• 대한환경공학회지
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• 제33권8호
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• pp.606-616
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• 2011

본 연구는 흡착제의 흡착특성을 이해하는데 이용되는 각종 흡착모델의 적용성을 평가하는데 목적이 있다. 이를 위해 상용의 음이온교환수지(PA-308)를 이용하여 $NO_3^-$에 대한 흡착특성을 회분식 실험을 통해 조사하였다. 흡착등온과 흡착속도 실험결과는 일반적으로 널리 이용되고 있는 다양한 흡착등온식과 반응속도식을 통해 모델화하였다. 흡착평형실험은 흡착등온식을 적용하는데 있어 실험조건이 미치는 영향을 확인하기 위해 흡착제의 투여량을 일정한 값으로 고정하고 흡착질의 농도변화에 따른 조건과 흡착질의 농도를 일정한 값으로 고정하고 흡착제의 투여량 변화에 따른 조건으로 나누어 수행하였다. 흡착질의 농도를 변화시키는 조건에서의 흡착평형은 Langmuir와 Freundlich 흡착등온식을 결합한 형태의 Sips 흡착등온식과 Redlich-Perterson 흡착등온식에 의해 수식화가 가능하였다. 한편, 흡착제의 무게를 변화시키는 조건에서의 흡착평형은 단층 흡착, 균일표면을 가정하는 Langmuir 흡착등온식과 잘 일치하는 경향을 보였다. 이상의 결과는 $NO_3^-$에 대한 음이온교환수지의 흡착 메커니즘이 흡착실험 조건에 의해 달라질 수 있음을 시사한다.

• 대한의용생체공학회:의공학회지
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• 제28권5호
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• pp.609-617
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• 2007

In this paper, a new rehabilitation training system was developed to improve equilibrium sense of the elderly by combining virtual reality technology with a fixed exercise bicycle. In order to evaluate the effectiveness of the training system, the elderly participated as test subject in the investigation of the influence of different the parameters on postural balance control. We measured three different running modes of virtual bicycle system with two successive sets. The parameters measured were running time, velocity, the weight movement, the degree of the deviation from the road, and the variables about the center of pressure. The repeated training, our results showed that the running capability of the elderly improve compared. In addition, it was found out that the ability of postural control and the equilibrium sense was improved with the presentation of the visual feedback information of the distribution of weight. From the results of this experiment, we showed that our newly developed system might be useful in the diagnosis of equilibrium sense or in the improvement of the sense of sight and, somatic, and vestibular sense of the elderly in the field of rehabilitation training.

• 전자공학회논문지SC
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• 제42권6호
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• pp.57-66
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• 2005

본 연구에서는 가상현실기술과 자전거를 이용하여 평형감각 실조환자의 진단 및 시각, 전정감각, 체성감각 등을 효율적으로 진단하고 자극, 훈련시킬 수 있는 자전거 시뮬레이터 시스템을 개발하였고, 이 시스템이 평형감각 훈련에 대한 효과를 고찰하였다. 실험 방법은 20대의 건강한 젊은 성인과 70대의 노인을 대상으로 자전거 주행 시에 나타나는 주행시간, 주행속도, 중앙선이탈도, 무게이동과 무게중심의 변화를 측정하여 가상 자전거 시스템이 평형감각 훈련에 어떠한 영향을 미치는지에 대한 유용성을 분석 하였다. 실험결과, 20대의 젊은 성인과 70대의 노인이 훈련 후 주행속도와 주행시간 중앙선 이탈도가 감소하였고, 좌우 무게이동과 무게중심 면적이 모두 감소하였으며 시각적 피드백의 효과가 평형감각에 더욱 유용하다는 결론을 얻었고 시각적 피드백의 효과를 이용하여 복합 감성정보를 활용한 헬스기구나 평형감각 재활 훈련에 활용할 수 있음을 알 수 있었다.

• 한국환경보건학회지
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• 제29권3호
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• pp.50-58
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• 2003

Removal of heavy metal ions (Cd$^{2+}$, Cr$^{3+}$, Cu$^{2+}$, Pb$^{2+}$) by several chitosans was studied and the molecular weight of chitosan was investigated in order to examine the effect of autoclaving. Chitosan were divided into 3 groups (A type, controlled chitosan; B type, autoclaved for 15 min; C type, autoclaved for 60 min). The heavy metal removal capacity and rate of B type chitosan were higher than those of A type and B type chitosan. The molecular weight of chitosan was decreased by the increase of autoclaving time. Therefore, the heavy metal capacity was not well correlated to the molecular weight. Freundlich and Langmuir isotherm was determined from the experimental results of equilibrium adsorption for individual heavy metal ions on chitosan. Langmuir isotherm was well fitted to this experimental data. The heavy metal removal capacity of B type chitosan was in the order of Pb$^{2+}$ > Cu$^{2+}$ > Cd$^{2+}$> Cr$^{3+}$.3+/.$.3+/.

• Environmental Analysis Health and Toxicology
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• 제22권4호
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• pp.299-304
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• 2007

This paper was studied to investigate the equilibrium state between organochlorine pesticides (OCPs) concentration of air and soil, and to know whether soil is a secondary pollution source of OCPs in air or not. The OCPs concentration of air ($C_{air}$) and soil ($C_{soil}$) is not related to molecular weight, vapor pressure ($P_L$) and octanol-air partition coefficient ($K_{oa}$). The slope of the regression line between soil-air partition coefficient ($K_{sa}$) and scavenging coefficient ($C_{soil}/C_{air}$) was 0.2952, which the OCPs concentration between air and soil did not reached to the equilibrium state. The soil/air fugacity quotients ($f_{soil}/f_{air}$) of p, p'-DDT/DDD/DDE and ${\beta}-HCH\;(0.30{\sim}0.67$), which is smaller than 1, means the deposit of OCPs from air to soil. However, $f_{soil}/f_{air}$ of heptachlor, heptachlor epoxide, ${\alpha}/{\gamma}-chlordane$, trans-nonachlor, endosulfan sulfate and ${\alpha}/{\gamma}-HCH\;(1.90{\sim}73.25)$, which is greater than 1, means that soil is secondary pollution source of OCPs in air.

• Geomechanics and Engineering
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• 제8권4호
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• pp.523-540
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• 2015

Based on limit equilibrium principles, this study presents a theoretical derivation of a new analytical formulation for estimating magnitude and lateral earth pressure distribution on a retaining wall subjected to seismic loads. The proposed solution accounts for failure wedge inclination, unit weight and friction angle of backfill soil, wall roughness, and horizontal and vertical seismic ground accelerations. The current analysis predicts a nonlinear lateral earth pressure variation along the wall with and without seismic loads. A parametric study is conducted to examine the influence of various parameters on lateral earth pressure distribution. Findings reveal that lateral earth pressure increases with the increase of horizontal ground acceleration while it decreases with the increase of vertical ground acceleration. Compared to classical theory, the position of resultant lateral earth force is located at a higher distance from wall base which in turn has a direct impact on wall stability and economy. A numerical example is presented to illustrate the computations of lateral earth pressure distribution based on the suggested analytical method.

• Korea-Australia Rheology Journal
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• 제14권1호
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• pp.17-23
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• 2002

A novel and simple method using a cylindrical penetrometer is being developed for the measurement of yield stress. The principle of this technique is based on the measurement of the static equilibrium of a falling penetrometer in a yield stress fluid. The yield stress is simply determined by a balance of forces acting on the penetrometer. The yield stress of Carbopol gels and $TiO_2$ suspensions has been measured using this method. The results are in reasonable agreement with the values from conventional methods. The effects of the dimensions and weight of the penetrometer have been examined. The long-term behaviour was also observed. No measurable creep was seen and equilibrium was found to be very quickly established. The cylindrical penetrometer technique promises to be a simple, quick and reliable static method for the measurement of yield stress.

• 로봇학회논문지
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• 제9권4호
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• pp.250-257
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• 2014

In this paper, a new mobile robot, so called a rollerbot, is presented, which has single body and rugby-ball shaped roller wheel. A rollerbot has single point contact on ground and low energy consumption in motion because of the reduced friction. By changing center of mass using a balancing weight, a rollerbot is able to get steering force. The vertical position of mass center of the rollerbot in this paper is designed to lie inside radius of the roller wheel, so that to have stable equilibrium position. Thus, the posture and the steering control of the rollerbot can be easily done by changing the center of mass. Kinematics of the rollerbot is derived by transformation of differential motion in this paper.

• Biotechnology and Bioprocess Engineering:BBE
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• 제7권6호
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• pp.367-370
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• 2002

Candida cylindracea lipase was immobilized by adsorption on acid washed glass beads. It was observed that protein loading of the support depends on the size of the particle, with smaller particle containing higher amount of protein per unit weight. Initial reaction rate linearly varied up to enzyme concentration of 17.25 U/mL. Amount of free fatty acids produced was linearly proportional up to the enzyme loading of 1650 $\mu$g/g of bead. Achievement of chemical equilibrium took longer time in the case of less protein loading. Degree of hydrolysis was found to decrease in second and third consecutive batch operations on repeated use of immobilized lipase.

• Korean Membrane Journal
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• 제1권1호
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• pp.8-24
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• 1999

free volume in polymers is defined as the difference of the specific volume and the volume which is not available for the particular molecular motion which is responsible or the process that is considered . Relations between free volume and viscosity free volume and diffusion coefficient are pre-sented both in the case of simple low molecular weight liquids and in the case of polymers. Molecular models and free volume models are reminded starting from the equilibrium state equation of Simha and Somcynski. The non equilibrium situations of specific volume of glass polymers below Tg are shown introducing different relaxation volume equations which involve different material's parameters and con-cept of the fictitious temperature. The diffusivity equations of Vrentas and Duda are introduced both for the glassy and rubbery states. The possibility of introducing time relaxation functions is also suggested. The importance of finding experimental evidences of the free volume is stressed. highlights of the free volume measurement methods are given in particular as to dilatometry photocromy fluorescence electron spin resonance small angle X-ray scattering positron annihilation spectroscopy.