theorem, the compatibility equation is obtained. This equation includes the coordinates of the backstrop fastening points to the door, which means that these points cannot be randomly selected. The technique of determining the warp and backstrops' fastening points position to the door is described. Conditions of directional (by angle of attack) and roll (in angle of roll) stability of the doors' equilibrium are presented. The equations presented in this paper comprise a mathematical model that allows, when designing the doors, to select optimal parameters, as well as to carry out adjustments for trawling purposes to ensure the stable movement of the doors and the entire trawl system.

• 대한토목학회논문집
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• 제9권1호
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• pp.11-23
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• 1989

본 논문에서는 guyed tower의 mooring system에 관한 수치해석결과를 제시하였다. 가상일의 원리와 유한요소법을 사용하여 기본식을 유도하였으며 케이블의 기하학적 비선형성을 고려하였다. 유체의 항력과 관성력은 Morrison식을 사용하여 고려하였으며 비선형 운동방정식의 해는 Newton-Raphson방법과 Newmark-${\beta}$ 방법을 사용하여 구하였다. Tower와 mooring line의 부착점에서의 초기경사각, 인장력, clump weight를 집중하중으로 이상화 시키는 종래의 해석방법의 문제점도 아울러 고찰하였다. 수치해석 예를 통하여 본 논문에서의 해석방법의 정당성을 입증하였다.

• 대한물리치료과학회지
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• 제9권1호
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• pp.53-59
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• 2002

This study is research for effect of the involved lower limb weight bearing training on symmetrical weight supporting rate improvement by practicing involved lower limb weight bearing training of three weeks period to improve standing equilibrium problem with asymmetric weight supporting rate of hemiplegia. In result of the study, it has shown that P-value incase of involved supporting rate is lower than level of significance $\alpha$<.05 and mean improvement rate of experienced group is higher in comparison with controlled group and experienced group. In changing quantity of involved maximum supporting rate, P-value is .26 and higher than level of significance $\alpha$<.05, and so it did not show significant difference statistically. But in case of experienced group between pre and post-test, involved side supporting rate and involved side maximum supporting rate showed significant improvement in all. In comparison of relative characteristic training effect difference, it was shown that train-learning effect on case of 40-60 years old, hemorrhagic patient and standard body bun of patient is valuable, which showed significant improvement in case of paralytic side and disease period, it did not show significant difference on excercise learning effect in two above cases. In the above result, we can say that continuous weight bearing training on the involved lower limb for three weeks period help improve the involved side supporting rate of hemiplegia. Accordingly, the weight bearing training on the involved lower limb is training method that patient can easily train with simple guidance of therapists, without being special expensive equipment. Furthermore it can be helpful to establish home therapeutic plan for hemiplegia through education of a patron.

• 한국초지조사료학회지
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• 제13권2호
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• pp.78-85
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• 1993

This experiment was carried out to select for the varieties with high environmental adaptability in mountainous pastures of Taekwalyong area, and the evaluation was based on the data of varietal differences of dry matter production and yield components in Tall fescue cutting at various developmental stages in growth period of autumn. The results were summarized as follows; 1. The varieties with high number of tillers per plant(NT) showed a high dry weight of plant(DW) in all autumn cuttings. These varieties(Barce1 and Fuego) may be more adaptable to mountainous pastures of Taekwalyon area than other varieties. 2. The number of tillers per plant(NT) was significantly positive correlated with dry weight of plant (DW), but dry weight of tiller(WT) was not significantly correlated with dry weight of plant(DW) in all autumn cuttings. 3. The multiple regression equations of autumn cutting stages with mean dry weight of plant(DW) and number of tillers per plant(NT) can be used to estimate the cutting time to obtain maximum mean dry weight of plant(DW) and the highest number of tillers per plant(NT). The maximum mean dry weight of plant(DW) and the highest number of tillers per plant(NT) was estimated at the time of 21 Oct. and 26 Oct, respectively. 4. Dead leaves tended to increase greatly after the 2nd cutting(l4 Oct.) in growth period of autumn. 5. The number of tillers per plant(NT) was an important yield component before tiller density achieved equilibrium, but dry weight of tiller(WT, including dead leaves) was of most significant as a yield determinant after maximum tiller density reached in growth period of autumn.

• 한국환경과학회지
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• 제12권12호
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• pp.1269-1276
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• 2003

In order to know the effect of atuoclaving on the heavy metal removal using chitosan, lead removal capacities and removal rates by various chitosans in aqueous solution were compared according to the various autoclaving time. The lead removal efficiencies and removal rates by the autoclaved chitosan were found to be on the order of 15 min(98％) ＞ 10 min(95％) ＞ 30 min(83％) ＞ 5 min(53％) ＞ 60 min(47％) ＞ 0 min(22％) chitosan. The molecular weight of chitosan was decreased by the increase of autoclaving time. Therefore, the heavy metal removal capacity was not well correlated to the molecular weight. Langmuir isotherm was well fitted to experimental results of equilibrium adsorption on chitosan. In order to examine the process of lead removal by the autoclaved chitosan, TEMs, SEMs and FT-IR analyses were used. The surface of autoclaved chitosan was much more porous and the lead removal was mainly occurred on the surface of chitosan. The structure of autoclaved chitosan was same as that of controlled chitosan.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2004년도 춘계학술대회 논문집
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• pp.410-415
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• 2004

Heavy-weight head slides may cause excessive inertia impact ＆ moment on the machine tool structure when they move or stop abruptly during operation. Consequently these inertia impact and unbalanced moment bring transient vibrations and rough sliding motions on the machine structure. Machine tool engineers have tried many kind of feed-slide designs in order to solve this problem; for example, the design optimization of the moving structure for minimum weight and maximum stiffness, box-in-box type slide design, and so on. In this article, force and moment equilibrium equations regarding to the inertia force ＆ moment were derived for each one of a mold M/C's head slides. Furthermore, five different design configurations of head slide assembly were reviewed for its design improvement regarding to force ＆ moment calculations and finite element structural analysis results.

• 환경위생공학
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• 제19권1호
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• pp.37-41
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• 2004

The removal efficiency of cadmium by chitosan complex isolated from Aspersillus oryzae was investigated through laboratory experiments. The results of the study are as follows. The adsorption kinetics of cadmium was reached the adsorption equilibrium in approximately 20 minutes and the removal efficiency was showed 95.8%. The effect of temperature on cadmium adsorption by chitosan complex shows that as the temperature increased, the amount of cadmium adsorption per unit weight of chitosan complex increased. The correlation between amount of cadmium adsorption per unit weight of chitosan complex and temperature was obtained through the coefficient of determination($R^2$). $R^2$ values was 0.854(p<0.05). A linearized Freundlich equation was used to fit the acquired experimental data. As a result, Freundlich constant, the adsorption intensity(1/n) was 0.550, and the measure of adsorption(k) was 2.181. So, it was concluded that adsorption of cadmium by chitosan complex is effective.